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Effect of Hydrodynamic Conditions on Corrosion Inhibition of Cu-Ni(90/10)Alloy in Seawater and Sulphide Containing Seawater Using 1,2,3-benzotriazole

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Journal of Materials Science & Technology 2014年第1期30卷 65-76页

作者： b.v.appa rao K.Chaitanya Kumar Department of Chemistry National Institute of Technology Warangal

Electrochemical studies of the effect of hydrodynamic conditions on corrosion inhibition of Cu-Ni （90/10） alloy in synthetic seawater and sulphide containing synthetic seawater by 1,2,3-benzotriazole （bTAH） are presented. Impedance, potentiodynamic polarization and cyclic voltammetric （Cv） studies are employed in the present investigation. The studies are carried out by using Cu-Ni （90/10） alloy rotating disc electrode at different rotation speeds and at different immersion periods. Reynolds numbers at each rotation speed infer that the flow of seawater is laminar. With increasing rotation speed of the electrode immersed in seawater without sulphide and bTAH, both the charge transfer resistance （Rot） and film resistance （Rf^lm） are increased. However, in the presence of sulphide ions and without bTAH, both the Rot and Rf,m are found to decrease with increasing rotation speed at identical immersion periods. Interestingly, when bTAH is added to seawater or seawater containing sulphide, both the Rot and Rf,m are increased to such a great extent that an inhibition efficiency of 99.99% is obtained. In the presence of bTAH, the phase angle bode plots are more broadened and the maximum values of phase angle are increased to a value close to 90~ as the rotation speed is increased. The bTAH film is highly protective even under hydrodynamic condition also. Potentiodynamic polarization studies infer that bTAH functions as a mixed inhibitor under hydrodynamic conditions also. Cv studies reveal that the protective bTAH film is stable even at anodic potentials of ＋850 mv vs Ag/AgCI.

关键词： Cu-Ni (90/10) alloy Rotating disc electrode Seawater Corrosion inhibition Electrochemical studies 1,2,3-benzotriazole

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Lactobionic Acid as a New Synergist in Combination with Phosphonate-Zn(Ⅱ)System for Corrosion Inhibition of Carbon Steel

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Journal of Materials Science & Technology 2014年第1期30卷 77-89页

作者： S.Srinivasa rao b.v.appa rao S.Roopas Kiran b.Sreedhar Department of Chemistry V.R.Siddhartha Engineering College(Autonomous) Department of Chemistry National Institute of Technology Warangal(NITW) INFN Sezione di Padova Inorganic & Physical Chemistry Division Indian Institute of Chemical Technology(IICT)

Studies on lactobionic acid introduced as a synergist in the presence of phosphonobutane-1,2,4-tricarboxylic acid （PbTC） and zinc ions for corrosion control of carbon steel in aqueous environment are presented. The investigations revealed that lactobionic acid （LbA） acts as an excellent synergist in corrosion inhibition. Optimum concentrations of all the three components of the ternary formulation are established by gravimetric studies. Potentiodynamic polarization studies indicate that the new ternary system is a mixed inhibitor. Impedance studies show that a protective film is formed on the metal surface in the presence of the inhibitor formulation. The film is found to exhibit its protective nature even at higher temperatures up to 60 ~C. Analysis of the protective film by X-ray photoelectron spectroscopy （XPS） and reflection absorption Fourier transform infrared （FTIR） spectroscopy infers the presence of Zn（OH）2, oxides and hydroxides of iron and the inhibitor molecules in the surface film probably in the form of a complex, [Zn（II）-PbTC-LbA]. The morphological studies by scanning electron microscopy （SEM） and the topographical studies by atomic force microscopy （AFM） also indicate the presence of protective film on the metal surface. A plausible mechanism of corrosion inhibition is proposed.

关键词： Corrosion inhibitor Carbon steel Synergism X-ray photoelectron spectroscopy Electrochemical impedance spectroscopy

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Difficult-to-culture bacteria in the rhizosphere:The underexplored signature microbial groups

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Pedosphere 2022年第1期32卷 75-89页

作者： Sadaf KALAM Anirban bASU appa rao PODILE Department of Plant Sciences School of Life SciencesUniversity of HyderabadHyderabad 500046(India)

Microorganisms represent a substantial portion of the earth’s biodiversity and biomass, and the plant rhizosphere is an innate reservoir teeming with heterogeneous microbes predominated by bacterial communities. Rhizospheric microbial diversity (genetic, phenotypic, and metabolic) has been extensively studied to understand the key ecological roles played by the microbial members, including plant growth promotion. The application of 16S rRNA gene sequencing and next-generation sequencing (NGS) technologies has revolutionized the discovery of novel bacterial groups that have remained undetected by traditional cultivation-based approaches. Such technological advancements have opened new vistas in our current understanding of predominant but concealed and missed bacterial diversity referred to as difficult-to-culture bacterial lineages, especially the predominant phyla Acidobacteria, verrucomicrobia,Planctomycetes, and Gemmatimonadetes. Regardless of their ubiquity and prevalence, little is known about their ecophysiology because of the non-availability of culturable members. More recently, there has been increased interest in understanding the cosmopolitan distribution and diversity of the difficult-to-culture bacteria, focusing on their role in driving complex plant-microbial interactions and mobilizing nutrients in soil and their potential as sources of novel bioactive metabolites. As an initial step, we review the distribution and significance of such bacterial phyla in soil, their ecophysiological roles, and their hidden plant growth promoting potential. The ability to select and deploy plant probiotic bacteria from the difficult-to-culture fraction of the bacterial community might open new avenues for improving crop health.

关键词： Acidobacteria ecophysiological roles Gemmatimonadetes microbial diversity Planctomycetes plant growth promotion verrucomicrobia

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Implications for the lithospheric structure of Cambay rift zone,western India:Inferences from a magnetotelluric study

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Geoscience Frontiers 2020年第5期11卷 1743-1754页

作者： Nagarjuna Danda C.K.rao Amit Kumar P.Rama rao P.b.v.Subba rao Dr.K.S.Krishnan Geomagnetic Research Laboratory IIGAllahabad221505India Indian Institute of Geomagnetism New PanvelNavi Mumbai410218India Department of Geophysics Andhra UniversityVisakhapatnam530003India

broad-band and long-period magnetotelluric(MT)data were acquired along an east-west trending traverse of nearly 200 km across the Kachchh,Cambay rift basins,and Aravalli-Delhi fold belt(ADFb),western *** regional strike analysis of MT data indicated an approximate N59°E geoelectric strike direction under the traverse and it is in fair agreement with the predominant geological strike in the study *** decomposed transverse electric(TE)-and transverse magnetic(TM)-data modes were inverted using a nonlinear conjugate gradient algorithm to image the electrical lithospheric structure across the Cambay rift basin and its surrounding *** studies show a thick(~1-5 km)layer of conductive Tertiary-Mesozoic sediments beneath the Kachchh and Cambay rift *** resistive blocks indicate presence of basic/ultrabasic volcanic intrusives,depleted mantle lithosphere,and different Precambrian structural *** crustal conductor delineated within the ADFb indicates the presence of fluids within the fault zones,sulfide mineralization within polyphase metamorphic rocks,and/or Aravalli-Delhi sediments/*** observed conductive anomalies beneath the Cambay rift basin indicate the presence of basaltic underplating,volatile(CO2,H2 O)enriched melts and channelization of melt fractions/fluids into crustal depths that occurred due to plume-lithosphere *** variations in electrical resistivity observed across the profile indicate that the impact of Reunion plume on lithospheric structures of the Cambay rift basin is more dominant at western continental margin of India(WCMI)and thus support the hypothesis proposed by Campbell&Griffiths about the plume-lithosphere interactions.

关键词： Cambay rift Deccan basalts Magnetotellurics Partial melt Reunion plume

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Representation of classifier distributions in terms of hypergeometric functions

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China Particuology 2007年第4期5卷 274-283页

作者： b.venkoba rao Engineering and Industrial Services Tata Consultancy Services Ltd.1 Mangaldas RoadPune 411001India

This paper derives alternative analytical expressions for classifier product distributions in terms of Gauss hypergeometric function, 2F1, by considering feed distribution defined in terms of Gates-Gaudin-Schumann function and efficiency curve defined in terms of a logistic function. It is shown that classifier distributions under dispersed conditions of classification pivot at a common size and the distributions are difference similar. The paper also addresses an inverse problem of classifier distributions wherein the feed distribution and efficiency curve are identified from the measured product distributions without needing to know the solid flow split of particles to any of the product streams.

关键词： Classifier Efficiency curve Inverse problem

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Superconducting magnetic energy storage for stabilizing grid integrated with wind power generation systems

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Journal of Modern Power Systems and Clean Energy 2019年第2期7卷 400-411页

作者： Poulomi MUKHERJEE v. v. rao Applied Superconductivity Laboratory Cryogenic Engineering Centre Indian Institute of TechnologyKharagpur

Due to the interconnection of various renewable energies and adaptive technologies, voltage quality and frequency stability of modern power systems are becoming erratic. Superconducting magnetic energy storage(SMES),for its dynamic characteristic, is very efficient for rapid exchange of electrical power with grid during small and large disturbances to address those *** addition,SMES plays an important role in integrating renewable sources such as wind generators to power grid by controlling output power of wind plant and improving the stability of power *** application of SMES in various power system operations depends on the proper location in the power system, exact energy and power ratings and appropriate controllers. In this paper, an effort is given to explain SMES device and its controllability to mitigate the stability of power grid integrated with wind power generation systems.

关键词： Power fluctuation Power quality Low voltage ride through Superconducting magnetic energy storage Superconductors Wind energy

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Crimean-Congo hemorrhagic fever:Pathogenesis,transmission and public health challenges

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World Journal of virology 2025年第1期14卷 63-72页

作者： Sita Kumari Karanam Kandra Nagvishnu Praveen Kumar Uppala Sandhya Edhi Srinivasa rao varri Department of Pharmaceutical biotechnology Maharajah’s College of PharmacyVizianagaram 535002Andhra PradeshIndia Department of Pharmacology Santhiram Medical College and General HospitalNandyal 518501Andhra PradeshIndia Department of Pharmacology Santhiram Medical College and General HospitalNandyal 518501Andhra PradeshIndia Department of Pharmaceutical AnalysisMaharajah's College of PharmacyVizianagaram 535002Andhra PradeshIndia

The dangerous Crimean-Congo hemorrhagic fever virus(CCHFv),an encapsulated negative-sense RNA virus of the family Nairoviridae,is transmitted from person to person via *** a case fatality rate between 10%to 40%,the most common ways that the disease may spread to humans are via tick bites or coming into touch with infected animals'blood or ***,the transfer of bodily fluids between individuals is another potential route of *** is a wide range of symptoms experienced by patients throughout each stage,from myalgia and fever to extreme bruising and excess *** management measures include minimising the spread of ticks from one species to another and from people to animals via the use of protective clothing,repellents,and proper animal *** order to prevent the spread of illness,healthcare workers must adhere to stringent *** the lack of an authorised vaccine,the main components of treatment now consist of preventative measures and supportive care,which may include the antiviral medicine *** still don't know very much about the virus's mechanisms,even though advances in molecular virology and animal models have improved our understanding of the pathogenesis of CCHFv.A critical need for vaccination that is both safe and effective,as well as for quick diagnosis and efficient treatments to lessen the disease's impact in areas where it is most *** steps towards lowering Crimean-Congo hemorrhagic fever mortality and morbidity rates were to anticipatethe future availability of immunoglobulin products.

关键词： Crimean-congo haemorrhagic fever Tick-borne illness Immunoglobulins viral hemorrhagic fever Antiviral therapy

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Microstructure, properties and hot workability of M300 grade maraging steel

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Defence Technology（防务技术） 2018年第1期14卷 51-58页

作者： K.v.A.Chakravarthi N.T.b.N.Koundinya S.v.S.Narayana Murty b.Nageswara rao Materials and Mechanical Entity Vikram Sarabhai Space Centre Research scholar Department of Mechanical Engineering K L University Department of Metallurgical Engineering and Materials Science Indian Institute of Technology Department of Mechanical Engineering K L University

This paper presents isothermal uniaxial compression test results of M300 grade maraging steel over a wide range of temperatures(900 e1200℃) and strain rates(0.001 e100 s^(-1)) to examine hot deformability and concurrent microstructural evolution. Processing map is generated and indicated the optimum processing parameters in the temperature range of 1125℃-1200℃ and strain rate range of 0.001 e0.1 s^(-1). High values of the efficiency of power dissipation, microstructural observations and EbSD results indicate softening mechanism to be the occurrence of dynamic recrystallisation. Material constants in a constitutive relation are evaluated from the flow stress data useful in computer modelling.

关键词： Activation energy Constitutive relation Hot deformation M300 grade maraging steel Processing map

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Genotype×year interaction of pod and seed mass and stability of Pongamia pinnata families in a semi-arid region

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Journal of Forestry Research 2020年第4期31卷 1333-1346页

作者： G.R.rao b.Sarkar b.M.K.Raju P.Sathi Reddy A.v.M.Subba rao Jessie Rebecca ICAR-Central Research Institute for Dryland Agriculture SantoshnagarHyderabadTelangana State 500059India Tropical Forest Research Institute(TFRI) Indian Council of Forestry Research&EducationMinistry of EnvironmentForest&Climate ChangeGovt.of IndiaJabalpur 482021India

Sixteen pongamia families were evaluated in a field experiment for eight consecutive years in dryland conditions to identify stable,high-yielding *** trial was conducted in a randomized complete block design with three *** family,consisting of nine trees per replication,was planted at a spacing of3 m x 3 *** stability was analyzed using(1)Eberhart and Russel’s regression coefficient(β_i)and deviation from regression(S_d^2),(2)Wrike’s ecovalence(W_i);(3)Shukla stability variance(σ_i^2);and(4)Piepho and Lotito’s stability index(L_i).Families were also analyzed for adaptability and stability using AMMI and GGE biplots graphical *** study revealed significant variances due to family and family x year interaction for pod and seed *** performed differently and ranked differently across *** performance of families was influenced by both genetic factor and environmental conditions in different *** families tested,TNMP20,Acc14,TNMP14 and Acc30 were high yielders for pods,and Acc14,Acc30,TNMP6,RAK19 and TNMP14 were high for seed *** to the Eberhart and Russell model,Acc30,TNMP14 and TNMP3 were stable across *** the graphical view of family x year interaction based on AMMI methods,TNMP3,TNMP4 and TNMP14 had greater stability with moderate seed yield,and Acc14 and Acc30 had moderate stability with high seed *** the other hand,GGE biplots revealed Acc14,Acc30 and TNMP14 as high yielders with moderate *** and GGE biplots were able to capture nonlinear parts of the family x year interaction that were not be captured by the Eberhart and Russel model while also identifying stable *** on different methodologies,Acc14,Acc30 and TNMP14 were identified as high yielding and stable families for promoting pongamia cultivation as a biofuel crop for semi-arid regions.

关键词： biofuel Pongamia Genetic diversity Stability AMMI (additive main effects multiplicative interaction) GGE biplots Multi-year trial SvD(singular value decomposition)

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An ecofriendly approach for corrosion control of 6061 Al-15%(v)SiC(P)composite and its base alloy

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Chinese Journal of Chemical Engineering 2017年第3期25卷 363-372页

作者： Charitha b.P. Padmalatha rao Department of chemistry Manipal Institute of TechnologyManipalUdupiKamatakaIndia

Corrosion inhibition characteristics of bio polymer dextran was studied for the corrosion control of 6061 Al-15%_((v)) SiC_((P)) composite and its base alloy in 1 mol·L^(-1) HCl. Standard electrochemical techniques such as potentiodynamic polarization(PDP) measurements and electrochemical impedance spectroscopy(EIS) method were adopted for corrosion rate measurement. Surface morphology was studied by scanning electron microscopy(SEM) and elemental mapping was done by energy dispersive X-ray(EDX) analysis. Suitable mechanism was proposed for corrosion and inhibition process. Results indicated that dextran acts as an excellent anticorrosive agent for the corrosion control of 6061 Al-15%_((v)) SiC_((P)) composite, with maximum inhibition efficiency of 91% for the concentration of 0.4 g·L^(-1) at 303 K. Dextran acted as a mixed type of inhibitor, and got physically adsorbed both on composite and base alloy by obeying Langmuir adsorption isotherm. Dextran is proved to be a green inhibitor with environmental and economic benefits.

关键词： 6061 Al-15%(v) SiC(p) composite Green inhibitor biopolymer Electrochemical studies SEM–EDX

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