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Review:Development of lanthanum strontium cobalt ferrite composite cathodes for intermediate-to low-temperature solid oxide fuel cells

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2013年第1期14卷 11-24页

作者： Nurul Akidah BAHARUDDIN Hamimah Abd RAHMAN andanastuti muchtar Abu Bakar SULONG Huda ABDULLAH Fuel Cell Institute Universiti Kebangsaan Malaysia43600 UKM BangiSelangorMalaysia Faculty of Mechanical and Manufacturing Engineering Universiti Tun Hussein Onn Malaysia86400 BatuPahatJohorMalaysia Department of Mechanical and Materials Engineering Faculty of Engineering and Built EnvironmentUniversiti Kebangsaan Malaysia43600 UKM BangiSelangorMalaysia Department of Electrical Electronic and Systems EngineeringFaculty of Engineering and Built EnvironmentUniversiti Kebangsaan Malaysia43600 UKM BangiSelangorMalaysia

Solid oxide fuel cells （SOFCs） offer high energy conversion, low noise, low pollutant emission, and low processing cost. Despite many advantages, SOFCs face a major challenge in competing with other types of fuel cells because of their high operating temperature. The necessity to reduce the operational temperature of SOFCs has led to the development of research into the materials and fabrication technology of fuel cells. The use of composite cathodes significantly reduces the cathode polarization resistance and expands the triple phase boundary area available for oxygen reduction. Powder preparation and composite cathode fabrication also affect the overall performance of composite cathodes and fuel cells. Among many types of cathode materials, lanthanum-based materials such as lanthanum strontium cobalt ferrite （Lal_xSrxCOl_yFey03_~） have recently been discovered to offer great compatibility with ceria-based electrolytes in performing as composite cathode materials for intermediate- to low-temperature SOFCs （IT-LTSOFCs）. This paper reviews various ceria-based composite cathodes for IT-LTSOFCs and focuses on the aspects of progress and challenges in materials technology.

关键词： Ceria-based composite cathode Lanthanum strontium cobalt ferrite Intermediate- to low-temperature solid oxidefuel cells (IT-LTSOFCs)

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Recent advances and influencing parameters in developing electrode materials for symmetrical solid oxide fuel cells

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International Journal of Minerals,Metallurgy and Materials 2023年第10期30卷 1933-1956页

作者： Wan Nor Anasuhah Wan Yusoff Nurul Akidah Baharuddin Mahendra Rao Somalu andanastuti muchtar Nigel P.Brandon Huiqing Fan Solid Oxide Fuel Cell Group Fuel Cell InstituteUniversiti Kebangsaan Malaysia43600UKM BangiSelangorMalaysia Department of Mechanical and Manufacturing Engineering Faculty of Engineering and Built EnvironmentUniversiti Kebangsaan Malaysia43600UKM BangiSelangorMalaysia Faculty of Engineering 2.06 Faculty BuildingImperial College LondonSW72 AZUK State Key Laboratory of Solidification Processing School of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an 710072China

This article delivers a robust overview of potential electrode materials for use in symmetrical solid oxide fuel cells(S-SOFCs),a relatively new SOFC *** this end,this article provides a comprehensive review of recent advances and progress in electrode materials for S-SOFC,discussing both the selection of materials and the challenges that come with making that *** article discussed the relevant factors involved in developing electrodes with nano/***,e.g.,non-cobalt and lithiated materials,are only a few of the electrode types now being ***,the phase structure and microstructure of the produced materials are heavily influenced by the synthesis *** into the possibilities and difficulties of the material are *** achieve the desired microstructural features,this article focuses on a synthesis technique that is either the most recent or a better iteration of an existing *** portion of this analysis that addresses the risks associated with manufacturing and the challenges posed by materials when fabricating S-SOFCs is the most *** article also provides important and useful recommendations for the strategic design of electrode materials researchers.

关键词： nano composites electrode microstructure tailoring oxidation symmetrical solid oxide fuel cell

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电泳沉积固体氧化物燃料电池关键参数研究综述（英文）

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2018年第11期19卷 811-823页

作者： Isyraf AZNAM Joelle Chia Wen MAH andanastuti muchtar Mahendra Rao SOMALU Mariyam Jameelah GHAZALI Fuel Cell Institute Universiti Kebangsaan Malaysia Department of Mechanical and Materials Engineering Faculty of Engineering and Built EnvironmentUniversiti Kebangsaan Malaysia

目的:电泳沉积是一种简单且具有成本效益的涂层技术。其出色的形态特征控制,适用于制造需要每个组件层都具有其独特属性的固体氧化物燃料电池。本文旨在综述电泳沉积的最新进展、制备稳定悬浮液所需的关键因素以及通过电泳沉积技术制造... 详细信息

目的:电泳沉积是一种简单且具有成本效益的涂层技术。其出色的形态特征控制,适用于制造需要每个组件层都具有其独特属性的固体氧化物燃料电池。本文旨在综述电泳沉积的最新进展、制备稳定悬浮液所需的关键因素以及通过电泳沉积技术制造固体氧化物燃料电池所涉及的相关参数。创新点:1.分析了维持悬浮液稳定性的关键参数,包括粒径和固体载荷等胶体相关参数以及介电常数和电导率等悬浮介质相关参数。2.讨论了这些参数对粒子流动性、电动电位和电泳沉积技术于固体氧化物燃料电池应用的综合效应。方法:1.对以往的研究进行综述,并总结电泳沉积技术制造固体氧化物燃料电池组件层的发展(表1),包括稳定悬浮液的制备以及电泳沉积工艺关键参数的优化。结论:鉴于每个固体氧化物燃料电池组件层都涉及不同类型的材料,且每种材料都需要特定的参数来实现有效沉积,因此,为了获得各组件层所需要的性能,制备悬浮液配方的正确性和电泳沉积工艺的优化显得至关重要。

关键词：固体氧化物燃料电池电泳沉积悬浮稳定性电动电位胶体

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