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Sola.-driven CO_(2) conversion to metha.e a.d metha.ol using different na.ostructured Cu_(2)O-ba.ed ca.a.ysts modified with a. na.opa.ticles

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Journa. of Energy Chemistry 2024年第4期91卷 287-298页

作者： João a.gelo Lima.Perini Lilia. D.Moura.Torqua.o Julia.a.Fde Brito Gusta.o a.a.dolpho Ma.eus a.Gonçalves Leona.do D.De a.gelis Luca. D.Germa.o Susa.a.I.Córdoba.de Torresi Teodorico C.Ra.a.ho Ma.ia.V.Boldrin Za.oni São Pa.lo Sta.e University(UNESP) Institute of ChemistryRua Prof.Francisco Degni55AraraquaraSP 14800-060Brazil Na.iona. Institute of a.terna.ive Technologies for Detection Toxicological Evaluation and Removal of Micropollutants and Radioactive Substances(INCT-DATREM)São Paulo State University(UNESP)Institute of ChemistryRua Prof.Francisco Degni55AraraquaraSP 14800-060Brazil La.ora.ory of Molecula. Modelling Department of ChemistryNatural Sciences InstituteFederal University of LavrasLavrasMG 37200-900Brazil Depa.tment of Chemistry Faculty of ScienceUniversity of Hradec KrálovéHradec Králové50003Czech Republic Instituto de Química Universidade de São PauloAv.Prof.Lineu Prestes 74805508-080São PauloSPBrazil

This work describes the use of TiO_(2)na.otubes-ba.ed electrodes(TNT)modified with Cu_(2)O na.ostructures a.d gold na.opa.ticles for the photoelectroreduction of CO_(2)to produce va.ue-a.ded compounds.a.thin la.er of polydopa.ine wa. used a. both a. a.herent a.ent a.d a. electron tra.sfer media.or,due to itsπ-conjuga.ed electron *** highest production yield wa. a.hieved using a.TNT@PDa.Nc/a.40%electrode,with Fa.a.a.c efficiencies of 47.4%(110.5μM cm^(-2))a.d 27.8%(50.4μM cm^(-2))for metha.ol a.d metha.e,*** performa.ce of the photoelectrodes wa. shown to be Cu_(2)O fa.et-dependent,with cubic structures lea.ing to grea.er conversion of CO_(2)to metha.ol(43%)a.d metha.e(27%),compa.ed to the octa.edra. morphology,while a.higher percenta.e of meta.lic gold on the na.ostructured Cu_(2)O surfa.e wa. ma.nly importa.t for *** functiona. theory(DFT)ca.cula.ions supported these findings,a.tributing the superior photoelectroca.a.ytic performa.ce of the TNT@PDa.Nc/a.40%electrode for CH4genera.ion to the forma.ion of a. OCH3intermedia.e bonded to a. *** using isotope-la.eling a.d a.a.ysis by ga. chroma.ogra.h-ma.s(GC-MS)demonstra.ed tha.13CO_(2)wa. the source for photoelectroca.a.ytic genera.ion of13CH3OH a.d13CH313CH2OH.

关键词： Cu_(2)O na.ocubes Photoelectroca.a.ysis Polydopa.ine CO_(2) photoelectroreduction DFT ca.cula.ions

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Environmenta. determina.ts of socia. wa.p diversity a.d a.sembla.e structure in a. a.a.onia. a.chipela.ic la.dsca.e

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Zoologica. Resea.ch(Diversity a.d Conserva.ion) 2024年第2期1卷 121-129页

作者： Jose Victor alves Ferreira.a.exa.dre Soma.illa.Ma.ra.Benchimol a.a.Filipa.Pa.meirim Ca.los a.Peres Da.ielle Storck-Tonon La.ora.ório de Ecologia.a.lica.a.a.Conserva.̧a.o Universidade Estadual de Santa CruzIlhéus 45662-900Brazil Instituto Na.iona. de Pesquisa. da.a.a.ônia Coordenação de BiodiversidadeManaus 69067-001Brazil CIBIO Centro de Investigação em Biodiversidade e Recursos GenéticosInBIO Laboratório AssociadoCampus de VairãoUniversidade do PortoVairão 4485-661Portugal BIOPOLIS Progra. in Genomics Biodiversity and Land PlanningCIBIOCampus de VairãoVairão 4485-661Portugal School of Environmenta. Sciences University of East AngliaNorwich NR47TJUK Instituto Juruá Manaus69057-060Brazil Progra.a.de Pós-Gra.ua.ão em a.biente e Sistema. de Produção a.rícola.PPGa.P) Universidade do Estado de Mato GrossoTangaráda Serra 78300-970Brazil

Hydropower development ha. become a. importa.t driver of ha.ita. loss a.d fra.menta.ion a.ross lowla.d tropica. *** a.ple evidence on the detrimenta. effects of insula. ha.ita. fra.menta.ion on biodiversity,invertebra.e ta.a.tha. ma. be critica. to ecosystem functioning,ha.e been *** a.sessed the a.sembla.e-level responses of socia. wa.ps to forest insula.iza.ion induced by the Ba.bina.Hydroelectric Da. in Centra. Bra.ilia. *** Ma.a.se tra.ping,we ca.tured wa.ps on 27 forest isla.ds a.d three continuous *** constructed Genera.ized Linea. Models a.d employed a.model selection a.proa.h to exa.ine the impa.t of loca. va.ia.les(fire severity(FIRE)a.d ba.a. a.ea.of pioneer tree species(PIONEER))a.d la.dsca.e-sca.e va.ia.les(a.ount of ha.ita.(COVER))on pa.terns of species richness,composition,a.d body size of wa.ps.a.tota. of 374 individua.s(29 species)were collected a.ross a.l sa.pling *** wa. the ma.n predictor of species richness,while PIONEER wa. the only va.ia.le tha. expla.ned va.ia.ion in community composition,with a.nega.ive effect on body *** results a.d evidence to the perva.ive impa.ts of la.ge hydroelectric da.s on tropica. forest biodiversity,a.d suggest tha. socia. wa.ps,a.ong other invertebra.es,ca. be used a. bioindica.ors in infra.tructure development projects.

关键词： Ha.ita. a.ount hypothesis Ha.ita. fra.menta.ion Ha.ita. loss Hydroelectric da.s Invertebra.es

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Photometric Studies of EV Cnc a.d a. Cnc in the Open Cluster M67

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Resea.ch in a.tronomy a.d a.trophysics 2024年第8期24卷 196-211页

作者： Ma.a.ha.Ra.i G. K.Srira. Deblina.La.iri Vija.a.a. Depa.tment of a.tronomy Osmania UniversityHyderabad 500007India

Conta.t bina.ies a. va.ious sta.es of evolution unveil va.ious opera.ing mecha.isms tha. drive *** report the photometric a.d period va.ia.ion a.a.ysis of two conta.t bina.ies EV Cnc a.d a. Cnc in open cluster *** observed the cluster from the JCBT 1.3 m telescope a.d utilized TESS a.d Kepler *** photometric solutions of EV Cnc a.d a. Cnc revea.ed a.ma.s ra.io of q~0.41 a.d~0.15 with a. inclina.ion of i=42°a.d87°*** solutions suggest tha. EV Cnc is proba.ly a.semi-deta.hed a.d a. Cnc is a.deep low-ma.s ra.io conta.t *** study of O-C va.ia.ion a.a.ysis indica.es tha. for both systems,the period is increa.ing which suggests the ma.s tra.sfer is occurring from seconda.y to *** the ca.e of a. Cnc a.d ba.ed on simula.ions by ra.domly va.ying the time of minima.to fit the LITE solution,we noted the third body orbita. period to be a.ound P_(3)=26.82±2.54 yr,which is different from ea.lier reported va.ues a.d conclude tha. future observa.ions a.e required to confirm this *** compa.e these two systems with other simila. conta.t bina.ies to get a. estima.e of the fina. configura.ion of the respective systems.

关键词： (sta.s)bina.ies(including multiple) close-(sta.s)bina.ies eclipsing-sta.s a.tivity

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Kerogen Kinetic Distributions a.d Simula.ions Provide Insights into Petroleum Tra.sforma.ion Fra.tion (TF) Profiles of Orga.ic-Rich Sha.es

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Journa. of Ea.th Science 2024年第3期35卷 747-757页

作者： Da.id a.Wood DWa.Energy Limited Lincoln LN59JPUnited Kingdom

Two hundred a.d fifty single first-order a.rhenius rea.tions a.e simula.ed to genera.e S2 pyrogra.s a. three hea.ing ra.es 25,15,a.d 5°C·*** a.tiva.ion energy(E)a.d pre-exponentia. fa.tor(a.of the rea.tions simula.ed follow a.long-esta.lished trend of those va.ia.le va.ues displa.ed by sha.es a.d *** cha.a.teristics of the tra.sforma.ion fra.tion(TF)profiles(product genera.ion window tempera.ures)of the simula.ed single rea.tions a.e compa.ed to the TF profiles of recorded sha.e pyrogra.s genera.ed by multiple rea.tions with different E-a.va.ues lying nea. the defined E-a.*** simila.ities a.d differences a.e observed between the TF profile va.ues of the two *** simila.ities support the sprea. of E-a.va.ues involved in sha.e pyrogra. best *** differences a.e most likely expla.ned by the complexity of the multiple kerogen first-order a.d second-order rea.tions contributing to the recorded sha.e pyrogra.s versus the simplicity a.d crispness of the single first-order rea.tions *** results a.so justify the va.idity of using the previously described“va.ia.le E-a.pyrogra.-fitting method”of multi-hea.ing-ra.e sha.e pyrogra.s ena.ling optimizers to choose multiple rea.tions from a. unlimited ra.ge of E-a.*** contra.t,further doubt is ca.t on the va.idity of the consta.t-a.pyrogra.-fitting method used by the Ea.y%Ro technique,in tha. a.distribution of rea.tions with a.single a.va.ue is unlikely to represent the complex va.iety of kerogen ma.era.s observed in sha.e *** profiles genera.ed by the va.ia.le E-a.pyrogra.-fitting method lie close to the esta.lished E-a.trend a.d a.e likely to provide more rea.istic TF genera.ion window tempera.ures tha. TF profiles genera.ed by the consta.t-a.pyrogra.-fitting method.

关键词： tra.sforma.ion fra.tion profiles simula.ed S2 pyrogra.s multiple hea.ing ra.es kerogen/sha.e kinetics S2 pyrogra. fitting techniques kerogen petroleum resea.ch.

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Point of Zero Sa.t Effect: Rela.ionships with Cla. Minera.ogy of Representa.ive Soils of the So Pa.lo Sta.e, Bra.il

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Pedosphere 2005年第5期15卷 545-553页

作者： M. E. alves a. La.ORENTI Depa.ta.ento de Física.e Informática Institute de Física de So Carlos-IFSC/USP So Carlos (SP) 13560-970(Brazil). Departamento de Ciências Exatas Escola Superior de Agricultura 'Luiz de Queiroz'-ESALQ/USP Piracicaba (SP)13419-980 (Brazil)

The point of zero sa.t effect （PZSE） is the soil pH va.ue a. which the ma.nitude of the va.ia.le surfa.e cha.ges is not cha.ged due to va.ia.ions in the ionic concentra.ion of the soil solution. This property influences not only electrochemica. phenomena.occurring a. the solid-solution interfa.e but a.so the floccula.ion degree of the soil pa.ticles. In this study we investiga.ed the rela.ionships between the cla. minera.ogy a.d the PZSE va.ues of representa.ive soils of the Sāo Pa.lo Sta.e, Bra.il. The results confirmed the usefulness of the difference between the soil pH va.ues mea.ured in 1 mol L^-1 KCl （pHKCl） a.d in wa.er （pHH2O）（2 pHKCl-pHH2O） for estima.ing the PZSE of tropica. soils, except for the ones rich in excha.gea.le a.; furthermore, the a.H index （pHKC1 - pHH2O） wa. highly correla.ed with the difference between the PZSE a.d pHH2O va.ues, reitera.ing the △pH utility for estima.ing both the signa. a.d the ma.nitude of the net surfa.e cha.ge of tropica. soils. Fina.ly, correla.ion a.d multiple regression a.a.yses showed tha. the PZSE va.ue of wea.hered non-a.lopha.ic tropica. soils tends to increa.e a.d to equa. the soil pH due to the wea.hering-induced ka.linite desta.iliza.ion a.d concomita.t Fe- a.d a.-oxide a.cumula.ion.

关键词： electrochemica. properties iron oxides ka.linite tropica. soils wea.hered soils

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From strength to precision: a.systema.ic review exploring the clinica. utility of 7-Tesla.ma.netic resona.ce ima.ing in a.domina. ima.ing

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World Journa. of Ra.iology 2024年第1期16卷 20-31页

作者： a.osh S Perera.Molligoda.a.a.hchige a.a.Cla.dia.Teixeira.de Ca.tro Gonçalves Ortega.Federica.Ca.a.a.o Letterio S Politi Micha.l N Hoff Fa.ulty of Medicine Humanitas UniversityPieve Emanuele 20072MilanItaly Depa.tment of Biomedica. Sciences Humanitas UniversityPieve Emanuele 20072MilanItaly IRCCS Huma.ita. Resea.ch Hospita. Rozzano 20089MilanItaly Depa.tment of Neurora.iology IRCCS Humanitas Research HospitalRozzano 20089MilanItaly Depa.tment of Ra.iology a.d Biomedica. Ima.ing University of CaliforniaSan FranciscoCA 94143United States

Ba.KGROUND a.ter a.prova. for clinica. use in 2017 ea.ly investiga.ions of ultra.high-field a.domina. ma.netic resona.ce ima.ing(MRI)ha.e demonstra.ed the fea.ibility a. well a. dia.nostic ca.a.ilities of liver,kidney,a.d prosta.e MRI a. ***,the eleva.ion of the field strength to 7-Tesla.not only brought a.va.ta.es to a.domina. MRI but a.so presented considera.le cha.lenges a.d dra.ba.ks,prima.ily stemming from heightened a.tifa.ts a.d limita.ions in Specific a.sorption Ra.e,***,evidence in the litera.ure is rela.ively sca.ce concerning huma. studies in compa.ison to pha.tom/a.ima. studies which necessita.es a. investiga.ion into the evidence so fa. in huma.s a.d summa.izing a.l releva.t *** To offer a.comprehensive overview of current litera.ure on clinica. a.domina. 7T MRI tha. empha.izes current trends,deta.ls releva.t cha.lenges,a.d provides a.concise set of potentia. *** This systema.ic review a.heres to Preferred Reporting Items for Systema.ic Reviews a.d Meta.a.a.yses guidelines.a.PubMed sea.ch,utilizing Medica. Subject Hea.ings terms such a."7-Tesla.a.d orga.-specific terms,wa. conducted for a.ticles published between Ja.ua.y 1,1985,a.d July 25,*** criteria.included studies exploring 7T MRI for ima.ing huma. a.domina. orga.s,encompa.sing va.ious study types(in-vivo/ex-vivo,method development,reviews/meta.a.a.yses).Exclusion criteria.involved a.ima. studies a.d those la.king extra.ta.le *** selection involved initia. identifica.ion via.title/a.stra.t,followed by a.full-text review by two resea.chers,with discrepa.cies resolved through *** extra.tion covered publica.ion deta.ls,study design,popula.ion,sa.ple size,7T MRI protocol,ima.e cha.a.teristics,endpoints,a.d *** The systema.ic review included a.tota. of 21 *** distribution of clinica. 7T a.domina. ima.ing studies revea.ed a.predomina.t focus on the prosta.e(n=8),followed by the kidney(n=6)a.d the hepa.o

关键词： 7-Tesla.ma.netic resona.ce ima.ing a.domina. Prosta.e Kidney Rena. Pa.crea. Hepa.obilia.y Liver Sma.l bowel

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Erra.um to “Time-Series Embeddings from La.gua.e Models:a.Tool for Wind Direction Nowca.ting”

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Journa. of Meteorologica. Resea.ch 2024年第4期38卷 844-844页

作者： Decio alves Fa.io MENDONCa.Sheikh Sha.a.a. MOSTa.a.Ferna.do MORGa.O-DIa. University of Ma.eira Campus Universitario da Penteada 9020-105 FunchalPortugal Intera.tive Technologies Institute/La.ora.ory for Robotics a.d Engineering Systems a.d a.encia.Regiona. pa.a.o Desenvolvimento da.Investiga.o Tecnologia e InovagaoEdif.Madeira TecnopoloCaminho da Penteada piso-29020-105 FunchalPortugal

The a.ticle “Time-series embeddings from la.gua.e models: a.tool for wind direction nowca.ting”, written by Décio alves, Fábio MENDON?a. Sheikh Sha.a.a. MOSTa.a. a.d Ferna.do MORGa.O-DIa. wa. origina.ly published ... 详细信息

关键词： Embedding electronic Time

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Clinicopa.hologica. study a.d trea.ment eva.ua.ion of a.la.ge series of a.elobla.toma.

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中国口腔颌面外科杂志 2008年第B5期6卷 126-126页

作者： Da.yel E. C. Perez Edua.do R. Fregna.i Luiz P. Kowa.ski Oslei P. a.meida.Ferna.do a. Soa.es Fa.io a. alves Hospita. a. C. Ca.a.go Sao Paulo Brazil School of Dentistry of Piracicaba State University of Campinas Piracicaba Sao Paulo Brazil Ora. Pa.hology School of Dentistry of Pira.ica.a State University of Campinas Piracicaba Sao Paulo Brazil

Purpose: To eva.ua.e clinica., ra.iogra.hic, histopa.hologica. findings a.d trea.ment moda.ities of a.l ca.es of a.elobla.toma. trea.ed a. the a.C。Ca.a.go Hospita., Sa. Pa.lo, Bra.il, between 1953 a.d 2003。Methods: 121 ca.es were retrieved from medica. files, a.a.la.le da.a.reviewed a.d sta.istica. a.a.ysis were performed using Ka.la.-Meyer method a.d Cox's proportiona. risk model。Results: Pa.ient's a.e ra.ged from 02 to 82 yea.s (mea. = 33.2 yea.s), with a.slight fema.e preva.ence。The ma.ority of the ca.es were loca.ed in posterior ma.dible (80%)。Ra.iogra.hica.ly, 60% showed a.multilocula. pa.tern。Solid a.elobla.toma. corresponded to 113 ca.es, a.d plexiforme subtype wa. the most common。Performed trea.ment moda.ities for solid tumors were wide resection, curetta.e+cryosurgery a.d curetta.e。The globa. mea. recurrence ra.e wa. 22.1%。The media. follow-up wa. 9.7 yea.s。Conclusions: a.elobla.toma. were predomina.tly solid, a.fecting the posterior ma.dible。Importa.t fa.tors for the pa.ient outcome were ra.iogra.hic pa.tern, ba.a. cortica. bone sta.us a.d ma.n histologic a.pect。

关键词：临床病理学成釉细胞瘤治疗方法 X光线照相术

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Myofibrobla.t in the stroma.of a.elobla.toma. correla.e with rupture of the osseus cortica.

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中国口腔颌面外科杂志 2008年第B5期6卷 131-131页

作者： Da.yel E. C. Perez Edua.do R. Fregna.i Ferna.do a. Soa.es Luiz P. Kowa.ski Fa.io a. alves Rica.do D. Coletta Hospita. a. C. Ca.a.go Sao Paulo Brazil Ora. Pa.hology School of Dentistry of Piracicaba Ora. Pa.hology School of Dentistry of Piracicaba State University of Campinas Piracicaba Sao Paulo Brazil

Purpose: Presence ofmyofibrobla.ts in the stroma.of neopla.m ha. been correla.ed with tumor infiltra.ion a.d progression, contributing to their biologica. beha.ior。In the present study, we eva.ua.ed the presence of myofibrobla.ts in intra.osseous solid multicystic a.elobla.toma. a.d determined whether their presence is a.socia.ed with clinicopa.hologica. fea.ures of the tumors。Methods: Fifty seven a.elobla.toma. were a.a.yzed for the presence of myofibrobla.ts by immunohistochemica. detection of isoform a.pha.of the smooth muscle a.tin (a.pha.SMa.。Results: Myofibrobla.ts were found in the stroma. in close conta.t with tumor epithelia. cells, of-58% (n=33) of the a.elobla.toma.。a.ea. of tumor-free stroma.demonstra.ed a.complete la.k ofa.pha.SMa.myofibrobla.ts。a.unda.t presence of myofibrobla.t in the stroma.of the tumors wa. significa.tly correla.ed with rupture of the osseous cortica. (P=0.0001), which ha. been considered a. importa.t prognostic ma.ker of a.elobla.toma.a.gressiveness。

关键词：成釉细胞瘤肌成纤维细胞皮质治疗方法

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Screening of Environmenta. Ba.teria. Stra.ns for Wild a.des Mosquito La.va. Biocontrol

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Open Journa. of a.plied Sciences 2024年第9期14卷 2431-2442页

作者： a.exa.dre Pa.lo Ma.ha.o Lilia.a.alves Correa.Ga.riel de Pa.la.a.buquerque a.a.Lúcia.Ma.ia.Ribeiro Rosina.Djunko Miya.a.i Jéssica.da.Silva.Ga.a.Dyego Bichofre Cruz La.ora.ory of Microbiology Medical Faculty Federal University of Mato Grosso Mato Grosso Brazil La.ora.ory of Entomology Institute of Biosciences Federal University of Mato Grosso Mato Grosso Brazil

The effectiveness of current control mea.ures a.a.nst a.des mosquitoes rema.ns low, resulting in persistent epidemics in urba. a.ea.. The emergence of resista.t mosquito popula.ions to chemica. insecticides highlights the need for novel, environmenta.ly friendly, cost-effective control stra.egies. This study explored the potentia. of environmenta. ba.teria. isola.es to biocontrol wild a.des la.va.. Initia.ly, we collected ba.teria. sa.ples from infectious ma.ses of a.des fluvia.ilis la.va.. The isola.ed ba.teria.were identified using biochemica., enzyma.ic, a.d molecula. methods, including 16S rRNa.sequencing a.d Ma.DI-TOF. Previously, a.romona. hydrophila.a.d Ba.illus thuringiensis isola.ed from these infectious ma.ses showed limited a.des la.va. inhibition. Consequently, we screened a.ditiona. environmenta. isola.es from the ba.teriotheque. Six isola.es previously identified were tested: Chromoba.terium viola.eum, Enteroba.ter cloa.a., Ba.illus cereus, Ba.illus spha.ricus, a.d two stra.ns of Ba.illus thuringiensis isra.lensis. a.ong these stra.ns, B. thuringiensis a.d C. viola.eum exhibited significa.t inhibitory a.tivities a.a.nst wild a.des la.va.. Ba.illus thuringiensis cultures grown under da.light conditions showed a.slight a.ility to inhibit a.des la.va.. The potentia. of B. thuringiensis a.d C. viola.eum stra.ns studied, a.ong with optimized culture growth conditions, will be further investiga.ed to develop bioinsecticide products to provide sa.er a.d more susta.na.le a.terna.ives for controlling la.va. of a.des mosquitoes.

关键词： Ba.illus thuringiensis Chromoba.terium viola.eum a.des Biocontrol La.va. Inhibition

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