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Frontiers of Chemical Science and Engineering 2022年第5期16卷 564-591页

作者： Pei Sean Goh Kar Chun Wong Tuck Whye Wong ahmad fauzi ismail Advanced Membrane Technology Research Centre(AMTEC) School of Chemical and Energy EngineeringFaculty of EngineeringUniversiti Teknologi Malaysia81310 Johor BahruMalaysia

Polyamide thin film composite membranes have dominated current reverse osmosis market on account of their excellent separation performances compared to the integrally skinned *** their very promising separation performance,chlorine-induced degradation resulted from the susceptibility of polyamide toward chlorine attack has been regarded as the Achilles’s heel of polyamide thin film *** free chlorine species present during chlorine treatment can impair membrane performance through chlorination and depolymerization of the polyamide selective *** material point of view,a chemically stable membrane is crucial for the sustainable application of membrane separation process as it warrants a longer membrane lifespan and reduces the cost involved in membrane *** strategies,particularly those involved membrane material optimization and surface modifications,have been established to address this *** review discusses membrane degradation by free chlorine attack and its correlation with the surface chemistry of *** advancement in the development of chlorine resistant polyamide thin film composite membranes is reviewed based on the state-of-the-art surface modifications and tailoring approaches which include the in situ and postfabrication membrane modifications using a broad range of functional *** challenges and future directions in this field are also highlighted.

关键词： reverse osmosis polyamide thin film composite membranes chlorine resistance surface modification

Surface modification of magnesium alloys using thermal and solid-state cold spray processes:Challenges and latest progresses

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Journal of Magnesium and Alloys 2022年第8期10卷 2025-2061页

作者： Mohammadreza Daroonparvar Hamid Reza Bakhsheshi-Rad Abbas Saberi Mahmood Razzaghi Ashish K Kasar Seeram Ramakrishna Pradeep L.Menezes Manoranjan Misra ahmad fauzi ismail Safian Sharif Filippo Berto Department of Mechanical Engineering University of NevadaRenoNV89501USA Advanced Materials Research Center Department of Materials EngineeringNajafabad BranchIslamic Azad UniversityNajafabadIran Department of Mechanical Engineering National University of Singapore9 Engineering Drive 1Singapore 117576Singapore Department of Chemical and Materials Engineering University of NevadaRenoNV89501USA Advanced Membrane Technology Research Center(AMTEC) Universiti Teknologi MalaysiaJohor Bahru 81310JohorMalaysia Faculty of Engineering Universiti Teknologi MalaysiaJohor Bahru 81310JohorMalaysia Department of Mechanical and Industrial Engineering Norwegian University of Science and Technology7491 TrondheimNorway

Potential engineering applications of magnesium(Mg)and Mg-based alloys,as the lightest structural metal,have made them a popular subject of ***,the inferior corrosion and wear characteristics significantly limit their application *** is widely recognized that surface treatment is the most commonly utilized technique for remarkably improving a substrate’s surface *** methods have been introduced for the surface treatment of Mg and Mg-based alloys to improve their corrosion behavior and tribological *** these,thermal spray(TS)technology provides several methods for deposition of various functional metallic,ceramic,cermet,or other coatings tailored to particular *** researches have shown the tremendous potential for thermal spray coated Mg alloys for biomedical and industrial *** this context,the cold spray(CS)method,as a comparatively new TS coating technique,can generate the coating layer using kinetic energy rather than combined thermal and kinetic energies,like the high-velocity oxy-fuel(HVOF)spray ***,the CS process,as a revolutionary method,is able to repair and refurbish with a faster turnaround time;it also provides solutions that do not require dealing with the thermal stresses that are part of the other repair processes,such as welding or other TS processes using a high-temperature *** this review paper,the recently designed coatings that are specifically applied to Mg alloys(primarily for industrial applications)employing various coating processes are *** of the increased utilization of CS technology for both 3D printed(additively manufactured)coatings and repair of structurally critical components,the most recent CS methods for the surface treatment,repair,and refurbishment of Mg alloys as well as their benefits and restrictions are then discussed and reviewed in ***,the prospects of this field of study are briefly discussed,along with a summa

关键词： Mg-based alloys Surface modification Thermal and cold spray processes Corrosion behavior Wear resistance

Potential use of nanofiltration like-forward osmosis membranes for copper ion removal

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Chinese Journal of Chemical Engineering 2020年第2期28卷 420-428页

作者： Wan Nur Ain Shuhada Abdullah Sirinan Tiandee Woeijye Lau Farhana Aziz ahmad fauzi ismail Advanced Membrane Technology Research Centre(AMTEC) Universiti Teknologi Malaysia81310 SkudaiJohorMalaysia School of Chemical and Energy Engineering Universiti Teknologi Malaysia81310 SkudaiJohorMalaysia Faculty of Science and Industrial Technology Prince of Songkla UniversitySurat Thani Campus84000 Surat ThaniThailand

The discharge of industrial effluent containing heavy metal ions would cause water pollution if such effluent is not properly *** this work,the performance of emerging nanofiltration(NF)like-forward osmosis(FO)membrane was evaluated for its efficiency to remove copper ion from ***,copper ion is removed from aqueous solution via adsorption and/or ion-exchange *** engineered osmosis method as proposed in this work considered four commercial NF membranes(i.e.,NF90,DK,NDX and PFO)where their separation performances were accessed using synthetic water sample containing 100 mg·L-1 copper ion under FO and pressure retarded osmosis(PRO)*** findings indicated that all membranes could achieve almost complete removal of copper regardless of membrane orientation without applying external driving *** high removal rates were in good agreement with the outcomes of the membranes tested under pressuredriven mode at 1 *** use of appropriate salts as draw solutes enabled the NF membranes to be employed in engineered osmosis process,achieving a relatively low reverse solute *** findings showed that the best performing membrane is PFO membrane in which it achieved N 99.4%copper rejection with very minimum reverse solute flux of<1 g·m-2·h-1.

关键词： Nanofiltration Forward osmosis Copper Divalent salt Water flux

Performance evaluation of polyamide nanofiltration membranes for phosphorus removal process and their stability against strong acid/alkali solution

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Chinese Journal of Chemical Engineering 2019年第8期27卷 1789-1797页

作者： Yen Khai Chai How Chun Lam Chai Hoon Koo Woei Jye Lau Soon Onn Lai ahmad fauzi ismail Department of Civil Engineering Lee Kong Chian Faculty of Engineering and ScienceUniversiti Tunku Abdul RahmanJalan Bandar Sg.LongBandar Sg.Long43000 KajangSelangorMalaysia Advanced Membrane Technology Research Centre(AMTEC) Universiti Teknologi Malaysia81310 SkudaiJohorMalaysia Department of Chemical Engineering Lee Kong Chian Faculty of Engineering and ScienceUniversiti Tunku Abdul RahmanJalan Bandar Sg.LongBandar Sg.Long43000 KajangSelangorMalaysia

In this study,a quantitative performance of three commercial polyamide nanofiltration(NF) membranes(i.e.,NF,NF90,and NF270) for phosphorus removal under different feed conditions was *** experiments were conducted at different feed phosphorus concentrations(2.5,5,10,and 15 mg·L^-1) and elevated pHs(pH 1.5,5,10,and 13.5) at a constant feed pressure of 1 MPa using a dead-end filtration *** rejection against total phosphorus generally increased with increasing phosphorus concentration regardless of membrane *** contrast,the permeate flux for all the membranes only decreased slightly with increasing phosphorus *** results also showed that the phosphorus rejections improved while water flux remained almost unchanged with increasing feed solution *** the three membranes were exposed to strong pHs(pH 1.5 and 13.5) for a longer duration(up to 6 weeks)it was found that the rejection capability and water flux of the membranes remained very similar throughout the duration,except for NF membrane with marginal decrement in phosphorus *** study also revealed that more phosphorus was adsorbed onto the membrane structure at alkaline conditions(pH 10 and 13.5) compared to the same membranes tested at lower pHs(pH 1.5 and 5).In eonelusion,NF270 membrane outperformed Nf and NF90 membranes owing to its desirable performance of water flux and phosphorus rejection particularly under strong alkali *** NF270 membrane achieved 14.0 L·m^-2·h^-1 and 96.5% rejection against 10 mg·L^-1 phosphorus solution with a pH value of 13.5 at the applied pressure of 1 MPa.

关键词： Membrane Nanofiltration Phosphorus removal pH Stability Humic acid

Eco-friendly method for synthesis of zeolitic imidazolate framework 8 decorated graphene oxide for antibacterial activity enhancement

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Particuology 2020年第2期18卷 24-32页

作者： Nazerah ahmad Nik Abdul Hadi Md Nordin Juhana Jaafar Nik ahmad Nizam Nik Malek ahmad fauzi ismail Muhammad Nabil Fikri Yahya Siti Aishah Mohd Hanim Mohd Sohaimi Abdullah Advanced Membrane Technology Research Centre Universiti Teknologi Malaysia81310 SkudaiJohorMalaysia Malaysian Institute of Chemical Engineering Technology-Universiti Kuala Lumpur Lot 1988Bandar VendorTaboh Naning78000 Alor GajahMelakaMalaysia Chemical Engineering Department Universiti Teknologi PETRONAS32610 Seri IskandarPerakMalaysia Department of Biosciences Faculty of ScienceUniversiti Teknologi Malaysia81310 SkudaiJohorMalaysia Centre for Student Innovation and Technology Entrepreneurship Universiti Teknologi Malaysia81310 SkudaiJohorMalaysia

We report a rapid method for synthesis of zeolitic imidazolate framework 8(ZIF-8)-decorated graphene oxide(GO)composites(ZGO)with good antibacterial *** ZGO composites were synthesized at room temperature with low GO to metal salt *** samples were characterized by X-ray diffraction,transmission electron microscopy,Fourier transform infrared spectroscopy,thermal gravimetric analysis,and surface area *** characterization results show that ZIF-8 with a size of approximately 120 nm is successfully decorated on the surface of GO sheets with the host ZIF-8 framework maintained in the synthesized composite,but there is a significant reduction in the Brunauer-Emmett-Teller surface *** antibacterial activities of the samples against Escherichia coli ATCC 11229 and Staphylococcus aureus ATCC 6538 as model strains of gram-negative and-positive bacteria,respectively,were determined by disc diffusion and minimum inhibitory concentration(MIC)***-1.0(1 wt%of ratio of GO to metal salt)shows the highest antibacterial activity with MIC values required to inhibit bacterial growth of *** and *** of 5 times lower than those of pristine *** antibacterial mechanisms are proposed based on field-emission scanning electron microscope images of the two bacteria after contact with the synthesized ***,owing to the simple synthesis,good stability,low chemical usage,and excellent antibacterial activity of the ZGO composites,they show great potential for application in the field of microbial contamination control.

关键词： Graphene oxide Metal-organic framework Hybrid nanocomposite Zeolitic imidazolate framework Antibacterial agent

Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes

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Journal of Advanced Ceramics 2017年第4期6卷 330-340页

作者： Mohammed Abdulmunem ABDULHAMEED Mohd Hafiz Dzarfan OTHMAN Haider Nadhom Azziz Al JODA ahmad fauzi ismail Takeshi MATSUURA Zawati HARUN Mukhlis A.RAHMAN Mohd Hafiz PUTEH Juhana JAAFAR Advanced Membrane Technology Research Centre(AMTEC) Faculty of Chemical and Energy EngineeringUniversiti Teknologi Malaysia81310 UTM Johor BahruJohorMalaysia Department of Petroleum and Petrochemical Engineering Engineering CollegeKerbala University56001 KerbalaIraq Department of Chemical and Biological Engineering University of OttawaOttawaOntarioK1N 6N5Canada Advanced Manufacturing&Materials Centre(AMMC) Faculty of Mechanical and Manufacturing EngineeringUniversiti Tun Hussein Onn MalaysiaParit Raja86400 Batu PahatJohorMalaysia Department of Environmental Engineering Faculty of Civil EngineeringUniversiti Teknologi Malaysia81310 UTM Johor BahruJohorMalaysia

Affordable hydrophobic hollow fibre membranes were prepared using kaolin and alumina based ceramic powders via a combined phase inversion and sintering technique,followed by a grafting with fluoroalkylsilane(FAS).The crux of the matter in this paper is to study the changes in the properties of the hollow fibre membranes(gas permeation,mechanical strength,pore size,porosity,tortuosity,morphology,and contact angle)by the addition of alumina(Al2O3)to the pure kaolin with mono or multiparticle *** varying the overall loading and particle size of alumina addition,different morphologies of the membranes were obtained due to the differences in the path lengths during phase inversion process for each solvent and nonsolvent *** successful grafting with FAS was evidenced by the increase in contact angle from nearly equal to zero degree before grafting to 140°after ***-alumina-4,one of the hollow fibres fabricated in this work,achieved a mean pore size of 0.25μm with the bending strength of 96.4 MPa and high nitrogen permeance of 2.3×10^(-5) mol·m^(-2)·Pa^(-1)·s^(-1),which makes the hollow fibre most suitable for the membrane contactor application.

关键词： ceramic membrane contactor hollow fibre kaolin hydrophobic

骨组织工程用可降解多孔含银镁基支架的合成及体外性能（英文）

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Transactions of Nonferrous Metals Society of China 2019年第5期29卷 984-996页

作者： Hamid Reza BAKHSHESHI-RAD Ehsan DAYAGHI ahmad fauzi ismail Madzlan AZIZ Ali AKHAVAN-FARID Xiongbiao CHEN Advanced Materials Research Center Department of Materials Engineering Najafabad Branch Islamic Azad University Advanced Membrane Technology Research Center (AMTEC) Universiti Teknologi Malaysia Department of Mechanical Engineering College of Engineering University of Saskatchewan Department of Mechanical Materials and Manufacturing Engineering University of Nottingham Malaysia Campus Division of Biomedical Engineering College of Engineering University of Saskatchewan

感染是骨损伤临床治疗中常见的并发症。镁基复合材料是一种可生物降解的抗菌生物材料,已被用于减少术后感染。本文作者合成含银镁基骨组织工程支架材料,并对其进行体外表征。通过造孔剂法制备4种不同银含量(0、0.5、1、和2 wt.%)的多孔... 详细信息

感染是骨损伤临床治疗中常见的并发症。镁基复合材料是一种可生物降解的抗菌生物材料,已被用于减少术后感染。本文作者合成含银镁基骨组织工程支架材料,并对其进行体外表征。通过造孔剂法制备4种不同银含量(0、0.5、1、和2 wt.%)的多孔镁基支架,用Mg-Ca-Mn-Zn-xAg (MCMZ-xAg)表示,其中x表示银含量。研究银含量对材料的孔隙结构、力学性能、生物活性和抑菌区的影响。采用X射线衍射分析(XRD)、扫描电镜(SEM)、透射电镜(TEM)和荧光显微镜对支架进行表征。体外腐蚀试验结果表明,银含量低的支架比银含量高的支架具有更好的耐腐蚀性。抗菌活性的检测结果表明MCMZ-Ag支架具有显著抑制大肠杆菌和(***)和金黄色葡萄球菌(***)生长的作用,且随着含银量的增加,MCMZ-Ag支架周围的抑菌区面积逐渐增加。然而,含银量过高会增加材料的细胞毒性。总之,含0.5wt.%Ag的支架因其具有连通的孔隙、足够的力学性能、抗菌活性和细胞黏附性能,在修复与替换受损和患病骨方面具有应用前景。

关键词：镁基支架生物相容性抗菌活性生物活性腐蚀行为

Effect of Synthesis Technique and Carbonate Content on the Crystallinity and Morphology of Carbonated Hydroxyapatite

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Journal of Materials Science & Technology 2013年第8期29卷 761-764页

作者： Chia Ching Kee Hanafi ismail ahmad fauzi Mohd Noor School of Materials and Mineral Resources Engineering Engineering CampusUniversiti Sains Malaysia14300 Nibong TebalPenangMalaysia

The syntheses of nanosized carbonated hydroxyapatite （CHA） were performed by comparing dropwise and direct pouring of acetone solution of Ca（NO3）2·4H2O into mixture of （NH4）2HPO4 and NH4HCO3 at room temperature controlled at pH 11. Direct pouring method was later applied to study the increment of carbonate content in syntheses. The as-synthesized powders were characterized by various characterization techniques. The crystallographic results of the produced powders were obtained from X-ray diffraction analysis, whilst the carbonate content in the produced powders was determined by the CHNS/O elemental analyzer. Fourier transform infrared analysis confirmed that the CHA powders formed were B-type. Field emission scanning electron microscopy revealed that the powders were highly agglomerated in nanosized range and hence energy filtered transmission electron microscopy was employed to show elongated particles which decreased with increasing carbonate content.

关键词： Bioceramic Carbonated hydroxyapatite Dropwise Direct pouring

Addition of surfactants to Low Salinity Waterflooding in microfluidics system to increase oil recovery

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Petroleum Research 2022年第4期7卷 486-494页

作者： Dito fauzi Winanda Sanggono Adisasmito Department of Chemical Engineering Institut Teknologi BandungPostal Address:Jalan Ganesha No.10Bandung 40132Indonesia Jalan Ganesha No.10 Bandung 40132Indonesia

This study was conducted to investigate the phenomenon of oil removal from inside pores using a self-designed microfluidic test *** artificial micromodel chip as a representation of porous rocks has been created with a uniform pore structure design and made of PMMA(Polymethyl Methacrylate)*** micromodel chip has a porosity of 27.8%as well as a permeability of 2.7 *** using the microfluidic test kit,this study has investigated how low salinity water(LSW)injection with MgCl_(2)divalent ions and the addition of anionic surfactant,linear alkylbenzene sulfonate mixed with nonionic surfactants,nonylphenol ethoxylate(NP-10)affects to oil *** injection of LSW and surfactant solution was carried out with different injection stages,injection rates and surfactant solutions *** images during the injection process are recorded for analysis,which is the advantage of dynamic testing using this microfluidic test kit over conventional *** this study,it is indicated that the selection of ions contained in LSW affects the success of LSW *** the surfactant injection rate from 50 mL/min to 20 mL/min can increase the oil recovery from 1.27%to 4.29%.Oil recovery was also higher on surfactant injection which resulted in lower interfacial tension of the system based on the calculation of interfacial tension obtained from the Chun-Huh and Ghosh equations from the Winsor *** all injection scenarios carried out in this study,the highest increase in oil recovery of 26.87%OOIP was obtained by injecting surfactant solutions directly in the secondary stage without prior LSW injection.

关键词： Low salinity waterflooding Microfluidic test kit Micromodel chip Oil recovery Surfactant

Voice to Face Recognition Using Spectral ERB-DMLP Algorithms

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Computers, Materials & Continua 2022年第10期73卷 2187-2204页

作者： fauzi A.Bala Osman N.Ucan Oguz Bayat School of Engineering and Natural Science Altinbas University34217Turkey College of Engineering Electrical and Electronic EngineeringMisurata UniversityLibya

Designing an authentication system for securing the power plants are important to allow only specific staffs of the power plant to access the certain blocks so that they can be restricted from using high risk-oriented *** authentication is also vital to prevent any security threats or risks like compromises of business server,release of confidential data *** conventional works attempted to accomplish better authentication,they lacked with respect to ***,the study aims to enhance the recognition rate by introducing a voice recognition system as a personal authentication based on Deep Learning(DL)due to its ability to perform effective *** study proposes Equivalent Rectangular Bandwidth and Deep Multi-Layer Perceptron(ERB-DMLP)as it has the ability to perform efficient and relevant feature extraction and faster *** algorithm also has the ability to establish effective correlation between voices and images and achieve the semantic relationship between *** preprocessing is initially performed to make it suitable for further processing by removing the noise and enhancing the quality of *** process is also vital to minimize the extra computations so that the overall efficacy of the system can be made flexible by considering the audio files as features and the images as labels to identify a person’s voice by classifying the extracted features from the ERB Feature *** is then passed as the input into DMLP model to classify the persons,and trained the model to make an accurate classification of audio with corresponding image labels,and perform the performance test based on the trained ***,relevant feature extraction and faster classification ability of the proposed work has made it explore better outcomes that is confirmed through results.

关键词： Authentication system power plant equivalent rectangular bandwidth deep multi-layer perceptron convolution neural network