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Electrochemical reduction of CO_2 and degradation of KHP on boron-doped diamond electrodes in a simultaneous and enhanced process

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Chinese Chemical Letters 2019年第2期30卷 509-512页

作者： Daibing Luo Shanhu Liu Kazuya Nakata Akira Fujishima Analytical ξ Testing Center Sichuan University Research Institute for Science and Technology Photocatalysis International Research Center Tokyo University of Science Henan Key Laboratory of Polyxometalate Chemistry Institute of Molecular and Crystal Engineering College of Chemistry and Chemical EngineeringHenan University

In this research a novel electrochemical system using dual boron-doped diamond (BDD) electrodes as the anode and cathode, for the first time, has been developed for CO_2 conversion and wastewater treatment in a synergetic and simultaneous process. On the BDD cathode CO_2 is converted into formaldehyde while in the anodic side organic wastes are decomposed on the BDD anode. Interestingly, when potassium hydrogen phthalate (KHP) was used as the organic model to be degraded in the anodic side, a higher efficiency of formaldehyde generation from CO_2 was observed on the BDD cathode. The enhanced effect of formaldehyde formation in the presence of KHP oxidation suggests that this novel electrochemical system can combine conversion of CO_2 to the form of high-value chemicals and wastewater purification in a simultaneous and harmonious process.

关键词： CO2 Wlectrochemical reduction Boron-doped diamond Wastewater treatment Formaldehyde

Hierarchical structures hydrogel evaporator and superhydrophilic water collect device for efficient solar steam evaporation

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Nano Research 2021年第4期14卷 1135-1140页

作者： Wenwei Lei Sovann Khan Lie Chen Norihiro Suzuki Chiaki Terashima Kesong Liu Akira Fujishima Mingjie Liu Key Laboratory of Bio-inspired Smart Interfacial Science and Technology of Ministry of Education School of ChemistryBeihang UniversityBeijing 100191China Photocatalysis International Research Center Tokyo University of Science2641 YamazakiNodaChiba 278-8510Japan

Efficient light absorption and trapping are of vital importance for the solar water evaporation by hydrogel-based photothermal conversion materials.Conventional strategies are focused on the development of the composition and structure of the hydrogers internal network.In our point of view,the importance of the surface structure of hydrogel has usually been underestimated or ignored.Here inspired by the excellent absorbance and water transportation ability of biological surface structure,the hierarchical structured hydrogel evaporators(HSEs)increased the light absorption,trapping,water transportation and water-air interface,which is the beneficial photothermal conversion and water evaporation.The HSEs showed a rapid evaporation rate of 1.77 kg·m^(-2)·h^(-1)at about 92%energy efficiency under one sun(1 kW·m^(-2)).Furthermore,the superhydrophilic window device was used in this work to collect the condensed water,which avoids the light-blocking caused by the water mist formed by the small droplets and the problem of the droplets stick on the device dropping back to the bulk water.Integrated with the excellent photothermal conversion hydrogel and superhydrophilic window equipment,this work provides efficient evaporation and desalination of hydrogel-based solar evaporators in practical large-scale applications.

关键词： light-trapping large-scale hierarchical structure hydrogel evaporator solar steam evaporation superhydrophilic window

Titanium Dioxide Photocatalysis:Present Status and Trends

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Titanium Dioxide Photocatalysis:Present Status and Trends

Sodium-doped carbon nitride nanotubes for efficient visible light-driven hydrogen production

中国化学会第二十五届学术年会

作者： Akira Fujishima Kanagawa Academy of Science and Technology Kawasaki-shi Kanagawa 213-0012 Japan

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Nano Research 2018年第4期11卷 2295-2309页

作者： Longshuai Zhang Ning Ding Muneaki Hashimoto Koudai Iwasaki Noriyasu Chikamori Kazuya Nakata Yuzhuan Xu Jiangjian Shi Huijue Wu Yanhong Luo Dongmei Li Akira Fujishima Qingbo Meng Key Laboratory for Renewable Energy Chinese Academy of Sciences (CAS) Beijing Key Laboratory for New Energy Materials and Devices Beijing National Laboratory for Condensed Matter Physics Institute of Physics CAS Beijing 100190 China Photocatalysis International Research Center Research Institute for Science and Technology Tokyo University of Science 2641 Yamazaki Noda Chiba 278-0022 Japan School of Physical Sciences University of Chinese Academy of Sciences Beijing 100049 China

Sodium-doped carbon nitride nanotubes （Nax-CNNTs） were prepared by a green and simple two-step method and applied in photocatalytic water splitting for the first time. Transmission electron microscopy （TEM） element mapping and X-ray photoelectron spectroscopy （XPS） measurements confirm that sodium was successfully introduced in the carbon nitride nanotubes （CNNTs）, and the intrinsic structure of graphitic carbon nitride （g-C3N4） was also maintained in the products. Moreover, the porous structure of the CNNTs leads to relatively large specific surface areas. Photocatalytic tests indicate that the porous tubular structure and Na＋ doping can synergistically enhance the hydrogen evolution rate under visible light （λ 〉 420 nm） irradiation in the presence of sacrificial agents, leading to a hydrogen evolution rate as high as 143 μmol·h-1 （20 mg catalyst）. Moreover, other alkali metal-doped CNNTs, such as Lix-CNNTs and Kx-CNNTs, were tested; both materials were found to enhance the hydrogen evolution rate, but to a lower extent compared with the Nax-CNNTs. This highlights the general applicability of the present method to prepare alkali metal-doped CNNTs; a preliminary mechanism for the photocatalytic hydrogen evolution reaction in the Nax-CNNTs is also proposed.

关键词： graphitic carbon nitrides,nanotubes,alkali metal doping,photocatalytic hydrogen production,hydrothermal/thermopolymerization processes,two-step synthesis

Development of a Coil-Shape Photocatalysis-Plasma Synergistic Reactor for a Practical and Long-Term Usable Air-Cleaner

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American Journal of Analytical Chemistry 2014年第8期5卷 467-472页

作者： Tsuyoshi Ochiai Yuji Hayashi Erina Ichihashi Tadashi Machida Yoshitsugu Uchida Shoko Tago Yuko Morito Akira Fujishima I’m PACT World Co. Ltd. Tokyo Japan Kanagawa Academy of Science and Technology Kawasaki Japan Photocatalysis International Research Center Tokyo University of Science Chiba Japan TANASHIN DENKI Co. Ltd. Tokyo Japan

A novel air-cleaner with a coil-shape photocatalysis-plasma synergistic reactor was developed. The air-cleaner showed 95% ± 1% reduction of a TVOCs concentration in tobacco smoke at “single-pass” condition. Air-purification activity of the air-cleaner was stably-maintained after the treatment of 12,000 cigarettes of tobacco smoke.

关键词： Photocatalysis Plasma Treatment Synergy Volatile Organic Compounds Air-Cleaner

二氧化钛光催化技术应用于室内甲醛降解的研究进展

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化学研究 2016年第4期27卷 502-513页

作者：刘山虎许庆峰邢瑞敏中田一弥寺岛千晶藤嶋昭河南大学化学化工学院河南开封475004 東京理科大学総合研究機構光触媒国際研究中心

随着人们健康意识的不断提升,室内空气中甲醛气体的净化引起了研究者广泛的关注.本文简要介绍了甲醛的危害以及来源;综述了国内室内建材、空气净化器研究中与二氧化钛光催化技术降解甲醛相关的专利,最后对本研究领域存在的问题以及未来... 详细信息

随着人们健康意识的不断提升,室内空气中甲醛气体的净化引起了研究者广泛的关注.本文简要介绍了甲醛的危害以及来源;综述了国内室内建材、空气净化器研究中与二氧化钛光催化技术降解甲醛相关的专利,最后对本研究领域存在的问题以及未来的研究方向进行了总结和展望.

关键词：室内甲醛 TiO2 光催化