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Frontiers of Chemical Science and Engineering 2024年第7期18卷 1-10页

作者： baoyu wu Hao Sun Xiaoxue Li Yinyi Gao Tianzeng Bao Hongbin wu Kai Zhu Dianxue Cao Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education College of Materials Science and Chemical EngineeringHarbin Engineering UniversityHarbin 150001China Hunan Hongshan New Energy Technology Co. LtdYiyang 413000China

Sodium-ion batteries(SIBs)have garnered significant interest in energy storage due to their similar working mechanism to lithium ion batteries and abundant reserves of sodium *** facile synthesis of a carbon-based anode materials with capable electrochemical performance is key to promoting the practical application of *** this work,a combination of petroleum pitch and recyclable sodium chloride is selected as the carbon source and template to obtain hard carbon(HC)anode for *** times and temperatures are optimized by assessing the sodium ion storage behavior of different HC *** optimized HC exhibits a remarkable capacity of over 430 mAh·g^(-1) after undergoing full activation through 500 cycles at a density of current of 0.1 A·g^(-1).Furthermore,it demonstrates an initial discharge capacity of 276 mAh·g^(-1) at a density of current of 0.5 A·g^(-1).Meanwhile,the optimized HC shows a good capacity retention(170 mAh·g^(-1) after 750 cycles)and a remarkable rate ability(166 mAh·g^(-1) at 2 A·g^(-1)).The enhanced capacity is attributed to the suitable degree of graphitization and surface area,which improve the sodium ion transport and storage.

关键词： petroleum pitch hard carbon sodium-ion batteries high rate recyclable template

Synergy of heterogeneous Co/Ni dual atoms enabling selective C-O bond scission of lignin coupling with in-situ N-functionalization

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Journal of Energy Chemistry 2024年第5期92卷 16-25页

作者： baoyu Wang Jinshu Huang Hongguo wu Ximing Yan Yuhe Liao Hu Li National Key Laboratory of Green Pesticide Key Laboratory of Green Pesticide&Agricultural BioengineeringMinistry of EducationState-Local Joint Laboratory for Comprehensive Utilization of BiomassCollege of Pharmacy&Center for R&D of Fine ChemicalsGuizhou UniversityGuiyang 550025GuizhouChina Guangxi Key Laboratory of Green Chemical Materials and Safety Technology Beibu Gulf UniversityQinzhou 535011GuangxiChina Guangzhou Institute of Energy Conversion Chinese Academy of SciencesGuangzhou 510640GuangdongChina

Selective cleavage of Csp^(2)-OCH_(3)bond in lignin without breaking other types of C-O bonds followed by N-functionalization is fascinating for on-purpose valorization of ***,a Co/Ni-based dual-atom catalyst CoNiDA@NC prepared by in-situ evaporation and acid-etching of metal species from tailor-made metal–organic frameworks was efficient for reductive upgrading of various lignin-derived phenols to cyclohexanols(88.5%–99.9%yields),which had ca.4 times higher reaction rate than the single-atom catalyst and was superior to state-of-the-art heterogeneous *** synergistic catalysis of Co/Ni dual atoms facilitated both hydrogen dissociation and hydrogenolysis steps,and could optimize adsorption configuration of lignin-derived methoxylated phenols to further favor the Csp^(2)-OCH_(3)cleavage,as elaborated by theoretical ***,the CoNi_(DA)@NC catalyst was highly recyclable,and exhibited excellent demethoxylation performance(77.1%yield)in real lignin monomer *** in-situ cascade conversion processes assisted by dual-atom catalysis,various high-value N-containing chemicals,including caprolactams and cyclohexylamines,could be produced from lignin.

关键词： Biomass conversion Heterogeneous catalysis Lignin Dual-atom catalyst Selective C-ocleavage

Low-cost dopant-free fluoranthene-based branched hole transporting materials for efficient and stable n-i-p perovskite solar cells

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Chinese Chemical Letters 2024年第10期35卷 187-193页

作者： Xinyu Yu Fei wu Xianglang Sun Linna Zhu baoyu Xia Zhong'an Li Key Laboratory for Material Chemistry of Energy Conversion and Storage Ministry of EducationHubei Key Laboratory of Material Chemistry and Service FailureSchool of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan 430074China Chongqing Key Laboratory for Advanced Materials and Technologies of Clean Energy Faculty of Materials&EnergySouthwest UniversityChongqing 400715China

It has been widely recognized that hole transporting materials(HTMs)play a key role in the rapid progress of perovskite solar cells(PVSCs).However,common organic HTMs such as spiro-OMe TAD not only suffer from high synthetic costs,but also usually require the additional chemical doping process to improve their hole transport ability,which unfortunately induces the terrible stability ***,it is urgent to develop low-cost dopant-free HTMs for efficient and stable *** this work,we have successfully developed a new class of efficient dopant-free fluoranthene-based HTMs(TPF1–5)with quite low lab synthetic costs by combining donor-acceptor and branched structure *** detailed structure-property study revealed that tuning the twisted arms at different substitution sites would regulate the intermolecular interactions and film-forming ability,thereby significantly affecting the performance of the *** applying these HTMs in conventional PVSCs,the dopant-free TPF1-based devices not only achieved the best efficiency of 21.76%,which is comparable to that of the doped spiro-OMeTAD control devices,but also showed much better operational stability,which maintained over 87%of the initial efficiency under maximum power point tracking after 1038 h.

关键词： Perovskite solar cells Holetransporting materials Dopant-free Fluoranthene Low-cost

Simulation Analysis of Deformation Control for Magnetic Soft Medical Robots

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IEEE/CAA Journal of Automatica Sinica 2024年第3期11卷 794-796页

作者： Jingxi Wang baoyu Liu Edmond Q.wu Jin Ma Ping Li Key Laboratory of Biomechanics and Mechanobiology(Beihang University) Ministry of Education Beijing Advanced Innovation Center for Biomedical Engineeringthe School of Biological Science and Medical EngineeringBeihang UniversityBeijing100083China IEEE the Department of Automation Shanghai Jiao Tong UniversityShanghai 200240China the Department of Aerospace Medicine Air Force Medical UniversityXi’an 710032China

Dear Editor,This letter presents a biocompatible cross-shaped magnetic soft robot and investigates its deformation mode control strategy through COMSOL modeling and *** soft robots offer novel avenues for precise trea... 详细信息

关键词： robot simulation COMSOL

Flexible interdigitated layered framework with multiple accessible active sites for high-performance CH_(3)I capture

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Science China Chemistry 2024年第5期67卷 1569-1577页

作者： Bo Tai baoyu Li Linwei He Zhonglin Ma Shujing Lin Mingxing Zhang Junchang Chen Fuqi wu Long Chen Xing Dai Fuyin Ma Zhifang Chai Shuao Wang State Key Laboratory of Radiation Medicine and Protection School for Radiological and interdisciplinary Sciences(RAD-X)and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education InstitutionsSoochow UniversitySuzhou 215123China

The development of adsorbent materials for effective capture of radioactive iodomethane(CH_(3)I) from the off-gas of used nuclear fuel reprocessing, remains a significant and challenging line of research because currently state-of-art adsorbents still suffer from low binding affinity with CH_(3)I. Here, we proposed a brand-new adsorption topological structure by developing a 2D interdigitated layered framework, named SCU-20, featuring slide-like channel with multiple active sites for CH_(3)I capture. The responsive rotating-adaptive aperture of SCU-20 enables the optimal utilization of all active sites within the pore for highly selective recognition and capture of CH_(3)I. A record-breaking CH_(3)I uptake capacity of 1.84 g/g was achieved under static sorption conditions with saturated CH_(3)I vapor. Both experimental and theoretical findings demonstrated that the exceptional uptake of SCU-20 towards CH_(3)I can be attributed to the confined physical electrostatic adsorption of F sites, coupled with the chemical nitrogen methylation reaction with uncoordinated N atoms of pyrazine. Moreover, dynamic CH_(3)I uptake capacity potentially allows for the capture of CH_(3)I in simulated real-world off gas reprocessing conditions. This study highlights the potential of SCU-20 as a promising candidate for efficient capture of iodine species and contributes to the development of effective solutions for radioactive iodine remediation.

关键词： 2D interdigitated layered framework iodomethane dual-sites electrostatic interaction physisorption and chemisorption

川东地区高陡复杂构造LWD跟踪有效储层的方法

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天然气工业 2014年第2期34卷 81-86页

作者：吉人吴胜姜艳玲张树东胡振平吴宝玉中国石油川庆钻探工程公司测井公司

随钻地质导向技术(LWD)是20世纪90年代发展起来的前沿技术,在高陡复杂构造上钻水平井,及时准确了解地层产状、识别储层特性,引导水平井的井眼轨迹沿着有效储层钻进是LWD数据解释的关键内容。为此,以四川盆地川东地区钻探石炭系的高陡构... 详细信息

随钻地质导向技术(LWD)是20世纪90年代发展起来的前沿技术,在高陡复杂构造上钻水平井,及时准确了解地层产状、识别储层特性,引导水平井的井眼轨迹沿着有效储层钻进是LWD数据解释的关键内容。为此,以四川盆地川东地区钻探石炭系的高陡构造为例,在对区域地质特征、构造背景和储层特征及分布规律的深入细致分析基础上,应用地震、录井、测井资料建立起了钻探目的层段的岩—电模型、钻前三维地质导向的井眼轨迹模型。实钻中,把钻前建立的目的层岩—电模型与随钻实时测量的自然伽马、电阻率信息进行对比,及时分析钻头所钻岩性在岩—电模型中的位置,判断井眼轨迹与地层相切关系,进而用电阻率信息分析储层特性来指导钻进井眼轨迹实时调整,确保水平井段有效储层的钻遇率。该导向模型的建立与数据解释的方法可供类似探区参考。

关键词：四川盆地川东地区高陡构造地质导向地质建模钻头位置地层倾角钻进方案

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BCTMP在高档涂布印刷纸中的应用前景

湖南造纸 2006年第3期 15-16页

作者：乌宝玉大宇制纸股份有限公司牡丹江157013

阐述了BCTMP在国内外的应用情况,列出了用在高档涂布纸中几种常用的BCTMP类型,并结合研究实践提出了应用中应注意的一些事项。

关键词： BCTMP 高档涂布印刷纸应用

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无线可充电传感器网络能耗分级充电策略

传感技术学报 2019年第8期32卷 1253-1260页

作者：吴宝瑜万鹏王高峰程瑜华杭州电子科技大学电子信息学院

在传统的无线传感器网络中,有限的电池能量会限制传感器网络的寿命。而在无线可充电传感器网络中,能量可以通过无线方式给传感器充电,延长传感器网络的寿命。利用充电小车等移动设备对无线传感器网络进行能量补充时,在一个充电周期内减... 详细信息

在传统的无线传感器网络中,有限的电池能量会限制传感器网络的寿命。而在无线可充电传感器网络中,能量可以通过无线方式给传感器充电,延长传感器网络的寿命。利用充电小车等移动设备对无线传感器网络进行能量补充时,在一个充电周期内减小充电小车的移动总路径,可以有效减少经济成本。基于无线可充电传感网中各节点的能耗差异性,结合蚁群算法和对旅行商(TSP)问题的研究,提出了基于能耗分级的非固定周期和固定周期两种小车充电策略。仿真结果表明,与传统的充电策略相比,两种新策略均能有效减少充电小车的移动总路径。

关键词：无线可充电传感网充电小车能耗分级蚁群算法

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婴儿Sweet综合征1例

中华皮肤科杂志 2022年第2期55卷 164-165页

作者：尹瑞瑞王博鹤吴宝玉徐州医科大学附属徐州市儿童医院皮肤科徐州221006

患儿女,7月龄,因头面部反复出现红色斑块1月余,伴间断发热1周于2019年3月21日就诊。患儿1个月前右面部无明显诱因出现环状红斑,高于皮面。曾于当地医院先后以湿疹、面癣等治疗(具体用药不详),未见好转。后左面部出现同样皮损,渐扩大。1... 详细信息

患儿女,7月龄,因头面部反复出现红色斑块1月余,伴间断发热1周于2019年3月21日就诊。患儿1个月前右面部无明显诱因出现环状红斑,高于皮面。曾于当地医院先后以湿疹、面癣等治疗(具体用药不详),未见好转。后左面部出现同样皮损,渐扩大。1周前出现间断性发热,最高38℃,且发现右上臂疫苗注射处出现同样皮损。近日病情逐渐加重,头部、前额、臀部、下肢出现同样皮损,面部皮损伴有糜烂、渗液,偶有发热。患儿早产4周,出生时无缺氧。父母体健,否认家族传染病及遗传病史,否认外伤史及饲养宠物史。

关键词：遗传病史红色斑块左面部具体用药间断性发热环状红斑周前面部皮损

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超临界CO2萃取法处理含油钻屑实验研究

钻采工艺 2019年第4期42卷 13-15,39页

作者：吴保玉李志航金祥哲中石油川庆钻探工程有限公司钻采工程技术研究院低渗透油气田勘探开发国家工程实验室

为探求提高超临界CO2萃取含油钻屑效率的最优方案,文章重点研究了萃取温度、萃取压力、萃取时间、挟带剂等关键参数对萃取效率的影响。根据CO2相态变化,设定超临界CO2萃取装置的温度、压力梯度变化,同时引入3种挟带剂,开展不同萃取参数... 详细信息

为探求提高超临界CO2萃取含油钻屑效率的最优方案,文章重点研究了萃取温度、萃取压力、萃取时间、挟带剂等关键参数对萃取效率的影响。根据CO2相态变化,设定超临界CO2萃取装置的温度、压力梯度变化,同时引入3种挟带剂,开展不同萃取参数的正交实验,采用红外分光光度法检测萃取后钻屑含油量。实验结果表明,稳压10MPa、恒温45℃,同时加入2%的非极性挟带剂石油醚,连续萃取2h后,钻屑含油量可降低至0.2%以下,且回收后的基础油相与白油成分接近,重复配置的油包水钻井液体系经150℃热滚16h后,检测流变、滤失等性能均未受影响。

关键词：超临界CO2 萃取含油钻屑挟带剂