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Applying the protective Mn-Co-La_(2)O_(3)Coating on Crofer 22 ApU Ferritic Stainless Steel Used as Solid Oxide Fuel Cell Interconnects

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Acta Metallurgica Sinica(English Letters) 2024年第5期37卷 872-888页

作者： Farhad Mohsenifar Hadi Ebrahimifar ahmad Irannejad Department of Materials Engineering and Metallurgy Faculty of EngineeringShahid Bahonar University of KermanKermanIran Mechanical Engineering Department Faculty of EngineeringHigher Education Complex of Bam76615-314BamIran Department of Materials Engineering Faculty of Mechanical and Materials EngineeringGraduate University of Advanced TechnologyKerman ***Iran

This research studies the effect of Mn-Co-La_(2)O_(3) coating synthesized by the electrodeposition method on the oxidation resistance and electrical conductivity of the Crofer 22 ApU stainless steel interconnect plates in solid oxide fuel *** test samples were characterized by a field emission scanning electron microscope(FESEM)equipped with energy dispersive spectroscopy(EDS),X-ray diffraction(XRD),and X-ray photoelectron spectroscopy(XpS).The oxidation kinetics of the coated and uncoated samples were studied by tracking their weight changes over time at 800°C,showing that the oxidation mechanism for all samples follows the parabolic *** oxidation rate constant(k_(p))values of the coated sample compared with that of the uncoated one indicated a reduction in the oxidation rate of the steel substrate in the presence of the Mn-Co-La_(2)O_(3) *** examination of the cross-section of different samples after the isothermal oxidation for 500 h at 800°C exhibited that applying the composite coating leads to a decrease in the thickness of the chromia layer formed on the steel ***,under these conditions,the area-specific resistance(ASR)of the coated sample(13.11 mΩcm^(2))is significantly lower than that of the uncoated one(41.45 mΩcm^(2)).

关键词： Area specific resistance Oxidation Fuel cell Composite coating

(Sm/Eu/Tm)^(3+) doped tantalum semiconductor system for photovoltaic and electrochemical functionality amplification

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Journal of Rare Earths 2024年第8期42卷 1586-1594,I0007页

作者： Shaan Bibi Jaffri Khuram Shahzad ahmad Isaac Abrahams Ibrahim A.A Materials and Environmental Chemistry Lab Lab-E21Department of Environmental SciencesFatima Jinnah Women UniversityRawalpindiPakistan School of physical and Chemical Sciences Queen Mary University of LondonLondonUnited Kingdom Department of Botany and Microbiology College of ScienceKing Saud UniversityP.O.Box 2455Riyadh11451Saudi Arabia

This work reports the synthesis,characterization,and energy focused applications of the novel lanthanides co-doped tantalum pentoxide hetero-system(Sm^(3+)-Eu^(3+)-Tm^(3+):Ta_(2)O_(5)).Ln^(3+)-doped Ta_(2)O_(5) express excellent opto-electronic features reflected by the narrow band gap energy of 3.87 *** vibrations confirm the presence of Ta-O-Ta and Ta-O *** synthesized system possesses orthorhombic geometry with 59.46 nm particle *** the smoother and compact morphology,the synthesized material succeeds in augmenting the performance of different systems aimed at energy *** ambient perovskite solar cell device fabricated with the Ln^(3+)-doped Ta_(2)O_(5) as an electron transport layer excels in achieving an efficiency and fill factor of 14.17% and 76% under artificial *** device was marked by the negligible hysteresis behavior showing profound photovoltaic *** electrochemical activity of the Ln^(3+)-doped Ta_(2)O_(5) decorated electrode was evaluated for electrical charge storage potential with pseudocapacitive behavior,With the highest specific capacitance of 355.39 F/g and quicker ionic diffusion rate,the designed electrode excels conventionally used ***-catalysis of water with Ln^(3+)-doped Ta_(2)O_(5) material indicates its capacity for H_(2) production with the lowest overpotential and Tafel slope values of 148 and 121.2 mV/dec,while the O_(2) generation is comparatively *** the stable electrochemical output,this rare earth modified material has the potential to replace conventionally used environmentally perilous and costly materials.

关键词： Lanthanide doping Rare earth materials perovskite solar cells Supercapacitors Water splitting

Soliton solutions for nonlinear variable-order fractional Korteweg-de Vries(KdV)equation arising in shallow water waves

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Journal of Ocean Engineering and Science 2024年第1期9卷 50-58页

作者： Umair Ali Hijaz ahmad Hanaa Abu-Zinadah Department of Applied Mathematics and Statistics Institute of Space TechnologyP.O.Box 2750Islamabad 44000Pakistan Near East University Operational Research Center in HealthcareNear East BoulevardPC:99138 Nicosia/Mersin 10Turkey Section of Mathematics International Telematic University UninettunoCorso Vittorio Emanuele II3900186 RomaItaly University of Jeddah College of ScienceDepartment of StatisticsJeddahSaudi Arabia

Nonlinear fractional differential equations provide suitable models to describe real-world phenomena and many fractional derivatives are varying with time and *** present study considers the advanced and broad spectrum of the nonlinear(NL)variable-order fractional differential equation(VO-FDE)in sense of VO Caputo fractional derivative(CFD)to describe the physical *** VO-FDE transforms into an ordinary differential equation(ODE)and then solving by the modified(G/G)-expansion *** ac-curacy,the space-time VO fractional Korteweg-de Vries(KdV)equation is solved by the proposed method and obtained some new types of periodic wave,singular,and Kink exact *** newly obtained solutions confirmed that the proposed method is well-ordered and capable implement to find a class of NL-VO *** VO non-integer performance of the solutions is studied broadly by using 2D and 3D graphical *** results revealed that the NL VO-FDEs are highly active,functional and convenient in explaining the problems in scientific physics.

关键词： Space-time VO fractional KdV equation modiﬁed(G′/G)-expansion method VO Caputo fractional derivative generalized Riccati equation

Shadows and weak gravitational lensing for black holes within Einstein-Maxwell-scalar theory

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Chinese physics C 2024年第9期48卷 234-243页

作者： ahmad Al-Badawi Mirzabek Alloqulov Sanjar Shaymatov Bobomurat Ahmedov Department of physics Al-Hussein Bin Talal UniversityP.O.Box:20Ma'an 71111Jordan Institute of Fundamental and Applied Research National Research University TIIAMEKori Niyoziy 39Tashkent 100000Uzbekistan University of Tashkent for Applied Sciences Str.Gavhar 1Tashkent 100149Uzbekistan Institute for Theoretical physics and Cosmology Zhejiang University of TechnologyHangzhou 310023China Western Caspian University Baku AZ1001Azerbaijan

In this study,we investigated the optical properties of charged black holes within the Einstein-Maxwellscalar(EMS)*** evaluated the shadow cast by these black holes and obtained analytical solutions for both the radius of the photon sphere and that of the *** observed that black hole parametersγandβboth influence the shadow of black *** also found that the photon sphere and shadow radius increase as a consequence of the presence of the parameterγ.Interestingly,the shadow radius decreases first and then remains unchanged owing to the impact of the parameterβ.Finally,we analyzed the weak gravitational lensing and total magnification of lensed images around black *** found that the charge of the black holes and the parameterβboth have a significant impact,reducing the deflection ***,the same behavior for the total magnification was observed,also as a result of the effect of the charge of the black holes and the parameterβ.

关键词： Einstein Maxwell gravity shadow gravitational weak lensing

Understanding the catalytic performance and deactivation behaviour of second-promoter doped pt/WO_(χ)/γ-Al_(2)O_(3) catalysts in the glycerol hydrogenolysis for selective and cleaner production of 1,3-propanediol

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Journal of Energy Chemistry 2024年第7期94卷 486-507页

作者： Rafik Rajjak Shaikh Sittichai Damruang Rais ahmad Khan Supareak praserthdam piyasan praserthdam Center of Excellence on Catalysis and Catalytic Reaction Engineering(CECC) Department of Chemical EngineeringFaculty of EngineeringChulalongkorn UniversityBangkok 10330Thailand Department of Chemistry College of ScienceKing Saud UniversityP.O.Box 2455Riyadh 11451Saudi Arabia High-performance Computing Unit(CECC-HCU) Centre of Excellence on Catalysis and Catalytic Reaction Engineering(CECC)Department of Chemical EngineeringFaculty of EngineeringChulalongkorn UniversityBangkok 10330Thailand

The selective aqueous-phase glycerol hydrogenolysis is a promising reaction to produce commercially useful 1,3-propanediol(1,3-pDO).The pt-WOx bifunctional catalyst can catalyse the glycerol hydrogenol-ysis but the catalyst deactivation via sintering,metal leaching,and coking can predominantly occur in the aqueous phase *** this work,the effect of reaction temperature,pressure and second promoter(Cu,Fe,Rh,Mn,Re,Ru,Ir,Sn,B,and p)on catalytic performance and deactivation behaviour of pt/WOx/-Al2O3 was *** doped with Rh,Mn,Re,Ru,Ir,B,and p,the second promoter boosts catalytic activity by promoting great dispersion of pt on support and increasing pt surface *** increased Bronsted acid sites lead to selective synthesis of 1,3-pDO than 1,2-propanediol(1,2-pDO).The characterization studies of fresh and spent catalysts reveal that the main cause of catalyst deactivation is the pt sintering,as interpreted based on XRD,CO chemisorption,and TEM *** pt sintering is affected depending on the second promoter that can either or reduce the interaction between pt,WO_(χ)/γ and Al_(2)O_(3).As an electron acceptor of pt in pt/WO_(χ)/γ-Al_(2)O_(3),Re and Mn as second promoters resulted in increased pt^(2+) on the catalytic surface,which strengthens the contact between pt andγ-Al_(2)O_(3) and WO_(χ),resulting in a decrease in pt *** metal leaching and coking are not affected by the presence of second *** catalyst modified with a second promoter possesses improved catalytic activity and 1,3-pDO production,however the stability continues to remain a *** present work unrav-elled the determining parameters of catalytic activity and deactivation,thus providing a promising pro-tocol toward effective catalysts for glycerol hydrogenolysis.

关键词： Glycerol hydrogenolysis 1,3-propanediol Metal-support interaction Second promoter Liquid phase Catalyst deactivation

Volume-complementary bipolar layered oxide enables stable symmetric sodium-ion batteries

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Nano Research 2024年第5期17卷 4125-4133页

作者： Bo peng Feng Wang Nazir ahmad Lai Yu Shenghua Chen Genqiang Zhang School of Materials Science and Engineering Key Laboratory of Efficient Conversion and Solid-state Storage of Hydrogen and Electricity of Anhui ProvinceAnhui University of TechnologyMa’anshan 243002China Hefei National Research Center for physical Sciences at the Microscale Chinese Academy of Sciences(CAS)Key Laboratory of Materials for Energy ConversionDepartment of Materials Science and EngineeringUniversity of Science and Technology of ChinaHefei 230026China National Innovation platform(Center)for Industry-Education Integration of Energy Storage Technology School of Chemical Engineering and TechnologyXi’an Jiaotong UniversityXi’an 710049China

The commercialization of sodium-ion batteries is based on developing low-cost,highly stable,and safe cathode and anode ***,the promising hard carbon anode and layered oxide cathode suffer from low sodium-embedded potential near 0.1 V and severe phase transitions,which cause safe problem and short lifespan,***,we design a low-strain bipolar p2-Na_(0.7)Ni_(0.25)Fe_(0.2)Ti_(0.55)O_(2) to solve the mentioned obstacles,whereas(Ni,Fe)and Ti provide charge compensation when it is used as cathode and anode,*** is revealed that the bipolar layered oxide undergoes solid-solution reaction when used as cathode or anode,and exhibits volume-complementary feature in a sodium-ion full-cell,as identified by in-situ X-ray ***,the safe symmetric sodium-ion full-cell exhibits excellent cyclic stability with 91.7%capacity retention after 200 *** work will provide a new horizon for designing safe and stable sodium-ion batteries.

关键词： sodium-ion batteries bipolar layered oxides solid-solution reaction volume complementation symmetric battery

Association of spiritual well-being with quality of life among undergraduate nursing students

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Journal of Integrative Nursing 2024年第1期6卷 49-54页

作者： ahmad SHAHID Hina HUSSAIN Nazia SHUAIB ahmad RASOOL Fatima YOUNIS Zoya NASAB Department of Nursing Professional College of Nursing and Health SciencesIslamabadPakistan Department of Nursing Rawal Institute of Health SciencesIslamabadPakistan Department of Nursing Rawal College of NursingIslamabadPakistan School of Nursing and Health Zhengzhou UniversityZhengzhouChina

Objective:The study was conducted with the aim of determining the spiritual well-being(SWB)of nursing students and its association with quality of life(QOL).Materials and Methods:A cross-sectional analytical study was conducted with a sample size of 504 nursing students collected from January 2023 to March 2023 in the nursing institutes of Khyber pakhtunkhwa,pakistan,using convenient sampling techniques.A Spiritual Health and Life-Orientation Measure(SHALOM)questionnaire for SWB and K-27 QOL(K-27 QOL)instrument were used for data collection that contains three ***:The number of female participants was in the majority(50.4%)compared to male nurses(49.6%).The overall mean score of SWB of the students was 3.79±0.48,while the mean K-27 QOL score was 3.73±*** were significant differences between the groups of gender(p=0.001),while no significant difference within the groups of semester(p=0.061)and college status(0.285).In QOL,there were significant differences within the groups of semester(p=0.000)and college status(p=0.036)while no significant difference in gender category(p=0.480).SHALOM score is positively and moderately correlated with QOL score(r=0.597,ppiritual practices are one of the important factors that are associated positively with QOL,therefore to enhance the QOL,it will require spiritual practices.

关键词： Nursing education nursing student quality of life spiritual nursing care spirituality well‑being

A Measurement Study of the Ethereum Underlying p2p Network

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Computers, Materials & Continua 2024年第1期78卷 515-532页

作者： Mohammad ZMasoud Yousef Jaradat ahmad Manasrah Mohammad Alia Khaled Suwais Sally Almanasra Electrical Engineering Department Al-Zaytoonah University of JordanAmman11733Jordan Mechanical Engineering Department Al-Zaytoonah University of JordanAmman11733Jordan Computer Science Department Al-Zaytoonah University of JordanAmman11733Jordan Faculty of Computer Studies Arab Open UniversityRiyadh11681Saudi Arabia

This work carried out a measurement study of the Ethereum peer-to-peer(p2p)network to gain a better understanding of the underlying *** was applied because it pioneered distributed applications,smart contracts,and ***,its application layer language“Solidity”is widely used in smart contracts across different public and private *** this end,we wrote a new Ethereum client based on Geth to collect Ethereum node ***,various web scrapers have been written to collect nodes’historical data fromthe Internet Archive and the Wayback Machine *** collected data has been compared with two other services that harvest the number of *** has collectedmore than 30% more than the other *** data trained a neural network model regarding time series to predict the number of online nodes in the *** findings show that there are less than 20% of the same nodes daily,indicating thatmost nodes in the network change *** poses a question of the stability of the ***,historical data shows that the top ten countries with Ethereum clients have not changed since *** popular operating system of the underlying nodes has shifted from Windows to Linux over time,increasing node *** results have also shown that the number of Middle East and North Africa(MENA)Ethereum nodes is neglected compared with nodes recorded from other *** opens the door for developing new mechanisms to encourage users from these regions to contribute to this ***,the model has been trained and demonstrated an accuracy of 92% in predicting the future number of nodes in the Ethereum network.

关键词： Ethereum measurement ethereum client neural network time series forecasting web-scarping wayback machine blockchain

Orbit Weighting Scheme in the Context of Vector Space Information Retrieval

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Computers, Materials & Continua 2024年第7期80卷 1347-1379页

作者： ahmad Ababneh Yousef Sanjalawe Salam Fraihat Salam Al-E’mari Hamzah Alqudah Department of Computer Science Faculty of Information TechnologyAmerican University of MadabaAmman11821Jordan Department of Cybersecurity Faculty of Information TechnologyAmerican University of MadabaAmman11821Jordan Artificial Intelligence Research Center(AIRC) College of Engineering and Information TechnologyAjman UniversityP.O.Box 346Ajman13306United Arab Emirates Information Security Department Faculty of Information TechnologyUniversity of PetraAmman11196Jordan Department of Data Science and Artificial Intelligence Faculty of Information TechnologyAmerican University of MadabaAmman11821Jordan

This study introduces the Orbit Weighting Scheme(OWS),a novel approach aimed at enhancing the precision and efficiency of Vector Space information retrieval(IR)models,which have traditionally relied on weighting schemes like tf-idf and *** conventional methods often struggle with accurately capturing document relevance,leading to inefficiencies in both retrieval performance and index size *** proposes a dynamic weighting mechanism that evaluates the significance of terms based on their orbital position within the vector space,emphasizing term relationships and distribution patterns overlooked by existing *** research focuses on evaluating OWS’s impact on model accuracy using Information Retrieval metrics like Recall,precision,InterpolatedAverage precision(IAp),andMeanAverage precision(MAp).Additionally,we assessOWS’s effectiveness in reducing the inverted index size,crucial for model *** compare OWS-based retrieval models against others using different schemes,including tf-idf variations and *** reveal OWS’s superiority,achieving a 54%Recall and 81%MAp,and a notable 38%reduction in the inverted index *** highlights OWS’s potential in optimizing retrieval processes and underscores the need for further research in this underrepresented area to fully leverage OWS’s capabilities in information retrieval methodologies.

关键词： Information retrieval orbit weighting scheme semantic text analysis Tf-Idf weighting scheme vector space model