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Electronic properties and photodegradation ability of Nd-TiO_(2)for phenol

Journal of Rare Earths 2022年第7期40卷 1063-1072页

作者： Zhimin Zhao Jinjia Liu Gala Sa aiju xu Inner Mongolia Key Laboratory of Green Catalysis College of Chemistry and Environmental ScienceInner Mongolia Normal UniversityHohhot 010022China State Key Laboratory of Coal Conversion Institute of Coal Chemistry Chinese Academy of SciencesTaiyuan 030001China National Energy Center for Coal to Clean Fuels Synfuels China Co.Ltd.Beijing 101400China

In this study,the photocatalytic activity of Nd-TiO_(2)photocatalysts obtained by common hydrothermal method was evaluated by practical experiments and theoretical calculations based on density functional theory(DFT).The synthesized photocatalysts were characterized by X-ray diffraction(XRD),N_(2)adsorption-desorption,Fourier transform infrared spectroscopy(FT-IR),high resolution transmission electron microscopy(HRTEM),X-ray photoelectron spectroscopy(XPS),UV-Vis diffuse reflectance spectroscopy(DRS),and photoluminescence(PL)to study their physical/chemical prope *** the same time,the photoelectronic performance was also *** photodegradation ability of asprepared photocatalysts and the effect of Nd doped amount and photocatalysts dosage were investigated by the photodegradation of phenol(30 mg/L)under 400 W metal halide lamp(UV-Vis).The effect of Nd on electronic properties of TiO_(2)and adsorption ability of phenol were *** show the red-shift wavelength of 0.5 mol%Nd-TiO_(2),indicating that its absorption capacity is stronger than pristine TiO_(2)in the same wavelength *** result of DFT calculations demonstrates that the optical bandgap of Nd-TiO_(2)is profoundly reduced,thus the light absorption ability is promoted,which will be responsible for the enhanced photocatalytic performance of Nd-TiO_(2).0.5 mol%Nd is an optimum value for photodegradation phenol,and phenol can be completely degraded by 0.5 mol%Nd-TiO_(2)for 210 min,the higher catalytic performance is derived from the efficient separation of e-/h+***,the adsorption energy calculations of phenol on TiO_(2)(101)and Nd-TiO_(2)(101)demonstrate that the Nd doping can significantly enhance the adsorption ability of phenol on catalyst surfaces because of the formation of Nd-O *** last,the stability measurement through four recycles exhibits that 0.5 mol%Nd-TiO_(2)possesses excellent stability.

关键词： TiO_(2) Hydrothermal method Density functional theory Phenol Photodegradation Rare earths

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Chlorinated phthalimide polymer donor as ultra-wide bandgap and deep HOMO guest for achieving highly efficient polymer solar cells

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Chinese Chemical Letters 2023年第4期34卷 501-506页

作者： Weichao Zhang Jianhua Huang Xiaoyu Lv Ming Zhang Wanru Liu Tianzi xu Jun Ning Alata Hexig Feng Liu aiju xu Chuanlang Zhan Inner Mongolia Autonomous University Key Laboratory of Advanced Materials Chemistry and Devices(AMC&DLab) Inner Mongolia Key Laboratory of Green CatalysisCollege of Chemistry and Environmental ScienceInner Mongolia Normal UniversityHuhhot 010022China College of Materials Science and Engineering Huaqiao UniversityXiamen 361021China Inner Mongolia Key Laboratory of Functional Materials Physics and Chemistry College of Physics and Electronic InformationInner Mongolia Normal UniversityHohhot 010022China School of Chemistry and Chemical Engineering Center for Advanced Electronic Materials and DevicesShanghai Jiao Tong UniversityShanghai 200240China

Quaternary approach has been receiving more and more attention due to its effectiveness in improving solar cell performance, while synthesis/selection of the fourth component is yet a key issue. Herein, we report a chlorinated phthalimide based donor polymer(namely Ph I-Cl) having an ultra-wide bandgap(2.10 e V) and a deep HOMO(-5.58 e V) level. Addition of Ph I-Cl as the third component of PM6:Y6 and the fourth of PM6:Y6:PC71BM increases both hole and electron mobilities and gives rise to more balanced charge carriers mobilities. Both the short-circuit current-density and fill-factor are increased and open-circuit voltage is well maintained, delivering 17.0% and 18.1% efficiencies, respectively. These results demonstrate that chlorination on the side thiophene of phthalimide-based donor polymer is a way to make deep HOMO and ultra-wide bandgap donor polymer guest used for highly efficient ternary and quaternary strategies.

关键词： Phthalimide polymer donor Quaternary strategy Polymer solar cell Wide bandgap Fullerene-free

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固相球磨法制备丙烷氧化脱氢V_2O_5/NiO催化剂

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催化学报 2009年第10期30卷 991-996页

作者：斯琴塔娜徐爱菊张宇照日格图内蒙古师范大学化学与环境科学学院内蒙古自治区功能材料物理与化学重点实验室内蒙古呼和浩特010022

以不同温度焙烧制备的NiO和V2O5为前驱物,采用固相球磨法制备了V2O5/NiO催化剂,考察了前驱物的焙烧温度对该催化剂丙烷氧化脱氢制丙烯反应性能的影响,并采用X射线衍射、N2物理吸附、电感耦合等离子体原子发射光谱、透射电子显微镜、H2... 详细信息

以不同温度焙烧制备的NiO和V2O5为前驱物,采用固相球磨法制备了V2O5/NiO催化剂,考察了前驱物的焙烧温度对该催化剂丙烷氧化脱氢制丙烯反应性能的影响,并采用X射线衍射、N2物理吸附、电感耦合等离子体原子发射光谱、透射电子显微镜、H2程序升温还原和X射线光电子能谱等对催化剂进行了表征.结果表明,固相球磨法制备的V2O5/NiO催化剂表现出较好的丙烷氧化脱氢制丙烯催化性能,当以400oC焙烧的氧化物为前驱体时,V2O5/NiO催化剂表面含有较多的未完全还原氧物种Oδ?,因而表现出了较高的丙烯选择性.在475oC反应时,丙烷转化率可达20.1%,丙烯选择性达到71.2%.

关键词：球磨五氧化钒氧化镍丙烷氧化脱氢

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NiO/高炉渣催化剂的丙烷氧化脱氢性能

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稀有金属材料与工程 2009年第A1期38卷 99-102页

作者：徐爱菊林勤照日格图张宇内蒙古师范大学内蒙古呼和浩特010022 北京科技大学北京100083

以攀钢高炉渣为载体,采用固体研磨法负载NiO,制备了NiO/高炉渣负载型催化剂,并以XRD、H2-TPR技术对催化剂进行表征,研究了其对丙烷氧化脱氢制丙烯反应的催化性能。结果表明:NiO的负载量为25%时催化剂表现最好的催化性能,在600℃时丙烷... 详细信息

以攀钢高炉渣为载体,采用固体研磨法负载NiO,制备了NiO/高炉渣负载型催化剂,并以XRD、H2-TPR技术对催化剂进行表征,研究了其对丙烷氧化脱氢制丙烯反应的催化性能。结果表明:NiO的负载量为25%时催化剂表现最好的催化性能,在600℃时丙烷转化率为34.64%,丙烯选择性为37.21%。此法为资源综合利用及减少环境污染提供了新方法。

关键词： NiO 高炉渣氧化脱氢

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Au/Fe(OH)_3/LaFeO_3催化剂的稳定性研究

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稀有金属材料与工程 2013年第5期42卷 967-970页

作者：贾美林图雅萨嘎拉王奖徐爱菊照日格图内蒙古师范大学内蒙古自治区绿色催化重点实验室内蒙古呼和浩特010022

以LaFeO3为载体,通过Fe(OH)3对载体进行改性,采用沉积沉淀法制备纳米金催化剂,并对催化剂进行XRD、XPS、AAS和BET测试,考察催化剂的活性和稳定性。结果显示,Fe(OH)3助剂的加入,对催化剂的活性提高不明显,但大大提高了催化剂在反应过程... 详细信息

以LaFeO3为载体,通过Fe(OH)3对载体进行改性,采用沉积沉淀法制备纳米金催化剂,并对催化剂进行XRD、XPS、AAS和BET测试,考察催化剂的活性和稳定性。结果显示,Fe(OH)3助剂的加入,对催化剂的活性提高不明显,但大大提高了催化剂在反应过程和放置过程中的稳定性。加入助剂的Au/Fe(OH)3/LaFeO3催化剂,由于Fe(OH)3和活性组分的相互作用,减缓了金颗粒的聚集,使得放置近半年的催化剂和新鲜催化剂具有相近的活性和稳定性。

关键词：金催化剂一氧化碳氧化钙钛矿氧化物

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数字金融发展与海洋战略性新兴产业融资环境优化

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海洋开发与管理 2022年第12期39卷 85-92页

作者：许霭鞠中国海洋大学经济学院青岛266100

海洋战略性新兴产业的发展需要充足的资金支持,优化融资环境是加快我国海洋战略性新兴产业发展的动力源泉。文章基于2011—2020年我国海洋战略性新兴产业上市公司的相关数据,探讨数字金融发展对相关企业融资环境的影响。研究结果表明:... 详细信息

海洋战略性新兴产业的发展需要充足的资金支持,优化融资环境是加快我国海洋战略性新兴产业发展的动力源泉。文章基于2011—2020年我国海洋战略性新兴产业上市公司的相关数据,探讨数字金融发展对相关企业融资环境的影响。研究结果表明:数字金融发展显著优化我国海洋战略性新兴产业的融资环境,其中数字化程度的优化作用最强,数字金融发展对北方地区融资环境的优化作用强于南方地区,数字金融发展通过提高市场化水平进而促进海洋战略性新兴产业融资环境的优化。研究结论可为我国数字金融发展和海洋战略性新兴产业技术创新等方面提供可靠证据和政策方向。

关键词：数字金融海洋新兴产业融资约束融资成本

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Riverine sulfate sources and behaviors in arid environment,Northwest China:Constraints from sulfur and oxygen isotopes

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Journal of Environmental Sciences 2024年第3期137卷 716-731页

作者： Yifu xu Wenjing Liu Bing xu Zhifang xu Key Laboratory of Cenozoic Geology and Environment Institute of Geology and GeophysicsChinese Academy of SciencesBeijing 100029China Innovation Academy for Earth Science Chinese Academy of SciencesBeijing 100029China University of Chinese Academy of Sciences Beijing 100049China

The fate of riverine sulfate ion (SO_(4)^(2-)) and its environmental effects in arid environment are difficult to evaluate due to its complicated sources and strongly coupled behaviors with water cycle which is significantly modified by *** understand the sulfur cycle in aquatic systems in arid environment,the chemical and sulfur and oxygen isotopic compositions (δ^(34)S_(SO4)and δ^(18)O_(SO4)) of major rivers around the Badain Jaran Desert,northwestern China,were *** rivers had averaged SO_(4)^(2-)content at 1336μmol/L,over 10times higher than the global *** δ^(34)S_(SO4)and δ^(18)O_(SO4)values ranged from-5.3‰to+11.8‰and+1.6‰to+12.8‰,*** end-member analysis and the inverse model showed that riverine sulfate was mainly derived from evaporites dissolution (0-87%),sulfide oxidation (13%-100%) and precipitation (0-33%),indicating heterogeneity in sulfur sources and behaviors along the river drainage with the lithology variations and climate *** isotopic tools combining with hydro-chemistry compositions could be applied to reveal sulfur cycle in arid *** on the calculation,sulfide oxidation plays the primary role in the headwater and upstream in the Qilian-Mountains area,where sulfide is widely *** the proportion of evaporites dissolution contributing to riverine sulfate is much higher in downstream in a drier ***,less precipitation and higher temperature can lead to more intensive evaporation,affecting the process of sulfide oxidation and enhancing the rates of evaporites dissolution and sulfate precipitation in the basin.

关键词： Sulfur and oxygen isotopes Source apportionment Inverse model Arid environment Inland rivers Northwestern China

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Laboratory evaluation of high-friction thin overlays for pavement preservation

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Frontiers of Structural and Civil Engineering 2024年第6期18卷 936-948页

作者： Ouming xu Rentao xu Lintong JIN School of Highway Chang’an UniversityXi’an 710064China School of Materials Science and Engineering Chang’an UniversityXi’an 710061China

Traditional asphalt concrete(AC)and stone matrix asphalt(SMA),which are used as thin asphalt overlays,are common maintenance strategies to enhancing ride quality,skid resistance,and ***,several studies have used a novel asphalt mixture known as a high-friction thin overlay(HFTO)to improve surface ***,it remains uncertain whether the laboratory properties of HFTO differ significantly from those of conventional *** study aims to evaluate the laboratory properties of HFTO mixtures and compare them with those of AC and *** mixtures with nominal maximum size of 9.5 mm were produced in the laboratory,and performance tests were conducted,including wheel tracking test,low temperature flexural creep test,moisture susceptibility test,Cantabro Abrasion Test,Marshall Test,sand patch test,British pendulum test,and indoor tire-rollingdown *** results showed that the HFTO exhibited a lower tire/pavement noise than the AC and ***,HFTO had superior high-temperature stability,larger macro texture,and higher skid resistance in comparison to those of AC,but lower than those of ***,HFTO mixtures may be considered a suitable replacement for traditional AC mixtures in regions where skid resistance and noise reduction are concerns.

关键词： road engineering pavement maintenance high friction thin overlay performance skid resistance tire/pavement noise

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Granting strength to aerogel fibers through encapsulation

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Science China Materials 2024年第4期67卷 1365-1366页

作者： Wenhui xu Department of Basic Chemistry School of PharmacyJiangxi University of Chinese MedicineNanchang 330004China

Aerogel fibers, distinguished by their lightweight nature, pronounced porosity, large surface area, and superior thermal insulation properties, have diversified applications in thermal management, energy devices, and environmental remediation[1]. However, compared with monolithic ones, these fibershaped aerogels exhibit limited mechanical strength and resilience due to their one-dimensional small size.

关键词： strength fibers thermal

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Aldehyde oxidase mediated enantioselective metabolic health risk of dinotefuran

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Science China Chemistry 2024年第6期67卷 2079-2091页

作者： Liwei xu Xinxin xu Hua Kuang Chuanlai xu Xiaoling Wu State Key Laboratory of Food Science and Resources Jiangnan UniversityWuxi214122China International Joint Research Laboratory for Biointerface and Biodetection and School of Food Science and Technology Jiangnan UniversityWuxi214122China Collaborative Innovation center of Food Safety and Quality Control in Jiangsu Province Jiangnan UniversityWuxi214122China

Chiral pollutants often pose significant differential environmental health *** this study,the biotransformation of chiral dinotefuran(DIN)and its enantioselective metabolic toxicity mechanisms have been systemically ***,reversedphase chromatography-high resolution mass spectrometry was developed to quantify the content of DIN R/S chiral enantiomer with pg level sensitivity,revealing a lower elimination rate constant(K_(e))of S-DIN(0.730 h^(-1))than R-DIN(0.746 h^(-1)).Secondly,the interaction mechanism between DIN metabolism and important endogenous bioactive molecules,such as aldehyde oxidase(AOX)and neurotransmitters,was *** DIN nitro-group was converted into a guanidine group by the reducing site of nearby flavin adenine dinucleotide(FAD)in AOX with the preferred higher affinity of ***,the endogenous tryptophan(Trp)aldehyde metabolic intermediate,5-hydroxyindoleacetaldehyde(5-HIAL),provides a persistent electron donor for DIN reduction via the oxidation-catalyzed site in AOX,resulting in remarkable up-regulation of monoamine neurotransmitters such as serotonin and ***,the higher level of neurotransmitters further mediated dysregulation of oxylipin homeostasis via the serotonergic pathway,where S-DIN exhibited more pronounced liver lipid damage and environmental health risk with the accumulated lipid biomarkers,oxidized triglyceride(OxTG)and oxidized sphingomyelin(OxSM).This study elucidates the AOX-mediated enantioselectivity metabolic pathway of DIN,providing a new analytical method for chiral pollutants and paves the way for their health risk assessments.

关键词： neonicotinoid dinotefuran enantiomer aldehyde oxidase metabolomics health risk

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