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Socio-economic development of countries based on the Composite Country Development Index(CCDI)

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Regional Sustainability 2023年第2期4卷 115-128页

作者： Kalamkas NURALINA Raissa BAIZHOLOVA Natalya ALEKSANDROVA viktor KONSTANTINOV Alexander BIRYUKOV Department of Economy Shakarim State University SemeiSemey071412Kazakhstan Department of Economics and Entrepreneurship L.N.Gumilyov Eurasian National UniversityNur-Sultan021801Kazakhstan Department of Personnel Management Transbaikal State UniversityChita672000Russia Department of Economics Finance and AccountingOrel State University302020Russia Department of Economic Theory and Analysis Sterlitamak Branch of the Ufa University of Science and TechnologySterlitamak453130Russia

World experience indicates the existence of significant imbalances in the development of *** problem of assessing the rational development of the regional and national economy is becoming urgent,since such assessments can prevent development imbalances across *** aim of this study is to elaborate a methodology to assess the countries’socio-economic development by integraring 12 modern indices of socio-economic development into the Composite Country Development Index(CCDI).The methodology of this research was based on a set of key indices that described socio-economic development level in four fields(social development,digital development,economic development,and environmental security)and then these indices were integrated into the *** study further applied factor analysis and R-Studio software to define the gaps of social and economic development in 59 selected countries using the trigonometric function of the angle *** correlation analysis confirmed the existence of a close interrelation among the studied *** paper noted that due to the emergence of new priorities,it is necessary to revise the assessment methodology of socio-economic development level and expand them to cover the decisive *** was confirmed by the results obtained,demonstrating various combinations of the development level in the four fields and their impact on the *** scientific contribution of this research is to form a methodology(e.g.,the CCDI)for evaluating the socio-economic development level of countries in the world.

关键词： Composite Country Development Index(CCDI) Correlation analysis Social development Digital development Economic development Environmental security

Assessment of health risk of the baikal region population associated with the wildfire air pollution:Approaches,modelling,digital environment

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Emerging Contaminants 2023年第1期9卷 33-40页

作者： Natalia Efimova Viacheslav Paramonov viktor Rukavishnikov Roman Fedorov Gennadiy Ruzhnikov Andrei Tsyrendorzhiyev East-Siberian Institute of Medical and Ecological Research 3“12a mikrorayon”Angarsk665827Irkutsk oblastRussia Matrosov Institute for System Dynamics and Control Theory of SB RAS 134 Lermontov St.Irkutsk664033Russia Rospotrebnadzor for the Republic of Buryatia 45Kluchevskaya St.Ulan-Ude670013Republic of BuryatiaRussia

The latest forecasts indicate wildfire activity in many parts of the *** smoke contains hazardous air pollutants such as carbon monoxide,nitrogen dioxide,ozone,particulate matter et ***,prediction of this impact and on time medical care are difficult due to the lack of digital decision-making *** aim of this study is to assess population health risks associated with the sub-daily exposure to wildfire smoke produced by massive foci of combustion near the populated areas and at a significant distance from *** consider reflex reactions as a response to a short-term *** maximum value of the 95th percentile from the series of observations at the monitoring point was used to assess the *** the mathematical description of the“concentration-effect”relationship,the model of individual thresholds is *** model describes a dependence as a straight line under the condition that the concentration is expressed in the form of a normalprobabilistic *** frequency of additional cases is determined by studying the number of requests for medical assistance(including calls for ambulance)with complaints of respiratory disorders,lacrimation,*** the territories affected by wildfires *** indicator is calculated per 1000 *** probability of negative biological effects in response to the impact of wildfire smoke is associated mainly with the content of CO and TPM in the conditions of the Baikal *** frequency of additional requests for medical care ranged from 0.137 to 0.933 per 1000 exposed population during the fire period in settlements where risk levels are>*** developed a digital environment that allows us to get information about harmful substances in the outdoor air from different sources and in different formats and data *** digital environment supports implementation of models for assessing hazards to human body organs.

关键词： Air pollution Wildfire Health risk Digital environment

Coexisting charge density wave and ferromagnetic instabilities in monolayer InSe

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npj Computational Materials 2022年第1期8卷 1101-1109页

作者： Evgeny A.Stepanov viktor Harkov Malte Rösner Alexander I.Lichtenstein Mikhail I.Katsnelson Alexander N.Rudenko CPHT CNRSEcole PolytechniqueInstitut Polytechnique de ParisF-91128PalaiseauFrance I.Institute of Theoretical Physics University of HamburgNotkestraße 922607HamburgGermany European X-Ray Free-Electron Laser Facility Holzkoppel 422869SchenefeldGermany Radboud University Institute for Molecules and Materials6525AJNijmegenThe Netherlands The Hamburg Centre for Ultrafast Imaging Luruper Chaussee 14922761HamburgGermany

Recently fabricated InSe monolayers exhibit remarkable characteristics that indicate the potential of this material to host a number of many-body *** this work,we systematically describe collective electronic effects in hole-doped InSe monolayers using advanced many-body *** this end,we derive a realistic electronic-structure model from first principles that takes into account the most important characteristics of this material,including a flat band with prominent van Hove singularities in the electronic spectrum,strong electron–phonon coupling,and weakly screened long-ranged Coulomb *** calculate the temperature-dependent phase diagram as a function of band filling and observe that this system is in a regime with coexisting charge density wave and ferromagnetic instabilities that are driven by strong electronic Coulomb *** regime can be achieved at realistic doping levels and high enough temperatures,and can be verified *** find that the electron–phonon interaction does not play a crucial role in these effects,effectively suppressing the local Coulomb interaction without changing the qualitative physical picture.

关键词： ferromagnetic charge wave

Towards electrochemical hydrogen storage in liquid organic hydrogen carriers via proton-coupled electron transfers

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Journal of Energy Chemistry 2022年第10期31卷 292-300,I0007页

作者： Hamid Ghorbani Shiraz Mikhail Vagin Tero-Petri Ruoko viktor Gueskine Krzysztof Karon Mieczystaw tapkowski Tobias Abrahamsson Thomas Ederth Magnus Berggren Xavier Crispin Laboratory of Organic Electronics Department of Science and Technology(ITN)Linkoping UniversitySE-60174 NorrkopingSweden Smart Photonic Materials Facuty of Engineering and Natural SciencesTampere UniversiyPBox 541.Tampere Fl-33101Finland Silesian University of Technology.Faculty of Chemistry Deparment of Physical Chemistry and Technology of PolymersM.Strzody 9.44-100 GliwicePoland dDepartment of Physics Chemistry and Biology(IFM)Linkoping UniversiySE-58183 LinkopingSweden

Green hydrogen is identified as one of the prime clean energy carriers due to its high energy density and a zero emission of CO_(2).A possible solution for the transport of H_(2)in a safe and low-cost way is in the form of liquid organic hydrogen carriers(LOHCs).As an alternative to loading LOHC with H_(2)via a two-step procedure involving preliminary electrolytic production of H_(2)and subsequent chemical hydrogenation of the LOHC,we explore here the possibility of electrochemical hydrogen storage(EHS)via conversion of proton of a proton donor into a hydrogen atom involved in covalent bonds with the LOHC(R)via a protoncoupled electron transfer(PCET)reaction:2nH^(+)+2ne^(-)+Rox■n H_(2)^(0)*** chose 9-fluorenone/fluorenol(Fnone/Fnol)conversion as such a model PCET *** electrochemical activation of Fnone via two sequential electron transfers was monitored with in-situ and operando spectroscopies in absence and in presence of different alcohols as proton donors of different reactivity,which enabled us to both quantify and get the mechanistic insight on *** possibility of hydrogen extraction from the loaded carrier molecule was illustrated by chemical activation.

关键词： Proton-coupled electron transfer Electrochemical hydrogen storage Hydrogen bonding agent Anion-radical Comproportionation

Desorption isotherms and isosteric heat of anaerobic fermentation residues

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Chinese Journal of Chemical Engineering 2019年第10期27卷 2510-2517页

作者： Tibor Poós viktor Szabó Department of Building Services and Process Engineering Faculty of Mechanical EngineeringBudapest University of Technology and EconomicsBertalan Lajos u.4-6H-1111 BudapestHungary

This paper presents the equilibrium desorption isotherms and the isosteric heat of sorption of a mixture containing mechanically dewatered fermentation residue(obtained from a blend of chicken,swine and cattle manure)used in biogas plants and corn spoiled silage in a ratio of 2:*** moisture desorption isotherms of the fermentation residue were determined at 32°C,40°C and 80°C and in the relative humidity range of 0.057/1 using static gravimetric *** equations were used to analyze the desorption data of Modified Henderson,Modified Halsey,Modified Oswin,Modified Chung–Pfost and Modified GAB *** constants of the model equations were calculated by non-linear regression *** Modified Henderson model fitted to the desorption isotherm data *** the proposed function,the final moisture content of the material can be determined as long as it can be dried in infinite time with the drying gas in the given *** isosteric heat of desorption was calculated by using the Modified Henderson model in the studied temperature range based on the Clausius–Clapeyron *** isosteric heat varied between 46 k J·mol-1 and 67 k J·mol-1 at moisture levels 1.91 b Xe<4.05 kgH2O·kgdP-1 for the material.

关键词： Desorption Equilibrium Model Measurement Isosteric heat

Selective and self-validating breath-level detection of hydrogen sulfide in humid air by gold nanoparticle-functionalized nanotube arrays

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Nano Research 2022年第3期15卷 2512-2521页

作者： Luis Antonio Panes-Ruiz Leif Riemenschneider Mohamad Moner Al Chawa Markus Löffler Bernd Rellinghaus Ronald Tetzlaff viktor Bezugly Bergoi Ibarlucea Gianaurelio Cuniberti Institute for Materials Science Max Bergmann Center of BiomaterialsTechnische Universität DresdenDresden 01062Germany Institute of Circuits and Systems Technische Universität DresdenDresden 01062Germany Dresden Center for Nanoanalysis(DCN) Center for Advancing Electronics Dresden(cfaed)Technische Universität DresdenDresden 01062Germany Life Science Incubator Sachsen GmbH&Co.KG Dresden 01307Germany Center for Advancing Electronics Dresden(cfaed) Technische Universität DresdenDresden 01062Germany

We demonstrate the selective detection of hydrogen sulfide at breath concentration levels under humid airflow,using a self-validating 64-channel sensor array based on semiconducting single-walled carbon nanotubes(sc-SWCNTs).The reproducible sensor fabrication process is based on a multiplexed and controlled dielectrophoretic deposition of *** sensing area is functionalized with gold nanoparticles to address the detection at room temperature by exploiting the affinity between gold and sulfur atoms of the *** devices functionalized with an optimized distribution of nanoparticles show a sensitivity of 0.122%/part per billion(ppb)and a calculated limit of detection(LOD)of 3 *** the self-validation,our sensors show increased stability and higher response levels compared to some commercially available electrochemical *** cross-sensitivity to breath gases NH3 and NO is addressed demonstrating the high selectivity to ***,mathematical models of sensors’electrical characteristics and sensing responses are developed to enhance the differentiation capabilities of the platform to be used in breath analysis applications.

关键词： chemiresistive gas sensors semiconducting carbon nanotubes gold nanoparticles hydrogen sulfide detection chemiresistor mathematical model

Mechanism of the Initial Stage of Thermal Decomposition of Nitroguanidine

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火炸药学报 2023年第1期46卷 31-40页

作者： Boris E.Krisyuk Danila A.Markin Timofey M.Sypko viktor V.Zakharov Nikita V.Chukanov Boris L.Korsunskiy Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry Russian Academy of Sciences142432prosp.Academician Semenov1ChernogolovkaMoscow RegionRussia Plekhanov Russian University of Economics Department of Chemistry and Physics36 Stremyanny laneMoscow 117997Russia Lomonosov Moscow State University Faculty of Fundamental Physical and Chemical engineeringGSP-11 Leninskie Goryp.51Moscow 119991Russia N.N.Semenov Federal Research Center for Chemical Physics Russian Academy of Science 4 Kosygina StreetBuilding 1Moscow 119991Russia

A theoretical and experimental study of the thermal decomposition of nitroguanidine(NQ) has been carried out. Various thermolysis channels were studied by quantum chemistry methods at the CCSD(or DLPNO-CCSD) level using the aug-cc-pVDZ basis set. It is shown that the lowest activation enthalpies(170-180kJ/mol) are characteristic of the reactions of NO2abstraction from the initial NQ and the reaction channel with the transfer of oxygen from the nitro group to carbon in the limiting stage. Additionally, the thermolysis of NQ was studied experimentally in a nonisothermal mode with heating rates from 1 to 10K/min. In these experiments, the weight loss of the sample, thermal effects, and mass spectra of the products were recorded. An analysis of the experimental data confirmed the results of a theoretical study of the mechanism of thermal decomposition of NQ. The main thermolysis products are N2O, HNCO, NH3, and NO2, which fully corresponds to quantum chemical calculations.

关键词： primary thermolysis steps quantum-chemical calculation mass spectrometry DSC TG

Origin of Luminescent Centers and Edge States in Low-Dimensional Lead Halide Perovskites:Controversies,Challenges and Instructive Approaches

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Nano-Micro Letters 2019年第2期11卷 109-126页

作者： Jiming Bao viktor G.Hadjiev Department of Electrical and Computer Engineering University of HoustonHoustonTX 77204USA Department of Chemistry University of HoustonHoustonTX 77204USA Materials Science and Engineering University of HoustonHoustonTX 77204USA Texas Center for Superconductivity University of HoustonHoustonTX 77204USA Department of Mechanical Engineering University of HoustonHoustonTX 77204USA

With only a few deep-level defect states having a high formation energy and dominance of shallow carrier non-trapping defects,the defect-tolerant electronic and optical properties of lead halide perovskites have made them appealing materials for high-efficiency,low-cost,solar cells and light-emitting *** such,recent observations of apparently deep-level and highly luminescent states in low-dimensional perovskites have attracted enormous attention as well as intensive *** observed green emission in 2D CsPb2Br5 and 0 D Cs4PbBr6 poses an enigma over whether it is originated from intrinsic point defects or simply from highly luminescent CsPbBr3 nanocrystals embedded in the otherwise transparent wide band gap *** nature of deep-level edge emission in 2D Ruddlesden–Popper perovskites is also not well *** this mini review,the experimental evidences that support the opposing interpretations are analyzed,and challenges and root causes forthe controversy are *** in the current density functional theory approaches to modeling of properties and intrinsic point defects in lead halide perovskites are also *** experimental approaches are suggested to better correlate property with structure of a material and help resolve the *** and identification of the origin of luminescent centers will help design and engineer perovskites for wide device applications.

关键词： Low-dimensional perovskites Luminescent centers Edge states Cesium lead halides Deep-level states Ruddlesden–Popper perovskites

Average stress-average strain tension-stiffening relationships based on provisions of design codes

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2011年第10期12卷 731-736页

作者： Gintaris KAKLAUSKAS viktor GRIBNIAK Rokas GIRDZIUS Department of Bridges and Special Structures Vilnius Gediminas Technical University Department of Strength of Materials Vilnius Gediminas Technical University

This research was aimed at deriving average stress-average strain tension-stiffening relationships in accordance with the provisions of design codes for reinforced concrete (RC) members. Using a proposed inverse technique, the tension-stiffening relationships were derived from moment-curvature diagrams of RC beams calculated by different code methods, namely Eurocode 2, ACI 318, and the Chinese standard GB 50010-2002. The derived tension-stiffening laws were applied in a numerical study using the nonlinear finite element software ATENA. The curvatures calculated by ATENA and the code methods were in good agreement.

关键词：增强的水泥(RC ) 代码技术使硬紧张数字建模