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World Journal of Nano Science and Engineering 2012年第3期2卷 117-125页

作者： Nadiia A.Ivashchenko Wojciech Gac valentyn A.Tertykh viktor v.Yanishpolskii Sergei A.Khainakov alla v.dikhtiarenko Sylwia Pasieczna-Patkowska Witold Zawadzki Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine KyivUkraine Faculty of Chemistry Maria Curie-Skłodowska UniversityLublinPoland Department of Organic and Inorganic Chemistry Faculty of ChemistryUniversity of OviedoOviedoSpain

Novel in-situ reduction approach was applied for the synthesis of palladium nanoparticles in the pores of mesoporous silica materials with grafted siliconhydride groups. Matrices possessing different structural properties (MCM-41, SBA-15 and Silochrom) were used. Samples were studied by nitrogen adsorption-desorption method, low-angle X-ray diffraction, transmission electron microscopy (TEM) and FT-IR/PAS spectroscopy. The temperature-programmed oxidation (TPO) and reduction (TPR) methods were applied to examine reducibility of palladium species. Palladium containing catalysts were tested in methane oxidation reaction. It was demonstrated that relatively large pores in SBA-15 type silica facilitated formation of well-dispersed palladium nanoparticles confined in the pores channels. In the case of MCM-41 support, metallic palladium nanoparticles were formed on the external surface. The obtained materials showed high catalytic activity. Lower activity of the samples containing small crystallites located in the pore volume at high temperatures was related to worse accessibility of active sites to the reation mixture.

关键词： Palladium Nanoparticles Siliconhydride Groups Mesoporous Ordered Silica MCM-41 SBA-15 Palladium-Containing Nanocomposites Methane Oxidation

Artificial enhancement of sturgeon stock in freshwater reservoirs:A case study on sterlet Acipenser ruthenus of the Kama reservoir

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Aquaculture and Fisheries 2024年第2期9卷 287-294页

作者： Pavel B.Mikheev Semyon N.Kazarinov alla G.Melnikova Stanislav v.Ponosov Nikolai G.Petrenko Andrei I.Nikiforov Alexey Yu Puzik Olga N.Elchenkova Perm State National Research University Perm614990Russia Khabarovsk Branch of the Federal State Budget Scientific Institution“Russian Federal Research Institute of Fisheries and Oceanography”“KhabarovskNIRO” Khabarovsk680038Russia Perm Branch of the Federal State Budget Scientific Institution“Russian Federal Research Institute of Fisheries and Oceanography”“PermNIRO” Perm614991Russia Federal State Budget Scientific Institution“Russian Federal Research Institute of Fisheries and Oceanography”“vNIRO” Moscow117454Russia Moscow State Institute of International Relations(University)of the Ministry for Foreign Affairs of Russia“MGIMO” Moscow117454Russia Department of State Control Supervision and Protection of Aquatic Biological Resources for Perm KraiMiddle-Volga Regional Office of the Federal Fishery AgencyPerm614990Russia

The paper presents the results of the sterlet sturgeon Acipenser ruthenus reintroduction into the Kama Reservoir(Perm Krai,Russia)by sterlet fry from hatcheries into the reservoir since *** effectiveness of hatchery releases was evaluated by monitoring gillnet sampling *** results showed that the species was reported throughout entire Kama Reservoir,which contrasts with 1988-1994 data,when the species was registered only at the upper part of the reservoir near the Kama River *** highest number and biomass values of catch per unit effort(CPUE)of the sterlet were found in submerged river channels-the deepest habitats with flow conditions which are close to the ecological requirements of the *** distribution of the sterlet within the channel biotopes of the reservoir is defined by reduced *** biggest individuals and the widest size range of the sterlet were typical for the upper area of the reservoir and Chusovskoy Bay,which have the greatest *** smallest sizes were typical for fish from catches near the dam of the reservoir,which is consistent with the published data on the distribution of sterlet in reservoir *** presented results may indicate the artificial formation of the sterlet stock in the Kama Reservoir maintained by hatchery *** revealed distribution of the sterlet in the reservoir determines the direction of further research on natural reproduction and thus formation of an artificially formed ***,future studies are required to assess the possibility of hybridization of the sterlet of artificial origin with natural populations of the species,since the low genetic diversity of the sterlet released into the Kama Reservoir which can lead to irreversible loss of genetic individuality of the natural stocks of the species in the catchment of upper course of the Kama River.

关键词： Sterlet Acipenser ruthenus Kama reservoir Hatchery releases CPUE Artificial stock formation

Maximum power point tracking using decision-tree machine-learning algorithm for photovoltaic systems

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Clean Energy 2022年第5期6卷 762-775页

作者： P.venkata Mahesh S.Meyyappan RamaKoteswara Rao alla Department of Electronics and Instrumentation Engineering Annamalai UniversityChidambaramIndia Department of Instrumentation Engineering Madras Institute of TechnologyChennaiIndia Department of EEE RVR&JC College of EngineeringGunturIndia

This work presents a machine-learning(ML)algorithm for maximum power point tracking(MPPT)of an isolated photovoltaic(Pv)*** to the dynamic nature of weather conditions,the energy generation of Pv systems is *** there is no specific method for effectively dealing with the non-linear data,the use of ML methods to operate the Pv system at its maximum power point(MPP)is desirable.A strategy based on the decision-tree(DT)regression ML algorithm is proposed in this work to determine the MPP of a Pv *** data were gleaned from the technical specifications of the Pv module and were used to train and test the *** algorithms predict the maximum power available and the associated voltage of the module for a defined amount of irradiance and *** boost converter duty cycle was determined using predicted *** simulation was carried out for a 10-W solar panel with a short-circuit current of 0.62 A and an open-circuit voltage of 21.50 v at 1000 W/m^(2) irradiance and a temperature of 25℃.The simulation findings demonstrate that the proposed method compelled the Pv panel to work at the MPP predicted by DTs compared to the existing topologies such asβ-MPPT,cuckoo search and artificial neural network *** the proposed algorithm,efficiency has been improved by>93.93%in the steady state despite erratic irradiance and temperatures.

关键词： boost converter decision tree maximum power point tracking photovoltaic system regression machine learning

A detailed reconstruction of changes in the factors and parameters of soil erosion over the past 250 years in the forest zone of European Russia(Moscow region)

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International Soil and Water Conservation Research 2022年第1期10卷 149-160页

作者： Andrey Zhidkin Daria Fomicheva Nadezhda Ivanova Tomas Dostal alla Yurova Mikhail Komissarov Josef Krasa v.v.dokuchaev soil science institute pyzhevskiy pereulok 7moscow119017russian federation Faculty of geography lomonosov moscow state universityleninskie gorygsp-1moscow119991russian federation Department of landscape water conservation faculty of civil engineeringczech technical university in praguethakurova 7prague16629czech republic Ufa institute of biology ufrc russian academy of sciencespr.oktyabrya 69ufa450054russian federation

Accelerated soil erosion is a major threat to soil,and there are great variations in the rate of soil erosion over time due to natural and human-induced *** temperate forest zone of Russia is character-ized by complex stages of land-use history(*** urbanization,agricultural development,land abandonment,etc.).We have for the first time estimated the rates of soil erosion by the WaTEM/SEDEM model(rainfall erosion)and by a regional model(snowmelt erosion)over the past 250 years(from 1780 to 2019)for a 100-km2 study site in the Moscow region of *** calculations were made on the basis of a detailed historical reconstruction of the following factors:the location of the arable land,crop rotation,the rain erosivity factor,and the maximum snow water *** area of arable land has decreased more than 3.5-fold over the past 250 *** the end of the 20th century,the rates of gross erosion had declined more than 5.5-fold(from 28×10^(3) to 5×10^(3) t·ha^(-1)yr^(-1))in comparison with the end of the 18th *** in the boundaries of arable land and also the relief features had led to a significant intra-slope accumulation of *** a result of sediment redeposition within the arable land,the variation in net soil erosion was significantly lower than the variation in gross soil *** changes in arable land area and in crop composition are the factors that have to the greatest extent determined the changes in soil erosion in this territory.

关键词： Anthropogenic soil erosion Soil erosion history Crop rotation Magnetic tracer method WaTEM/SEDEM

Nitroxy-and azidomethyl azofurazans as advanced energetic materials

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Defence Technology（防务技术） 2022年第8期18卷 1369-1381页

作者： Aleksei B.Sheremetev Svetlana F.Mel'nikova Elizaveta S.Kokareva Ruslan E.Nekrutenko Kirill v.Strizhenko Kyrill Yu Suponitsky Thanh Dat Pham alla N.Pivkina valery P.Sinditskii Zelinsky Institute of Organic Chemistry Russian Academy of Sciences47 Leninsky ProspMoscow119991Russia Saint Petersburg State Institute of Technology 26 Moskovskii PrSt Petersburg190013Russia Mendeleev University of Chemical Technology Moscow125047Russia N.N.Semenov Federal Research Center for Chemical Physics Russian Academy of Sciences4 Kosygina Str119991MoscowRussia

Progress in the rocket industry is only possible on the basis of new, higher performance and more environmentally friendly materials compared to up-to-date propellant ingredients for liquid, solid, gelled and hybrid propellant systems. In this work, synthetic methods have been developed for the preparation of new energetic azofurazans bearing nitroxymethyl or azidomethyl groups. All prepared compounds were fully characterized by multinuclear NMR and IR spectroscopies, as well as elemental analyses. An analysis of the structural features based on the X-ray single-crystal diffraction made it possible to discuss their influence on the densities of the azofurazans of this study. Thermal decomposition and combustion of nitroxymethyl and azidomethyl azofurazans were studied using a number of complementary experimental techniques, namely thermogravimetry, differential scanning calorimetry, manometry, microthermocouple measurements in the combustion wave. The structural and physical characteristics of these new energetic analogues illustrate the extent to which the nature of the explosophoric groups can be used to tune the performace of the azofurazan framework. These azofurazans possess positive calculated enthalpy of formation and are promising candidates for new environmentally friendly energetic materials.

关键词： Azofurazan Azide Nitrate ester X-ray Combustion

A historical literature review of coronary microvascular obstruction and intra-myocardial hemorrhage as functional/structural phenomena

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The Journal of Biomedical Research 2023年第4期37卷 268-289页

作者： Leonid N.Maslov Natalia v.Naryzhnaya Sergey v.Popov Alexandr v.Mukhomedzyanov Ivan A.Derkachev Boris K.Kurbatov Andrey v.Krylatov Feng Fu Jianming Pei vyacheslav v.Ryabov Evgenii v.vyshlov Svetlana v.Gusakova alla A.Boshchenko Akpay Sarybaev Laboratory of Experimental Cardiology Cardiology Research InstituteTomsk National Research Medical Center of the Russian Academy of SciencesTomskTomsk Region 634012Russia Department of Physiology and Pathophysiology National Key Discipline of Cell BiologySchool of Basic Medicinethe Fourth Military Medical UniversityXi'anShaanxi 710032China Siberian State Medical University TomskTomsk Region 634050Russia National Center of Cardiology and Internal Medicine Bishkek 720040Kyrgyzstan.

The analysis of experimental data demonstrates that platelets and neutrophils are involved in the no-reflow phenomenon,also known as microvascular obstruction(MvO).However,studies performed in the isolated perfused hearts subjected to ischemia/reperfusion(I/R)do not suggest the involvement of microembolization and microthrombi in this *** intracoronary administration of alteplase has been found to have no effect on the occurrence of MvO in patients with acute myocardial ***,the major events preceding the appearance of MvO in coronary arteries are independent of microthrombi,platelets,and *** cells appear to be the target where ischemia can disrupt the endothelium-dependent vasodilation of coronary ***,reperfusion triggers more pronounced damage,possibly mediated by *** and intra-myocardial hemorrhage contribute to the adverse post-infarction myocardial ***,pharmacological agents used to treat MvO should prevent endothelial injury and induce relaxation of smooth *** conditioning protocols have been shown to prevent MvO,with L-type Ca2+channel blockers appearing the most effective in treating MvO.

关键词： heart ischemia reperfusion microvascular obstruction intra-myocardial hemorrhage

Thermobarometry of Inclusions: Implications to the Structure of Lithospheric Mantle and Evolution in Time and Diamond Formation

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Acta Geologica Sinica(English Edition) 2021年第S1期95卷 18-21页

作者： Igor v.ASHCHEPKOv alla M.LOGvINOvA Zdislav v.SPETSIUS v.S.Sobolev Institute of Geology and Mineralogy SB RAS Novosibirsk 630090Russia Alrosa Stock Company Mirny 678174Russia

Thermobarometric calculations for mineral diamond inclusions and associations(DIA)provide a systematic comparison of PTXFO2 conditions for different cratons worldwide,using a database of 4440 mineral EPMA analyses(Ash... 详细信息

关键词： diamond inclusions craton garnet clinopyrogene orthopyroxene geothermal regime manle lithosphere

How to stabilize standard perovskite solar cells to withstand operating conditions under an ambient environment for more than 1000 hours using simple and universal encapsulation

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Journal of Energy Chemistry 2023年第3期78卷 246-252,I0008页

作者： Nikolai A.Belich Andrey A.Petrov Pavel A.Ivlev Natalia N.Udalova alla A.Pustovalova Eugene A.Goodilin Alexey B.Tarasov Laboratory of New Materials for Solar Energetics Faculty of Materials ScienceLomonosov Moscow State University119991 MoscowRussia Department of Chemistry Lomonosov Moscow State University119991 MoscowRussia

We introduce a simple and universal scalable encapsulation strategy for perovskite solar cells based on thermal vacuum evaporation of MgF2or MoO3-xcapping layer followed by sealing the device with glass and Uv-curable *** proposed encapsulation method is beneficial to most of the other known encapsulation approaches being fully harmless to perovskite and transporting layers and processible at room *** deposition of the capping layer promotes efficient removal of water,oxygen and organic solvent residuals from the device prior to sealing and could be easily performed using standard equipment for metal electrode *** proposed strategy is transferrable to any lab-scale perovskite solar cell prototypes regardless of their geometry and architecture and results in excellent stability of the devices in ambient air and long operating *** the 1000 hours stability test at ambient air(30%-60% RH),the cells preserved 92.9% of their initial efficiency on average under 1 Sun illumination at constant maximum power point tracking(MPPT,ISOS-L-1) and over 96% under sto rage in the dark(ISOS-D-1),thus evidencing for the high effectiveness of the proposed encapsulation approach.

关键词： Perovskite solar cells Halide perovskites Encapsulation High stability ISOS-L-1

Do reactive oxygen species damage or protect the heart in ischemia and reperfusion?Analysis on experimental and clinical data

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The Journal of Biomedical Research 2023年第4期37卷 255-267页

作者： Leonid N.Maslov Natalia v.Naryzhnaya Maria Sirotina Alexandr v.Mukhomedzyanov Boris K.Kurbatov alla A.Boshchenko Huijie Ma Yi Zhang Feng Fu Jianming Pei viacheslav N.Azev vladimir A.Pereverzev Cardiology Research Institute Tomsk National Research Medical Centerthe Russian Academy of SciencesTomskTomsk Region 634012Russia Department of Physiology Hebei Medical UniversityShijiazhuangHebei 050017China Department of Physiology and Pathophysiology National Key Discipline of Cell BiologySchool of Basic Medicinethe Fourth Military Medical UniversityXi'anShaanxi 710032China The Branch of the Institute of Bioorganic Chemistry Russian Academy of SciencesPushchinoMoscow Oblast 142290Russia Department of Normal Physiology Belarusian State Medical UniversityMinsk 220083Belarus

The role of reactive oxygen species(ROS)in ischemic and reperfusion(I/R)injury of the heart has been discussed for more than 40 *** has been demonstrated that reperfusion triggers a multiple increase in free radical generation in the isolated *** were found to have the ability to mitigate I/R injury of the ***,it is unclear whether their cardioprotective effect truly depends on the decrease of ROS levels in myocardial *** high doses and high concentrations of antioxidants were experimentally used,it is highly likely that the cardioprotective effect of antioxidants depends on their interaction not only with free radicals but also with other *** has been demonstrated that the antioxidant N-2-mercaptopropionyl glycine or NDPH oxidase knockout abolished the cardioprotective effect of ischemic ***,there is evidence that ROS protect the heart against the I/R injury.

关键词： reactive oxygen species free radicals antioxidants heart reperfusion patients

Early Holocene climate signals from stable isotope composition of ice wedges in the Chara Basin,northern Transbaikalia,Russia

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Geoscience Frontiers 2018年第2期9卷 471-483页

作者： Yurij K.vasil’chuk alla C.vasil’chuk Julia v.Stanilovskaya Geography and Geology Departments Lomonosov Moscow State UniversityMoscowRussia Sergeev Environmental Geoscience Institute of the Russian Academy of Sciences Russia

Stable isotope composition of syngenetic and epigenetic ice wedges, radiocarbon age, and pollen spectra of the surrounding deposits were studied during long term investigations at the "Belyi Klyuch" site on the first(6-8 m height) terrace of the Chara River(720 m.a.s.l.) in northern Transbaikalia to assess climatic conditions during ice-wedge formation. It was revealed that Holocene ice wedges had been formed from 10 to 7.5 ka 14 C BP. The isotope composition(δ^(18)O, δ~2 H) of relict ice wedges is the lightest and amounts-23‰ and-185‰, correspondingly. The isotopic compositions of ice lenses from sandy loam above ice wedges are-15.7‰, and-133‰; of small ice wedge in peat and sand are-15.3‰ and-117.9‰, *** of the ice wedge isotope composition has yielded that mean winter temperatures during cold stages of Holocene optimum were lower than today, during warm stages they were close to modern ones. During the coldest stages of Holocene optimum the total annual freezing index varied from-5100 to-5700 ℃ degree days, i.e. 300-600 ℃ degree days colder than during extremely severe modern winters. The total annual thawing index varied from 1300 to 1800 ℃ degree days, which was slightly higher than modern ones.

关键词： Holocene Ice wedge Stable isotopes Southern permafrost areas Northern Transbaikalia