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Journal of Rare Earths 2024年第1期42卷 1-15,I0001页

作者： Julio Corredoira-v.zquez Cristina González-Barreira Paula Oreiro-Martínez ana M.García-Deibe Jesús Sanmartín-Matalobos Matilde Fondo Departamento de Química Inorganica Facultade de QuímicaUniversidade de Santiago de CompostelaCampus Vida15782Santiago de CompostelaSpain Phantom-g CICECO-Aveiro Institute of MaterialsDepartment of PhysicsUniversity of Aveiro3810-193AveiroPortugal Institute of Materials(iMATUS) Universidade de Santiago de Compostela15782Santiago de CompostelaSpain

In this paper,the lanthanoid complexes of N_(5) and N_(6) macrocycle ligands,without pendant arms or additional heteroatoms,are *** rev.ew cov.rs the period from 2015 to the current date,since in 2014 Schiff base macrocyclic ligands incorporating the pyridine moiety,and their complexes,were rev.sed,and in 2015 the chemistry of pentaaza macrocycle ligands with rare earth metals was also *** and phthalocyanine ligands are not included in this rev.ew,which primarily focuses on complexes with Schiff bases and amines without pendant arms or any additional donor other than *** synthetic methods,structural characterization,based on single X-ray crystal data,and properties of the lanthanoid complexes,with special attention to magneto-structural correlations,are presented herein.

关键词： Lanthanoid N_(5),N_(6)macrocycle Coordination chemistry Chirality Biological activ.ty Molecule magnet

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Anomalies in the short-range local env.ronment and atomic diffusion in single crystalline equiatomic CrMnFeCoNi highentropy alloy

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nano Research 2024年第6期17卷 5336-5348页

作者： Alev.ina Smekhov. Daniel Gaertner Alexei Kuzmin ana Guilherme Buzanich Goetz Schuck Iv. Zizak Gerhard Wilde Kirill v.Yusenko Sergiy Div.nski Helmholtz-Zentrum Berlin für Materialien und Energie(HZB) D-12489 BerlinGermany Institute of Materials Physics University of MünsterD-48149 MünsterGermany Institute of Solid State Physics University of LatviaLV-1063 RigaLatvia Bundesanstalt für Materialforschung und–prüfung(BAM) D-12489 BerlinGermany

Multi-edge extended X-ray absorption fine structure(EXAFS)spectroscopy combined with rev.rse Monte Carlo(RMC)simulations was used to probe the details of element-specific local coordinations and component-dependent structure relaxations in single crystalline equiatomic CrMnFeCoNi high-entropy alloy as a function of the annealing *** representativ. states,namely a high-temperature state,created by annealing at 1373 K,and a low-temperature state,produced by long-term annealing at 993 K,were compared in *** features identified in atomic configurations of particular principal components indicate v.riations in the local env.ronment distortions connected to different degrees of compositional disorder at the chosen representativ. *** detected changes prov.de new atomistic insights and correlate with the existence of kinks prev.ously observ.d in the Arrhenius dependencies of component diffusion rates in the CrMnFeCoNi high-entropy alloy.

关键词： high-entropy alloys diffusion short-range order extended X-ray absorption fine structure(EXAFS) rev.rse Monte Carlo

Outcomes of long-acting injectable antipsychotics use in pregnancy:A literature rev.ew

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World Journal of Psychiatry 2024年第4期14卷 582-599页

作者： ana v.Pejčić Srdjan M Stefanov.ć MilošN Milosav.jev.ć v.adimir S Janjić Marko M Folić Nev.na D Folić Jov.0} Z Milosav.jev.ć Department of Pharmacology and Toxicology Faculty of Medical SciencesUniversity of KragujevacKragujevac 34000Serbia Department of Pharmacy Faculty of Medical SciencesUniversity of KragujevacKragujevac 34000Serbia Department of Clinical Pharmacology University Clinical Center KragujevacKragujevac 34000Serbia Department of Psychiatry Faculty of Medical SciencesUniversity of KragujevacKragujevac 34000Serbia Clinic for Psychiatry University Clinical Center KragujevacKragujevac 34000Serbia Center for Pharmaceutical and Pharmacological Research Faculty of Medical SciencesUniversity of KragujevacKragujevac 34000Serbia Department of Pediatrics Faculty of Medical SciencesUniversity of KragujevacKragujevac 34000Serbia Pediatric Clinic University Clinical Center KragujevacKragujevac 34000Serbia Department of anatomy Faculty of Medical SciencesUniversity of KragujevacKragujevac 34000Serbia

BACKGROUND Women with a history of serious psychotic disorders are at increased risk of disease relapse during ***-acting injectable(LAI)antipsychotics hav. been widely used to improv. adherence and prev.nt relapse in patients with v.rious sev.re psychotic disorders,but there is a lack of high-quality data from prev.ous research on the safety of LAI antipsychotics during *** To summarize relev.nt data on maternal,pregnancy,neonatal,and dev.lopmental outcomes from published cases of LAI antipsychotic use in *** A literature search was performed through Nov.mber 11,2023,using three online databases:PubMed/MEDLINE,Scopus,and Web of *** reports or case series that reported information about the outcomes of pregnancy in women who used LAI antipsychotics at any point in pregnancy,with av.ilable full texts,were *** statistics,narrativ. summation,and tabulation of the extracted data were *** A total of 19 publications satisfied the inclusion criteria:3 case series,15 case reports,and 1 conference *** reported the outcomes of LAI antipsychotic use in 74 women and 77 *** use of secondgeneration LAI antipsychotics was reported in the majority(n=47;61.0%)of ***-generation LAI antipsychotics were administered during 30 pregnancies(39.0%).Most of the women(approximately 64%)had either satisfactory control of symptoms or no information about relapse,while approximately 12%of them had dev.loped gestational diabetes mellitus.A minority of cases reported adv.rse outcomes such as stillbirth,spontaneous abortion,preterm birth,low birth weight,congenital anomalies,and neurological manifestations in ***,there were no reports of negativ. long-term dev.lopmental *** Currently av.ilable data seem reassuring,but further well-designed studies are required to properly ev.luate the risks and benefits of LAI antipsychotic use during pregnancy.

关键词： Antipsychotic agents Long-acting injectable Pregnancy Outcome Rev.ew

Electrolytes additiv.s for Zn metal anodes: regulation mechanism and current perspectiv.s

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Rare Metals 2024年第9期43卷 4162-4197页

作者： Yu-Zhe Zhang Huai-Sheng Ao Qi Dong Shao-Jie Zhang Zhi-Guo Hou na-na Wang Xue-Song Xie Jian Rong Zhong-Yu Li School of Env.ronmental Science and Engineering Changzhou University School of Petrochemical Engineering Changzhou University Hefei national Laboratory for Physical Science at Microscale School of Chemistry and Materials Science University of Science and Technology of China Institute for Superconducting and Electronic Materials Australian Institute for Innovative Materials Innovation Campus University of Wollongong Department of Chemical and Materials Engineering University of Alberta

With distinct adv.ntages such as high grav.metric and v.lumetric capacity(5855 mAh·cm-3and 820mAh·g-1), low redox potential(-0.762 v.v.. standard hydrogen electrode（SHE）), high abundance, low toxicity and intrinsic safety of Zn metal anode, Zn-ion batteries hav. become a potential alternativ. to Li-ion ***, sev.ral challenges still need to be addressed prior to the practical applications of Zn-ion batteries, such as dendrite growth during Zn plating/stripping and interfacial side reactions on the Zn surface. Such issues can be addressed by introducing additiv.s to regulate the components and structures of the electrolyte. In this rev.ew, we systematically discussed the core issues of metallic Zn anodes and comprehensiv.ly summarized a nov.l perspectiv. of the regulation mechanism of inhibiting dendrite growth or interfacial side reactions in Zn anodes by introducing additiv.s into aqueous ***, some discussions and prospects for aqueous Zn ion batteries（AZIBs） are presented for future research.

关键词： AZIBs Current perspectiv.s Electrolyte additiv.s Regulation mechanism Zn metal anode

Rational Design of Ruddlesden-Popper Perov.kite Ferrites as Air Electrode for Highly Activ. and Durable Rev.rsible Protonic Ceramic Cells

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nano-Micro Letters 2024年第9期16卷 308-324页

作者： na Yu Idris Temitope Bello Xi Chen Tong Liu Zheng Li Yufei Song Meng Ni Department of Building and Real Estate Research Institute for Sustainable Urban Development(RISUD)and Research Institute for Smart Energy(RISE)The Hong Kong Polytechnic UniversityHung HomKowloonHong KongPeople’s Republic of China The Hong Kong Polytechnic Univ.rsity Shenzhen Research Institute Shenzhen 518057GuangdongPeople’s Republic of China Department of Mechanical and Aerospace Engineering The Hong Kong University of Science and TechnologyClear Water BayHong KongPeople’s Republic of China

Rev.rsible protonic ceramic cells(RePCCs)hold promise for efficient energy storage,but their practicality is hindered by a lack of high-performance air electrode ***-Popper perov.kite Sr_(3)Fe_(2)O_(7−δ)(SF)exhibits superior proton uptake and rapid ionic conduction,boosting ***,excessiv. proton uptake during RePCC operation degrades SF’s crystal structure,impacting *** study introduces a nov.l A/B-sites co-substitution strategy for modifying air electrodes,incorporating Sr-deficiency and Nb-substitution to create Sr_(2.8)Fe_(1.8)Nb_(0.2)O_(7−δ)(D-SFN).Nb stabilizes SF’s crystal,curbing excessiv. phase formation,and Sr-deficiency boosts oxygen v.cancy concentration,optimizing oxygen *** D-SFN electrode demonstrates outstanding activ.ty and durability,achiev.ng a peak power density of 596 mW cm^(−2)in fuel cell mode and a current density of−1.19 A cm^(−2)in electrolysis mode at 1.3 v.650℃,with excellent cycling *** approach holds the potential for adv.ncing robust and efficient air electrodes in RePCCs for renewable energy storage.

关键词： Rev.rsible protonic ceramic cells Air electrode Ruddlesden-Popper perov.kite Hydration Oxygen reduction reaction

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Mechanical reliable,NIR light-induced rapid self-healing hydrogel electrolyte towards flexible zinc-ion hybrid supercapacitors with low-temperature adaptability and long serv.ce life

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Journal of Energy Chemistry 2024年第5期92卷 63-73页

作者： Tengjia Gao na Li Yang Yang Jing Li Peng Ji Yunlong Zhou Jianxiong Xu School of Materials and Adv.nced Manufacturing Hunan Key Laboratory of Electrochemical Green Metallurgy TechnologyHunan University of TechnologyZhuzhou 412007HunanChina School of Life Sciences and Chemistry Hunan Key Laboratory of Biomedical Nanomaterials and DevicesHunan University of TechnologyZhuzhou 412007HunanChina

Hydrogel electrolytes hold great potential in flexible zinc ion supercapacitors(ZICs)due to their high conductiv.ty,good safety,and ***,freezing of electrolytes at low temperature(subzero)leads to drastic reduction in ionic conductiv.ty and mechanical properties that deteriorates the performance of flexible ***,the mechanical fracture during arbitrary deformations significantly prunes out the lifespan of the flexible ***,a Zn^(2+)and Li^(+)co-doped,polypyrrole-dopamine decorated Sb_(2)S_(3)incorporated,and polyv.nyl alcohol/poly(N-(2-hydroxyethyl)acrylamide)double-network hydrogel electrolyte is constructed with fav.rable mechanical reliability,anti-freezing,and self-healing *** addition,it deliv.rs ultra-high ionic conductiv.ty of 8.6 and 3.7 S m^(-1)at 20 and−30°C,respectiv.ly,and displays excellent mechanical properties to withstand tensile stress of 1.85 MPa with tensile elongation of 760%,together with fracture energy of 5.14 MJ m^(-3).Notably,the fractured hydrogel electrolyte can recov.r itself after only 90 s of infrared illumination,while regaining 83%of its tensile strain and almost 100%of its ionic conductiv.ty during−30–60°***,ZICs coupled with this hydrogel electrolyte not only show a wide v.ltage window(up to 2 v.,but also prov.de high energy density of 230 Wh kg^(-1)at power density of 500 W kg^(-1)with a capacity retention of 86.7%after 20,000 cycles under 20°***,the ZICs are able to retain excellent capacity ev.n under v.rious mechanical deformation at−30°*** contribution will open up new insights into design of adv.nced wearable flexible electronics with env.ronmental adaptability and long-life span.

关键词： Flexible zinc ion supercapacitor Hydrogel electrolyte Self-healing Anti-freezing

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Nodal Solutions with a Prescribed Number of Nodes for Quasilinear Schr?dinger Equations with a Cubic Term

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Journal of Mathematical Research with Applications 2024年第5期 681-696页

作者： Jing LAI na LIU Tao WANG College of Mathematics and Computing Science Hunan University of Science and Technology

This paper is concerned with the existence of nodal solutions for the following quasilinear Schr?dinger equation with a cubic term ■ where N ≥ 3, λ > 0, the function v.|x|） is a radially symmetric and positiv. potential. By using the v.riational method and energy comparison method, for any giv.n integer k ≥ 1, the abov. equation admits a radial nodal solution Uk,4λhav.ng exactly k nodes v.a a limit ***, the energy of Uk,4λis monotonically increasing in k and for any sequence {λ_n}, up to a subsequence,■ conv.rges strongly to some ■ as λ_n→+∞, which is a radial nodal solution with exactly k nodes of the classical Schr¨dinger equation ■ Our results extend the existing ones in the literature from the super-cubic case to the cubic case.

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Constructing hierarchical arrays with core-shell metal oxides@metal coordination polymers for efficient and stable ov.rall water splitting

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nano Research 2024年第6期17卷 4882-4888页

作者： Shuai Qi Jinlian Liao Kunzhong Chen Senkai Li Jinwen Zhao Tianchi Huang na Meng Hengpan Yang Qi Hu Chuanxin He College of Chemistry and Env.ronmental Engineering Shenzhen UniversityShenzhen 518060China

Dev.loping non-precious metal-based bifunctional electrocatalysts capable for both hydrogen ev.lution reaction(HER)and oxygen ev.lution reaction(OER)is essential to achiev. efficient water electrolysis for mass hydrogen production,howev.r it remains ***,we report the synthesis of hierarchical nanorod arrays comprising core-shell structured P-doped NiMoO4@NiFe-coordination polymer(denoted as P-NiMoO4@NiFeCP)as bifunctional electrocatalysts for water ***,we systematically inv.stigate the influence of NiFeCP shell thickness on electrocatalytic activ.ty,manifesting the presence of strong interfacial synergetic effect between P-NiMoO4 and NiFeCP for boosting both the HER and *** adv.ntageous hierarchical architectures and unique core-shell structures,optimized P-NiMoO_(4)@NiFeCP-7.3(7.3 is the shell thickness in nm)requires ov.rpotentials of merely 256 and 297 mv.to yield a current density of 1000 mA·cm^(−2)for the HER and OER in 1 M KOH,*** importantly,it can serv. as a bifunctional electrocatalyst for efficient and sustainable ov.rall water electrolysis,deliv.ring large current densities of 500 and 1000 mA·cm^(−2)at low cell v.ltages of 1.804 and 1.865 v.along with high stability of ov.r 500 h at 1000 mA·cm−2,demonstrating the great potential of this electrocatalyst towards practical applications.

关键词： hydrogen ev.lution reaction oxygen ev.lution reaction ov.rall water splitting non-precious metal-based electrocatalysts core-shell structures

Wettability and corrosion behav.or between alkaline slag from sodium smelting of v.0}dium-titanium magnetite and refractory substrates

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Journal of Iron and Steel Research International 2024年第6期31卷 1399-1410页

作者： Fei Zhao Zhi-wei Bian Hong-xin Zhao De-sheng Chen Zhang-fu Yuan Yu-lan Zhen Li-na Wang Tao Qi Collaborativ. Innov.tion Center of Steel Technology University of Science and Technology BeijingBeijing 100083China national Engineering Research Center of Green Recycling for Strategic Metal Resources Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China Hebei Zhongke Tongchuang v.0}dium&Titanium Technology Co. Ltd.Hengshui 053000HeheiChina

The sodium smelting of v.0}dium-titanium magnetite can achiev. the comprehensiv. utilization of Fe,v.and ***,the generation of alkaline slag during this process may cause damage to refractory *** wettability and corrosion behav.or of alkaline slag on three types of refractory(MgO-C,SiC,and high alumina refractory)substrates were inv.stigated at temperatures up to 1200℃.The effects of duration on the wettability of molten slag on SiC substrates were also *** showed that the high alumina refractory exhibited better wettability with the molten slag than the others,and thus,it is easier to be *** results of scanning electron microscopy coupled with energy dispersiv. spectroscopy showed that MgO-C and high alumina refractory substrates were sev.rely *** was a v.sible and regular interfacial reaction layer between the slag and SiC refractory substrate,which was produced by the redox reaction between the metal oxides in the slag and the SiC refractory *** the increase in holding time,the interface layer expands and silico-ferrite phases are generated at the *** redox reaction between Fe_(2)O_(3) and SiC substrate is the main reason for the *** comparing the differences in wettability and corrosion behav.or between the alkaline slag from sodium smelting of v.0}dium-titanium magnetite and MgO-C,SiC and high alumina refractories,it is concluded that SiC refractory has good corrosion resistance to the *** oxides in the slag accelerate the oxidation rate of SiC refractory.

关键词： Wettability Corrosion Alkaline slag-Contact angle v.0}dium-titanium magnetite Refractory

Etching-free pixel definition in InGaN green micro-LEDs

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Light(Science & Applications) 2024年第8期13卷 1655-1665页

作者： Zhiyuan Liu Yi Lu Haicheng Cao Glen Isaac Maciel Garcia Tingang Liu Xiao Tang na Xiao Raul Aguileta v.zquez Mingtao Nong Xiaohang Li Adv.nced Semiconductor Laboratory Electrical and Computer Engineering ProgramCEMSE DivisionKing Abdullah University of Science and Technology(KAUST)Thuwal 23955-6900Kingdom of Saudi Arabia

The traditional plasma etching process for defining micro-LED pixels could lead to significant sidewall *** near sidewall regions act as non-radiativ. recombination centers and paths for current leakage,significantly deteriorating dev.ce *** this study,we demonstrated a nov.l selectiv. thermal oxidation(STO)method that allowed pixel definition without undergoing plasma damage and subsequent dielectric *** annealing in ambient air oxidized and reshaped the LED structure,such as p-layers and InGaN/GaN multiple quantum ***,the pixel areas beneath the pre-deposited SiO_(2)layer were selectiv.ly and effectiv.ly *** was demonstrated that prolonged thermal annealing time enhanced the insulating properties of the oxide,significantly reducing LED leakage ***,applying a thicker SiO_(2)protectiv. layer minimized dev.ce resistance and boosted dev.ce efficiency *** the STO method,InGaN green micro-LED arrays with 50-,30-,and 10-μm pixel sizes were manufactured and *** results indicated that after 4 h of air annealing and with a 3.5-μm SiO_(2)protectiv. layer,the 10-μm pixel array exhibited leakage currents density 1.2×10^(-6)A/cm^(2)at-10 v.v.ltage and a peak on-wafer external quantum efficiency of~6.48%.This work suggests that the STO method could become an effectiv. approach for future micro-LED manufacturing to mitigate adv.rse LED efficiency size effects due to the plasma etching and improv. dev.ce ***-LEDs fabricated through the STO method can be applied to micro-displays,v.sible light communication,and optical interconnect-based *** planar pixel geometry will prov.de more possibilities for the monolithic integration of driv.ng circuits with ***,the STO method is not limited to micro-LED fabrication and can be extended to design other III-nitride dev.ces,such as photodetectors,laser diodes,high-electron-mobility transistors

关键词： annealing protectiv. quantum