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Carbon dots-derived three-dimensional-ordered macroporous host with high penetrability and catalytic activity for LSBs under lean electrolyte

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Rare Metals 2024年第6期43卷 2560-2573页

作者： Jiao-Zi Duan Hua-Yu Pei Quan Yang Xue li Xin ba.Xue Yong Jun-ling guo Si-Yu Lu Green Catalysis Center College of ChemistryZhengzhou UniversityZhengzhou 450001China Country State Center for International Cooperation On Designer Low-Carbon&Environmental Materials School of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001China Hubei Institute of Quality Supervision Inspection Wuhan 430061China Department of Chemistry University of SheffieldSheffeld S37HFUK

The practical energy density of lithium-sulfur ba.teries(LSBs)is seriously limited by the high electrolyte-to-sulfur ratios(E/S).The E/S can be reduced by employing hosts with easy-to-infiltrate structure that ensures the uniform distribution of a lean electrolyte and high catalytic activity that can suppress"shuttle effect"via accelerating the slow conversion of soluble poly sulfides to insoluble *** the easy-to-infiltrate structures,the three-dimensional-ordered macroporous(3DOM)structure is easier to scale preparation and more suitable for the existing industrial ***,it is difficult to obtain the 3DOM with(1)high penetrability due to the high viscosity of frequently-used organic polymer precursors and(2)high catalytic activity due to the low confinement effect,meaning that uniformly dispersed small-sized catalytic materials are difficult to load on ***,using carbon dots(CDs)with both organic and inorganic properties as a precursor and aggregation limiting agent,a 3DOM host with high penetrability and homodispersed Ni particles of small sizes(Ni-CDs-3DOM)was *** this host:(1)CDs precursor with suitable viscosity can improve the penetrability.(2)CDs can effectively inhibit the agglomeration of Ni particles.(3)Uniformly dispersed small-size Ni particles offer high-efficiency catalytic activity toward sulfur ***,the Ni-CDs-3DOM/sulfur cathode exhibits high sulfur utilization and stable cycling performance even under high sulfur loading(5.5 mg·cm^(-2))and low E/S(6.5μl·mg^(-1)).This work indicates the usefulness of CDs in constructing hosts for LSBs with high energy density.

关键词： lithium-sulfur ba.teries Carbon dots Catalytic action Easy-to-infiltrate structure Lean electrolyte

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Integrated interface between composite electrolyte and cathode with low resistance enables ultra-long cycle-lifetime in solid-state lithium-metal ba.teries

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Science China Chemistry 2021年第4期64卷 673-680页

作者： Zhuo li Xin guo State Key Laboratory of Material Processing and Die&Mould Technology Laboratory of Solid State IonicsSchool of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China

We report a three-dimensional(3D)nanofiber-reinforced solid composite electrolyte with a 3D li^(+)-conducting ceramic network of li_(6.2)5Ga_(0.25)La_(3)Zr_(2)O_(12)(LLZO)*** from the 3D structure,the composite shows a high ionic conductivity of 3.2×10^(-4)S cm^(-1)and li-ion transference number of 0.32 at room *** interfacial resistance between the composite solid electrolyte and cathode is mitigated by creating an integrated interfacial structure,in which the polyethylene oxide(PEO)-lithiumbis(trifluoromethylsulphonyl)imide(liTFSI)binder and ionic liquids(ILs)form a viscoelastic ***,intimate contact,low interfacial impedance,and fast ion-transport between the cathode and the solid electrolyte are simultaneously ***-state lithium metal ba.teries with the li Fe PO_(4) cathode deliver a superior capacity(158.0 m A h g^(-1))and significant capacity retention(90.4%retention after 800 cycles)at 60℃.Moreover,the smooth and uniform li surface after long-term cycling confirms the successful suppression of the dendrite *** integrated interfacial structure provides a solution to the interfacial problem and improves the cycling performance in solid-state li-metal ba.teries.

关键词： composite solid electrolyte li_(7)La_(3)Zr_(2)O_(12)nanofiber interfacial resistance solid-state ba.tery

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Surface nanostructure formation mechanism of 45 steel induced by supersonic fine particles pomba.ding

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Journal of University of Science and Technology Beijing 2008年第5期15卷 561-567页

作者： Dema ba.Shining Ma Changqing li Fanjun Meng Department of Remanufacture Engineering Academy of Armored Force Engineering Beijing 100072 China

By means of supersonic fine particles bomba.ding （SFPB）,a nanostructured surface layer up to 15 μm was fabricated on a 45 steel plate with ferrite and pearlite phases. To reveal the grain refinement mechanism of SFPB-treated 45 steel,microstructure features of various sections in the treated surface were systematically characterized by X-ray diffraction （XRD）,scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. Grain size increases with an increase of depth from the treated surface. Plastic deformation and grain refinement processes are accompanied by an increase in strain. Plastic deformation in the proeutectoid ferrite phases has precedence over the pearlite phases. Grain refinement in the ferrite phases involves： the onset of dislocation lines （Dls）,dislocation tangles （DTs） and dense dislocation walls （DDWs） in the original grains; the formation of fine lamellar and roughly equiaxed cells separated by DDWs; by dislocation annihilation and rearrangement,the transformation of DDWS into subboundaries and boundaries and the formation of submicron grains or subgrains; the successive subdivision of grains to finer and finer scale,resulting in the formation of highly misoriented nano-grains. By contrast,eutectoid cementite phase accommodated strain in a sequence as follows： onset of elongated,bended and shear deformation under deformation stress of ferrites,short and thin cementites with a width of about 20-50 nm and discontinuous length were formed. Shorter and thinner cementites were developed into ultra-fine pieces under the action of high density dislocation and strains. At the top surface,some cementites were decomposed under severe plastic deformation. Experimental evidences and analysis indicate that surface nanocrystallization of 45 steel results from dislocation activities,high strains and high strain rate are necessary for the formation of nanocrystallites.

关键词： surface nanocrystallization grain refinement mechanism microstructure 45 steel

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基于改进Transformer模型的多元时间序列预测

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南阳师范学院学报 2025年第1期24卷 38-45页

作者：程艺锐李果南阳师范学院人工智能与软件工程学院河南南阳473061

在无线数据传输中,环境干扰和网络拥塞导致的数据丢包和缺失问题显著影响了时间序列预测的稳定性。为了解决这个问题,提出了一种名为TFKNet的时间序列预测模型。该模型基于Transformer的多维时间序列数据预测方法,在传统Transformer模... 详细信息

在无线数据传输中,环境干扰和网络拥塞导致的数据丢包和缺失问题显著影响了时间序列预测的稳定性。为了解决这个问题,提出了一种名为TFKNet的时间序列预测模型。该模型基于Transformer的多维时间序列数据预测方法,在传统Transformer模型的基础上,结合时间卷积网络(TCN)和傅立叶频率特征提取技术增强了模型对局部特征的捕捉能力和多频率特征的提取能力,引入Kernel Attention Networks(KAN)提高了模型的预测性能。实验结果表明,与Transformer、Informer、Reformer、Autoformer传统方法相比,TFKNet模型在时间序列长预测任务中预测误差MAE分别平均降低0.0522、0.1117、0.1209、0.1922。

关键词：数据预测 Transformer TCN KAN 傅立叶频率特征

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Rethinking the urba. resilience:Extension and connotation

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Journal of Safety Science and Resilience 2022年第4期3卷 398-403页

作者： Rui ba.Chenyang Wang Luyao Kou Xiaojing guo Hui Zhang School of National Security People’s Public Security University of ChinaBeijing100038China Institute of Public Safety Research Tsinghua UniversityBeijing100084China

In recent years,urba. resilience has attracted increasing attention from researchers and managers from the international community at the national,regional,and urba. *** multi-dimensional and cross-disciplinary investigations,campaigns,and outlines have significantly promoted the development goal of re-silience in cities ***,the existing definitions and interpretations of urba. resilience still call for a more comprehensive,systematic,and exhaustive analysis as urba.ization accelerates and the complex risks of various safety events *** this end,we rethink the extension and connotation of urba. resilience ba.ed on a review and analysis of critical hotspots,realistic demand,and development trends.A conceptual classification with three aspects and three typical tiers of urba. resilience is proposed,which further promotes a new definition and interpretation by incorporating the resilience extension of urba. *** addition,the six-dimensional characteristics are extracted to furnish the urba. resilience connotation,and four-stage improvement measures are introduced *** addition,the newly developed urba. resilience is applied to a case analysis of a large-scale disaster,which demonstrates the necessity and significance of this *** new extension and connotation investigation will be helpful for the improvement and implementation of urba. resilience,thereby guiding the construction of resilient cities.

关键词： Urba. resilience Infrastructure Social units Complex systems

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绿豆R2R3-MYB转录因子家族鉴定及其类黄酮合成调控基因的筛选

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作物学报 2025年第1期51卷 117-133页

作者：郭飞翔李春霞周爽郭彬彬张均马超河南科技大学农学院/河南省旱地农业工程技术研究中心河南洛阳471000

R2R3-MYB转录因子家族在植物次生代谢物合成、胁迫应答和生长发育等生命过程起着重要的调控作用。本研究基于生物信息学鉴定了绿豆(Vigna radiata L.)全基因组水平的R2R3-MYB转录因子,并对其理化性质、系统进化、染色体定位、启动子顺... 详细信息

R2R3-MYB转录因子家族在植物次生代谢物合成、胁迫应答和生长发育等生命过程起着重要的调控作用。本研究基于生物信息学鉴定了绿豆(Vigna radiata L.)全基因组水平的R2R3-MYB转录因子,并对其理化性质、系统进化、染色体定位、启动子顺式作用元件及基因结构做了预测分析;此外,转录组数据和实时荧光定量PCR(QuantitativeReal-timePCR,RT-PCR)分析该转录因子在不同组织、逆境胁迫下的表达模式;并基于相关分析及蛋白互作网络,筛选到可能参与调控绿豆类黄酮生物合成的R2R3-MYB成员。结果表明,共鉴定到168个R2R3-MYB成员,其中145个分布于11条染色体, 23个成员染色体信息未知;大多数R2R3-MYB含有3个外显子,编码99~1645个氨基酸,均为亲水性蛋白;系统进化将绿豆R2R3-MYB基因家族分为30个亚组(V1~V30),不同亚组成员的基因结构存在差异;共线性分析表明,片段复制事件均进行了纯化选择;启动子顺式作用元件分析表明,绿豆R2R3-MYB基因启动子区含有大量激素响应、胁迫响应及少量的类黄酮合成响应等元件;基因表达分析表明,在叶片、叶柄、下胚轴和籽粒种皮中表达量较高的成员分别占15.5%、16.1%、16.1%和10.7%。RT-PCR分析发现,几乎所有的R2R3-MYB家族成员在低温胁迫下的相对表达量显著下调,不同成员对逆境胁迫有不同的响应模式。蛋白互作与相关性分析可知,VrMYB6、VrMYB77、VrMYB93这3个基因可能参与了绿豆类黄酮生物合成的调控。

关键词：绿豆 R2R3-MYB转录因子转录因子家族分析类黄酮合成调控基因

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light People:*** Mazur speaks about ultrafast optics and education

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light(Science & Applications) 2024年第3期13卷 402-406页

作者： Chenzi guo Yang li Changchun Institute of Optics Fine Mechanics and PhysicsChinese Academy of SciencesChangchunChina State Key Laboratory of Precision Measurement Technology and Instrument Department of Precision InstrumentTsinghua UniversityBeijingChina

*** Mazur is a great influencer over and beyond the optics *** a physicist,he is a pioneer of ultrafast optics and was one of the inventors of colliding-pulse mode-locked *** an educator,he not only gave talks to thousands,but also revolutionized teaching with his globa.ly renowned methodology“Peer Instruction”.As a leader and entrepreneur,he co-founded several companies and was President of Optica(formerly the Optical Society)and currently is the Chair of the Optica ***,light:Science&Applications talked with *** Mazur about his opinions on research,education and *** full interview video can be found in the Supplementary File.

关键词： optics education companies

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A unified stochastic damage model for concrete ba.ed on multi-scale energy dissipation analysis

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Science China(Technological Sciences) 2024年第3期67卷 863-877页

作者： guo ChengGong li Jie College of Civil Engineering Tongji UniversityShanghai 200092China State Key Laboratory of Disaster Reduction in Civil Engineering Shanghai 200092China

This work proposes a unified damage model for concrete within the framework of stochastic damage mechanics. ba.ed on the micro-meso stochastic fracture model(MMSF), the nonlinear energy dissipation process of the microspring from nanoscale to microscale is investigated. In nanoscale, the rate process theory is adopted to describe the crack growth rate;therefore, the corresponding energy dissipation caused by a representative crack propagation can be obtained. The scale gap from nanoscale to microscale is bridged by a crack hierarchy model. Thus, the total energy dissipated by all cracks from the nanoscale to the microscale is gained. It is found that the fracture strain of the microspring can be derived from the above multi-scale energy dissipation analysis. When energy dissipation is regarded as some microdamage to the microspring, the constitutive law of the microspring is no longer linearly elastic, as previously assumed. By changing the expression of the damage evolution law from fracture strain to energy dissipation threshold, the new damage evolution model is derived. The proposed model can not only replicate the original static model but also extend to cases of rate dependence. By deriving the fracture strain under different strain rates, the rate sensitivity of concrete materials can be reflected. The model parameters can be conveniently obtained by identifying them with experimental data. Finally, several numerical examples are presented to verify the proposed model.

关键词： concrete damage model stochastic damage rate dependent energy dissipation

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Non-fragile guaranteed cost control of discrete-time fuzzy bilinear system

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Journal of Systems Engineering and Electronics 2010年第4期21卷 629-634页

作者： guo Zhang Junmin li School of Science Xidian University Xi'an 710071 P. R. China Department of Electronical Engineering and Automation Luoyang Institute of Science and Technology Luoyang 471023 P. R. China

This paper focuses on the problem of non-fragile guaranteed cost control for a class of T-S discrete-time fuzzy bilinear systems（DFBS）.ba.ed on the parallel distributed compensation（PDC） approach,the sufficient conditions are derived such that the closed-loop system is asymptotically stable and the cost function value is no more than a certain upper bound in the presence of the additive controller gain *** non-fragile guaranteed cost controller can be obtained by solving a set of bilinear matrix inequalities（BMIs）.The Van de Vusse model is utilized to demonstrate the validity and effectiveness of the proposed approach.

关键词： discrete-time fuzzy bilinear system(DFBS) nonfragile control guaranteed cost control bilinear matrix inequality(BMI).

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Genesis and microscopic characteristics of tight reservoirs in the Fengcheng Formation, at the southern margin of the Mahu Sag

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Energy Geoscience 2023年第3期4卷 127-138页

作者： Luning ba. Wenbiao Huang Jun Qin Zongbin Zhang Zhongchen ba.Zhenhua ba. Yibing guo Heng li School of Geosciences China University of Petroleum(East China)QingdaoShandong266580China Research Institute of Exploration and Development PetroChina Xinjiang Oilfield CompanyKaramayXinjiang834000China Research Institute of Exploration and Development PetroChina Daqing Oilfield CompanyDaqingHeilongjiang163712China

The tight reservoirs of the Fengcheng Formation at the southern margin of the Mahu Sag have strong heterogeneity due to the diversity in their pore types, sizes, and structures. The microscopic characteristics of tight reservoirs and the mechanisms that generate them are of significance in identifying the distribution of high-quality reservoirs and in improving the prediction accuracy of sweet spots in tight oil reservoirs. In this paper, high-pressure mercury intrusion (HPMI) and nuclear magnetic resonance (NMR) experiments were carried out on samples from the tight reservoirs in the study area. These experimental results were combined with cluster analysis, fractal theory, and microscopic observations to qualitatively and quantitatively evaluate pore types, sizes, and structures. A classification scheme was established that divides the reservoir into four types, ba.ed on the microstructure characteristics of samples, and the genetic mechanisms that aided the development of reservoir microstructure were analyzed. The results show that the lower limit for the tight reservoir in the Fengcheng Formation is Φ of 3.5% and K of 0.03 mD. The pore throat size and distribution span gradually decrease from Type I, through Type II and Type III reservoirs to non-reservoirs, and the pore type also evolves from dominantly intergranular pores to intercrystalline pores. The structural trend shows a decrease in the ba.l-stick pore-throat system and an increase in the branch-like pore-throat system. The dual effects of sedimentation and diagenesis shape the microscopic characteristics of pores and throats. The sorting, roundness, and particle size of the original sediments determine the original physical properties of the reservoir. The diagenetic environment of ‘two alkalinity stages and one acidity stage’ influenced the evolution of pore type and size. Although the cementation of authigenic minerals in the early alkaline environment adversely affected reservoir properties, it also

关键词： Tight reservoir Pore-thr 0at structure Reservoir classification Diagenesis Fengcheng Formation Mahu Sag

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