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Defence Technology（防务技术） 2022年第10期18卷 1748-1759页

作者： Chun-yan Li Sheng Kong Dong-jie Liao Chong-wei An bao-yun ye Jing-yu Wang School of Environment and Safety Engineering North University of ChinaTaiyuan030051ShanxiChina Shanxi Engineering Technology Research Center for Ultrafine Powder North University of ChinaTaiyuan030051ShanxiChina Taiyuan Institute of Technology Taiyuan030008ShanxiChina

Three-dimensional(3D)micro-jet printing is a droplet deposition technique based on liquid-phase *** improve the deposition density and performance of energetic films with micro/nanoscale on an energetic chip,polydopamine(PDA)was utilized as a linker bridge to induce the in-situ self-assembly of CL-20-based energetic film via 3D micro-jet *** self-assembly was extensively characterized by confocal laser scanning microscopy(CLSM),SEM,power-XRD,XPS,and *** performance of the self-assembled film was verified by the mechanical properties and detonation properties,and a possible self-assembly mechanism in the layer-by-layer micro-jet printing process was *** results indicated PDA-induced self-assembly enhanced the physical entanglement between the binders and energetic crystal,reduced the porosity from 15.87%to 11.28%,and improved the elastic modulus and the detonation performance of the CL-20-based energetic *** work proposes a novel and promising energetic film design and fabrication strategy to enhance the interaction between the energetic composite layers in the micro-jet printing process.

关键词： CL-20-Based energetic film Micro-jet printing Polydopamine Self-assembly

3D direct writing and micro detonation of CL-20 based explosive ink containing O/W emulsion binder

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Defence Technology（防务技术） 2022年第8期18卷 1340-1348页

作者： Zhan-xiong Xie Chong-wei An bao-yun ye Jia-qing Mu Chun-yan Li Min-jie Li Song-jin Liu School of Environment and Safety Engineering North University of ChinaTaiyuanShanxi030051China Shanxi Engineering Technology Research Center for Ultrafine Powder North University of China030051TaiyuanChina No.55 Research Institute of China North Industries Group CorporationChangchun130012China

The booming development of DIW technology present an unprecedented prospect in energetic materials field and has attracted great interest due to its relative simplicity and high flexibility of ***,a novel CL-20 based explosive ink formulation have been developed successfully for MEMS initiation systems via DIW *** designed PVA/GAP into an oil-in-water(O/W)emulsion,in the way that the aqueous solution of PVA as water phase,the ethyl acetate solution of GAP as oil phase,the combination of Tween 80 and SDS as emulsifier,BPS as a curing agent of *** ideal formulation with good shear-thinning rheology properties and clear gel point was prepared using only 10 wt%*** dual-cured network formed during the curing process made the printed sample have good mechanical *** printed samples had satisfactory molding effect without cracks or fractures,the crystal form of CL-20 not changed and the thermal stability have *** of explosive inks via DIW in micro-scale grooves had excellent detonation performances,which critical detonation size was 1×0.045 mm,detonation velocity was 7129 m/s and when the corner reaching 150°can still detonated *** study may open new avenues for developing binder systems in explosive ink formulations.

关键词： Direct writing Explosive ink Emulsion binder system CL-20 based energetic composites Micron detonation

Performances and direct writing of CL-20 based ultraviolet curing explosive ink

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Defence Technology（防务技术） 2022年第1期18卷 140-147页

作者： Sheng Kong Dong-jie Liao Yu-meng Jia Chong-wei An Chun-yan Li bao-yun ye Bi-dong Wu Jing-yu Wang Hao Guo Zhi-wei Hong School of Environment and Safery Engineering North University of China Taivuan Shanxi 030051PR China Shanxi Engineering Technology Research Centre for Ultrafine Powder North University of China Taiyuan Shanxi030051PR China Huayin Norinco Group Test and Measuring Acudemy Co Id714200 ShanxiChina Zhongkexin Engineering Consulting Co Ltd100000 Beijing China

A new type of explosive ink formulation that can be quickly cured was prepared with unsaturated polyester as binder,styrene as active monomer,2,4,6-trimethylbenzoyl-diphenylphosphine oxide as photoinitiator,and hexanitrohexaazaisowurtzitane(CL-20)as the main *** the explosive inkdirect writing technology was used to charge the micro-sized energetic devices,the curing mechanism of the explosive ink was discussed,and the microstructure,safety performance and explosive transfer performance of the explosive ink molded samples were tested and *** indicate that the composite material has a fast curing molding speed,its hardness can reach 2H within 8 *** crystal form of CL-20 in the molded sample is still *** CL-20 based UV-curing explosive ink formulation has good compatibility,its apparent activation energy is increased by about 3.5 kj/*** composite presents a significant reduction in impact sensitivity and its characteristic drop height can reach 39.8 cm,whichis about 3 times higher than the raw *** the line width of charge is 1.0 mm,the critical thickness of the explosion can reach 0.015 mm,and the explosion velocity is 7129 m/s when the charge density is 1.612 g/cm^(3).

关键词： MEMS Tuze CL-20 UV-curing Explosive ink Detonation perfor mance

Digital measuring the ocular morphological parameters of guinea pig eye in vivo with Python

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International Journal of Ophthalmology(English edition) 2024年第2期17卷 239-246页

作者： Yue Di Zhong-bao Qiao Hai-yun ye Xin-Yue Li Wen-Ting Luo Wang-Yi Fang Tong Qiao Department of Ophthalmology Shanghai Children’s HospitalSchool of MedicineShanghai Jiao Tong UniversityShanghai 200062China

AIM:To quantitatively measure ocular morphological parameters of guinea pig with Python ***:Thirty-six eyeballs of eighteen 3-weekold guinea pigs were measured with keratometer and photographed to obtain the horizontal,coronal,and sagittal planes *** corresponding photo pixels-actual length ratio was acquired by a proportional *** edge coordinates were identified artificially by ginput *** and conic curve fitting were applied to fit the contour of the eyeball in the sagittal,coronal and horizontal *** curvature,curvature radius,eccentricity,tilt angle,corneal diameter,and binocular separation angle were calculated according to the geometric ***,the eyeballs were removed,canny edge detection was applied to identify the contour of eyeball in *** results were compared between in vivo and in ***:Regarding the corneal curvature and curvature radius on the horizontal and sagittal planes,no significant differences were observed among results in vivo,in vitro,and the *** horizontal and vertical binocular separation angles were 130.6°±6.39°and 129.8°±9.58°*** the corneal curvature radius and eccentricity in vivo,significant differences were observed between horizontal and vertical ***:The Graphical interface window of Python makes up the deficiency of edge detection,which requires too much definition in *** are significant differences between guinea pig and human beings,such as exotropic eye position,oblique oval eyeball,and obvious discrepancy of *** study helps evaluate objectively the ocular morphological parameters of small experimental animals in emmetropization research.

关键词： ocular morphological parameters guinea pig digital measurement Python

Direct ink writing of 3D-Honeycombed CL-20 structures with low critical size

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Defence Technology（防务技术） 2020年第3期16卷 588-595页

作者： bao-yun ye Chang-kun Song Hao Huang Qian-bing Li Chong-wei An Jing-yu Wang School of Environment and Safety Engineering North University of China030051 TaiyuanChina Shanxi Engineering Technology Research Center for Ultrafine Powder North University of China030051 TaiyuanChina China North Industries Group Corporation Limited 100821BeijingChina

3D-Honeycombed CL-20 structures with low critical size of detonation have been fabricated successfully for intelligent weapon systems using a micro-flow direct ink writing(DIW) *** CL-20-based explosive ink for DIW technology was prepared by a two-component adhesive system with waterborne polyurethane(WPU) and ethyl cellulose(EC).Not only the preparation of the explosive ink but also the principle of DIW process have been investigated *** explosive ink displayed stro ng shea rthinning behavior that permitted layer-by-laye r deposition from a fine nozzle onto a substrate to produce complex *** EC content was varied to alter the pore structure distribution and rheological behavior of ink samples after *** deposited explosive composite materials are of a honeycombed structure with high porosity,and the pore size distribution increases with the increase of EC *** phase change was observed during the preparation *** WPU and EC show good compatibility with CL-20 *** high activation energy was realized in the CL-20-based composite ink compared with that of the refined CL-20 due to the presence of non-energetic but stable *** detonation performance of the composite materials can be precisely controlled by an adjustment in the content of *** 3D honeyco mbed CL-20 structures,which are fabricated by DIW technology,have a very small critical detonation size of less than 69 μm,as demonstrated by wedge shaped charge *** ink can be used to create 3D structures with complex geometries not possible with traditional manufacturing techniques,which presents a bright future for the development of intelligent weapon systems.

关键词： Hexanitrohexaazaisowurtzitane(CL-20) Direct ink writing Micro-electro-mechanical system(MEMS) Pore structure Detonation performance

Degradation-adaptive neural network for jointly single image dehazing and desnowing

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Frontiers of Computer Science 2024年第2期18卷 247-249页

作者： Erkang CHEN Sixiang CHEN Tian ye yun LIU School of Ocean Information Engineering Jimei UniversityXiamen 361021 China College of Artificial Intelligence Southwest UniversityChongqing 400715 China

1 Introduction In harsh winter scenes,the captured images often suffer from hazeand snowdegradationssimultaneously,which significantly affect the performance of high-level computer vision ***,most existing dehazing methods[1-4]and desnowing methods[5-7]are specialized to address only one type of weather-related degradation,and they struggle to effectively handle multiple types of degradations.

关键词： neural handle computer

Deep decalcification of factory-provided freezing acidolysis solution to achieveα-high-strength gypsum

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Chinese Journal of Chemical Engineering 2024年第5期69卷 143-151页

作者： Wencai ye Yulu Li Yonggang Dong Lin Yang yun Yi Jianxin Cao School of Chemistry and Chemical Engineering Guizhou UniversityGuiyang 550025China Engineering Research Center of Efficient Utilization for Industrial Waste Guizhou UniversityGuiyang 550025China Key Laboratory of Guizhou Province for Green Chemical Industry and Clean Energy Technology Guizhou UniversityGuiyang 550025China

The freezing acidolysis solution of the nitric acid-phosphate fertilizer process has a high calcium content,which makes it difficult to produce fine phosphate and high water-soluble phosphate fertilizer ***,based on the potential crystallization principle of calcium sulfate in NH_(4)NO_(3)-H_(3)PO_(4)-H_(2)O,the deep decalcification(*** removal)technology to achieveα-high-strength gypsum originated from freezing acidolysis-solutions has been firstly proposed and ***,calcium can be removed from the factory-provided freezing acidolysis-solution by neutralizing it with ammonia,followed by the addition of ammonium sulfate *** a result,the formation of calcium sulfate in the reaction system undergoes the nucleation and growth of CaSO_(4)·2H_(2)O(DH),as well as its dissolution and crystallization into short columnarα-CaSO_(4)·0.5H_(2)O(α-HH).Remarkably,with the molar ratio of SO_(4)^(2-)/Ca^(2+)at 1.8,the degree of neutralization(NH_(3)/HNO_(3) molar ratio)at 1.7,the reaction temperature of 94℃,and the reaction time of 300 min,the decalcification rate can reach 86.89%,of which the high-strengthα-CaSO_(4)·0.5H_(2)O(α-HH)will be ***,the deep decalcification product meets the standards for the production of fine phosphates and highly water-soluble phosphate ***,the 2 h flexural strength ofα-HH is 5.3 MPa and the dry compressive strength is 36.8 MPa,which is up to the standard of commercialα-HH.

关键词： Nitrophosphate Ammonia neutralization Deep decalcification High-strengthα-hemihydrate gypsum Controlled crystallization at atmospheric pressure

Identifying the enhancement mechanism of Al/MoO_(3) reactive multilayered films on the ignition ability of semiconductor bridge using a one-dimensional gas-solid two-phase flow model

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Defence Technology（防务技术） 2024年第3期33卷 168-179页

作者： Jianbing Xu Yuxuan Zhou yun Shen Yueting Wang Yinghua ye Ruiqi Shen School of Chemistry and Chemical Engineering Nanjing University of Science and TechnologyNanjing 210094China Micro-Nano Energetic Devices Key Laboratory of MIIT Nanjing 210094China Institute of Space Propulsion Nanjing University of Science and TechnologyNanjing 210094China

Energetic Semiconductor bridge(ESCB)based on reactive multilayered films(RMFs)has a promising application in the miniature and intelligence of initiator and pyrotechnics *** the ignition enhancement mechanism of RMFs on semiconductor bridge(SCB)during the ignition process is crucial for the engineering and practical application of advanced initiator and pyrotechnics *** this study,a one-dimensional(1D)gas-solid two-phase flow ignition model was established to study the ignition process of ESCB to charge particles based on the reactivity of Al/MoO_(3) *** order to fully consider the coupled exothermic between the RMFs and the SCB plasma during the ignition process,the heat release of chemical reaction in RMFs was used as an internal heat source in this *** is found that the exothermal reaction in RMFs improved the ignition performance of *** the process of plasma rapid condensation with heat release,the product of RMFs enhanced the heat transfer process between the gas phase and the solid charge particle,which accelerated the expansion of hot plasma,and heated the solid charge particle as well as gas phase region with low *** addition,it made up for pressure loss in the gas *** the plasma dissipation process,the exothermal chemical reaction in RMFs acted as the main heating source to heat the charge particle,making the surface temperature of the charge particle,gas pressure,and gas temperature rise *** result may yield significant advantages in providing a universal ignition model for miniaturized ignition devices.

关键词： Ignition enhancement mechanism 1D gas-solid two-phase flow Al/MoO_(3)reactive multilayered films Semiconductor bridge Miniaturized ignition device

Atroposelective Synthesis of 2-Arylindoles via Chiral Phosphoric Acid-Catalyzed Direct Amination of Indoles

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Chinese Journal of Chemistry 2024年第7期42卷 731-735页

作者： Wen bao ye-Hui Chen Yu-Wei Liu Shao-Hua Xiang Bin Tan School of Pharmacy&StateKey Laboratory of Applied Organic Chemistry Lanzhou UniversityLanzhouGansu 730000China Shenzhen Grubbs Institute Department of ChemistrySouthern University of Science and TechnologyShenzhenGuangdong 518055China

Indole-based atropisomers are a very important class of axially chiral ***,the atroposelective synthesis of axially chiral 2-arylindole remains largely *** this study,we report the successful synthesis of atropisomeric 2-arylindoles using direct amination of indoles with p-quinonediimines in the presence of chiral phosphoric acid as a *** acts as an aminating reagent through formal polarity inversion of *** malonate group on the 2-aryl of 2-indoles was found to be essen-tial for high enantioselectivity of the *** could be due to the additional interaction between the ester group and the cata-lyst,as well as the intramolecular hydrogen *** findings provide a new strategy for the asymmetric construction of 2-arylindole atropisomers.

关键词： Chiral phosphoric acid Quinonediimines Direct amination Nucleophilic addition Asymmetric catalysis Enantioselectivity Axially chiral 2-arylindole Atroposelective synthesis

Dynamic shielding of bacterial outer membrane vesicles for safe and efficient chemo-immunotherapy against tumors

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Nano Research 2024年第2期17卷 836-847页

作者： Shuping Li Xin Li Jiaqi Meng Weier bao Shuang Wang Peng ye Xiao-Dong Gao Wei Wei Key Laboratory of Carbohydrate Chemistry and Biotechnology Ministry of Education School of BiotechnologyJiangnan UniversityWuxi 214122China State Key Laboratory of Biochemical Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Chemical Engineering University of Chinese Academy of SciencesBeijing 100049China

Bacterial outer membrane vesicles(OMVs)are potent immunostimulants of regulating the tumor microenvironment(TME)for immunotherapy,and can be used to deliver ***,the severe systemic inflammatory response triggered by OMVs upon intravenous(i.v.)injection has limited their ***,we developed a safe and effective strategy by conjugating doxorubicin-loaded serum albumin(SA-DOX,AD)onto the surface of OMVs using a matrix metalloproteinase(MMP)-cleavable peptide linker(cL).This approach enabled the dynamic shielding of OMVs to reduce the systemic side effects while simultaneously enhancing the anti-tumor effects through ***,the resulting OMV-cL-AD formulation exhibited significantly enhanced accumulation at the tumor site after ***,facilitated by the SA decoration on the OMVs ***,the shield on the OMV-cL-AD was cleaved by the over-expressed MMP in the TME,leading to the release of both OMVs and *** process provided OMV-induced immunotherapy and DOX-induced chemotherapy,resulting in synergistic tumor *** conclusion,our work demonstrated the potential of OMV-cL-AD as an effective immunochemotherapy strategy that can prolong the survival time of mice without inducing side effects.

关键词： outer membrane vesicles doxorubicin tumor microenvironment immunotherapy chemotherapy