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Green bio-synthesis of Ni/montmorillonite nanocomposite using extract of Allium jesdianum as the nano-catalyst for electrocatalytic oxidation of methanol

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Chinese Journal of Chemical Engineering 2020年第10期28卷 2555-2565页

作者： Mohammad Hossein Sheikh-Mohseni Sajjad Sedaghat Pirouz Derakhshi aliakbar safekordi Department of Chemistry Science and Research BranchIslamic Azad UniversityTehranIran Department of Chemistry Shahr-e-Qods BranchIslamic Azad UniversityShahr-e-QodsIran Department of Chemistry North Tehran BranchIslamic Azad UniversityTehranIran

In this work,synthesis of Ni nanoparticles was carried out successfully by water extract of Allium jesdianum as a biochemical reducing agent in the presence of montmorillonite clay(MMT)as a natural solid support for the first *** the electrochemical activity of the synthesized nanocomposite was investigated in methanol electrocatalytic *** with high cation exchange capacity and nano layer structure was exposed to ion exchange conditions in nickel *** Ni^2+ion exchanged form was used in this process as a source of ions and also capping *** extract of Allium jesdianum used as a reducing agent due to abundant availability of phenolic and flavonoid *** synthesized Ni/MMT nanocomposite was characterized using UV–Vis spectroscopy(UV–Vis),Fourier Transform Infrared Spectroscopy(FT-IR),X-ray diffraction(XRD),Scanning Electron Microscopy(SEM),Transmission electron microscopy(TEM)and Energy-dispersive X-ray spectroscopy(EDX).The surface of prepared modified electrode has been characterized using SEM to evaluate the morphology,showing uniform dispersion of Ni nanoparticles with mean diameter of 12 to 20 *** modified carbon paste electrode was then used in methanol electrocatalytic oxidation *** oxidation on the proposed modified electrode surface occurs at 0.6 V and 0.3 V in alkaline and acidic medium ***,the results showed the better performance of modified electrode toward methanol electrocatalytic oxidation in comparison with carbon paste electrode that is modified by ion exchanged *** transfer coefficients and apparent charge transfer rate constant for the modified electrode in the absence of methanol in alkaline medium were respectively found as:αa=0.53,αc=0.37 and ks=1.6×10^-1 s^-***,the average value of catalytic rate constant for the electrocatalytic oxidation of methanol by the prepared nano-catalyst was estimated to be about 0.9 L·mol^-1·s^-1 by chronoamperometry *** prepare

关键词： Green biosynthesis Nanoparticles Montmorillonite Biocatalysis Methanol electrocatalytic oxidation Fuel cell

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Effect of Sintering Temperature on Microstructure and Hydrogen Permeation Properties of Perovskite Membrane

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Journal of Materials Science & Technology 2013年第2期29卷 137-141页

作者： Marzieh Heidari Akbar Zamaniyan aliakbar safekordi Ensieh Ganji Babakhani Mahdi Amanipour Chemical Engineering Department Sharif University of Technology Gas Department Research Institute of Petroleum Industry

The BaCe0.9Y0.1O3-δ （BCY） perovskite membrane was successfully synthesized by liquid citrate method. The phase structure of the powder was characterized by X-ray diffraction （XRD）. Scanning electron microscopy （SEM） was used to characterize microstructures of the membrane sintered under various conditions. Sintering temperatures and dwell time during sintering influence the final microstructure of the ceramic. Results showed that increasing sintering temperature resulted in a dense membrane with clear grains. An increase of dwell time was favorable to produce membranes with larger grains in the sintered ceramics. A density of 5.87 g/cm3 was reached for the membrane after sintering at 1200 ℃ with dwell time of 10 h. This resulted in the formation of dense membranes with clear structure and average grain size of 0.27 μm. The influence of microstructure on the hydrogen permeation flux through BCY was observed by measuring the hydrogen permeation flux, and the results showed that hydrogen permeation flux increases with increasing the average grain size of the membrane. From H2 permeation rates, it was found that bulk diffusion rather than surface reaction played the dominant role in H2 transport.

关键词： Ceramic membrane Perovskite Sintering Microstructure Hydrogen permeation

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Green bio-synthesis of Ni/montmorillonite nanocomposite using extract of Allium jesdianum as the nano-catalyst for electrocatalytic oxidation of methanol

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中国化学工程学报（英文版） 2020年第10期

作者： Mohammad Hossein Sheikh-Mohseni Sajjad Sedaghat Pirouz Derakhshi aliakbar safekordi

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