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Lithiophilic Li-Si alloy-solid electrolyte interface enabled by high-concentration dual salt-reinforced quasi-solid-state electrolyte

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Journal of Energy Chemistry 2024年第8期95卷 216-230,I0005页

作者： Yuanxing Zhang Ling Zhang Zhiguang Zhao Yuxiang Zhang Jingwen Cui Chengcai Liu Daobin Mu Yuefeng Su Borong wu feng wu School of Materials Science and Engineering Beijing Institute of TechnologyBeijing 100081China Chongqing Innovation Center Beijing Institute of TechnologyChongqing 401120China Collaborative Innovation Center of Electric Vehicles in Beijing Beijing 100081China

Solid polymer electrolytes(SPEs)are urgently required to achieve practical solid-state lithium metal batteries(LMBs)and lithium-ion batteries(LIBs),Herein,we proposed a mechanism for modulating interfacial conduction and anode interfaces in high-concentration SPEs by *** electrolyte exhibits superior ionic conductivity and remarkable interface compatibility with salt-rich clusters:(1)polymer-plastic crystal electrolyte(P-PCE,TPU-SN matrix)dissociates ion pairs to facilitate Li+transport in the electrolyte and regulates Li^(+)diffusion in the *** crosslinking structure of the matrix compensates for the loss of mechanical strength at high-salt concentrations;(2)dual-anion TFSI^(-)_(n)-DFBOP^(-)_(m)in the Li^(+)solvation sheath facilitates facile Li^(+)desolvation and formation of salt-rich clusters and is conducive to the formation of Li conductive segments of TPU-SN matrix;(3)theoretical calculations indicate that the decomposition products of LiDFBOP form SEI with lower binding energy with LiF in the SN system,thereby enhancing the interfacial electrochemical redox kinetics of SPE and creating a solid interface SEI layer rich in *** a result,the optimized electrolyte exhibits an excellent ionic conductivity of9.31×10^(-4)S cm^(-1)at 30℃and a broadened electrochemical stability up to 4.73 *** designed electrolyte effectively prevents the formation of Li dendrites in Li symmetric cells for over 6500 h at0.1 mA cm^(-2).The specific Li-Si alloy-solid state half-cell capacity shows 711.6 mAh g^(-1)after 60 cycles at 0.3 A g^(-1).Excellent rate performance and cycling stability are achieved for these solid-state batteries with Li-Si alloy anodes and NCM 811 *** 811‖Prelithiated silicon-based anode solid-state cell delivers a discharge capacity of 195.55 mAh g^(-1)and a capacity retention of 97.8%after 120 *** 811‖Li solid-state cell also delivers capacity retention of 84.2%after 450 cycles.

关键词： Prelithiation Li-Si alloy anode Solid-state electrolyte SEI layer

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Efficient and stable PtFe alloy catalyst for electrocatalytic methanol oxidation with high resistance to CO

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Journal of Energy Chemistry 2024年第3期90卷 327-336,I0008页

作者： Qian Yang Sifan Zhang fengshun wu Lihua Zhu Guang Li Mingzhi Chen An Pei Yingliang feng Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry College of Chemistry and Chemical EngineeringFaculty of Materials Metallurgy and ChemistryJiangxi University of Science and TechnologyGanzhou 341000JiangxiChina College of Chemistry and Chemical Engineering Xiamen UniversityXiamen 361005FujianChina

Direct methanol fuel cells(DMFC) are widely considered to be an ideal green energy conversion device but their widespread applications are limited by the high price of the Pt-based catalysts and the instability in terms of surface CO toxicity in long-term ***,the PtFe alloy nanoparticles(NPs) with small particle size(~4.12 nm) supported on carbon black catalysts with different Pt/Fe atomic ratios(Pt_(1)Fe_(2)/C,Pt_(3)Fe_(4)/C,Pt_(1)Fe_(1)/C,and Pt_(2)Fe_(1)/C) are successfully prepared for enhanced anti-CO poisoning during methanol oxidation reaction(MOR).The optimal atomic ratio of Pt/Fe for the MOR is 1:2,and the mass activity of Pt_(1)Fe_(2)/C(5.40 A mg_(Pt)^(-1)) is 13.5 times higher than that of conventional commercial Pt/C(Pt/C-JM)(0.40 A mg_(Pt)^(-1)).The introduction of Fe into the Pt lattice forms the PtFe alloy phase,and the electron density of Pt is reduced after forming the PtFe ***-situ Fourier transform infrared results indicate that the addition of oxyphilic metal Fe has reduced the adsorption of reactant molecules on Pt during the *** doping of Fe atoms helps to desorb toxic intermediates and regenerate Pt active sites,promoting the cleavage of C-O bonds with good selectivity of CO_(2)(58.1%).Moreover,the Pt_(1)Fe_(2)/C catalyst exhibits higher CO tolerance,methanol electrooxidation activity,and long-term stability than other Pt_(x)Fe_(y)/C catalysts.

关键词： Alloy catalyst PtFe Methanol oxidation In-situ FTIR CO resistance

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A Calculation Method of Double Strength Reduction for Layered Slope Based on the Reduction of Water Content Intensity

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工程与科学中的计算机建模(英文) 2024年第1期138卷 221-243页

作者： feng Shen Yang Zhao bingyi Li Kai wu School of Civil Engineering Suzhou University of Science and TechnologySuzhou215011China R&D Department Suzhou Jcon Greenbuild Fabricated Co.Ltd.Suzhou215004China

The calculation of the factor of safety(FOS)is an important means of slope *** paper proposed an improved double strength reductionmethod(DRM)to analyze the safety of layered *** physical properties of different soil layers of the slopes are different,so the single coefficient strength reduction method(SRM)is not enough to reflect the actual critical state of the *** that the water content of the soil in the natural state is the main factor for the strength of the soil,the attenuation law of shear strength of clayey soil changing with water content is *** paper also establishes the functional relationship between different reduction ***,a USDFLD subroutine is programmed using the secondary development function of finite element *** the relationship between field variables and calculation time realizes double strength reduction applicable to the layered ***,by comparing the calculation results of different examples,it is proved that the stress and displacement distribution of the critical slope state obtained by the improved method is more realistic,and the calculated safety factor is more *** newly proposedmethod considers the difference of intensity attenuation between different soil layers under natural conditions and avoids the disadvantage of the strength reduction method with uniform parameters,which provides a new idea and method for stability analysis of layered and complex slopes.

关键词： Double strength reduction slopes stability water content factor of safety numerical methods

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Efficient nitrate electroreduction over Mn-doped Cu catalyst via regulating N-containing intermediates adsorption configuration

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Science China Chemistry 2024年第6期67卷 1969-1975页

作者： Limin wu Shunhan Jia Libing Zhang Ruhan Wang Jiaqi feng Xiaofu Sun Buxing Han Beijing National Laboratory for Molecular Sciences CAS Laboratory of Colloid and Interface and ThermodynamicsCAS Research/Education Center for Excellence in Molecular SciencesCenter for Carbon Neutral ChemistryInstitute of ChemistryChinese Academy of SciencesBeijing100190China School of Chemical Sciences University of Chinese Academy of SciencesBeijing100049China College of Chemical Engineering and Environment China University of PetroleumBeijing102249China Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular EngineeringEast China Normal UniversityShanghai200062China

The electrochemical reduction of NO_(3)^(-)to NH_(3)holds promise for economic and environmental benefits,presenting an energyefficient alternative to the traditional Haber-Bosch ***,challenges exist due to its sluggish kinetics,multiple intermediates,and various reaction *** this study,Mn-doped-Cu catalyst was synthesized and employed for electrochemical NO_(3)^(-)-to-NH_(3)*** doping of Mn into Cu resulted in exceptional performance,achieving a FE of 95.8%and an NH_(3)yield rate of 0.91 mol g^(-1)h^(-1)at-0.6 V in a neutral electrolyte at low NO_(3)^(-)*** experimental studies and theoretical calculations revealed that the Mn dopant enhanced the kinetic rate of NO_(2)~--to-NH_(3)and induced a distinct configuration of**** alteration decreased the energy barrier of*NO-to-*NOH,consequently promoting the conversion of NO_(3)^(-)-to-NH_(3).

关键词： nitrate reduction electrocatalysis ammonia synthesis N-intermediate green chemistry

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The hydrophobic cluster on the surface of protein is the key structural basis for the SDS-resistance of chondroitinase VhChlABC

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Marine Life Science & Technology 2024年第1期6卷 93-101页

作者： Juanjuan Su Hao wu Chengying Yin fengchao Zhang feng Han Wengong Yu School of Medicine and Pharmacy Ocean University of ChinaQingdao 266003China Laboratory for Marine Drugs and bioproducts Qingdao Marine Science and Technology CenterQingdao 266237China Key Laboratory of Marine Drugs Ministry of EducationQingdao 266003China Shandong Provincial Key Laboratory of Glycoscience and Glycoengineering Qingdao 266003China

The application of chondroitinase requires consideration of the complex microenvironment of the *** previous research reported a marine-derived sodium dodecyl sulfate(SDS)-resistant chondroitinase *** study further investigated the mechanism of VhChlABC resistance to *** on the hydrophobic cluster on its strong hydrophilic surface,it was found that the reduction of hydrophobicity of surface residues Ala181,Met182,Met183,Ala184,Val185,and Ile305 significantly reduced the SDS resistance and *** dynamics(MD)simulation and molecular docking analysis showed that I305G had more conformational flexibility around residue 305 than wild type(WT),which was more conducive to SDS insertion and *** affinity of A181G,M182A,M183A,V185A and I305G to SDS was significantly higher than that of *** conclusion,the surface hydrophobic microenvironment composed of six residues was the structural basis for SDS *** feature could prevent the binding of SDS and the destruction of hydrophobic packaging by increasing the rigid conformation of protein and reducing the binding force of *** study provides a new idea for the rational design of SDS-resistant proteins and may further promote chondroitinase research in the targeted therapy of lung diseases under the pressure of pulmonary surfactant.

关键词： Hydrophobic cluster Protein surface SDS-resistance Chondroitinase

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Enhanced bioethanol production from sugarcane bagasse:combination of liquid hot water and deep eutectic solvent pretreatment for optimized enzymatic saccharification

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Frontiers of Chemical Science and Engineering 2024年第8期18卷 1-13页

作者： Xiaoling Xian biying Li Shiyong feng Jiale Huang Xinyuan Fu Ting wu Xiaoqing Lin School of Chemical Engineering and Light Industry Guangdong Provincial Key Laboratory of Plant Resources BiorefineryGuangdong University of TechnologyGuangzhou 510006China

In the present study,a sustainable pretreatment methodology combining liquid hot water and deep eutectic solvent is proposed for the efficient fractionation of hemicellulose,cellulose,and lignin from sugarcane bagasse,thereby facilitating the comprehensive utilization of both C5 and C6 *** application of this combined pretreatment strategy to sugarcane bagasse led to notable enhancements in enzymatic saccharification and subsequent *** results demonstrate that liquid hot water-deep eutectic solvent pretreatment yielded 85.05±0.66 g·L^(-1)of total fermentable sugar(glucose:60.96±0.21 g·L^(-1),xylose:24.09±0.87 g·L^(-1))through enzymatic saccharification of sugarcane ***,fermentation of the pretreated sugarcane bagasse hydrolysate yielded 34.33±3.15 g·L^(-1)of *** findings confirm the effectiveness of liquid hot water-deep eutectic solvent pretreatment in separating lignocellulosic components,thus presenting a sustainable and promising pretreatment method for maximizing the valuable utilization of biomass resources.

关键词： sugar cane bagasse synergistic pretreatment enzymatic saccharification ethanol

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Handgrip Strength and Low Muscle Strength Rate in Chinese Adults-China,2020

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China CDC weekly 2024年第32期6卷 821-824,I0004-I0006页

作者： Jiarong Zhu Jingjing Wang Chaoqun Fan Dongming wu Qiang feng Department of National Fitness and Scientific Exercise Research Center China Institute of Sport ScienceBeijingChina

Summary What is already known on this topic?Handgrip strength(HS)serves as a diagnostic marker for low muscle strength rate(LMSR)and reflects the level of skeletal *** the past two decades,global data indicate a downward trend in HS across various *** is added by this report?According to the latest national data,the mean HS among Chinese adults aged 20 years and older was recorded at 40.4 kg for males and 25.1 kg for females in 2020.A decline in HS was observed with increasing age,particularly among ***,lower HS values were reported in rural areas,whereas LMSR was more prevalent in these *** are the implications for public health practice?The analysis of HS and LMSR among Chinese adults is essential for the development and implementation of targeted interventions aimed at improving HS prevalence *** analysis is highly significant for public health,contributing to increased public awareness of LMSR and the promotion of preventative measures.

关键词： strength promotion analysis

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Covalent organic framework monolayer:Accurate syntheses and advanced application

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Nano Research 2024年第7期17卷 6603-6618页

作者： Guangyuan feng Xiaojuan Li Miao Zhang Jiabi Xu Zhiping Liu Lingli wu Shengbin Lei Key Laboratory of Organic Integrated Circuit Ministry of Education and Tianjin Key Laboratory of Molecular Optoelectronic SciencesDepartment of ChemistrySchool of Science and Collaborative Innovation Center of Chemical Science and Engineering(Tianjin)Tianjin UniversityTianjin 300072China Medical College Northwest Minzu UniversityLanzhou 730000China School of Chemistry and Chemical Engineering Lanzhou Jiaotong UniversityLanzhou 730070China

Covalent organic framework(COF)monolayers,with atomically thin,ordered networks,and rich functionality,are widely studied due to their unusual structure/property ***,synthesizing COF monolayer has remained an unmet challenge due to the difficulty of controlling reactions at the monolayer limit with large-scale *** identification and development of new reactions and polymerization conditions are critical for the further advancement of COF monolayer ***,as one-molecule-thick a freestanding films,COF monolayer offers an ideal material *** advanced applications of COF monolayer have been explored in recent *** review provides an overview of the current state of precise synthetic strategies for COF monolayer,highlighting the advantages and limitations of different synthetic approaches and key challenges related to enhancing quality,and emphasizing the unique benefits of COF monolayer as both an ideal model system and for advanced applications.

关键词： covalent organic frameworks monolayer accurate syntheses advanced application

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Experimental study on the compression-shear performance of a new-type circumferential joint of shield tunnel

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Underground Space 2024年第1期14卷 138-155页

作者： Ziyang Zhou Kun feng Yiteng Liu Bohan wu Chunfang Lu Gang Lin Chuan He Key Laboratory of Transportation Tunnel Engineering of Ministry of Education Southwest Jiaotong UniversityChengdu 610031China China Academy of Railway Sciences Corporation Limited Beijing 100081China China Railway Eryuan Engineering Group Co. Ltd.Chengdu 610031China

To investigate the compression-shear behavior of a new circumferential joint based on the sleeve-straight bolt combination type connection of large-diameter shield tunnels,a series of full-scale joint experiments was carried *** the process of the experiment,more attention was paid to the specimen displacement,bolt stress and joint damage *** the basis of these experiment phenomena,this study discussed the compression-shear bearing process of the new connector,analyzed the damage mode of the joint structure,and finally evaluated the performance of the new *** is found that the bearing process of the joint can be divided into four stages:the transitional stage for overcoming the friction of the concrete,the sleeve bearing stage for the sleeve bearing shear loads alone,the combined bearing stage for bearing shear loads by the connector system,and the structural damage stage for structural instability and *** speaking,affected by connector position and hand hole,the positive compression-shear stiffness of the joint is less than the negative compression-shear stiffness,and the positive shear strength of the joint is greater than the negative shear *** increase of longitudinal axial force will improve the compression-shear performance of the *** relationship between longitudinal axial force and joint stiffness is a logarithmic *** use of new type of connector can effectively improve the compression-shear stiffness of joints under low shear loads,but the application of straight bolts will lose part of the strength performance.

关键词： Shield tunnel New type of connector Shear resistance Full-scale experiment Circumferential joint

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Dynamic characteristics of nonlinear vibration isolator for gas turbine

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International Journal of Mechanical System Dynamics 2024年第3期4卷 374-383页

作者： Teng Wang Linhan feng Lei Zhang Chunhui Zhang Yue wu Naval Research Institute BeijingChina

In this study,a theoretical model of the vibration isolation system of the gas turbine is developed and numerically solved.A simplified finite element(FE)model was also established to determine the response under the shock *** results of the FE model are used to verify the effectiveness of the theoretical model and the numerical *** influence of isolator stiffness,vibration isolator damping,and vibration isolator nonlinear stiffness coefficient on the shock response of the vibration isolation system is studied using the controlled-variable *** parameters(stiffness,damping,and nonlinear coefficient)enter into the shock resistance design of gas turbine vibration isolators.

关键词： gas turbine vibration isolator theoretical model damping dynamic characteristics

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