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Enhanced figure of merit for famatinite Cu_(3)SbSe_(4)via band structure tuning and hierarchical architecture

Journal of Materiomics 2023年第6期9卷 1263-1272页

作者： Lijun Zhao Haolin Ye Xinmeng Wu Jian Yang Lihua Yu Zhongqi Shi Shahid Hussain Guanjun Qiao Junhua Xu bangzhi ge Li Wang Chongjian Zhou School of Materials Science and Engineering Jiangsu University of Science and TechnologyZhenjiang212100JiangsuChina State Key Laboratory of Solidification Processing Key Laboratory of Radiation Detection Materials and DevicesMinistry of Industry and Information TechnologyNorthwestern Polytechnical UniversityXi'an710072ShaanxiChina School of Materials Science and Engineering Jiangsu UniversityZhenjiang212013JiangsuChina State Key Laboratory for Mechanical Behavior of Materials Xi'an Jiaotong UniversityXi'an710049ShaanxiChina

The p-type Te-free Cu_(3)SbSe_(4)with famatinite structure is a potential candidate for thermoelectric materials due to the low cost and eco-friendly constituent elements.However,its strong bipolar effect and high lattice thermal conductivity(klat)are the main challenges for its performance enhancement.Herein,we report a new strategy to enhance its figure of merit zT~0.86 at 673 K for Cu_(3)Sb_(0.95)Fe_(0.05)Se_(2.8)S_(1.2)via band structure tuning and hierarchical architecture.Firstly,S substituted Se atoms in lattice can widen the band gap to alleviate the bipolar effect.Secondly,Fe doping in Sb site significantly increases the density of states,thus increasing the carrier effective mass,and obtaining a remarkably high Seebeck coefficient of~560 mV/K at 300 K.Moreover,the induced hierarchical architecture defects resulting in a minimum klat of~0.48 W·m^(-1)·K^(-1)at 673 K.Consequently,the improved Seebeck coefficient combined with low thermal conductivity leads to an enhanced zT.

关键词： Cu3SbSe4-Based materials Defects Band gap Thermoelectric properties Solid solution

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Synthesis of nearly spherical AlN particles by an in-situ nitriding combustion route

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Journal of Advanced Ceramics 2021年第2期10卷 291-300页

作者： Zhilei Wei Kang Li bangzhi ge Chaowei Guo Hongyan Xia Yajie Guo Zhongqi Shi State Key Laboratory for Mechanical Behavior of Materials Xi’an Jiaotong UniversityXi’an710049China Engineering Research Center of Transportation Materials of Ministry of Education School of Materials Science and EngineeringChang’an UniversityXi’an710064China

Spherical AlN powders with micrometer size have attracted great attention owing to their good fluidity and dispersity. However, the industrial preparation methods usually require high temperature and long soaking time, which lead to the high cost and limit the wide application of the products. Herein, nearly spherical AlN particles with the average size of 2.5 μm were successfully synthesized via an in-situ combustion synthesis method. The effect of N_(2) pressure, NH_(4)Cl content, and Al particle size on the combustion reaction procedure, phase composition, and microstructure of the products was systematically investigated. The results showed that the decreased N_(2) pressure, increased NH_(4)Cl content, and Al particle size led to the decreasing of combustion temperature and speed, which further affected the morphology of the products. As a result, low N_(2) pressure(0.2 MPa), a small amount of NH4Cl(0.5 wt%), and fine Al particles(~2.5 μm) contributed to a moderate combustion temperature and facilitated the formation of nearly spherical AlN particles. In addition, based on the gas-releasing assisted quenching experiments and thermo-kinetic analysis, a two-step growth mechanism for the nearly spherical AlN particles was rationally proposed. The present method shows the advantages of low cost and high efficiency for preparing nearly spherical AlN particles, which can be used as raw materials for electronic substrates and fillers for packaging materials.

关键词： combustion synthesis AlN microstructure growth mechanism

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Preparation and anisotropic thermophysical properties of SiC honeycomb/Al-Mg-Si composite via spontaneous infiltration

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Progress in Natural Science:Materials International 2019年第2期29卷 177-183页

作者： Zhejian Zhang Zhongqi Shi Biguo Yang bangzhi ge Xiaoyu Zhang Yajie Guo State Key Laboratory for Mechanical Behavior of Materials Xi'an Jiaotong University Engineering Research Center of Transportation Materials of Ministry of Education School of Materials Science and Engineering Chang'an University

The SiC honeycomb/Al-Mg-Si composite with interpenetrated microstructure was prepared by spontaneous infiltration of Al-8 wt%Mg-7 wt%Si alloy into directional porous SiC honeycomb served as reinforcement. The microstructure and anisotropic thermophysical properties of this composite were also examined. The results showed that the initial microstructure of the SiC honeycomb can be retained and the as-prepared SiC honeycomb/Al-Mg-Si composite exhibited significantly anisotropic characteristics. Meanwhile, the alloying treatment on the Al matrix can avoid the generation of Al;C;and promote the wettability between Al and SiC.Particularly,the directional porous SiC honeycomb with such a low ceramic content（19 vol.%） made it possible for the composite to have a higher thermal conductivity(138.3 W/（m?K）) in the axial direction and a lower coefficient of thermal expansion(11.40 × 10;/K) in the radial direction.The influences of the SiC honeycomb reinforcement on the anisotropic thermophysical properties were also studied by the theoretical models in comparing with the experimental results.

关键词： SiC honeycomb Al-Mg-Si alloy Spontaneous infiltration Anisotropy Thermophysical properties

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