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Design, synthesis, and nanoengineered modification of spherical graphene surface by layered double hydroxide (LDH) for removal of As (Ⅲ) from aqueous solutions

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Chinese Journal of Chemical Engineering 2023年第1期53卷 374-380页

作者： Najma Kamali jahan B.Ghasemi Ghodsi Mohammadi Ziarani Sahar Moradian Alireza Badiei School of Chemistry College of ScienceUniversity of TehranTehranIran Department of Organic Chemistry Faculty of ChemistryAlzahra UniversityVanak SquareTehranIran

In this study, new nano spherical graphene modified with LDH(Layered Double Hydroxide) was prepared and used to remove As(Ⅲ) ion from aqueous solutions. At first, graphene oxide was synthesized from graphite using a well-known Hammer method. The obtained graphene oxide solution was sprayed in octanol solution under different temperatures and sprayed speed as influenced variables. The structure and physical characterization of synthesized spherical graphene oxide were determined by various techniques,including FT-IR, N_(2) adsorption–desorption, SEM, TEM, and EDX. In the next step, the hydrothermal method was applied to deposition LDH on the spherical graphene oxide. The synthesized spherical graphene modified by LDH was used to remove As(Ⅲ) as a toxic heavy metal ion. The effect of influenced variables including p H, contact time, amount of sorbent, and type eluent studied and the optimum values were as 8, 30, 50, and HCl(0.5 mol·L^(-1)), respectively. After optimization, the studied sorbent was shown a high adsorption capacity(149.3 mg·g^(-1)). The adsorption mechanism and kinetic models exhibited good agreement with the Langmuir isotherm and pseudo-second-order trends, respectively. Besides, the synthesized product was tested for seven times without significant loss in its sorption efficiency.

关键词： Graphene-based spherical adsorbent Layered double hydroxide(LDH) Adsorption Spray-assisted deep-frying

Prevention and treatment of hypoxia-induced colorectal cancer damage in albino Wister rats

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Life Research 2024年第1期7卷 16-23页

作者： Ishrat jahan Manju Pandey Shalini Pal Bushra Jabi Mohd Yaqub Khan Gaurav Kaithwas Department of Pharmaceutical Sciences Babasaheb Bhimrao Ambedkar UniversityLucknow 226025 India Institute of Pharmacy Shri Ramswaroop Memorial UniversityBarabanki 225003India School of Pharmaceutical Education&Research Jamia HamdardNew Delhi 110062India Institute of Pharmacy Azad Institute of Pharmacy and ResearchLucknow 226008India

Background:In the early metastasis of colon cancer,cancer cells detach,migrate,and infiltrate surrounding tissues,including lymph vessels and blood *** heterogeneity arises from both tumor cells and distinct *** of blood vessels,creates hypoxic regions within the tumors,fostering cancer stem cell-like properties due to reduced oxygen and nutrient *** hypoxia,tumor cells shift to a glycolytic pathway,producing more lactic acid that acidifies the microenvironment and leads to unstable heart rate variability(HRV)factors,weight disparity,and a higher incidence of aberrant crypt foci(ACF).These hypoxic-induced parameters promote cancer cell invasion,increase radiation resistance,and facilitate cancer cell ***:In this study,we induced hypoxia-preneoplastic colon damage in albino Wister rats by administrating 1,2-dimethyl hydrazine(DMH).After successfully creating a hypoxic environment in albino Wister rats,resulting in preneoplastic colon damage,we randomly allocated Wistar albino rats into seven groups,each containing 8 animals,and conducted a 6-week *** 1-Normal control(administered 1 mM EDTA+saline,2 ml/kg/day,p.o.);group 2-Toxic control(administered DMH,30 mg/kg/week,s.c.);group 3-Standard treatment(DMH,30 mg/kg/week,*** 6 weeks),followed by 5-fluorouracil and Leucovorin(25 mg/kg each on 1^(st),3^(rd),7^(th),and 10^(th) days,*** 6 weeks administration of DMH);group 4-Low dose of P1(DMH,30 mg/kg/week,s.c.+P1,2 mg/kg,i.v.,weekly for 3 weeks);group 5-High dose P1(DMH,30 mg/kg/week,s.c.+P1,4 mg/kg,i.v.,weekly for 3 weeks),group 6-Low dose of P2(DMH,30 mg/kg/week,s.c.,+P2,2 mg/kg,i.v.,weekly for 3 weeks),group 7-High dose of P2(DMH,30 mg/kg/week,s.c.,+P2,4 mg/kg,*** for 3 weeks).Results:DMH-treated rats exhibited alterations in HRV factors,weight disparity,elevated gastric pH,increased total acidity,a higher incidence of ACF,and changes in antioxidant markers(TBARs,SOD,catalase,GSH).Bri

关键词： colon cancer 1,2,4-triazine derivatives oxidative stress hypoxia-induced colon carcinogenesis

Energy Management of Networked Smart Railway Stations Considering Regenerative Braking, Energy Storage System, and Photovoltaic Units

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Energy Engineering 2023年第1期120卷 69-86页

作者： Saeed akbari Seyed Saeed Fazel Hamed Hashemi-Dezaki School of Railway Engineering Iran University of Science and TechnologyTehran13114-16846Iran Department of Electrical and Computer Engineering University of KashanKashan***Iran Research and Innovational Center for Electrical Engineering(RICE) Faculty of Electrical EngineeringUniversity ofWest Bohemia(UWB)Pilsen30100Czech Republic

The networking of microgrids has received significant attention in the form of a smart *** this paper,a set of smart railway stations,which is assumed as microgrids,is connected *** has been tried to manage the energy exchanged between the networked microgrids to reduce received energy from the utility ***,the operational costs of stations under various conditions decrease by applying the proposed *** smart railway stations are studied in the presence of photovoltaic(PV)units,energy storage systems(ESSs),and regenerative braking *** regenerative braking is one of the essential ***,the stochastic behaviors of the ESS’s initial state of energy and the uncertainty of PV power generation are taken into account through a scenario-based *** networked microgrid scheme of railway stations(based on coordinated operation and scheduling)and independent operation of railway stations are *** proposed method is applied to realistic case studies,including three stations of Line 3 of Tehran Urban and Suburban Railway Operation Company(TUSROC).The rolling stock is simulated in the MATLAB ***,the coordinated operation of networked microgrids and independent operation of railway stations are optimized in the GAMS environment utilizing mixed-integer linear programming(MILP).

关键词： Energy management system(EMS) smart railway stations coordinated operation photovoltaic generation regenerative braking uncertainty scenario-based model mixed-integer linear programming(MILP)

Toxicity evaluation of ZnO and TiO_2 nanomaterials in hydroponic red bean(Vigna angularis) plant:Physiology, biochemistry and kinetic transport

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Journal of Environmental Sciences 2018年第10期30卷 140-152页

作者： Shanaz jahan Yatimah Binti Alias Ahmad Farid Bin Abu Bakar Ismail Bin Yusoff Department of Geology Environmental and Earth Sciences Faculty of Science University of Malaya Department of Chemistry Faculty of Science University of Malaya University Malaya Centre for Ionic Liquids (UMCi L) University of Malaya

The toxicity and kinetic uptake potential of zinc oxide（Zn O） and titanium dioxide（TiO2）nanomaterials into the red bean（Vigna angularis） plant were investigated. The results obtained revealed that Zn O, due to its high dissolution and strong binding capacity, readily accumulated in the root tissues and significantly inhibited the physiological activity of the plant. However, TiO2 had a positive effect on plant physiology, resulting in promoted growth. The results of biochemical experiments implied that Zn O, through the generation of oxidative stress, significantly reduced the chlorophyll content, carotenoids and activity of stress-controlling enzymes. On the contrary, no negative biochemical impact was observed in plants treated with TiO2. For the kinetic uptake and transport study, we designed two exposure systems in which Zn O and TiO2 were exposed to red bean seedlings individually or in a mixture approach. The results showed that in single metal oxide treatments, the uptake and transport increased with increasing exposure period from one week to three ***, in the metal oxide co-exposure treatment, due to complexation and competition among the particles, the uptake and transport were remarkably decreased. This suggested that the kinetic transport pattern of the metal oxide mixtures varied compared to those of its individual constituents.

关键词： Metal oxides Physiological impacts Biochemical impacts Uptake kinetics Translocation Growth inhibition

Laboratory-and Field-Phenotyping for Drought Stress Tolerance and Diversity Study in Lentil (Lens culinaris Medik.)

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Phyton-International Journal of Experimental Botany 2021年第3期90卷 949-970页

作者： Shahida Akter Israt jahan MdAmir Hossain Mohammad Anwar Hossain Department of Genetics and Plant Breeding Bangladesh Agricultural UniversityMymensingh2202Bangladesh

Drought susceptibility and low genetic variability are the major constraints of lentil(Lens culinaris Medik.)production *** of an efficient pre-field drought phenotyping technique and identification of diversified drought tolerant lentil genotype(s)are therefore vital and *** separate experiments were conducted using thirty diverse lentil genotypes to isolate drought tolerant genotype(s)as well as to assess their *** both of the experiments,significant(p≤0.01)variation in genotype(G),treatment(T)and G X T was observed for most of the studied *** experiment I,genotypes were examined for drought tolerance at the seedlings stage under hydroponic conditions by assessing root and shoot *** the 30 genotypes studied,BM-1247,BM-1227 and BM-502 were selected as highly tolerant to drought stress as they showed maximum seedling survivability and minimum reduction in growth parameters under drought *** experiment II,the genotypes were assayed for diversity and drought stress tolerance based on morphological traits grown under field *** stress caused a substantial reduction in yield attributing traits,however,the genotypes BM-1247,BM-981,BM-1227 and BM-502 were categorized as drought tolerant genotypes with less than 20%yield *** field screening result of drought stress tolerance was coincided well with the results of laboratory *** divergence study reflected the presence of considerable diversity among the *** laboratory and field screening results,the genotypes,BM-1247,BM-1227,BM-981 and BM-502 were selected as the best drought tolerant *** information can be exploited for further breeding in developing drought tolerance in lentil.

关键词： Lentil water stress seedling survival yield attributing traits phenotypic diversity

Hydrogen Storage Capacity of C120 Nanocapsules： Density Functional Theory Based Treatments

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Communications in Theoretical Physics 2011年第3期55卷 519-526页

作者： M.D. Ganji Gh. Valizadeh M. jahan-tigh Department of Chemistry Islamic Azad University Ghaemshahr Branch Mazandaran Iran

The adsorption of hydrogen molecule on the external surface of pure 0120 nanocapsule and endohedrallyH2 @C120 complex has been examined using the density functional theory calculations. Several different bonding configu- rations are considered for the hydrogen molecule approaching the outer surface of the considered nanocages. It has been found that the adsorbed H2 molecule bound weakly to the outer surface of the pure C1~0 nanocapsules in agreement with the recent experimental and theoretical results while, it prefers to be adsorbed rather strongly on the side wall of the endohedrally /-/2@C120 complex. The adsorption of a single layer and bi-layer of two tt2 molecules on the most stable states of the considered H2@C120 complex appears to be feasible, although the molecules of the second layer are weakly bound. Furthermore, it is found that the formation of 100% coverage is favorable thermodynamically, which corresponds to about 20% by weight storage of 1-12 molecules. Thus, surprisingly, we arrive at the prediction that the C120 nanocapsules can be implemented as a novel material for energy storage.

关键词： adsorption encapsulation hydrogen storages carbon nanocapsule ab initio calculations

Modules with Finitely Many Submodules

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Algebra Colloquium 2016年第3期23卷 463-468页

作者： S. akbari S. Khalashi Ghezelahmad E. Yaraneri Department of Mathematical Sciences Sharif University of Technology P.O. Box 11155-9415 Tehran Iran School of Mathematics Institute for Research in Fhndamental Sciences (IPM) P.O. Box 19395-5746 Tehran Iran School of Mathematics Iran University of Science and Technology Tehran Iran Department of Mathematics Istanbul Technical University Istanbul Turkey

In this paper, we study modules having only finitely many submodules over any ring which is not necessarily commutative. We try to understand how such a module decomposes as a direct sum. We justify that any module V having only finitely many submodules over any ring A is an extension of a cyclic A-module by a finite A-module. Under some assumptions on A, such as commutativity of A, we prove that an A-module V has finitely many submodules if and only if V can be written as a direct sum of a cyclic A-module having only finitely many A-submodules and a finite A-module.

关键词： direct sum module submodule

Impacts of climate gradients on the vegetation phenology of major land use types in Central Asia （1981-2008）

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Frontiers of Earth Science 2012年第2期6卷 206-225页

作者： jahan KARIYEVA Willem J.D. van LEEUWEN Connie A. WOODHOUSE School of Geography and Development The University of Arizona Tucson AZ 85721 USA School of Natural Resources and the Environment - Office of Arid Lands Studies - Arizona Remote Sensing Center The University of Arizona Tucson AZ 85721 USA

Time-series of land surface phenology （LSP） data offer insights about vegetation growth patterns. They can be generated by exploiting the temporal and spectral reflectance properties of land surface components. Inter- annual and seasonal LSP data are important for under- standing and predicting an ecosystem＇s response to variations caused by natural and anthropogenic drivers. This research examines spatio-temporal change patterns and interactions between terrestrial phenology and 28 years of climate dynamics in Central Asia. Long-term （1981-2008） LSP records such as timing of the start, peak and length of the growing season and vegetation productivity were derived from remotely sensed vegetation greenness data. The patterns were analyzed to identify and characterize the impact of climate drivers at regional scales. We explored the relationships between phenologi- cal and precipitation and temperature variables for three generalized land use types that were exposed to decade- long regional drought events and intensified land and water resource use： rainfed agriculture, irrigated agriculture, and non-agriculture. To determine whether and how LSP dynamics are associated with climate patterns, a series of simple linear regression analyses between these two variables was executed. The three land use classes showed unique phenological responses to climate variation across Central Asia. Most of the phenological response variables were shown to be positively correlated to precipitation and negatively correlated to temperature. The most substantial climate variable affecting phenological responses of all three land use classes was a spring temperature regime. These results indicate that future higher temperatures would cause earlier and longer growing seasons.

关键词： phenology land use climate variability

An evaluation of harvesting costs in present and planned operations: case study—Waston District of Mazandaran Wood and Paper Industries

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Journal of Forestry Research 2018年第1期29卷 215-220页

作者： Majid Lotfalian Mohammad Ali akbari Gorji Seyed Ataollah Hoseini Maryam Kazemi Department of Forestry Faculty of Natural Resources Sari University of Agricultural Sciences and Natural Resources Forestry Master of Science Graduates Faculty of Natural Resources Sari University of Agricultural Sciences and Natural Resources Department of Forestry Faculty of Natural ResourcesTehran University

Amongst all forest utilization phases, harvesting plays a key role as the beginning phase of the utilization cycle and has a significant effect on the following *** this research, in order to examine the reduction of costs with respect to present and planned operations, the starting time of the harvesting or cutting phase and work flow were recorded. The starting time of each phase of the entire operation was recorded as well. Before harvesting the marked tree, the appropriate felling direction was determined and the azimuth of the correct direction was *** results indicate that there was not a meaningful relationship between the differences in direction of a leaning tree compared with the felling direction. However, there was a significant relationship between the difference of the defined and felling direction and the difference in tree leaning and defined direction. The same trend was observed between tree leaning and felling directions and tree leaning and defined directions. On the other hand,there was no significant relationship between tree leaning and felling directions and the defined and tree felling directions. In addition, this research shows that with an increase in tree volume, the time for tree cutting ***, when the difference of tree leaning and felling direction decreased, the time to cut the tree *** regression equation is Y = 168.9–0.14（the difference between tree leaning and felling direction）＋ 0.7（volume）.

关键词： Chainsaw Felling direction Cutting time Tree leaning direction