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Chinese Chemical Letters 2022年第2期33卷 730-742页

作者： Nkongolo Tshamala Aristote Kangyu Zou andi di Wentao Deng Baowei Wang Xinglan Deng Hongshuai Hou Guoqiang Zou Xiaobo Ji College of Chemistry and Chemical Engineering Central South UniversityChangsha 410083China Department of Materials and Environmental Chemistry Stockholm UniversityStockholm 10691Sweden

Sodium-ion batteries(SIBs) have gained more scientists’ interest, owing to some facts such as the natural abundance of Na, the similarities of physicochemical characteristics between Li and Na. The irreversible Na+ions consumption during the first cycle of charge/discharge process(due to the formation of the solid electrolyte interface(SEI) on the electrode surface and other irreversible reactions) is the factor that determines high performance SIBs and largely reduces the capacity of the full cell SIBs. Thus, the initial coulombic efficiency(ICE) of SIBs for both anode and cathode materials, is a key parameter for high performance SIBs, and the point is to increase the transport rate of the Na+ions. Therefore, developing SIBs with high ICE and rate performance becomes vital to boost the commercialization of SIBs. Here we provide a review on the methods to improve the ICE and the rate performance, by summarizing some methods of improving the ICE and rate performance of the anode and cathode materials for SIBs, and end by a conclusion with some perspectives and recommendations.

关键词： Initial coulombic efficiency Rate performance Sodium-ion batteries Anode materials Cathode materials

Mitigating the Jahn-Teller distortion driven by the spin-orbit coupling of lithium manganate cathode

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Journal of Energy Chemistry 2022年第9期31卷 379-387,I0011页

作者： Shu Zhang Hongyi Chen Jun Chen Shouyi Yin Yu Mei Lianshan Ni andi di Wentao Deng Guoqiang Zou Hongshuai Hou Xiaobo Ji State Key Laboratory of Powder Metallurgy College of Chemistry and Chemical EngineeringCentral South UniversityChangsha 410083HunanChina Department of Materials and Environmental Chemistry Stockholm UniversityStockholm 10691Sweden

Spinel LiMn_(2)O_(4)is recognized as one of the most competitive cathode candidates for lithium-ion batteries ascribed to environmentally benign and rich sources.However,the wholesale application of LiMn_(2)O_(4)is predominately plagued by its severe capacity degradation,mainly associated with the innate Jahn-Teller effect.Herein,single-crystalline LiMn_(2)O_(4)with Eu^(3+) doping is rationally designed to mitigate the detrimental Jahn-Teller distortion by tuning the chemical environment of MnO_(6) octahedra and accommodating localized electron,based on the unique aspheric flexible 4f electron orbit of rare-earth metal ions.Notably,the stretching of MnO_(6) octahedron stemmed from the Jahn-Teller effect in Eu-doped LiMn_(2)O_(4)is effectively suppressed,confirmed by theoretical calculation.Meanwhile,the structural stability of the material has been significantly enhanced due to the robust Mn–O band coherency and weakened phase transition,proved by synchrotron radiation absorption spectrum and operando X-ray diffraction.The corresponding active cathode manifests superior long-cycle stability after 300 loops at 2C and displays only a 0.011%capacity drop per cycle even at 5C.Given this,this modification tactic sheds new light on achieving superior long-cycle performances by suppressing distortion in various cathode materials.

关键词： Spinel lithium manganate Spin-orbit coupling Jahn-Teller distortion Cathode material

In situ infrared, Raman and X-ray spectroscopy for the mechanistic understanding of hydrogen evolution reaction

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Journal of Energy Chemistry 2024年第3期90卷 632-651,I0014页

作者： andi Haryanto Kyounghoon Jung Chan Woo Lee Dong-Wan Kim Department of Chemistry Kookmin UniversitySeoul 02707Republic of Korea School of Civil Environmental and Architectural EngineeringKorea UniversitySeoul 02841Republic of Korea

Hydrogen production by water reduction reactions has received considerable attention because hydrogen is considered a clean-energy carrier,key for a sustainable energy future.Computational methods have been widely used to study the reaction mechanism of the hydrogen evolution reaction(HER),but the calculation results need to be supported by experimental results and direct evidence to confirm the mechanistic insights.In this review,we discuss the fundamental principles of the in situ spectroscopic strategy and a theoretical model for a mechanistic understanding of the HER.In addition,we investigate recent studies by in situ Fourier transform infrared(FTIR),Raman spectroscopy,and X-ray absorption spectroscopy(XAS) and cover new findings that occur at the catalyst-electrolyte interface during HER.These spectroscopic strategies provide practical ways to elucidate catalyst phase,reaction intermediate,catalyst-electrolyte interface,intermediate binding energy,metal valency state,and coordination environment during HER.

关键词： Hydrogen evolution reaction Infrared spectroscopy Raman spectroscopy X-ray absorption spectroscopy Reaction mechanism

Role of CYP311A1 in wing development of Drosophila melanogaster

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Insect Science 2024年第3期31卷 748-758页

作者： Xubo Zhang Mengqi Liu andi Cheng Bernard Moussian Jianzhen Zhang Wei Dong Shanxi Key Laboratory of Nucleic Acid Biopesticides Institute of Applied BiologyShanxi UniversityTaiyuanChina College of Life Science Shanxi UniversityTaiyuanChina INRAE CNRSInstitut Sophia AgrobiotechSophia AntipolisUniversite Cote d'AzurNiceFrance

Lipid homeostasis is crucial for growth and development of organisms.Several cytochrome P450 monooxygenases(CYPs)are involved in lipid metabolism.The function of Cyp3llal in the anterior midgut as a regulator of phosphatidylethanolamine(PE)metabolism in Drosophila melanogaster has been demonstrated,as depletion of Cyp31lal caused larval growth arrest that was partially rescued by supplying PE.In this study,we investigated the role of CYP311A1 in wing morphogenesis in Drosophila.Using the GAL4-UAS system,Cyp31lal was selectively knocked down in the wing disc.A deformed wing phenotype was observed in flies with reduced Cyp31lal transcripts.BOdiPY and oil red O staining revealed a reduction of neutral lipids in the wing disc after the depletion of Cyp31lal.In addition,we observed an enhanced sensitivity to Eosin Y penetration in the wings of Cyp31lal knocked-down flies.Moreover,the reduction of CYP311A1 function in developing wings does not affect cell proliferation and apoptosis,but entails disordered Phalloidin or Cadherin distribution,suggesting an abnormal cell morphology and cell cortex structure in wing epithelial cells.Taken together,our results suggest that Cyp3llal is needed for wing morphogenesis by participating in lipid assembly and cell homeostasis.

关键词： apoptosis cell cortex cell proliferation Cyp31lal lipid wing

Factors associated with the incidence of patient falls in hospitals:A scoping review

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Journal of Integrative Nursing 2024年第2期6卷 117-126页

作者： Nurul AINANI andi Masyitha IRWAN Posgraduate Nursing Program Faculty of NursingHasanuddin UniversityMakassarIndonesia Department of Gerontological Nursing Faculty of NursingHasanuddin UniversityMakassarIndonesia

When a patient falls within a hospital setting,there is a significant increase in the risk of severe injury or health complications.Recognizing factors associated with such falls is crucial to mitigate their impact on patient safety.This review seeks to analyze the factors contributing to patient falls in hospitals.The main goal is to enhance our understanding of the reasons behind these falls,enabling hospitals to devise more effective prevention strategies.This study reviewed literature published from 2013 to 2022,using the Arksey and O’Malley methodology for a scoping review.The research literature was searched from seven databases,namely,PubMed,Sciencedirect,Wiley Library,Garuda,Global Index Medicus,Emerald Insight,and Google Scholar.The inclusion criteria comprised both qualitative and quantitative primary and secondary data studies centered on hospitalized patients.Out of the 893 studies analyzed,23 met the criteria and were included in this review.Although there is not an abundance of relevant literature,this review identified several factors associated with falls in hospitals.These encompass environmental,patient,staff,and medical factors.This study offers valuable insights for hospitals and medical personnel aiming to enhance fall prevention practices.Effective prevention efforts should prioritize early identification of patient risk factors,enhancement of the care environment,thorough training for care staff,and vigilant supervision of high-risk patients.By comprehending the factors that contribute to patient falls,hospitals can bolster patient safety and mitigate the adverse effects of falls within the health-care setting.

关键词： Associated factors patient falls patient safety

Socio-economic vulnerability level in the Jeneberang watershed in Gowa Regency,South Sulawesi Province,Indonesia

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Regional Sustainability 2024年第1期5卷 69-79页

作者： andi Rachmat ARFADLY Hazairin ZUBAIR MAHYUDdiN Andang Suryana SOMA Graduate School Hasanuddin UniversityMakassar90245Indonesia Faculty of Agriculture Hasanuddin UniversityMakassar90245Indonesia

Jeneberang watershed is vital,particularly for people living in Gowa Regency(South Sulawesi Province,Indonesia),who benefit from its many advantages.Landslides and floods occur every year in the Jeneberang watershed,so it is imperative to understand the socio-economic vulnerability of this region.This research aims to identify the vulnerability level of the Jeneberang watershed so that the government can prioritize areas with high vulnerability level and formulate effective strategies to reduce these the vulnerability.Specifically,this study was conducted in 12 districts located in the Jeneberang watershed.The primary data were collected from questionnaires completed by community members,community leaders,and various stakeholders,and the secondary data were from the Landsat satellite imagery in 2020,the Badan Push Statistic of Gowa Regency,and some governmental agencies.The socio-economic vulnerability variables were determined using the Multiple Criteria Decision Analysis(MCDA)method,and each variable was weighted and analyzed using the Geographical Information System(GIS).The study reveals that the levels of socio-economic vulnerability are affected by variables such as population density,vulnerable groups(disabled people,elderly people,and young people),road network and settlement,percentage of poor people,and productive land area in the Jeneberang watershed.Moreover,all of the 12 districts in the Jeneberang watershed are included in the medium vulnerability level,with the mean percentage of socio-economic vulnerability around 50.92%.The socio-economic vulnerability of Bajeng,Pallangga,and Somba Opu districts is categorized at high level,the socio-economic vulnerability of Bungaya,Parangloe,and Tombolo Pao districts is classified as medium level,and the remaining 6 districts(Barombong,Bontolempangan,Bontomarannu,Manuju,Parigi,and Tinggimoncong)are ranked as low socio-economic vulnerability.This study can help policy-makers to formulate strategy that contributes to the protection of biodiversity and sustainable

关键词： Socio vulnerability Economic vulnerability Population density Vulnerable groups Road network and settlement Productive land area Jeneberang watershed

Circ_0053943 complexed with IGF2BP3 drives uveal melanoma progression via regulating N6-methyladenosine modification of Epidermal growth factor receptor

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Oncology Research 2024年第5期32卷 983-998页

作者： andi ZHAO YUE WANG ZIJIN WANG QING SHAO QI GONG HUI ZHU SHIYA SHEN HU LIU XUEJUAN CHEN Department of Ophthalmology The First Affiliated Hospital with Nanjing Medical UniversityNanjing210029China The First Clinical Medical College Nanjing Medical UniversityNanjing211166China Department of Ophthalmology Nanjing First HospitalNanjing Medical UniversityNanjing210006China

Numerous studies have characterized the critical role of circular RNAs(circRNAs)as regulatory factors in the progression of multiple cancers.However,the biological functions of circRNAs and their underlying molecular mechanisms in the progression of uveal melanoma(UM)remain enigmatic.In this study,we identified a novel circRNA,circ_0053943,through re-analysis of UM microarray data and quantitative RT-PCR.Circ_0053943 was found to be upregulated in UM and to promote the proliferation and metastatic ability of UM cells in both in vitro and in vivo settings.Mechanistically,circ_0053943 was observed to bind to the KH1 and KH2 domains of insulin-like growth factor 2 mRNA-binding protein 3(IGF2BP3),thereby enhancing the function of IGF2BP3 by stabilizing its target mRNA.RNA sequencing assays identified epidermal growth factor receptor(EGFR)as a target gene of circ_0053943 and IGF2BP3 at the transcriptional level.Rescue assays demonstrated that circ_0053943 exerts its biological function by stabilizing EGFR mRNA and regulating the downstream mitogen-activated protein kinase/extracellular signal-regulated kinase(MAPK/ERK)signaling pathway.Collectively,circ_0053943 may promote UM progression by stabilizing EGFR mRNA and activating the MAPK/ERK signaling pathway through the formation of a circ_0053943/IGF2BP3/EGFR RNA-protein ternary complex,thus providing a potential biomarker and therapeutic target for UM.

关键词： Uveal melanoma Hsa_circ_0053943 IGF2BP3 EGFR MAPK/ERK signaling pathway

Self-Assembled Protein Hybrid Nanofibrils for Photosynthetic Hydrogen Evolution

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CCS Chemistry 2024年第3期6卷 812-823页

作者： Weijian Chen Xiantao Hu andi Hu Luyang Ji Yiming Huang Hao Heng Fude Feng Shu Wang Department of Polymer Science and Engineering School of Chemistry and Chemical EngineeringNanjing UniversityJiangsuNanjing 210023 Beijing National Laboratory for Molecular Sciences Key Laboratory of Organic SolidsInstitute of ChemistryChinese Academy of SciencesBeijing 100190

In artificial photosynthesis systems,synthetic diiron complexes are popular[FeFe]-hydrogenase mimics,which are attractive for the fabrication of photocatalyst-protein hybrid structures to amplify hydrogen(H2)generation capability.However,constructing a highly bionic and efficient catalytic hybrid system is a major challenge.Notably,we designed an ideal hybrid nanofibrils system that incorporates the crucial components:(1)a[FeFe]-H2ase mimic,which has a three-arm architecture(named triFeFe)for more interaction sites and higher catalytic activity and(2)uniform hybrid nanofibrils as the biological environment in which cysteine-catalyst coordination and the hydrogen-bonding network play a vital role in both catalyst binding and hydrogen evolution reaction activity.The assembled hybrid nanofibrils achieve efficient H2 generation with a turnover number of 2.3×103,outperforming previously reported diiron catalyst-protein hybrid systems.Additionally,the hybrid nanofibrils work with photosynthetic thylakoids to produce H2,without extra photosensitizers or electron shuttle proteins,which advances the bioengineering of living systems for solar-driven biofuel production.

关键词： hybrid photocatalyst in situ assembly amyloid fibrils photosynthetic hydrogen evolution thylakoid

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对融合特征敏感的三维点云识别与分割

西安交通大学学报 2024年第5期58卷 52-63页

作者：朱安迪达飞鹏盖绍彦东南大学自动化学院南京210096 东南大学复杂工程系统测量与控制教育部重点实验室南京210096

三维点云分类分割网络忽视了融合特征中的冗余信息,缺乏放大有效特征占比能力,不能充分挖掘特征的表达性。在CurveNet网络基础上,提出了一种能够筛选和丰富融合特征的方法,对点云的识别与分割效果达到了较先进水平。首先,提出了对融合... 详细信息

三维点云分类分割网络忽视了融合特征中的冗余信息,缺乏放大有效特征占比能力,不能充分挖掘特征的表达性。在CurveNet网络基础上,提出了一种能够筛选和丰富融合特征的方法,对点云的识别与分割效果达到了较先进水平。首先,提出了对融合特征具有筛选能力的特征选择子网络,利用结合了打分机制的Top K算子选出包含有效信息的融合特征,并且能够自适应地赋予被选特征权重。其次,在聚合曲线特征模块中增加了两个新分支,分别学习曲线内部点距离特征和曲线之间的线距离特征,通过快速通道相关性注意力机制提取各分支的内部相关性,增强了网络特征的信息描述能力。实验结果表明,分类任务在ModelNet40数据集上准确率达到了93.8%,分割任务在ShapeNet Part数据集上平均交并比达到了86.4%。与基准网络相比,分类效果与分割效果均有所提高,证明了算法的有效性。

关键词：三维点云融合特征筛选曲线特征注意力机制分类分割

束缚应激通过激活Rho/ROCK通路诱导大鼠杏仁核血脑屏障的损伤

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南方医科大学学报 2024年第3期44卷 411-419页

作者：许光明高安迪丛斌中央司法警官学院法医学教研室河北保定071000 河北医科大学法医学院//河北省法医学重点实验室河北石家庄050017

目的探讨Rho/ROCK信号通路在束缚应激诱导大鼠杏仁核血脑屏障损伤过程中的作用及机制。方法选取60只SPF级雄性SD大鼠建立束缚应激模型,将大鼠分为4组:Control组(n=15,每日禁食水6 h);Stress组(n=15,每日束缚6 h);Stress+Fasudil组(n=15... 详细信息

目的探讨Rho/ROCK信号通路在束缚应激诱导大鼠杏仁核血脑屏障损伤过程中的作用及机制。方法选取60只SPF级雄性SD大鼠建立束缚应激模型,将大鼠分为4组:Control组(n=15,每日禁食水6 h);Stress组(n=15,每日束缚6 h);Stress+Fasudil组(n=15,每日束缚6 h,束缚前0.5 h给予腹腔注射1 mg/100 g Fasudil溶液);Fasudil组(n=15,每日给予腹腔注射1 mg/100 g Fasudil溶液)。用高架十字迷宫实验(EPM)检测各组大鼠行为学变化,ELISA检测血清CORT和S100B水平,检测脑组织伊文思蓝(EB)的渗漏情况以评估渗透性的改变,免疫荧光法和Western blotting方法检测紧密连接蛋白Claudin-5、Occludin、ZO-1的表达变化,Pull-down实验和Western blotting检测Rho/ROCK通路的激活情况,透射电镜观察脑微血管内皮细胞超微结构的形态变化。结果与Control组相比,Stress组和Stress+Fasudil组大鼠表现出了明显的焦虑样行为;Stress组和Stress+Fasudil组血清CORT含量均显著高于Control组(Pdil组相比,Stress组EB渗漏含量和S100B含量均显著升高(Pdil组(Pdil组;脑微血管内皮细胞超微结构显示,Stress组呈现显著的形态学改变。结论束缚应激能够通过激活Rho/ROCK信号通路诱导大鼠杏仁核血脑屏障的损伤。

关键词：束缚应激血脑屏障杏仁核 Rho/ROCK通路紧密连接渗透性