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Curing Kinetics of Tannin and Lignin Biobased Adhesives Determined by DSC and ABES

Journal of Renewable Materials 2022年第8期10卷 2117-2131页

作者： Jaša Saražin Ida Poljanšek antonio Pizzi MilanŠernek University of Ljubljana Biotechnical FacultyLjubljana1000Slovenia Universitéde Lorraine LERMAB-ENSTIB Epinal88000France

The curing process of two biobased adhesives:pine tanninhexamine(TH)and organosolv lignin non-isocyanate polyurethane(NIPU),suitable for interior nonstructural use,were compared with commercial urea-formaldehyde(UF)*** in chemical structure before and after the curing process were observed with Fouriertransform infrared spectroscopy(FTIR).The process of adhesive curing was monitored with differential scanning calorimetry(DSC)and the automated bonding evaluation system(ABES).Both DSC and ABES measurements confirmed UF as the fastest and NIPU as the slowest curing adhesive *** into account the ABES results,the optimal pressing parameters for the TH adhesive would be 4 min at 175℃,for the NIPU adhesive 7 min at 200℃and for the UF 1.5 min at 100℃.Strong linear correlation was observed between mechanical and chemical curing for the UF and NIPU adhesives,whereas lower correlation was observed for the TH *** all observed adhesives,the DSC measurements were underestimating the curing process determined by ABES in the first part and overestimating it at the *** underestimation was the most evident with the TH adhesive and the less with the UF *** comparing the uncured and cured FTIR spectra of all three types of adhesives,a drastic decrease in the characteristic band of-OH groups at 3330–3400 cm^(−1)and an increase in the signal intensity at 2920 cm^(−1)of aliphatic-CH2-groups were *** the UF adhesive,the C=O stretching frequency has shifted from 1632 cm^(−1)for uncured to three different bands at 1766,1701,and 1655 cm^(−1)for cured *** sharp band for phenolic alcohols at 1236 cm^(−1)of C–O stretch and hydroxyl O–H functional group at 1009 cm^(−1)and at 684 cm^(−1)of uncured TH adhesive diminished during curing,which indicates that a crosslinking reaction occurs via-OH *** peak of the C=O group of urethane bridges at 1697 cm^(−1)for uncured NIPU shifted to lower wavenumber at 1633 cm^(−1)for cured NIPU.

关键词： Biobased adhesives curing kinetics tannin lignin ABES DSC FTIR

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Parking Availability Prediction with Coarse-Grained Human Mobility Data

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Computers, Materials & Continua 2022年第6期71卷 4355-4375页

作者： Aurora Gonzalez-Vidal Fernando Terroso-Sáenz antonio Skarmeta University of Murcia Murcia30003Spain Universidad Católica de Murcia(UCAM) Murcia30107Spain

Nowadays,the anticipation of parking-space demand is an instrumental service in order to reduce traffic congestion levels in urban *** purpose of our work is to study,design and develop a parking-availability predictor that extracts the knowledge from human mobility data,based on the anonymized human displacements of an urban area,and also from weather *** of the existing solutions for this prediction take as contextual data the current road-traffic state defined at very high temporal or spatial ***,access to this type of fine-grained location data is usually quite limited due to several economic or privacy-related *** overcome this limitation,our proposal uses urban areas that are defined at very low spatial and temporal *** conducted several experiments using three Artificial Neural Networks:Multilayer Perceptron,Gated Recurrent Units and bidirectional Long Short Term Memory networks and we tested their suitability using different combinations of *** metrics are provided for the sake of comparison within our study and between other *** solution has been evaluated in a real-world testbed in the city of Murcia(Spain)integrating an open human-mobility dataset showing high accuracy.A MAPE between 4%and 10%was reported in horizons of 1 to 3 h.

关键词： Parking space human mobility mining recurrent neural networks prediction

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Hydrolysable Chestnut Tannin Extract Chemical Complexity in Its Reactions for Non-Isocyanate Polyurethanes(NIPU)Foams

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Journal of Renewable Materials 2023年第6期11卷 2823-2848页

作者： Elham Azadeh antonio Pizzi Christine Gerardin-Charbonnier Philippe Gerardin LERMAB Faculty of Science and TechnologyUniversity of LorraineVandoeuvre les Nancy54506France LERMAB University of LorraineEpinal88051France

Non-isocyanate polyurethane(NIPU)foams from a commercial hydrolysable tannin extract,chestnut wood tannin extract,have been prepared to determine what chemical species and products are taking part in the reactions *** method is based on two main steps:the reaction with dimethyl carbonate and the formation of urethane bonds by further reaction of the carbonated tannin with a diamine-like hexamethylene *** hydroxyl groups on the tannin polyphenols and on the carbohydrates intimately linked with it and part of a hydrolysable tannin are the groups involved in these *** carbohydrate skeleton of the hydrolysable tannin is also able to participate through its hydroxyl groups to the same two reactions rendering the whole molecular complex able to react to form *** analysis by Matrix-Assisted Laser Desorption Ionization(MALDI-TOF)mass spectrometry and 13C Nuclear Magnetic Resonance(13C NMR)to further investigate the reaction mechanisms involved revealed the unsuspected complexity of chestnut hydrolysable tannin,with different fragments reacting in different manners forming a hardened network of considerable *** the morphology and performance of these types of foams changes slightly with the change in the amount of glutaraldehyde and hexamine hardeners,the best performing foam formulation previously determined was scanned by SEM and analysed chemically for the structures formed.

关键词： Hydrolysable tannin chestnut tannin non-isocyanate bio polyurethanes NIPU MALDI-ToF ^(13)C NMR SEM bio-based materials

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MUF Resins Improved by Citric Acid as Adhesives for Wood Veneer Panels

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Journal of Renewable Materials 2023年第2期11卷 539-553页

作者： Claudio Del Menezzi antonio Pizzi Siham Amirou Xuedong Xi Department of Forestry Engineering Faculty of TechnologyUniversity of BrasiliaBrasíliaBrazil LERMAB University of LorraineNancyFrance SeniorPost-Doctoral Internship LERMAB-ENSTIBUniversity of LorraineEpinalFrance Yunnan Key Laboratory of Wood Adhesives and Glue Products College of Material Science and EngineeringSouthwest Forestry UniversityKunmingChina International Joint Research Center for Biomass Materials Southwest Forestry UniversityKunmingChina

This article presents the first applied results of using citric acid in combinations with a melamine-urea-formal-dehyde(MUF)resin for bonding wood *** chemical reactions involved are shown based on a MALDI ToF analysis of the reaction of the MUF resin with citric *** preliminary results of the physical and mechanical properties of the LVL prepared are also *** from Populus sp were used to manufacture 5-layer laminated veneer lumber(LVL)of small *** combinations of the amount of citric acid,MUF spread rate and pressing parameters were *** bonded with 20%of citric acid+100 g/m^(2)of MUF,hot-pressed using a 3-step process with maximum 1.5 MPa of pressure yielded the board with better dimensional stability and mechanical *** could be concluded that citric acid in combination with MUF can be used for bonding wood veneer and the research should be continued to study further the parameters involved and to enhance the results.

关键词： LVL wood adhesives citric acid MUF resins MALDI ToF mechanical performance

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Influence of parameters on the microstructure of a duplex stainless steel joint welded by a GMAW welding process

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Progress in Natural Science:Materials International 2022年第4期32卷 415-423页

作者： Sandra Chacón-Fernández antonio Portolés García Gerardo Romaní Labanda Universidad Politécnica de Madrid Escuela Técnica Superior de Ingenieros Industriales UPM

Duplex stainless steels（DSSs） are widely used in industry for their desirable properties. Any fusion welding technique modifies the microstructure and, consequently, the properties of the material. This paper presents a parametric study of the variables that determine the energy contribution（current, voltage and welding speed） and the structural modifications produced during gas metal arc welding. The analysis comprises metallographic study,phase balance, dimensioning of the weld beads and tensile and hardness tests. The influence of the variables studied on the thermal cycles obtained（temperatures reached and cooling rate） was determined by using a finite element model. The results showed that, in addition to the indicated parameters, the parameter power transfer per volume（W/m3） and the geometry in the bead must be controlled due to their influence on the heat flow distribution and phase balance.

关键词： Welding Heat input GMAW Duplex stainless steels (DSS) Finite element model (FEM)

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Edge robotics:are we ready?an experimental evaluation of current vision and future directions

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Digital Communications and Networks 2023年第1期9卷 166-174页

作者： Milan Groshev Gabriele Baldoni Luca Cominardi antonio de la Oliva Robert Gazda University Carlos Ⅲ of Madrid Leganes28028MadridSpain ZettaScale Technology SARL Saint-Aubin91190France InterDigital Inc. WilmingtonDE19809USA

Cloud-based robotics systems leverage a wide range of Information Technologies(IT)to offer tangible benefits like cost reduction,powerful computational capabilities,data offloading,***,the centralized nature of cloud computing is not well-suited for a multitude of Operational Technologies(OT)nowadays used in robotics systems that require strict real-time guarantees and *** computing and fog computing are complementary approaches that aim at mitigating some of these challenges by providing computing capabilities closer to the *** goal of this work is hence threefold:i)to analyze the current edge computing and fog computing landscape in the context of robotics systems,ii)to experimentally evaluate an end-to-end robotics system based on solutions proposed in the literature,and iii)to experimentally identify current benefits and open challenges of edge computing and fog *** show that,in the case of an exemplary delivery application comprising two mobile robots,the robot coordination and range can be improved by consuming real-time radio information available at the ***,our evaluation highlights that the existing software,wireless and virtualization technologies still require substantial evolution to fully support edge-based robotics systems.

关键词： Edge robotics experimental fog MEC Virtualization ROS Fog05

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CRISPR-Cas-based plant genome engineering goes viral

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Molecular Plant 2023年第4期16卷 660-661页

作者： Jose-antonio Daros Fabio Pasin Fernando Merwaiss Instituto de Biologia Molecular y Celular de Plantas(CSiC-Universitat Politecnica deValencia) 46022ValenciaSpain

Biotechnological advances in the field of plant biology based on the bacterial and archaeal CRiSPR-Cas systems promise a new generation of crop plants that are more productive and nutritive,resistant to pest and pathogens,and better adapted to environmental ***,application of this technology in plants still encounters some burdens,especially related to the expression of the CRISPR-Cas reaction components in plant cells.

关键词： plant CRISPR adapted

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Effect of Zn binding to phytate and humic substances on its uptake by wheat(Triticum durum L.)as affected by carbonates and Fe oxides

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Pedosphere 2022年第6期32卷 823-832页

作者： Ana M.GARCÍA-LÓPEZ Ramiro RECENA antonio DELGADO Department of Agronomy ETSIAUniversity of SevilleSeville 41013(Spain)

Although complexation with soil organic matter may improve zinc(Zn)bioavailability to plants,the effect of Zn sorbent surface on the use of complexed Zn by plants remains *** objective of this research was to elucidate how Zn complexation with humic substances(HS)and phytate affects the uptake of Zn by wheat plants depending on the main sorbent surface in growth media,i.e.,carbonates and Fe *** this end,two pot experiments were performed,one using Fe oxide-coated siliceous as the siliceous growth medium sand and the other using a mixture of calcareous sand and siliceous sand as the calcareous growth *** experiment involved three Zn sources,Zn-HS complex,Zn phytate,and ZnSO_(4).All sources were applied with surface irrigation at two Zn rates(0.25 and 2 mg kg^(-1) growth medium).The Zn-HS complex significantly increased Zn uptake by plants in both media,relative to the other two Zn sources,but no significant difference was observed between Zn phytate and ZnSO_(4).In the calcareous medium,Zn-HS complex and Zn phytate resulted in significantly higher dry biomass yields of wheat than ZnSO_(4).In the siliceous medium,spike and shoot dry biomass yields with Zn-HS complex at the low rate and Zn phytate at both rates were not significantly different from those with ZnSO_(4) at the high *** harvest,approximately 50%of the Zn applied as Zn-HS complex remained extractable by diethylenetriaminepentaacetic acid(DTPA),while this proportion was less than 20%for the other Zn ***,Zn-HS complex and Zn phytate are sources of available Zn for plants,and they are more effective than ZnSO_(4) in increasing plant growth,particularly when carbonates are the main Zn sorbent surface.

关键词： calcareous growth medium micronutrient organic matter organic phosphorus Zn availability Zn deficiency Zn sorbent surface Zn source

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Hepatocellular carcinoma as the Rose of Jericho:from the desert of sorafenib,to the blossoming of immunotherapy

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Hepatobiliary Surgery and Nutrition 2022年第3期11卷 485-488页

作者： antonio D’Alessio Lorenza Rimassa Department of Surgery&Cancer Imperial College LondonHammersmith HospitalLondonUK Department of Biomedical Sciences Humanitas UniversityPieve EmanueleMilanItaly Medical Oncology and Hematology Unit Humanitas Cancer CenterIRCCS Humanitas Research HospitalRozzanoMilanItaly

According to its etymology,the English word“liver”is related to the verb“to live”,and indeed there are few domains of oncology research as lively as liver *** therapeutic landscape of hepatocellular carcinoma(HCC)has been rapidly changing over the last years,after the successful introduction of immune checkpoint inhibitors(ICIs)as standard of care for the treatment of unresectable or metastatic HCC(uHCC).Following more than a decade of tyrosine kinase inhibitors(TKIs)as the only available treatment for advanced HCC,in 2020 the results of the IMbrave150 trial radically changed the therapeutic algorithm(1,2).The combination of the anti-programmed death ligand 1(PD-L1)monoclonal antibody(mAb)atezolizumab and the anti-vascular endothelial growth factor(VEGF)mAb bevacizumab outperformed sorafenib in terms of overall survival(OS)and progression-free survival(PFS),meeting both its co-primary *** combination has been recognised as the new first-line standard of care by all major scientific societies,and it has been approved by regulatory agencies worldwide(3).

关键词： sorafenib immunotherapy monoclonal

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A Mixed Radiative-Convective Technique for the Calibration of Heat Flux Sensors in Hypersonic Flow

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Fluid Dynamics & Materials Processing 2022年第2期18卷 189-203页

作者： antonio Esposito Marcello Lappa Rocco Pagliara Gennaro Spada Department of Industrial Engineering University of NaplesNaples80125Italy Department of Mechanical and Aerospace Engineering University of StrathclydeGlasgowG11XJUK Cheminox srl San Vito dei Normanni(BR)72019Italy

The ability to measure the very high heat fluxes that typically occur during the hypersonic re-entry phase of space vehicles is generally considered a subject of great importance in the aerospace *** of the sensors used for these measurements need to be checked periodically and re-calibrated *** bottleneck relates to the need to procure thermal sources that are able to generate reliable reference heat fluxes in the range between 100 and 1000 kW/m^(2)(as order of magnitude).In the present study,a method is presented by which,starting from a calibration system with a capacity of approximately 500 kW/m^(2) only,heat fluxes in the range of interest for hypersonic applications are *** related procedure takes advantage of established standards for the characterization of a radiative heat *** also builds on the hybrid radiative-convective nature of typical hypersonic heat fluxes and the yet poorly explored possibility to use convective sources of heat to produce high-intensity *** reliability of such a strategy has been tested using a high enthalpy supersonic flow facility relying on an electric arc-heater and pure Nitrogen as work ***-point heat fluxes have been successfully measured(with reasonable accuracy)in the range between 600 and 1500 kW/m^(2) for values of the centerline enthalpy spanning the interval from to 6 to 24 MJ/kg.

关键词： Photometry heat flux sensor calibration facility radiative source convective source

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