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Confined electric field in nano-sized channels of ionic porous framework towards unique adsorption selectivity

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Chinese Chemical Letters 2025年第02期36卷 465-469页

作者： Congyan liu Xueyao Zhou Fei Ye Bin Jiang bo liu School of Chemistry and Materials Science University of Science and Technology of China

Efficient selective adsorption and separation using porous frameworks are critical in many industrial processes,where adsorption energy and dynamic diffusion rate are predominant factors governing *** are highly susceptible to framework charge,which plays a significant role in selective ***,ionic porous frameworks can be divided into two *** of them is composed of a charged backbone and counter *** framework with zwitterionic channels is another *** is composed of regular and alternating arrangements of cationic and anionic building ***,we report a hydrogen-bonded ionic framework （HIF） of{（CN3H6）2[Ti（μ2–O）(SO4)2]}_nwith 1D channel exhibits unique adsorption selectivity for Ar against N2and *** functional theory （DFT） results suggest that CO2cannot be adsorbed by HIF at the experimental temperature due to a positive adsorption free *** addition,due to a relatively large diffusion barrier at 77 K,N2molecules hardly diffuse in HIF channels,while Ar has a negligible diffusion *** unique net positively-charged space in the channel is the key to the unusual phenomena,based on DFT simulations and structural *** findings in this work proposes the new adsorption mechanism and provides unique perspective for special separation applications,such as isotope and noble gasses separations.

关键词： Adsorption Channel Guanidinium Positive electric field Selectivity

Charge polarity inversion and zincophilicity improvement for chitosan separator towards durable aqueous zinc-ion batteries

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Journal of Energy Chemistry 2025年第2期101卷 110-119页

作者： Jiaqi Yu bo liu Hong Ma Zehua Fan Xiang Han Qinghua Tian Jizhang Chen Co-Innovation Center of Efficient Processing and Utilization of Forest Resources College of Materials Science and Engineering Nanjing Forestry University College of Mathematics and Physics Jinggangshan University Key Laboratory of Surface & Interface Science of Polymer Materials of Zhejiang Province School of Chemistry and Chemical Engineering Zhejiang Sci-Tech University

Aqueous zinc-ion batteries encounter enormous challenges such as Zn dendrites and parasitic *** modification is a highly effective strategy to address these *** the advantages of low cost,nontoxicity,biodegradability,good film-forming ability,superior hydro phi licity,and rich functional groups,chitosan is an ideal matrix for constructing ***,the presence of positive charges within chitosan in weakly acidic electrolytes is unfavorable for dendrite ***,Schiff base reaction is introduced to modify chitosan matrix,transforming its charge polarity from positive to ***,NbN with excellent zincophilicity is coated onto chitosan matrix,forming a Janus separator with low thickness of 19 μm and considerably improved mechanical *** resultant separator can promote the transport of Zn2+ions while triggering a repulsive shielding effect against anions,therefore dramatically enhancing Zn2+ion transfer number from 0.28 to *** separator can also facilitate desolvation process,improve exchange current density,restrict two-dimensional Zn2+ion diffusion,and enhance electrochemical kinetics,contributing to significantly inhibited dendrite growth,by-product formation,and hydrogen ***,stable and reversible Zn stripping/plating process is enabled for over 2500 h at 2 mA cm-2and 2 mAh *** great rate capability and excellent cyclability can be achieved for full batteries even under harsh *** work provides new insights into separator design for Zn-based batteries.

关键词： Aqueous zinc-ion batteries Charge polarity regulation Chitosan utilization Dendrite inhibition Separator modification

Dispatchable Capability of Aggregated Electric Vehicle Charging in Distribution Systems

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Energy Engineering 2025年第1期122卷 129-152页

作者： Shiqian Wang bo liu Yuanpeng Hua Qiuyan Li Binhua Tang Jianshu Zhou Yue Xiang Economic and Technology Research Institute State Grid Henan Electric Power CompanyZhengzhou450052China College of Electrical Engineering Sichuan UniversityChengdu610065China

This paper introduces a method for modeling the entire aggregated electric vehicle(EV)charging process and analyzing its dispatchable *** methodology involves developing a model for aggregated EV charging at the charging station level,estimating its physical dispatchable capability,determining its economic dispatchable capability under economic incentives,modeling its participation in the grid,and investigating the effects of different scenarios and EV penetration on the aggregated load dispatch and dispatchable *** results indicate that using economic dispatchable capability reduces charging prices by 9.7%compared to physical dispatchable capability and 9.3%compared to disorderly ***,the peak-to-valley difference is reduced by 64.6%when applying economic dispatchable capability with 20%EV penetration and residential base load,compared to disorderly charging.

关键词： Aggregated charging dispatchable capability peak shaving and valley filling the economics of charging demand response

Deep learning identification of novel autophagic protein-protein interactions and experimental validation of Beclin 2-Ubiquilin 1 axis in triple-negative breast cancer

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Oncology Research 2025年第1期33卷 67-81页

作者： XIANG LI WENKE JIN LIFENG WU HUAN WANG XIN XIE WEI HUANG bo liu State Key Laboratory of Southwestern Chinese Medicine Resources School of Pharmacy and College of Medical TechnologyChengdu University of Traditional Chinese MedicineChengdu611137China Department of Biotherapy Cancer Center and State Key Laboratory of BiotherapyWest China HospitalSichuan UniversityChengdu610041China

Background:Triple-negative breast cancer(TNBC),characterized by its lack of traditional hormone receptors and HER2,presents a significant challenge in oncology due to its poor response to conventional *** is an important process for maintaining cellular homeostasis,and there are currently autophagy biomarkers that play an effective role in the clinical treatment of *** contrast to targeting protein activity,intervention with proteinprotein interaction(PPI)can avoid unrelated crosstalk and regulate the autophagy process with minimal interference ***:Here,we employed Naive Bayes,Decision Tree,and k-Nearest Neighbors to elucidate the complex PPI network associated with autophagy in TNBC,aiming to uncover novel therapeutic ***,the candidate proteins interacting with Beclin 2 were initially screened in MDA-MB-231 cells using Beclin 2 as bait protein by immunoprecipitation-mass spectrometry assay,and the interaction relationship was verified by molecular docking and CO-IP experiments after *** formation,cellular immunofluorescence,cell scratch and 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide(MTT)tests were used to predict the clinical therapeutic effects of manipulating candidate ***:By developing three PPI classification models and analyzing over 13,000 datasets,we identified 3733 previously unknown autophagy-related *** network analysis revealed the central role of Beclin 2 in autophagy regulation,uncovering its interactions with 39 newly identified ***,the CO-IP studies identified the substantial interaction between Beclin 2 and Ubiquilin 1,which was anticipated by our model and discovered in immunoprecipitation-mass spectrometry assay ***,in vitro investigations showed that overexpressing Beclin 2 increased Ubiquilin 1,promoted autophagy-dependent cell death,and inhibited proliferation and metastasis in MDA-MB-231 ***:This study not

关键词： Triple-negative breast cancer(TNBC) Autophagy Protein-protein interactions(PPI) Artificial intelligence(AI) Beclin 2 Ubiquilin 1

Super-high bed sintering for iron ores:variation and optimization of bed resistance

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Journal of Iron and Steel Research International 2025年第1期32卷 40-51页

作者： Liang-ping Xu Lin Xiong Hui-bo liu Xi-duan Yang Ai-xiang Mao Pei-dun Chen Guang-hui Li School of Minerals Processing and Bioengineering Central South UniversityChangsha410083HunanChina Central Research Institute Baosteel Group Co.Ltd.Shanghai201900China Manufacturing Management Department Guangdong Zhongnan Iron and Steel Co.Ltd.Shaoguan512123GuangdongChina Technology and Development Center Shandong Taishan Iron and Steel Group Co.Ltd.Jinan271100ShandongChina

As the bed depth increases,sintering yield increases,but the productivity *** reveal the reasons for the decrease in productivity and explore targeted solutions,the bed resistance of mixtures,wet zone,and combustion zone was analyzed in the *** results showed that the decreased porosity of mixture resulted in the increased bed resistance by 160.56%when the bed depth increased from 600 to 1000 *** improving porosity of 1%by adding loosening bars with optimized size and distribution,the bed resistance decreased,and the productivity increased by 5%.The increase in bed depth increased the thickness of the wet zone from 120 to 680 mm and the resistance from 1.56 to 8.83 *** using a three-stage intensive mixer and pre-adding water for granulation,the moisture of mixture was reduced by 0.6%,and the sintering productivity increased by 4%.Besides,the high bed resistance is mainly caused by the increase in the thickness of the combustion zone from 31.9 to 132.7 mm,and the bed resistance increased from 0.70 to 5.62 *** bed resistance of the combustion zone at 900 mm was increased by 90.51%compared to 700 *** optimization of the distribution of coke breeze,the thickness of combustion zone at the lower layer decreased from 132.7 to 106.84 mm and permeability improved significantly.

关键词： Super-high bed sintering Bed resistance Permeability Productivity Wet zone Combustion zone

Purtscher-like retinopathy associated with COVID-19:a case report

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International Journal of Ophthalmology(English edition) 2025年第1期18卷 187-189页

作者： Wen-bo liu Yi Cai Miao Zhou Hashimoto Kinji Ming-Wei Zhao Xuan Shi Department of Ophthalmology Peking University People’s Hospital/Eye Disease and Optometry InstituteBeijing Key Laboratory of Diagnosis and Therapy of Retinal and Choroid DiseasesCollege of OptometryPeking University Health Science CenterBeijing 100044China

Dear Editor,We report a case of Purtscher-like retinopathy in a patient with coronavirus disease 2019(COVID-19).Fundus examination revealed extensive peripapillary white retinal patches(Purtscher’s fleckens)and cotton-wool spots(CWS)with minor hemorrhage bilaterally,consistent with Purtscher-like *** coherence tomography angiography(OCTA)showed multiple irregular areas of capillary nonperfusion.

关键词： Purtscher retinopathy capillary

Deep learning-based software engineering: progress,challenges, and opportunities

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Science China(Information Sciences) 2025年第1期68卷 57-144页

作者： Xiangping CHEN Xing HU Yuan HUANG He JIANG Weixing JI Yanjie JIANG Yanyan JIANG bo liu Hui liu Xiaochen LI Xiaoli LIAN Guozhu MENG Xin PENG Hailong SUN Lin SHI bo WANG Chong WANG Jiayi WANG Tiantian WANG Jifeng XUAN Xin XIA Yibiao YANG Yixin YANG Li ZHANG Yuming ZHOU Lu ZHANG School of Journalism and Communication Sun Yat-sen University School of Software Technology Zhejiang University School of Software Engineering Sun Yat-sen University School of Software Dalian University of Technology School of Computer Science and Technology Beijing Institute of Technology Key Laboratory of High Confidence Software Technologies (Peking University) Ministry of EducationSchool of Computer Science Peking University State Key Laboratory for Novel Software Technology Nanjing University School of Computer Science and Engineering Beihang University Institute of Information Engineering Chinese Academy of Sciences School of Computer Science Fudan University State Key Laboratory of Complex & Critical Software Environment (CCSE) School of Software Beihang University School of Computer and Information Technology Beijing Jiaotong University School of Computer Science and Technology Harbin Institute of Technology School of Computer Science Wuhan University Huawei Technologies

Researchers have recently achieved significant advances in deep learning techniques, which in turn has substantially advanced other research disciplines, such as natural language processing, image processing, speech recognition, and software engineering. Various deep learning techniques have been successfully employed to facilitate software engineering tasks, including code generation, software refactoring, and fault localization. Many studies have also been presented in top conferences and journals, demonstrating the applications of deep learning techniques in resolving various software engineering tasks. However,although several surveys have provided overall pictures of the application of deep learning techniques in software engineering,they focus more on learning techniques, that is, what kind of deep learning techniques are employed and how deep models are trained or fine-tuned for software engineering tasks. We still lack surveys explaining the advances of subareas in software engineering driven by deep learning techniques, as well as challenges and opportunities in each subarea. To this end, in this study, we present the first task-oriented survey on deep learning-based software engineering. It covers twelve major software engineering subareas significantly impacted by deep learning techniques. Such subareas spread out through the whole lifecycle of software development and maintenance, including requirements engineering, software development, testing, maintenance, and developer collaboration. As we believe that deep learning may provide an opportunity to revolutionize the whole discipline of software engineering, providing one survey covering as many subareas as possible in software engineering can help future research push forward the frontier of deep learning-based software engineering more systematically. For each of the selected subareas,we highlight the major advances achieved by applying deep learning techniques with pointers to the available datasets i

关键词： deep learning software engineering software benchmark software artifact representation survey

Establishment and verification of theoretical model for underwater light-sheet Scheimpflug LiDAR system

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Science China(Technological Sciences) 2025年第1期68卷 50-57页

作者： Fei FENG Guojun WU bo liu Xu ZHAO Yafeng WU Jinghan XU Xi’an Institute of Optics and Precision Mechanics Chinese Academy of SciencesXi’an 710119China University of Chinese Academy of Sciences Beijing 100049China

The Scheimpflug imaging in the air can increase the depth-of-view and has been well studied with an accurate Scheimpflug imaging ***,there is no corresponding underwater light-sheet Scheimpflug(ULSS)imaging *** a result,imaging accuracy cannot be ensured in the design phase,which mainly relies on the *** this paper,the ULSS imaging model is firstly established,which gives the relationship between the pixel number and target distance,as well as that between the target distance and range resolution.A new experimental bracket and an underwater Scheimflug imaging lens were designed and *** on this new device,several experiments were carried out in a pool to study the range resolution of this ULSS LiDAR,by which the correctness of the imaging model was *** also shows that the newly designed ULSS LiDAR can achieve a millimeter-level resolution within 8 m.

关键词： underwater optical detection 3D detection range resolution Scheimpflug imaging LiDAR

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作为一种动态化和成长性的行动诗学——第三代诗人经典化问题重释与反思

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当代文坛 2025年第2期 122-129页

作者：刘波三峡大学文学与传媒学院

作为1980年代重要的先锋文学思潮，第三代诗人对朦胧诗的反叛、激进的出场方式和特殊的文本传播途径，已经在当年及后来的经典化过程中形成了一种特别的现象。第三代诗人以行动的力量打破了过去单一化的诗歌写作格局，在更多元的层面强... 详细信息

作为1980年代重要的先锋文学思潮，第三代诗人对朦胧诗的反叛、激进的出场方式和特殊的文本传播途径，已经在当年及后来的经典化过程中形成了一种特别的现象。第三代诗人以行动的力量打破了过去单一化的诗歌写作格局，在更多元的层面强化了诗歌的现代意识与先锋精神，从而在青春写作的现场构成了一种行动和成长的诗学。随着第三代诗人的诗歌传播，其诗学的经典化也在刊物发表、选本运作、诗集出版和批评史乃至文学史的评价与定位中获得了逐步确立的可能性。然而，第三代诗人在从行动到文本的经典化过程中，也因其行动大于文本的局限性，引起了很多争议，导致缺乏深度经典化的势能。第三代诗人经典化的落实，最终还是个体诗人通过持续性写作才能得以实现。

关键词：第三代诗人经典化行动诗学成长诗学

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