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Role of iron ore in enhancing gasification of iron coke:Structural evolution,influence mechanism and kinetic analysis

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 58-69页

作者： Jie Wang Wei Wang Xuheng chen Junfang bao Qiuyue Hao Heng Zheng Runsheng Xu School of Chemistry and Materials Science Hubei Engineering UniversityXiaogan 432000China Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education Wuhan University of Science and TechnologyWuhan 430081China Institue of Ironmaking Technology Baosteel Central Research InstituteShanghai 201999China State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China

The utilization of iron coke provides a green pathway for low-carbon *** uncover the influence mechanism of iron ore on the behavior and kinetics of iron coke gasification,the effect of iron ore on the microstructure of iron coke was ***,a comparative study of the gasification reactions between iron coke and coke was conducted through non-isothermal thermogravimetric *** findings indicate that compared to coke,iron coke exhibits an augmentation in micropores and specific surface area,and the micropores further extend and *** provides more adsorption sites for CO_(2) molecules during the gasification process,resulting in a reduction in the initial gasification temperature of iron *** the heating rate in non-isothermal gasification can enhance the reactivity of iron *** metallic iron reduced from iron ore is embedded in the carbon matrix,reducing the orderliness of the carbon structure,which is primarily responsible for the heightened reactivity of the carbon *** kinetic study indicates that the random pore model can effectively represent the gasification process of iron coke due to its rich pore ***,as the proportion of iron ore increases,the activation energy for the carbon gasification gradually decreases,from 246.2 kJ/mol for coke to 192.5 kJ/mol for iron coke 15wt%.

关键词： low-carbon ironmaking iron coke gasification structural evolution kinetic model

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《高等数学B》课程建设的认识和实践

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上海第二工业大学学报 2005年第4期22卷 70-73页

作者：陈宝冲上海第二工业大学基础部

依据我校定位,结合国内高等职业院校数学课程改革情况,对我校文科专业的《高等数学B》课程建设与教学改革作了初步分析,论述了《高等数学B》教学改革的重要性,并相应进行了有益的实践探索,取得了一定的成效,提出了一些建设性建议。

关键词：课程设计教学改革建议 Mathematica软件

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Multiphase reaction spinning of high-temperature resistant weavable SiO_(2)-Kevlar hybrid aerogel fibers

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Nano Research 2025年第1期18卷 424-433页

作者： Yunna chen Wenlu Zhang Qingyang Li Wenbin Li chong He School of Textile Science and Engineering Wuhan Textile UniversityWuhan 430200China State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430200China

Advanced aerogel fibers possess numerousadvantages amalgamating the attributes of aerogels and fibermaterials, rendering them invaluable in the realm of thermalmanagement and regulation. However, the achievement ofrobust mechanical properties and increased temperaturestability is still a major challenge for the majority of aerogelfibers. Herein, SiO_(2)-Kevlar hybrid aerogel fibers with bioniccore-shell structure were prepared by reaction spinning andweaved into fabric. Kevlar nanowires dispersion is pumpedinto a bath comprising a self-synthesized silica sol, whichfacilitates the hybridization of biphasic aerogels through thegel reaction. Precise control over the diameter (200-800 μm)and structure of the wet gel fibers was achieved throughmeticulous adjustment of the spinning solution composition and spinning parameters. Subsequent freeze-drying processfacilitates the formation of a core-shell hybrid structure, in which the SiO_(2) aerogel layer effectively encapsulate the Kevlaraerogel core fiber. Taking full advantage of the mechanical properties of the Kevlar core fiber, the resulting SiO_(2)-Kevlaraerogel fibers exhibit commendable weaving characteristics (51.8 MPa). Furthermore, SiO_(2)-Kevlar aerogel fabrics exhibitenhanced thermal insulation characteristics with a thermal conductivity of 0.037 W/(m·K). As a result of the presence ofexternal SiO_(2) aerogel layer, the overall temperature resistance performance of the SiO_(2)-Kevlar fabric reach up to 700 ℃.

关键词： aerogel fibers SiO_(2)aerogel Kevlar aerogel reaction spinning thermal protective performance

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An all-round Al-Chemist with a scientific mind

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National Science Review 2022年第10期9卷 158-168页

作者： Qing Zhu Fei Zhang Yan Huang Hengyu Xiao Lu Yuan Zhao Xu Chun Zhang Tao Song Xin Sheng Tang Xiang Li Guo He bao chen chong Jun Yi Zhou Yi Han Zhang Baicheng Zhang Jia Qi Cao Man Luo Song Wang Gui Lin Ye Wan Jun Zhang Xin chen Shuang Cong Donglai Zhou Huirong Li Jialei Li Gang Zou Wei Wei Shang Jun Jiang Yi Luo Hefei National Research Center for Physical Sciences at the Microscale School of Chemistry and Materials Science University of Science and Technology of China School of Information Science and Technology University of Science and Technology of China Hefei Ji Shu Quantum Technology Co.Ltd Hefei National Laboratory University of Science and Technology of China

The realization of automated chemical experiments by robots unveiled the prelude to an artificial intelligence(AI) *** AI-based systems or robots with specific chemical skills have been demonstrated,but conducting all-round scientific research remains ***,we present an all-round AI-Chemist e quipped with scientific data intelligence that is capable of performing basic tasks generally re quired in chemical *** on a service platform,the AI-Chemist is able to automatically read the literatures from a cloud database and propose experimental plans *** can control a mobile robot in-house or online to automatically execute the complete experimental process on 14workstations,including synthesis,characterization and performance *** experimental data can be simultaneously analysed by the computational brain of the AI-Chemist through machine learning and Bayesian optimization,allowing a new hypothesis for the next iteration to be *** competence of the AI-Chemist has been scrutinized by three different chemical *** the future,the more advanced all-round AI-Chemists equipped with scientific data intelligence may cause changes to the landscape of the chemical laboratory.

关键词： AI-Chemist computational brain mobile robot machine reading all-round research

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A surface engineering strategy for the stabilization of zinc metal anodes with montmorillonite layers toward long-life rechargeable aqueous zinc ion batteries

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Journal of Energy Chemistry 2025年第1期100卷 94-105页

作者： Wenbo Wang Ruifeng Xu Xu Zhang Peiyu Wang bao Yang Bingjun Yang Juan Yang Kailimai Su Pengjun Ma Yanan Deng Xianfeng Fan Wanjun chen Key Laboratory for Electronic Materials College of Electrical Engineering Northwest Minzu University Resource Chemistry and Energy Materials Research Center State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences University of Chinese Academy of Sciences Institute for Materials and Processes School of Engineering University of Edinburgh

Rechargeable aqueous zinc-ion batteries （AZIBs） exhibit appreciable potential in the domain of electrochemical energy ***,there are serious challenges for AZIBs,for instance zinc dendrite growth,hydrogen evolution reaction （HER）,and corrosion side ***,we propose a surface engineering modification strategy for coating the montmorillonite （MMT） layer onto the surface of the Zn anode to tackle these issues,thereby achieving high cycling stability for rechargeable *** results reveal that the MMT layer on the surface of the Zn anode is able to provide ordered zincophilic channels for zinc ions migration,facilitating the reaction kinetics of zinc *** functional theory（DFT） calculations and water contact angle （CA） tests prove that MMT@Zn anode exhibits superior adsorption capacity for Zn2+and better hydrophobicity than the bare Zn anode,thereby achieving excellent cycling ***,the MMT@Zn||MMT@Zn symmetric cell holds the stable cycling over 5600 h at 0.5 mA cm-2and 0.125 m A h cm-2,even exceeding 1800 h long cycling under harsh conditions of 5 m A cm-2and 1.25 m A h *** MMT@Zn||V2O5full cell reaches over 3000 cycles at 2 A g-1with excellent rate ***,this surface engineering modification strategy for enhancing the electrochemical performance of AZIBs represents a promising application.

关键词： Surface engineering strategy Montmorillonite layer Protection mechanism of Zn anode Cycling stability Aqueous zinc ion batteries

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Synthesis and Mass Spectrometry Characterization of the Pd（Ⅱ）-Substituted Phosphotungstate K9H3Pd3(A-α-PW9O34)2·24H2O

Synthesis and Mass Spectrometry Characterization of the Pd（...

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中国化学会第六届全国结构化学学术会议

作者： Zheng-Guo Lin,Hai-Ying Ma,Bo Wang,~* bao-Kuan chen,chong Xu,Jie Cao,Chang-Wen Hu~* Key Laboratory of Cluster Science,Ministry of Education of China,School of Chemistry, Beijing Institute of Technology,Beijing 100081,P.R.China

＜正＞Polyoxometalates（POMs） are metal oxide cluster compounds have shown great potential in many fields with an enormous diversity of ***,the investigation of noble-metal-contained POMs derivatives become an area of great importance and have drawn much attention due to their applications in *** construction of palladium（Ⅱ） substituted heteropolytungstates is important but still is a

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Recent Advances in Fibrous Materials for Hydroelectricity Generation

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Nano-Micro Letters 2025年第2期17卷 109-133页

作者： Can Ge Duo Xu Xiao Feng Xing Yang Zheheng Song Yuhang Song Jingyu chen Yingcun Liu chong Gao Yong Du Zhe Sun Weilin Xu Jian Fang College of Textile and Clothing Engineering Soochow UniversitySuzhou 215123People’s Republic of China National Engineering Laboratory for Modern Silk Soochow UniversitySuzhou 215123People’s Republic of China State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430200People’s Republic of China Institute of Functional Nano&Soft Materials(FUNSOM) Soochow UniversitySuzhou 215123People’s Republic of China Department of Electrical and Computer Engineering University of MassachusettsAmherstMA 01003USA Department of Materials Imperial College LondonSouth Kensington CampusLondon SW72AZUK College of Textile Science and Engineering Zhejiang Sci-Tech UniversityHangzhou 310018People’s Republic of China School of Materials Science and Engineering Shanghai Institute of Technology100 Haiquan RoadShanghai 201418People’s Republic of China

Depleting fossil energy sources and conventional polluting power generation pose a threat to sustainable *** generation from ubiquitous and spontaneous phase transitions between liquid and gaseous water has been considered a promising strategy for mitigating the energy *** materials with unique flexibility,processability,multifunctionality,and practicability have been widely applied for fibrous materials-based hydroelectricity generation(FHG).In this review,the power generation mechanisms,design principles,and electricity enhancement factors of FHG are first ***,the fabrication strategies and characteristics of varied constructions including 1D fiber,1D yarn,2D fabric,2D membrane,3D fibrous framework,and 3D fibrous gel are ***,the advanced functions of FHG during water harvesting,proton dissociation,ion separation,and charge accumulation processes are analyzed in ***,the potential applications including power supply,energy storage,electrical sensor,and information expression are also ***,some existing challenges are considered and prospects for future development are sincerely proposed.

关键词： Hydroelectricity Fibrous material Streaming potential Ion diffusion

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Literature study on traditional Chinese medicine syndromes after renal transplantation

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World Journal of Transplantation 2025年第1期15卷 150-155页

作者： Yun-Peng Guo Ling-Xue bao Yu-Yang Wang Quan Wen Gai Hang Bo chen Tongliao Clinical Medical College Inner Mongolia Medical UniversityTongliao 028000Inner Mongolia Autonomous RegionChina Department of Urology Tongliao People's HospitalTongliao 028000Inner Mongolia Autonomous RegionChina

BACKGROUND Kidney transplantation is the most effective means to treat patients with renal failure,but its postoperative problems such as rejection reactions,immunosuppressant poisoning,chronic transplant kidney nephropathy,*** have not been effectively *** study searched for literature on traditional Chinese medicine(TCM)syndromes after kidney transplantation in China,conducted statistical analysis of the results,and sought to identify the underlying *** To understand the TCM syndromes after renal transplantation and associated rules and provide a theoretical basis for further clinical *** The literature pertaining to TCM syndromes in renal transplantation,published in the China National Knowledge Infrastructure,Wanfang database,and WIP database from 1970 to 2021,was meticulously searched and comprehensively and statistically *** Following the established inclusion and exclusion criteria,13 studies were selected for ***-renal transplantation,no significant discrepancy was noted among the groups based on the location of TCM ***,when categorized according to TCM pathogenic factors,the groups with spleen and kidney yang deficiency,as well as liver and kidney yin deficiency,exhibited a statistically significant difference in the *** Currently,the research on TCM syndromes pertaining to renal transplantation is in its nascent *** is imperative to conduct a multicentric,large-scale survey of TCM syndromes subsequent to renal transplantation in the ensuing years.

关键词： Kidney transplantation Syndrome Literature analysis Traditional Chinese medicine Systematic review

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Classical-Noise-Free Sensing Based on Quantum Correlation Measurement

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Chinese Physics Letters 2021年第1期38卷 3-9页

作者： Ping Wang chong chen Ren-bao Liu Department of Physics and The Hong Kong Institute of Quantum Information Science and Technology The Chinese University of Hong KongShatinNew TerritoriesHong KongChina

Quantum sensing,using quantum properties of sensors,can enhance resolution,precision,and sensitivity of imaging,spectroscopy,and *** intriguing question is:Can the quantum nature(quantumness)of sensors and targets be exploited to enable schemes that are not possible for classical probes or classical targets?Here we show that measurement of the quantum correlations of a quantum target indeed allows for sensing schemes that have no classical *** a concrete example,in the case that the second-order classical correlation of a quantum target could be totally concealed by non-stationary classical noise,the higher-order quantum correlations can single out a quantum target from the classical noise background,regardless of the spectrum,statistics,or intensity of the *** a classical-noise-free sensing scheme is *** finding suggests that the quantumness of sensors and targets is still to be explored to realize the full potential of quantum *** opportunities include sensitivity beyond classical approaches,non-classical correlations as a new approach to quantum many-body physics,loophole-free tests of the quantum foundation,et cetera.

关键词： quantum totally stationary

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Microstructure and Lattice Parameters of AIN Particle-Reinforced Magnesium Matrix Composites Fabricated by Powder Metallurgy

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Acta Metallurgica Sinica(English Letters) 2015年第11期28卷 1354-1363页

作者： Jie chen chong-Gao bao Yong Wang Jin-Ling Liu Challapalli Suryanarayana State Key Laboratory for Mechanical Behavior of Materials School of Materials Science and EngineeringXi'an Jiaotong University State Key Laboratory of Traction Power School of Mechanics and EngineeringSouthwest Jiaotong University Department of Mechanical and Aerospace Engineering University of Central Florida

Magnesium matrix composites reinforced with AlN particles were fabricated by the powder metallurgy technique. The evolution of lattice constants and solid solubility levels of Al in α-Mg and the microstructure of Mg-Al/AlN composites were investigated in the present study. The results showed that the solid solubility of Al in α-Mg reached a relatively high level by the P/M process with a long time of milling. X-ray diffraction showed that the peaks of Mg phase clearly shifted to higher angles. The lattice constants and cell volume decreased significantly compared with those of standard Mg due to a significant amount of Al incorporated into α-Mg in the form of substitutional solid solution. The degree of lattice deformation decreased at a low sintering temperature and increased at higher sintering temperatures due to the presence of AlN. Microstructural characterization of the composites revealed a necklace distribution of AlN particles in the Mg matrix. Heat treatment led to precipitation of Mg17Al12 from the supersaturated α-Mg solid solution. The pre- cipitate exhibited granular and lath-shaped morphologies in Mg matrix and ftocculent precipitation around AlN particles.

关键词： Metal matrix composite AIN particle Microstructure Lattice parameter Powder metallurgy Solid solubility

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