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Status and prospects for symmetric organic redox flow batteries

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Journal of Energy Chemistry 2025年第1期100卷 125-143页

作者： Md al Raihan C.Adam Dyker Department of Chemistry University of New Brunswick

As environmental concerns from fossil fuel consumption intensify, large-scale energy storage becomes imperative for the integration of renewable sources like wind, hydro, and solar with the electrical *** flow batteries, particularly those employing organic molecules, are positioned as a key technology for this purpose. This review explores the growing field of symmetric organic redox flow batteries(ORFBs) within this context. Unlike traditional asymmetric designs based on unique active materials for each electrode, symmetric ORFBs involve a single bipolar species for both electrodes. This review highlights the benefits of a symmetric design, and categorizes five distinct classes of organic bipolar molecules used in both aqueous and non-aqueous solvents. By providing a comprehensive overview of their cell cycling and performance characteristics, the strengths and weaknesses of the diverse categories of bipolar molecules are highlighted for both solvent systems, as are opportunities for future development. This should guide new research directions and advance the development of practical symmetric ORFBs.

关键词： Redox flow battery Symmetric battery Organic battery Aqueous electrolyte Non-aqueous electrolyte

Nanosecond pulse and dual-wavelength Q-switched 1.5 μm fiber laser using MAX phase Cr2TialC2 saturable absorber

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Optoelectronics Letters 2025年第1期21卷 7-12页

作者： Ahmed Shakir al-HITI Hiba HASSAN Department of Electrical Engineering Faculty of Engineering University of Anbar Department of Laser and Optoelectronics Engineering University of Technology-Iraq

We demonstrated a new type of MAX phase material, chromium titanium aluminum carbide（Cr2TialC2） polymer film, to generate a passively Q-switched erbium-doped fiber laser（EDFL）. The film thickness was measured to be around 45 μm, which was fabricated using the embedding method with polyvinyl alcohol（PVA） polymer as hoster. The saturable absorber（SA） film demonstrates a dual-wavelength passively Q-switched EDFL which operates at 1 531 nm and 1 560.19 nm, respectively. The Q-switching pulse duration could be varied from 2.46 μs to 770 ns, while the repetition rate varied from 92.76 kHz to 106.6 kHz with an increasing input pumping range from 154 mW to 300 mW. The maximum output power and pulse energy of 15.05 mW and 141.18 nJ were obtained at the maximum input power of 300 mW, respectively.

关键词： Saturable absorbers

Comparative chemical sensor for detection of chromium(Ⅵ) in aqueous solution

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Optoelectronics Letters 2025年第1期21卷 21-27页

作者： Sura H.al-REKABI A.A.alWAHIB Electrical Technique Department Al Suwayrah Technical Institute Middle Technical University Laser and Optoelectronics Department University of Technology-Iraq

A process for purifying aqueous solutions containing heavy and toxic metals such as chromium（Cr） has been investigated. One of the extremely harmful pollutants in rivers and seawater is the heavy metal ions due to their direct impacts on human, animals and plants are hexavalent Cr（Ⅵ）. Consequently, highly sensitive sensor to detect Cr is essential. Surface plasmon resonance（SPR） technique has attracted huge research interest in detecting heavy metals specifically. In this study, three types of prism-based SPR sensor, gold（Au）/silver（Ag）, Au/polyaniline（PANI） and Au/titanium dioxide（TiO2） nanostructured films, are investigated as potential sensing material to detect the presence of Cr（Ⅵ） ions in water. The base Au layer with thickness of 48.3 nm is deposited on a glass slide for all sensors. For Au/Ag, Au/PANI nanofibers and Au/TiO2sensor films, the Cr（Ⅵ） concentration is varied from 1 ppm to 15 ppm with sensitivity of 0.270 °ppm-1, 0.082 °ppm-1and 0.039 °ppm-1, respectively. Based on these results, the Au/PANI nanofibers are the most sensitive to Cr（Ⅵ） among the tested sensing materials.

关键词： Titanium dioxide

Effects of P301L-TAU on post-translational modifications of microtubules in human iPSC-derived cortical neurons and TAU transgenic mice

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Neural Regeneration Research 2025年第8期20卷 2348-2360页

作者： Mohamed Aghyad al Kabbani Christoph Köhler Hans Zempel Institute of Human Genetics Faculty of Medicine and University Hospital CologneUniversity of CologneCologneGermany Center for Molecular Medicine Cologne(CMMC) University of CologneCologneGermany Center Anatomy Department ⅡMedical FacultyUniversity of CologneCologneGermany

TAU is a microtubule-associated protein that promotes microtubule assembly and stability in the *** is missorted and aggregated in an array of diseases known as *** are essential for neuronal function and regulated via a complex set of post-translational modifications,changes of which affect microtubule stability and dynamics,microtubule interaction with other proteins and cellular structures,and mediate recruitment of microtubule-severing *** impairment of microtubule dynamics causes neuronal dysfunction,we hypothesize cognitive impairment in human disease to be impacted by impairment of microtubule *** therefore aimed to study the effects of a disease-causing mutation of TAU(P301L)on the levels and localization of microtubule post-translational modifications indicative of microtubule stability and dynamics,to assess whether P301L-TAU causes stability-changing modifications to *** investigate TAU localization,phosphorylation,and effects on tubulin post-translational modifications,we expressed wild-type or P301L-TAU in human MAPT-KO induced pluripotent stem cell-derived neurons(i Neurons)and studied TAU in neurons in the hippocampus of mice transgenic for human P301L-TAU(p R5 mice).Human neurons expressing the longest TAU isoform(2N4R)with the P301L mutation showed increased TAU phosphorylation at the AT8,but not the p-Ser-262 epitope,and increased polyglutamylation and acetylation of microtubules compared with endogenous TAU-expressing neurons.P301L-TAU showed pronounced somatodendritic presence,but also successful axonal enrichment and a similar axodendritic distribution comparable to exogenously expressed 2N4R-wildtype-TAU.P301L-TAU-expressing hippocampal neurons in transgenic mice showed prominent missorting and tauopathy-typical AT8-phosphorylation of TAU and increased polyglutamylation,but reduced acetylation,of microtubules compared with non-transgenic *** sum,P301L-TAU results in changes in micr

关键词： human induced pluripotent stem cell microtubules P301L pR5 mice TAU tauopathy tubulin code

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The integration of FAO-CropWat Model and GIS Techniques for Estimating Irrigation Water Requirement and Its Application in the Gaza Strip

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Natural Resources 2011年第3期2卷 146-154页

作者： husam al-najar 不详

In the Gaza Strip irrigation practices are only based on the farmer’s own experience, they determine when and how to irrigate crops based on the appearance of the soil and the climatic conditions. Even though FAO-CropWat model is used for many countries to estimate irrigation water requirements, it is rarely used for Gaza Strip. In the current re-search, it is the first attempt to model the historical available meteorological data to estimate the irrigation water requirements for the most common cultivated crops (citrus, almonds, date palms, grapes) and to compare the results with the farmer irrigation practices. The model results show that, the reference evapotranspiration accounts for 1451 ± 5 mm/year. Therefore the irrigation water requirements estimated to be 763, 722, 1083, 591 mm/year in average for Citrus, almonds, Date palm, Grapes, respectively. The farmer irrigation practice exceeding the irrigation water requirement by 30%. The spatial distribution of irrigation water requirements in the entire area of Gaza Strip is shown on maps derived by GIS technique based on data from eight meteorological stations. Irrigation water quality is not optimal in the Gaza Strip, chemical analysis of irrigation wells indicate high salinity and SAR ratio. The obtained results from the model could be a good management tool for the planners and decision makers to minimize the overexploitation of the groundwater and to build fair and strict regulations to optimize the water use in agricultural sector in the Gaza Strip which characterized by semi-arid region.

关键词： Cropwat Model FAO Irrigation Demand Gaza Strip Evapo-Transpiration

Improving the Segmentation of Arabic Handwriting Using Ligature Detection Technique

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Computers, Materials & Continua 2024年第5期79卷 2015-2034页

作者： husam Ahmad al Hamad Mohammad Shehab College of Computer Sciences and Informatics Amman Arab UniversityAmman11953Jordan

Recognizing handwritten characters remains a critical and formidable challenge within the realm of computervision. although considerable strides have been made in enhancing English handwritten character recognitionthrough various techniques, deciphering Arabic handwritten characters is particularly intricate. This complexityarises from the diverse array of writing styles among individuals, coupled with the various shapes that a singlecharacter can take when positioned differently within document images, rendering the task more perplexing. Inthis study, a novel segmentation method for Arabic handwritten scripts is suggested. This work aims to locatethe local minima of the vertical and diagonal word image densities to precisely identify the segmentation pointsbetween the cursive letters. The proposed method starts with pre-processing the word image without affectingits main features, then calculates the directions pixel density of the word image by scanning it vertically and fromangles 30° to 90° to count the pixel density fromall directions and address the problem of overlapping letters, whichis a commonly attitude in writing Arabic texts by many people. Local minima and thresholds are also determinedto identify the ideal segmentation area. The proposed technique is tested on samples obtained fromtwo datasets: Aself-curated image dataset and the IFN/ENIT dataset. The results demonstrate that the proposed method achievesa significant improvement in the proportions of cursive segmentation of 92.96% on our dataset, as well as 89.37%on the IFN/ENIT dataset.

关键词： Arabic handwritten segmentation image processing ligature detection technique intelligent recognition

Hydro-Geochemical Characteristics of Groundwater Beneath the Gaza Strip

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Journal of Water Resource and Protection 2011年第5期3卷 341-348页

作者： Muhammad al-Khatib husam al-najar 不详

The main objective of the current research is to investigate the deterioration of groundwater quality due to the over-pumping in the coastal area of the Gaza Strip. One hundred and two (102) samples from 44 municipal water wells in the Gaza Strip were collected and analyzed for major cations like, Ca2+ and Mg2+ by Titration, Na+ and K+ by Flame photometer;anions like, Cl- and HCO3- by Titration, NO3- by spectrophotometer and SO42- by turbidity meter. The groundwater in the region mainly consists of NaCl, CaHCO3-and NaHCO3-. The saline load of groundwater is in first place controlled by chloride, sodium and calcium concentrations. The spatial changes of ionic ratios of rCa2+/(rHCO3- +? rSO42-) and the relationship between sodium and chloride in the coastal area indicate that the aquifer experienced sea-water intrusion.

关键词： Groundwater Salinity Piper Diagrams Durov Diagram Sea Intrusion

Spatial landslide susceptibility assessment using machine learning techniques assisted by additional data created with generative adversarial networks

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Geoscience Frontiers 2021年第2期12卷 625-637页

作者： husam A.H.al-Najjar Biswajeet Pradhan Centre for Advanced Modelling and Geospatial Information Systems(CAMGIS) Faculty of Engineering and ITUniversity of Technology Sydney2007NSWAustralia Department of Energy and Mineral Resources Engineering Sejong UniversityChoongmu-gwan209Neungdong-roGwangin-guSeoul05006Republic of Korea Center of Excellence for Climate Change Research King Abdulaziz UniversityP.O.Box 80234Jeddah21589Saudi Arabia Earth Observation Center Institute of Climate ChangeUniversiti Kebangsaan Malaysia43600UKMBangiSelangorMalaysia

In recent years,landslide susceptibility mapping has substantially improved with advances in machine ***,there are still challenges remain in landslide mapping due to the availability of limited inventory *** this paper,a novel method that improves the performance of machine learning techniques is *** proposed method creates synthetic inventory data using Generative Adversarial Networks(GANs)for improving the prediction of *** this research,landslide inventory data of 156 landslide locations were identified in Cameron Highlands,Malaysia,taken from previous projects the authors worked ***,slope,aspect,plan curvature,profile curvature,total curvature,lithology,land use and land cover(LULC),distance to the road,distance to the river,stream power index(SPI),sediment transport index(STI),terrain roughness index(TRI),topographic wetness index(TWI)and vegetation density are geo-environmental factors considered in this study based on suggestions from previous works on Cameron *** show the capability of GANs in improving landslide prediction models,this study tests the proposed GAN model with benchmark models namely Artificial Neural Network(ANN),Support Vector Machine(SVM),Decision Trees(DT),Random Forest(RF)and Bagging ensemble models with ANN and SVM *** models were validated using the area under the receiver operating characteristic curve(AUROC).The DT,RF,SVM,ANN and Bagging ensemble could achieve the AUROC values of(0.90,0.94,0.86,0.69 and 0.82)for the training;and the AUROC of(0.76,0.81,0.85,0.72 and 0.75)for the test,*** using additional samples,the same models achieved the AUROC values of(0.92,0.94,0.88,0.75 and 0.84)for the training and(0.78,0.82,0.82,0.78 and 0.80)for the test,*** the additional samples improved the test accuracy of all the models except *** a result,in data-scarce environments,this research showed that utilizing GANs to generate supplementary samples is

关键词： Landslide susceptibility Inventory Machine learning Generative adversarial network Convolutional neural network Geographic information system

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Annealing Effects on the Structural, Optical, and UV Photoresponse Properties of ZnO Nanostructures Prepared by RF-Magnetron Sputtering at Different Deposition Temperatures

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Acta Metallurgica Sinica(English Letters) 2015年第2期28卷 230-242页

作者： husam S.al-Salman M.J.Abdullah School of Physics University Sains Malaysia Department of Physics College of Science University of Basrah

Undoped ZnO nanostructures were deposited on SiO2/Si substrates via radio 11：equency magnetron sputtenng at different deposition temperatures （room temperature, 200, 300, and 400 ℃）. The prepared samples were annealed at 500 ℃ for 2 h under an N2 flow. The structural, surface morphological, optical, and photoresponse characteristics of ZnO nanostructures as deposited and after annealing were then investigated. The energy bandgaps of all samples after annealing （3.22-3.28 eV） decreased compared with those of the as-deposited specimens. The barrier height increased when the deposition temperature increased and reached 0.77 eV at 400 ℃ after annealing with a leakage current of 0.17 gA at a 5 V bias. The UV photodetector device which was deposited at the optimal temperature of 300 ℃, has 12.51 × 10^3% pho- tosensitivity, 2.259 pA dark current, 0.508 s response time, and 0.466 s recovery time. The dark current significantly decreased for all samples after annealing. The proposed UV photodetectors exhibit high performance, high photosensi- tivity, shorter response and recovery times, and excellent stability at lower bias voltages of 5 and 2 V.

关键词： Undoped ZnO UV photoresponse Deposition temperatures Annealing effect

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