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Polyoxometalates coupled covalent organic frameworks as highly active photothermal nanoreactor for CO_(2)cycloaddition

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Nano Research 2024年第7期17卷 5975-5984页

作者： Tian wang Yunqing Zhu Wei wang Junfeng Niu Zhiyi Lu Peilei He school of Environmental science and Engineering Shaanxi University of Science and TechnologyXi’an 710021China Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology of Zhejiang Province Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China College of Environmental science and Engineering North China Electric Power UniversityBeijing 102206China University of Chinese Academy of sciences Beijing 100049China

Covalent organic frameworks(COFs)-based nanoreactors have attracted broad interest in many fields due to their voidconfinement ***,the inherent drawback of conventional nanoreactors is the lack of internal active sites,which limits their widespread ***,we report the construction of hierarchical COF(Eb-TFP)nanoreactor with pre-synthesized polyoxometalates(POM,[PV_(2)W_(10)O_(40)]^(5–)(PV_(2)W_(10)))clusters encapsulated inside of COF(POM@COF).PV_(2)W_(10)@Eb-TFP anchors nucleophilic-group(br–ions)and PV_(2)W_(10)anion cluster within the COF framework via electrostatic interactions,which not only simplifies the reaction system but also enhances catalytic *** reaction performance of the PV_(2)W_(10)@Eb-TFP nanoreactor can be tuned to achieve excellent catalytic activity in CO_(2)cycloaddition reaction(CCR)for~97.63%conversion and~100%selectivity under visible light irradiation.A mechanistic study based on density functional theory(DFT)calculations and insitu characterization was also carried *** summary,we have reported a method for achieving the uniform dispersion of POM single clusters into COF nanoreactor,demonstrating the potential of POM@COF nanoreactor for synergistic photothermal catalytic CO_(2)cycloaddition.

关键词： photothermal nanoreactor CO_(2)cycloaddition polyoxometalate photothermal-synergistic catalysis covalent organic frameworks

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A concise review on surface and structural modification of porous zeolite scaffold for enhanced hydrogen storage

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Chinese Journal of Chemical Engineering 2024年第6期70卷 33-53页

作者： b.A.Abdulkadir R.s.R.Mohd Zaki A.T.Abd Wahab s.N.Miskan Anh-Tam Nguyen Dai-Viet N.Vo H.D.setiabudi Centre for Research in Advanced Fluid&Processes Universiti Malaysia Pahang Al-Sultan AbdullahLebuh Persiaran Tun Khalil YaakobGambangPahang 26300Malaysia Faculty of Chemical&Process Engineering Technology Universiti Malaysia Pahang Al-Sultan AbdullahLebuh Persiaran Tun Khalil YaakobGambangPahang 26300Malaysia Center of Excellence for Green Energy and Environmental Nanomaterials(CE@GrEEN) Nguyen Tat Thanh University300A Nguyen Tat ThanhDistrict 4Ho Chi Minh City 755414Viet Nam

Investigating zeolites as hydrogen storage scaffolds is imperative due to their porous nature and favorable physicochemical ***,the storage capacity of the unmodified zeolites has been rather unsatisfactory(0.224%-1.082%(mass))compared to its modified ***,the contemporary focus on enhancing hydrogen storage capacities has led to significant attention towards the utilization of modified zeolites,with studies exploring surface modifications through physical and chemical treatments,as well as the integration of various active *** enhanced hydrogen storage properties of zeolites are attributed to the presence of aluminosilicates from alkaline and alkaline-earth metals,resulting in increased storage capacity through interactions with the charge density of these ***,there is a great demand to critically review their role such as well-defined topology,pore structure,good thermal stability,and tunable hydrophilicity in enhanced hydrogen *** article aimed to critically review the recent research findings based on modified zeolite performance for enhanced hydrogen *** of the factors affecting the hydrogen storage capacities of zeolites that can affect the rate of reaction and the stability of the adsorbent,like pressure,structure,and morphology were studied,and ***,future perspectives,recommendations,and directions for modified zeolites were discussed.

关键词： Zeolites Hydrogen storage surface modification Adsorption Active metal

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Exploring one material for dual applications:A red-emitting Mg2GeO4:Eu3+ nanophosphor for future generation energy efficient WLEDs and dosimetric applications

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Journal of Rare Earths 2024年第10期42卷 1835-1845页

作者： Akshay Arjun G.P.Darshan s.C.sharma H.Nagabhushana D.V.sunitha H.b.Premkumar Department of Physics Faculty of Mathematical and Physical SciencesM.S.Ramaiah University of Applied Sciences Jain University C.N.R.Rao Centre for Advanced Materials Tumkur University school of Applied sciences (Physics) REVA University

The envisaged design and developme nt of individual mate rials to excavate a broader spectrum of desired properties and offer multiple applications are highly *** this in mind,a series of forsterite-structured Mg2GeO4:Eu3+（1 mol%-9 mol%） nanophosphors was synthesized via a solution combustion method using oxalyl dihydrazide as a *** X-ray diffraction patterns confirm the orthorhombic crystal system with a Puma space *** results clearly show irregularly shaped cluster-like structures with aggregation of the *** diffuse reflectance spectra,the optical energy band gap of the Mg2GeO4:Eu3+（1 mol%-9 mol%） nanophosphors was estimated and obtained to be～4.12-4.32 *** photoluminescence emission spectra exhibit intense peaks at ～579,589,610,661,and 707 nm,which are due to characteristic5D0→7F0,5D0→7F1,5Do→7F2,5D0→7F3and5D0→7F4transitions of Eu3+ions,*** Commission International de L'Eclairage color coordinates are gradually tuned from pale red（0.5980,0.4012） to a pure red（0.6385,0.3611） *** glow peaks showcase excellent super-linear response at low doses of γ-irradiations,indicating that the prepared phosphor can be used in thermoluminescent personal dosimetry which is a biological tissue *** aforementioned results demonstrate that the prepared Mg2GeO4:Eu3+（1 mol%-9 mol%） nanophosphors are considered an excellent candidate for dual applications,i.e.,red component in future generation white-light-emitting diodes（WLEDs） and personal dosimetric applications.

关键词： Dosimetry Nanophosphors Photoluminescence Photometric properties Rare earths Thermoluminescence

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sodium nitroprusside as a signal molecule for up-regulating membrane characteristics,antioxidant defense system to improve flax productivity under water stress

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Oil Crop science 2024年第3期9卷 160-169页

作者： N.M.Al-Ashkar b.A.bakry H.M.s.El-bassiouny M.M.s.Abdallah M.s.sadak botany Department Agricultural and Biological Research InstituteNational Research Centre33 El Bohouth Street P.O.12622DokkiGizaEgypt Field Crops Research Department Agricultural and Biological Research InstituteNational Research Centre33 El Bohouth Street P.O.12622DokkiGizaEgypt

Water stress is a critical environmental adversity that significantly impacts the growth,development,and yield of flax *** this study,flax seeds were cultivated under different water irrigation requirements(WIR)(100%,75%,and 50%)to investigate the effects of exogenously supplied nitric oxide(NO)donor sodium nitroprusside(sNP)as foliar treatments at concentrations of 0.0 mmol/L,0.5 mmol/L,1.0 mmol/L,and 2.0 mmol/*** stress led to a significant decrease in plant growth,photosynthetic pigments,yield components such as oil and total carbohydrate *** also resulted in an increase in leaf H2O2 production,lipid peroxidation levels and activities of enzymatic antioxidants including polyphenol oxidase,superoxide dismutase,and nitrate reductase ***,foliar application of sNP improved photosynthetic pigments and antioxidant defense system which mitigated the negative impact of water stress on growth and yield productivity by reducing oxidative damage caused by reactive oxygen species *** use of sNP also decreased H_(2)O_(2) accumulation levels,lipid peroxidation levels,and improved membrane *** treatment at concentration of 2 mmol/L showed superior results compared to other concentrations with extremely significant increases observed in yield characteristics such as oil content,total carbohydrate percentages,and unsaturated fatty acids to saturated fatty acids ratio.

关键词： Flax Fatty acid sodium nitroprusside Antioxidant enzymes Yield

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Construct a 3D microsphere of HMX/b/Al/PTFE to obtain the high energy and combustion reactivity

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Defence Technology（防务技术） 2024年第2期32卷 45-54页

作者： Jian wang Jie Chen Yaofeng Mao Yongjun Deng Wei Cao Fude Nie Jun wang Institute of Chemical Materials China Academy of Engineering PhysicsMianyang 621999PR China shock and Vibration of Engineering Materials and structures Key Lab of sichuan Province Mianyang 621010PR China

Metal(aluminum and boron)based energetic materials have been wildly applied in various fields including aerospace,explosives and micro-devices due to their high energy ***,the low combustion efficiency and reactivity of metal fuels,especially boron(b),severely limit their practical ***,multi-component 3D microspheres of HMX/b/Al/PTFE(HbA)have been designed and successfully prepared by emulsion and solvent evaporation method to achieve superior energy and combustion *** reactivity and energy output of HbA are systematically measured by ignitionburning test,constant-volume explosion vessel system and bomb *** to the increased interfacial contact and reaction area,HbA shows higher flame propagation rate,faster pressurization rate and larger combustion heat of 29.95 cm/s,1077 kPa/s,and 6164.43 J/g,which is 1.5 times,3.5 times,and 1.03 times of the physical mixed counterpart(HbA-P).Meanwhile,HbA also shows enhanced energy output and reactivity than 3D microspheres of HMX/b/PTFE(Hb)resulting from the high reactivity of *** reaction mechanism of 3D microspheres is comprehensively investigated through combustion emission spectral and thermal analysis(TG-DsC-Ms).The superior reactivity and energy of HbA originate from the surface etching of fluorine to the inert shell(Al_(2)O_(3) and b_(2)O_(3))and the initiation effect of Al to *** work offers a promising approach to design and prepare high-performance energetic materials for the practical applications.

关键词： HMX/b/Al/PTFE 3D microspheres surface etching Reaction mechanism

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Functional microfluidics:theory,microfabrication,and applications

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International Journal of Extreme Manufacturing 2024年第3期6卷 140-173页

作者： Mingzhu Xie Ziheng Zhan Yinfeng Li Junkai Zhao Ce Zhang Zhaolong wang Zuankai wang Interdisciplinary Research Center of Low-carbon Technology and Equipment College of Mechanical and Vehicle EngineeringHunan UniversityChangsha 410082People’s Republic of China Energy Research Institute of shandong Academy of sciences Qilu University of Technology(Shandong Academy of Sciences)Jinan 250014People’s Republic of China Qian Xuesen Laboratory of space Technology China Academy of Space Technology(CAST)Beijing 100094People’s Republic of China Department of Mechanical Engineering Hong Kong Polytechnic UniversityHong Kong Special Administrative Region of China 999077People’s Republic of China

Microfluidic devices are composed of microchannels with a diameter ranging from ten to a few hundred ***,quite a small(10-9–10-18l)amount of liquid can be manipulated by such a precise *** the past three decades,significant progress in materials science,microfabrication,and various applications has boosted the development of promising functional microfluidic *** this review,the recent progress on novel microfluidic devices with various functions and applications is ***,the theory and numerical methods for studying the performance of microfluidic devices are briefly ***,materials and fabrication methods of functional microfluidic devices are ***,the recent significant advances in applications of microfluidic devices are highlighted,including heat sinks,clean water production,chemical reactions,sensors,biomedicine,capillaric circuits,wearable electronic devices,and ***,perspectives on the challenges and future developments of functional microfluidic devices are *** review aims to inspire researchers from various fields engineering,materials,chemistry,mathematics,physics,and more—to collaborate and drive forward the development and applications of functional microfluidic devices,specifically for achieving carbon neutrality.

关键词： capillary theory functional devices functional microfluidics

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sENEX-mediated CDK4/6 inhibition promotes senescence and confers apoptosis resistance in b-cell non-Hodgkin lymphoma

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bIOCELL 2024年第3期48卷 453-462页

作者： JIYU wang LIUYING YI KEKE HUANG YANGYANG wang HUIPING wang ZHIMIN ZHAI Department of Hematology The Second Affiliated Hospital of Anhui Medical UniversityHefei230601China Department of Hematology The Fourth Affiliated HospitalZhejiang University School of MedicineYiwu322000China

background:The primary cause of treatment failure in patients with refractory or relapsed b-cell non-Hodgkin lymphoma(r/r b-NHL)is resistance to current therapies,and therapy-induced senescence(TIs)stands out as a crucial mechanism contributing to tumor drug ***,we analyzed sENEX/Rho GTPase Activating Protein 18(ARHGAP18)expression and prognostic signiﬁcance in doxorubicin-induced b-NHL-TIs model and r/r b-NHL patients,investigating its target in b-NHL cell senescence and the effect of combining speciﬁc inhibitors on apoptosis resistance in b-NHL-TIs ***:Raji cells were transfected with the human sENEX shRNA recombinant lentiviral vector(sh-sENEX)and the empty vector negative(NC)to construct a stable transfection cell line with knockdown of *** of sENEX-silencing on b-NHL-TIs formation,cell function and cell cycle-related pathways was *** doxorubicin(DOX)-inducible senescent b-NHL cells combined with the speciﬁc cyclin dependent kinase 4/6(CDK4/6)inhibitor Palbociclib to observe that blocking CDK4/6 effects on TIs *** expression of 21 b-NHL patients and 8 healthy controls were analyzed by qRT-PCR,and the correlation between its expression and clinical indicators were ***:The downregulation of sENEX expression promotes G1-s phase transition and apoptosis while inhibiting cell proliferation,collectively suppressing the formation of TIs in *** of CDK4/6 promotes the DOX-induced G1 phase arrest to enhance TIs formation in b-NHL cells which can reverse the regulatory effect of silencing sENEX on b-NHL cell cycle regulation and *** expression levels of sENEX were notably elevated in b-NHL patients compared to healthy controls,and Elevated expression levels of sENEX were associated with poor prognosis of b-NHL ***:sENEX enhances apoptosis resistance in b-NHL by inhibiting CDK4/6,thereby preventing G1-s phase transition and promoting TIs formation.

关键词： sENEX b-cell non-Hodgkin lymphoma CDK4/6 G1-s phase transition Therapy-induced senescence Apoptosis resistance

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Microstructural Evolutions and Mechanical Properties of Energetic Al_(1) (TiZrNbTaMoCr)_(15) High-Entropy Alloys

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Acta Metallurgica sinica(English Letters) 2024年第4期37卷 620-632页

作者： Xuan-Hong Cai Zhen-Hua wang ben Niu Jin-Feng Li Qing wang show authors Key Laboratory of Materials Modification by Laser Ion and Electron Beams(Ministry of Education)Engineering Research Center of High Entropy Alloy Materials(Liaoning Province)School of Materials Science and EngineeringDalian University of TechnologyDalian116024China Institute of Materials China Academy of Engineering PhysicsMianyang621908China

The present study focuses on investigating the microstructural evolutions and mechanical properties of energetic Al_(1)(TiZrNbTaMoCr)_(15) refractory high-entropy alloys with the different heat treatments at low Al content state. It is found that even with a reduction in the Al content, the strength of these alloys remains unaffected at room temperature and high temperature, while the plasticity improves significantly. In particular, the coherent bCC/b_(2) microstructure with needle-like b_(2) nanoprecipitates dispersed into the bCC matrix is formed in 873 K-aged Al_(1)Ti_(6)Zr_(2)Nb_(3)Ta_(3)Mo_(0.5)Cr_(0.5) alloy. Therefore, this alloy exhibits the highest compression yield strength (σ_(Ys) = 1333 and 717 MPa) at room temperature and 1073 K, respectively. After 973 K-aged, the coherent bCC/b_(2) microstructure underwent destabilization, and the b_(2) phase transforms into the brittle Zr5Al3 phase which then coarsens and dominates the microstructure of s3-AlTa_(3) alloy after 1073 K-aged. Moreover, these current alloys exhibit exceptionally high theoretical exothermic enthalpy (ΔH), surpassing 11606 J·g^(−1), which highlights their significant potential as innovative high-performance energetic structural materials.

关键词： Refractory high-entropy alloy Coherent microstructure Mechanical property Exothermic enthalpy

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Advancing Evaluation of Microplastics Thresholds to Inform Water Treatment Needs and Risks

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Environment & Health 2024年第7期2卷 441-452页

作者： Omar s.Chowdhury Philip J.schmidt William b.Anderson Monica b.Emelko Department of Civil and Environmental Engineering University of Waterloo200 University Avenue WestWaterlooON N2L 3G1Canada

Although human health impacts of microplastics are not well understood,concern regarding chemical contaminants retained on or within them is *** water providers are increasingly asked about these risks,but strategies for evaluating them and the extent of treatment needed to manage them are currently *** can potentially induce health effects if the concentration of contaminants adsorbed to them exceeds predetermined drinking water guidelines(e.g.,Maximum Contaminant Levels).The risk posed by microplastics due to adsorbed contaminants is difficult to determine,but a worst-case scenario can be evaluated by using adsorption ***,a“Threshold Microplastics Concentration”(TMC)framework is developed to evaluate whether waterborne microplastic concentrations can potentially result in the intake of regulated contaminants on/in microplastics at levels of human health concern and identify treatment targets for managing associated health *** the TMC does not indicate an immediate health risk;it informs the need for detailed risk assessment or further treatment evaluation to ensure particle removal targets are ***,the TMC concept and framework provide an updateable,science-based screening tool to determine if there is a need for detailed risk assessment or treatment modification due to waterborne microplastics in supplies used for potable water production.

关键词： drinking water treatment chemical contaminants adsorption capacity risk management maximum contaminant level

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Achieving high-performance sodium metal anodes: From structural design to reaction kinetic improvement

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Nano Research 2024年第3期17卷 1288-1312页

作者： Jing Xu Jianhao Yang Yashuang Qiu Yang Jin Tianyi wang bing sun Guoxiu wang Research Center of Grid Energy storage and battery Application School of Electrical and Information EngineeringZhengzhou UniversityZhengzhou 450001China College of Chemistry and Chemical Engineering Yangzhou University Yangzhou 225009China Centre for Clean Energy Technology School of Mathematical and Physical SciencesFaculty of ScienceUniversity of Technology SydneyUltimoNSW 2007Australia

sodium metal is one of the ideal anodes for high-performance rechargeable batteries because of its high specific capacity(~1166 mAh·g^(-1)),low reduction potential(-2.71 V compared to standard hydrogen electrodes),and low ***,the unstable solid electrolyte interphase,uncontrolled dendrite growth,and inevitable volume expansion hinder the practical application of sodium metal *** present,many strategies have been developed to achieve stable sodium metal ***,we systematically summarize the latest strategies adopted in interface engineering,current collector design,and the emerging methods to improve the reaction kinetics of sodium deposition ***,the strategies of constructing protective layers are reviewed,including inorganic,organic,and mixed protective layers through electrolyte additives or ***,the classification of metal-based,carbon-based,and composite porous frames is discussed,including their function in reducing local deposition current density and the effect of introducing sodiophilic ***,the recent progress of alloys,nanoparticles,and single atoms in improving Na deposition kinetics is systematically ***,the future research direction and the prospect of high-performance sodium metal batteries are proposed.

关键词： sodium metal anodes interface engineering current collector design reaction kinetics sodium deposition processes

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