检索结果-南通市图书馆

The Mechanism of heating Rate on the Secondary Recrystallization Evolution in Grain Oriented Silicon Steel

在线全文

学校读者我要写书评

暂无评论

Journal of Wuhan University of Technology(Materials Science) 2025年第1期40卷 275-282页

作者： GAO Qian LI Jun WANG Xianhui CAO Laifu GONG Jian LI bo Central Iron and Steel Research Institute Group Beijing 100081China Shougang Zhixin Electromagnetic Material R&D(Beijing)Co. Ltd.Beijing 101300China Beijing Shougang Co. Ltd.Qian’an 064404China

Grain-oriented silicon steels were prepared at different heating rates during high temperature annealing,in which the evolution of magnetic properties,grain orientations and precipitates were *** illustrate the Zener factor,the diameter and number density of precipitates of interrupted testing samples were statistically *** effect of precipitate ripening on the Goss texture and magnetic property was *** indicated that the trend of Zener factor was similar under different heating rates,first increasing and then decreasing,and that the precipitate maturing was greatly inhibited as the heating rate *** recrystallization was developed at the temperature of 1010℃when a heating rate of 5℃/h was used,resulting in Goss,Brass and{110}oriented grains growing abnormally and a magnetic induction intensity of ***,increasing the heating rate to 20℃/h would inhibit the development of undesirable oriented grains and obtain a sharp Goss ***,when the heating rate was extremely fast,such as 40℃/h,poor secondary recrystallization was developed with many island grains,corresponding to a decrease in magnetic induction intensity to 1.87 *** a suitable heating rate of 20℃/h,the sharpest Goss texture and the highest magnetic induction of 1.94 T with an onset secondary recrystallization temperature of 1020℃were found among the experimental variables in this *** heating rate affected the initial temperature of secondary recrystallization by controlling the maturation of precipitates,leading to the deviation and dispersion of Goss texture,thereby reducing the magnetic properties.

关键词： high temperature annealing heating rate secondary recrystallization grain oriented silicon steel

A versatile synthetic strategy towards rare earth based metal-organic frameworks

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Science China Chemistry 2025年

作者： Quan Shi Yun-hao Xu Ming-hui Chen Peng Zhao Wen-bo Deng Ji Xiong Kai Guo Ya-Qing Feng Bao Zhang School of Chemical Engineering and Technology Tianjin University Tianjin Collaborative Innovation Center of Chemical Science and Engineering Guangdong Laboratory Chemistry & Fine Chemical Industry Jieyang Center

Rare earth metal-organic frameworks (RE-MOFs) have drawn wide attention owing to diverse network structures and various application ***,due to the unpredictable formation of the nodes,it is still challenging to design novel RE-MOFs.A novel versatile strategy was developed employing a RE-acetate complex (RE2(Ch3COO)6·4h2O) as a precursor to construct RE-MOFs.2D RE-MOFs (RE-DBP) and 3D RE-MOFs (RE-TCPP) could be obtained by using dicarboxylic porphyrin ligands h2DBP and tetracarboxylic porphyrin ligands h2TCPP,*** RE-MOFs were further synthesized to verify the universality of the *** crystalline RE-MOFs could also be prepared at room temperature via the developed strategy,which could significantly promote large-scale preparation and practical application of *** proof of the concept,the performance of porphyrin-based RE-MOFs was investigated in the photocatalytic cycloaddition of CO2with *** the RE-DBP(Co) MOFs,Tb-DBP(Co) exhibited the best photocatalytic performance,which was also greater than that of the corresponding 3D MOF Tb-TCPP(Co) due to the optimal 2D structure and thus the accelerated photogenerated charge separation and transfer *** work not only provides a novel versatile strategy to design and develop RE-MOFs,but also proposes a promising approach for the potential bulk production of RE-MOFs at room temperature.

关键词：

Unraveling the impacts of intermolecular interaction on morphology evolution for highly efficient organic solar cells and modules

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Science China Chemistry 2025年第01期 264-272页

作者： Xueqing Ma Yingying Cheng Yuqiang Liu Xinming Zheng Guangliu Ran hongxiang Li Xinyue Cui Andong Zhang Wenkai Zhang Pei Cheng Wenchao huang Zhishan bo Beijing Key Laboratory of Energy Conversion and Storage Materials College of Chemistry Beijing Normal University College of Textiles and Clothing State Key Laboratory of Bio-fibers and Eco-textiles Qingdao University Key State Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of Technology Department of Physics and Applied Optics Beijing Area Major Laboratory Center for Advanced Quantum Studies Beijing Normal University State Key Laboratory of Polymer Materials Engineering College of Polymer Science and Engineering Sichuan University

Understanding the effect of intermolecular interaction on the growth dynamic of active layers is critical for advancing organic solar cells(OSCs). however, the diverse structure of donors and acceptors makes the research challenging. Additives with customizable structures and properties could simplify this complexity. herein, we meticulously tailor two additives of 3,4-ethylenedioxythiophene(EDOT) and 2,5-dibromo-3,4-ethylenedioxythiophene(DBEDOT), possessing distinct intermolecular interaction features to elaborate the inherent relationship. It is found that varied interaction strengths can alter film formation processes. The enhanced intermolecular interaction between the DBEDOT and non-fullerene acceptor BTP-e C9-4F results in pre-aggregation and longer crystallization duration of BTP-e C9-4F, facilitating the formation of films with compact molecular packing and decent phase separation. Thus, exciton dissociation and charge transport become more efficient. Finally, devices processed with DBEDOT exhibit a remarkable power conversion efficiency of 19.35% in small-area OSCs and 14.11% in bladecoated 5 cm × 5 cm organic solar mini-modules. Especially, OSCs can maintain 80% of their initial efficiency after continuous annealing at 85 °C for over 2,100 h.

关键词：

同方期刊数据库

Synthesis of highly ordered Large Size Mesoporous Silica and Effect of Stabilization as Enzyme Supports in Organic Solvent

在线全文

学校读者我要写书评

暂无评论

Chemical Research in Chinese Universities 2002年第2期18卷 200-205页

作者： LI bo Inagaki S Miyazaki C Takahashi h Toyota Central R&D Labs. Inc.411YokomichiNagakute choAichi 4801192Japan

FSM 16, MCM 41 and SBA 15 types of hexagonal mesoporous silica with a highly ordered 2 dimensional structure were synthesized by using different silicon sources and surfactants. In the 2 dimensional silicate framework, pore size can be uniformly controlled by the combined use of the surfactants having different alkyl chain lengths and the swelling agents(triisopropyl benzene). The pore diameter of FSM 16 and MCM 41 can be expanded to be 10 nm, SBA 15 to be 15 nm. The crystal regularity was decreased with the increase of the pore diameter. In FSM 16 derived from kanemite(silicon source) and MCM 41 from water glass, their anionic characteristics on the pore wall may be stronger than those of SBA 15 derived from oligomeric tetramethoxysilane(TMOS). We have successfully used FSM 16 and MCM 41 to immobilize the enzyme having cationic residues below isoelectric point. The level of adsorption of enzymes in FSM 16 and MCM 41 was relatively high, but was low in SBA 15 support. The mechanism of enzyme to be adsorbed in mesoporous silica was suggested to be the ionic interactions. In aqueous solutions, horseradish peroxidase(hTP) was immobilized in FSM 16 with 8.9 nm mesopores and the highest loading amount(183 mg/mg FSM) was obtained, but for the FSM 16 of pore diameter 30 nm only an amount of 28 mg/mg FSM was obtained. The catalytic activity in the organic solvent was high when hRP was immobilized in FSM 16 and MCM 41, but it was low in case of SBA 15.

关键词： Mesoporous silica Surfactant Swelling agent Enzyme Activity

FEM modelling of single-core sandwich and 2-core multilayer beams containing foam aluminum core and metallic face sheets under monolithic bending

在线全文

学校读者我要写书评

暂无评论

Progress in Natural Science:Materials International 2011年第2期21卷 127-138页

作者： Jiang-bo ShA T.h.YIP M.h.TEO School of Materials Science and Engineering Beihang UniversityBeijing 100191China School of Materials Engineering Nanyang Technological UniversityNanyang AvenueSingapore 639698Singapore

This present paper dealt with bending deformation and failure behavior of sandwich and multilayer beams composed of aluminum foam core and metallic face sheets by finite element method(FEM) and four-point bending *** revealed that collapse of the multilayer beams is dominated by two basic modes:indentation(ID) and core shear(CS).ID is dominated by the maximum compressive strain and CS by the maximum shear *** failure of the sandwich beams depends on if the face sheets show ID mode in the multilayer beams or *** a multilayer beam is dominated by ID mode,the sandwich beams with similar face sheets and same core thickness would also show ID *** a multilayer beam fails fully by CS mode,no ID characteristic would appear in similar face sheet single-core *** failed by ID mode have a potential to consume more bending deformation energy than those dominated by CS *** dense foam can bear higher loading,which in turn,increases the ability of absorbing deformation energy for a *** applications of deformation energy absorption aspect,beams containing foam core and metallic face sheets should be designed to have a tendency of ID mode failure.

关键词： aluminum foam finite element method sandwich and multilayer beams indentation core shear

东北典型盐碱湿地碳排放的水深临界阈值及其温度依赖性

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

湖泊科学 2025年第1期37卷 159-170,I0015-I0017页

作者：李姝臻刘强甘罗扬武海涛王波北京师范大学环境学院水环境模拟国家重点实验室北京100875 北京师范大学环境学院教育部水沙科学重点实验室北京100875 中国科学院长春分院长春130022 吉林莫莫格国家级自然保护区白城137316

作为全球重要的碳库,湿地在缓解气候变化方面发挥了重要作用。然而在全球变暖背景下,湿地的碳排放(尤其是甲烷(Ch_(4))排放)存在高度变异性和不确定性,极大地削弱了湿地碳库功能的发挥。为了探究不同水深梯度下东北盐碱湿地碳排放通量... 详细信息

作为全球重要的碳库,湿地在缓解气候变化方面发挥了重要作用。然而在全球变暖背景下,湿地的碳排放(尤其是甲烷(Ch_(4))排放)存在高度变异性和不确定性,极大地削弱了湿地碳库功能的发挥。为了探究不同水深梯度下东北盐碱湿地碳排放通量的特征,本研究以莫莫格湿地为主要研究区,选取5种代表性植被(芦苇(Phragmites australis)、扁秆藨草(bolboschoenus planiculmis)、三江藨草(Schoenoplectus nipponicus)、香蒲(Typha orientalis ***)和碱蓬(Suaeda glauca)),布设Marsh Organ中型实验生态系统模拟不同水深生境,揭示Ch_(4)和二氧化碳(CO_(2))排放通量变化及其环境影响因子。结果表明,莫莫格湿地-10~50 cm水深范围内5种代表性植被生长季Ch_(4)排放通量范围为0.07~86.74 mg/(m^(2)·h),平均值为8.89 mg/(m^(2)·h),其主要环境影响因素为水深、气温和表层10 cm土壤含水量;在研究水深范围内,代表性植被生长季CO_(2)排放通量范围为10.59~1891.08 mg/(m^(2)·h),平均值为450.12 mg/(m^(2)·h),其主要环境影响因素为水深、气温和表层10 cm土壤含水量。不同植被对碳排放的贡献量有所差异,具体来说,芦苇和香蒲的Ch_(4)排放通量最高,而藨草的CO_(2)排放通量最高。碳排放随水深变化呈现分段规律,Ch_(4)排放随水深变化呈现先增加后减少的趋势,而CO_(2)则呈现相反规律,随水深变化先减小后增加,其水深临界阈值均出现在22 cm处。在不同水深范围内,CO_(2)排放对于水深的敏感性均大于Ch_(4),且当水深大于22 cm时,Ch_(4)和CO_(2)均呈现出更高的水深敏感性。碳排放在不同水深范围对温度的敏感程度不同,当水深小于22 cm时,Ch_(4)和CO_(2)均呈现出更高的温度敏感性,然而当水深大于22 cm时,二者对温度均不敏感。结果表明升温背景下,东北典型盐碱湿地水陆过渡区关键生态系统在不同水深范围内呈现出不对称的响应模式,频繁的水位波动会极大地改变湿地碳排放格局,从而影响到湿地碳功能的稳定发挥。

关键词：碳排放水深温度依赖性莫莫格湿地阈值

The Mechanism of heating Rate on the Secondary Recrystallization Evolution in Grain Oriented Silicon Steel

在线全文

学校读者我要写书评

暂无评论

Journal of Wuhan University of Technology(Materials Science) 2025年第1期 275-282页

作者：高倩 LI Jun WANG Xianhui CAO Laifu GONG Jian LI bo Central Iron and Steel Research Institute Group Shougang Zhixin Electromagnetic Material R&D (Beijing) Co. Ltd. Beijing Shougang Co. Ltd.

Grain-oriented silicon steels were prepared at different heating rates during high temperature annealing, in which the evolution of magnetic properties, grain orientations and precipitates were studied. To illustrate the Zener factor, the diameter and number density of precipitates of interrupted testing samples were statistically calculated. The effect of precipitate ripening on the Goss texture and magnetic property was investigated. Data indicated that the trend of Zener factor was similar under different heating rates, first increasing and then decreasing, and that the precipitate maturing was greatly inhibited as the heating rate increased. Secondary recrystallization was developed at the temperature of 1 010 ℃ when a heating rate of 5 ℃/h was used, resulting in Goss, Brass and {110} oriented grains growing abnormally and a magnetic induction intensity of 1.90T. Furthermore, increasing the heating rate to 20 ℃/h would inhibit the development of undesirable oriented grains and obtain a sharp Goss texture. however, when the heating rate was extremely fast, such as 40 ℃/h, poor secondary recrystallization was developed with many island grains, corresponding to a decrease in magnetic induction intensity to 1.87 T. At a suitable heating rate of 20 ℃/h, the sharpest Goss texture and the highest magnetic induction of 1.94 T with an onset secondary recrystallization temperature of 1 020 ℃ were found among the experimental variables in this study. The heating rate affected the initial temperature of secondary recrystallization by controlling the maturation of precipitates, leading to the deviation and dispersion of Goss texture, thereby reducing the magnetic properties.

关键词：

Game and Dynamic Communication Path-Based Pricing Strategies for Microgrids Under Communication Interruption

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

IEEE/CAA Journal of Automatica Sinica 2023年第4期10卷 1032-1047页

作者： bo Zhang Chunxia Dou Dong Yue Ju h.Park Yudi Zhang Zhanqiang Zhang Institute of Advanced Technology Nanjing University of Posts and TelecommunicationsNanjing 210023China Department of Electrical Engineering Yeungnam UniversityGyeongsan 38541South Korea Nanjing University Nanjing 210093China.She is now with the University of BristolBristol BS81QUUK

Nowadays,the microgrid cluster is an important application scenario for energy *** trading,one of the most important research directions is the issue of *** determine reasonable pricing for the microgrid cluster,data communication is used to create the cyber-physical system(CPS),which can improve the observability of ***,the following works are carried out in the *** the physical layer:1)Regarding trading between microgrids and the load,based on the generalized game theory,an optimal pricing strategy is proposed,which takes into account the interactive relationships among microgrids and transforms the pricing problem into a Nikaido-Isoda function to obtain the optimal prices conveniently;2)Regarding peer-to-peer trading between two microgrids,based on evolutionary game theory and the penalty mechanism,the optimal sale price of the seller is selected with boundary *** the cyber layer,regarding the communication interruption issue existing in pricing(i.e.,the game process),based on the principle of matching the performance of the path with the importance degree of the data,a dynamic regulating method of paths is proposed,i.e.,adopting a new path to re-transmit the interrupted data to the ***,the effect of the proposed strategies is verified by case studies.

关键词： Communication interruption dynamic regulating

Photoluminescence and ratiometric thermo-response of Eu^(2+)and Eu^(3+)in BaAl_(2)B_(2)O_(7):Eu^(2+),Eu^(3+)phosphor materials

在线全文

学校读者我要写书评

暂无评论

Journal of Rare Earths 2024年第7期42卷 1240-1249,I0002页

作者： Ziyao Wang haitao Fu Xiufeng Zhan bo Tong Guofeng Ma h.T.(Bert)hintzen Institute of Innovative Science and Technology Shenyang UniversityShenyang110044China College of Mechanical Engineering Shenyang UniversityShenyang110044China Faculty of Applied Sciences Delft University of Technology2629 JBDelftthe Netherlands

A novel Eu^(2+)-Eu^(3+)co-activated ratiometric thermo-sensitive phosphor was developed and synthesized by solid-state *** valence state of Eu,photoluminescence and thermo-sensitive performance of the phosphor prepared either in ambient air or carbothermally were investigated and *** phosphor shows high sensitivity(Sa=0.0173 K^(-1),S_(r)=0.461%/K)and superior signal discriminability(Δν∼10380 cm^(−1)).The thermo-sensitive performance is subject to the dual effects of different thermo-responses by Eu^(2+)versus Eu^(3+)combined with energy transfer from Eu^(2+)to Eu^(3+),so that the sensitivity of the phosphor in the temperature range presents a non-monotonic *** development of the BaAl_(2)B_(2)O_(7):Eu^(2+),Eu^(3+)phosphor is not only expected to be relevant for application in the field of temperature sensing,but also of reference significance for improving the sensitivity by means of energy transfer between co-activator ions over a wider temperature range of Eu^(2+)-Eu^(3+)co-activated ratiometric thermo-sensitive phosphors.

关键词： Photoluminescence Ratiometric thermo-response Phosphor Eu^(2+)/Eu^(3+) Rare earths