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Toward a comprehensive hypothesis of oxygen-evolution reaction in the presence of iron and gold

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Journal of Energy Chemistry 2024年第2期89卷 172-183,I0005页

作者： Negah Hashemi Jafar hussain Shah Cejun Hu Subhajit Nandy Pavlo Aleshkevych Sumbal Farid Keun Hwa Chae Wei Xie Taifeng Liu Junhu Wang Mohammad Mahdi Najafpour Department of Chemistry Institute for Advanced Studies in Basic Sciences(IASBS)Zanjan 45137-66731Iran Center for Advanced Mössbauer Spectroscopy Mössbauer Effect Data CenterDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina Key Lab of Advanced Energy Materials Chemistry(Ministry of Education) Renewable Energy Conversion and Storage CenterCollege of ChemistryNankai UniversityTianjin 300071China Advanced Analysis Center Korea Institute of Science and TechnologySeoul 02792Republic of Korea Institute of Physics Polish Academy of SciencesWarsaw 02-668Poland National and Local Joint Engineering Research Center for Applied Technology of Hybrid Nanomaterials Henan UniversityKaifeng 475004HenanChina Center of Climate Change and Global Warming Institute for Advanced Studies in Basic Sciences(IASBS)Zanjan 45137-66731Iran Research Center for Basic Sciences&Modern Technologies(RBST) Institute for Advanced Studies in Basic Sciences(IASBS)Zanjan 45137-66731Iran

This study investigates the effects of Fe on the oxygen-evolution reaction(OER)in the presence of *** distinct areas of OER were identified:the first associated with Fe sites at low overpotential(~330 mV),and the second with Au sites at high overpotential(~870 mV).Various factors such as surface Fe concentration,electrochemical method,scan rate,potential range,concentration,method of adding K_(2)Fe O_(4),nature of Fe,and temperature were varied to observe diverse behaviors during OER for Fe O_(x)H_(y)/*** amounts of Fe ions had a significant impact on OER,reaching a saturation point where the activity did not increase *** electronic interaction between Fe and Au ions was indicated by X-ray photoelectron spectroscopy(XPS)and electron paramagnetic resonance(EPR)*** situ visible spectroscopy confirmed the formation of Fe O_(4)^(2-)during *** situ Mossbauer and surfaceenhanced Raman spectroscopy(SERS)analyses suggest the involvement of Fe-based species as intermediates during the rate-determining step of OER.A lattice OER mechanism based on Fe O_(x)H_(y)was proposed for operation at low *** functional theory(DFT)calculations revealed that Fe oxide,Fe-oxide clusters,and Fe doping on the Au foil exhibited different activities and stabilities during *** study provides insights into the interplay between Fe and Au in OER,advancing the understanding of OER mechanisms and offering implications for the design of efficient electrocatalytic systems.

关键词： DFT calculation Fe/Au electrocatalysis Mechanism Oxygen evolution Water oxidation

Enhancing alkyne semi-hydrogenation through engineering metal-support interactions of Pd on oxides

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Nano Research 2024年第5期17卷 3707-3713页

作者： Yuefeng Wu Xiaotong Lu Pengfei Cui Wenyu Jia Jun Zhou Yuan Wang hussain Zahid Yuxin Wu Muhammad Umer Rafique Xiong Yin Baoshan Li Leyu Wang Guolei Xiang State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing 100029China CAS Key Laboratory of Science and Technology on Applied Catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China College of Chemical Engineering Beijing University of Chemical TechnologyBeijing 100029China

Supported Pd catalysts show superior activities for olefin productions from alkynes through semi-hydrogenation reactions,but over-hydrogenation into alkanes highly decreases olefin *** phenylacetylene semi-hydrogenation as a model reaction,here we explore the optimization approaches toward better Pd catalysts for alkyne semi-hydrogenation through investigating support effect and metal-support *** results show that the states of Pd with supports can be tuned by varying oxide reducibility,loading ratios,and *** our system,0.06 wt.%Pd on rutile-TiO_(2) nanorods shows the highest activity owing to the synergistic effects of single-atoms and *** reducibility can change the filling degrees of Pd 4d orbitals through varying interfacial bonding strengths,which further affect catalytic activity and selectivity.

关键词： alkyne semi-hydrogenation support effect metal-support interaction Pd catalyst single-atom catalyst

能源地带和绿色道路 ——以伊朗、巴基斯坦和安哥拉的一带一路为例

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能源地带和绿色道路 ——以伊朗、巴基斯坦和安哥拉的一带一路为例

作者： hussain Shahid 吉林大学

学位级别：硕士

在资本主义世界经济中,2008年的全球金融危机对全球经济产生了深远的影响,促使中国认识到迫切需要加强主权国家之间的合作和相互依存,以遏制和缓解当前和未来的金融危机。从2013年开始,中国政府决定启动“一带一路”倡议,即现在广为人... 详细信息

在资本主义世界经济中,2008年的全球金融危机对全球经济产生了深远的影响,促使中国认识到迫切需要加强主权国家之间的合作和相互依存,以遏制和缓解当前和未来的金融危机。从2013年开始,中国政府决定启动“一带一路”倡议,即现在广为人知的“一带一路”倡议(The BRI Initiative)。基本上,除了中国的国内因素外,“一带一路”倡议旨在支持全球欠发达国家,特别关注跨区域基础设施发展和能源合作。截至2023年8月,根据《2023年中国“一带一路”倡议投资报告》,过去10年累计参与“一带一路”倡议达到1万亿美元大关(1.016万亿美元)的历史纪录。这主要由约5,960亿美元的基础设施建设合同和4,200亿美元的非金融投资组成。其中,自2013年宣布“一带一路”倡议以来,能源领域一直是“一带一路”跨区域合作计划中最重要的部分之一。在此背景下,在本IR硕士论文中,笔者计划研究中国与三个东道国在“一带一路”框架下的跨区域能源合作关系:(1)伊朗、(2)巴基斯坦和(3)安哥拉。具体而言,在研究设计方面,这是为了发现“一带一路”倡议对这些东道国绿色能源合作项目的积极影响。然后,我们考察了三个不同东道国在同一时期内如何体验“一带一路”跨区域绿色能源合作及发展情况。首先,本文概述了有关2008年全球金融危机的背景知识,进而概述了在所谓“(全球性的)地缘经济碎片化”的宏观背景下中国如何通过“一带一路”倡议做出新的应对方案。时至今日,根据“一带一路”总体规划,中国一直强调中国与“一带一路”成员国之间能源合作的重要性,以及基础设施合作作为支持互利发展的积极作用。本文的主要研究问题如下:“一带一路”倡议如何推进与其他发展中国家的绿色能源合作项目?为了回答这个问题,我们将对(1)伊朗、(2)巴基斯坦和(3)安哥拉进行较为深入的案例研究,特别关注它们在“一带一路”倡议下的跨区域绿色能源合作项目。在此背景下,我们分别分析了三个东道国的全球、区域和国内的不同情况。这与全球市场在宏观层面上的“地缘经济碎片化”以及它们在微观层面与中国的绿色能源合作项目密切相关。这将包括部分塑造“一带一路”结果的其他外部因素。譬如,从案例分析的视角看,这与它们的地缘政治现实密切相关:①对伊朗在中东地区形成的一种‘国际政治性的遏制’状态、②对巴基斯坦在南亚地区形成的一种‘地缘政治性的半遏制’状态以及 ③对安哥拉在非洲大陆形成的一种‘历史性的边缘化’状态。因此,这些案例研究的结果可以阐明中国与东道国之间相当复杂的地缘政治和地缘经济的互动关系,澄清“一带一路”的跨区域绿色能源合作项目所带来的新挑战和新机遇基于上述内容,这篇IR硕士论文由五章组成。在第一章中,它通过列出研究问题并简要概述‘债务陷阱外交’等争议及其在IR研究中的辩论作为引言。在这里,我们还通过关注中国与东道国之间的基础设施建设和(绿色)能源合作,探讨了“一带一路”不断增长的全球网络。更具体地说,这源于他们对绿色能源基础设施项目的迫切需求。有鉴于此,笔者试图深入研究“一带一路”的这些新绿色能源合作项目所带来的积极性经济影响然后,这部分将包括与中国“一带一路”相关的在全球经济方面‘地缘经济碎片化’的文献综述。因此,它为以下章节奠定了基础,并帮助我们建立一种分析框架。值得注意的是,在分析框架上,首先考察从“一带一路”到“能源带、绿色之路”范式的概念转变。通过这种方式,我们可以了解“一带一路”对能源合作及其绿色能源合作领域的积极影响。然后,在方法论上,笔者计划对三个“一带一路”东道国进行较为深入的案例研究:①中东的伊朗 ②南亚的巴基斯坦、③非洲的安哥拉。它可以为我们提供与“一带一路”倡议在不同区域和不同国家实施相关的具体挑战、机遇和结果之间的逻辑关系的见解。第二章重点研究伊朗与中国的绿色能源合作的第一个案例。为此,首先它提供了有关伊朗在21世纪资本主义世界经济中的‘不利’地缘政治地位的背景知识。这一部分对于理解伊朗在中国“一带一路”倡议背景下伊朗所面临的地缘政治挑战和经济机遇具有重要意义。然后,针对伊朗这个中东国家,我们深入探讨了伊朗在全球、区域和国内的现实情况,涉及国际社会宏观层面的‘地缘经济的碎片化’以及伊朗与中国在微观层面的全面能源合作关系。在此背景下,从双边全面能源合作关系的角度看,笔者继续分析“一带一路”倡议如何推动与伊朗的跨区域合作,如何促进伊朗的国内经济及其在中东地区的可持续性发展。具体而言,就伊朗与中国的全面能源合作而言,这可分为三个相互独立而又相互关联的领域:(1)“一带一路”倡议中以化石燃料为导向合作项目;(2)“一带一路”倡议中以绿色能源为导向的合作项目;(3)“一带一路”倡议中以可持续发展为导向的合作项目。基于这些,“一带一路”倡议显然可以改善伊朗以全面能源合作为中心的基础设施欠

关键词：一带一路绿色能源合作基础设施建设跨区域交通运输地缘政治

Chemical constituents and anticoagulant activity from Delphinium brunonianum Royle

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未来食品学报(英文) 2024年第3期4卷 241-247页

作者： Changyang Ma Sitan Chen Syed Arif hussain Rizvi Huihui Zhou Wenyi Kang Xuefeng Xi Zhenhua Liu National R&D Center for Edible Fungus Processing Technology Henan UniversityKaifeng 475004China Joint International Research Laboratory of Food&Medicine Resource Function Henan ProvinceKaifeng 475004China Pakistan Agricultural Research Council Islamabad 450000Pakistan College of Physical Education Henan UniversityKaifeng 475004China

Delphinium brunonianum Royle belongs to Ranunculaceae family and has the effects of dispelling wind to relieve itching and cooling blood to *** was found that the extracts of *** had good anticoagulant activity which was extracted with 70%ethanol in our previous ***,16 compounds were isolated and identified from the extract of ***,among which compounds 5,7-10,12,14,15-16 were isolated from this genus for the first time,and compounds 2-4 were isolated from this plant for the first *** the coagulation activity assay showed that compounds 10,14 and 15 had good anticoagulant activity by activated partial thromboplastin time(APTT),thrombin time(TT)and prothrombin time(PT)in vitro.

关键词： Delphinium brunonianum Royle 9-Hydroxy-megastigma-4,7-dien-3-one-9-β-Dglucopyranoside 4-O-α-D-Glucosyl benzoic acid Isolariciresinol 4-O-β-D-glucopyranoside Anticoagulant activity

Metal-organic framework-based single-atom electro-/ photocatalysts: Synthesis, energy applications, and opportunities

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Carbon Energy 2024年第1期6卷 1-43页

作者： Munir Ahmad Jiahui Chen Jianwen Liu Yan Zhang Zhongxin Song Shahzad Afzal Waseem Raza Liaqat Zeb Andleeb Mehmood Arshad hussain Jiujun Zhang Xian-Zhu Fu Jing-Li Luo Shenzhen Key Laboratory of Energy Electrocatalytic Materials Guangdong Research Center for Interfacial Engineering of Functional MaterialsCollege of Materials Science and EngineeringShenzhen UniversityShenzhenGuangdongChina College of Physics and Optoelectronic Engineering Shenzhen UniversityShenzhenGuangdongChina College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhenGuangdongChina Department of Environmental Engineering China Jiliang UniversityHangzhouZhejiangChina Institute for Advanced Study Shenzhen UniversityShenzhenGuangdongChina School of Bioengineering Dalian University of TechnologyDalianLiaoningChina College of Materials Science and Engineering Fuzhou UniversityFuzhouFujianChina Institute for Sustainable Energy Shanghai UniversityShanghaiChina

Single-atom catalysts(SACs)have gained substantial attention because of their exceptional catalytic ***,the high surface energy limits their synthesis,thus creating significant challenges for further *** the last few years,metal–organic frameworks(MOFs)have received significant consideration as ideal candidates for synthesizing SACs due to their tailorable chemistry,tunable morphologies,high porosity,and chemical/thermal *** this perspective,this review thoroughly summarizes the previously reported methods and possible future approaches for constructing MOF-based(MOF-derived-supported and MOF-supported)***,MOF-based SAC's identification techniques are briefly assessed to understand their coordination environments,local electronic structures,spatial distributions,and catalytic/electrochemical reaction *** review systematically highlights several photocatalytic and electrocatalytic applications of MOF-based SACs for energy conversion and storage,including hydrogen evolution reactions,oxygen evolution reactions,O_(2)/CO_(2)/N_(2) reduction reactions,fuel cells,and rechargeable *** light is also shed on the future development of this highly exciting field by highlighting the advantages and limitations of MOF-based SACs.

关键词： carbon energy generation MOF-derived-supported MOF-supported single atoms

Deep Transfer Learning Techniques in Intrusion Detection System-Internet of Vehicles: A State-of-the-Art Review

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Computers, Materials & Continua 2024年第8期80卷 2785-2813页

作者： Wufei Wu Javad Hassannataj Joloudari Senthil Kumar Jagatheesaperumal Kandala N.V.P.SRajesh Silvia Gaftandzhieva Sadiq hussain Rahimullah Rabih Najibullah Haqjoo Mobeen Nazar Hamed Vahdat-Nejad Rositsa Doneva School of Information Engineering Nanchang UniversityNanchang330031China Department of Computer Engineering Technical and Vocational University(TVU)Tehran***Iran Department of Computer Engineering University of BirjandBirjand***Iran Department of Computer Engineering Babol BranchIslamic Azad UniversityBabol***Iran Department of Electronics&Communication Engineering Mepco Schlenk Engineering CollegeSivakasi626005India School of Electronics Engineering VIT-AP UniversityNear Vijayawada522237India Faculty of Mathematics and Informatics University of Plovdiv Paisii HilendarskiPlovdiv4000Bulgaria Examination Branch Dibrugarh UniversityDibrugarh786004India Department of Computer Engineering Faculty of EngineeringUniversity of BirjandBirjand***Iran Faculty of Electrical and Computer Engineering University of BirjandBirjand***Iran Malaysian Institute of Information Technology Universiti Kuala LumpurKuala Lumpur50250Malaysia Faculty of Physics and Technology University of Plovdiv Paisii HilendarskiPlovdiv4000Bulgaria

The high performance of IoT technology in transportation networks has led to the increasing adoption of Internet of Vehicles(IoV)*** functional advantages of IoV include online communication services,accident prevention,cost reduction,and enhanced traffic *** these benefits,IoV technology is susceptible to cyber-attacks,which can exploit vulnerabilities in the vehicle network,leading to perturbations,disturbances,non-recognition of traffic signs,accidents,and vehicle *** paper reviews the state-of-the-art achievements and developments in applying Deep Transfer Learning(DTL)models for Intrusion Detection Systems in the Internet of Vehicles(IDS-IoV)based on anomaly ***-IoV leverages anomaly detection through machine learning and DTL techniques to mitigate the risks posed by *** systems can autonomously create specific models based on network data to differentiate between regular traffic and *** these techniques,transfer learning models are particularly promising due to their efficacy with tagged data,reduced training time,lower memory usage,and decreased computational *** evaluate DTL models against criteria including the ability to transfer knowledge,detection rate,accurate analysis of complex data,and *** review highlights the significant progress made in the field,showcasing how DTL models enhance the performance and reliability of IDS-IoV *** examining recent advancements,we provide insights into how DTL can effectively address cyber-attack challenges in IoV environments,ensuring safer and more efficient transportation networks.

关键词： Cyber-attacks internet of things internet of vehicles intrusion detection system

Impact of liver metastasis on immunotherapy in gastric carcinoma

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World Journal of Gastrointestinal Surgery 2024年第10期16卷 3084-3086页

作者： Mushtaq Chalkoo Mohd Yaqoob Bhat Yaser hussain Wani Department of Surgery Government Medical CollegeSrinagar 190014Jammu and KashmirIndia Department of General Surgery Government Medical College SrinagarSrinagar 190010Jammu and KashmirIndia Post Graduate Department of Minimal Access and General Surgery Government Medical College SrinagarSrinagar 190010Jammu and KashmīrIndia

The editorial discusses the impact of liver metastasis on immunotherapy efficacy in gastric cancer(GC)*** metastasis can hinder the effectiveness of immunotherapy by altering the immune microenvironment,leading to systemic loss of T-cells and reduced treatment *** suggest that liver meta-stases serve as a negative baseline factor for immunotherapy efficacy,resulting in poorer progression-free survival and objective response *** such as liver-mediated radiotherapy may help improve treatment outcomes by reshaping the liver’s immune microenvironment and reducing T-cell ***-ing the complex interplay between liver metastasis and immunotherapy response is crucial for optimising patient care in GC.

关键词： Immunotherapy Liver metastasis Immune tolerance Gastric carcinoma Hepatic Siphoning

Combined Application of Biostimulants and EDTA Improved Wheat Productivity under Cadmium Stress

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Phyton-International Journal of Experimental Botany 2024年第7期93卷 1647-1665页

作者： abida Aziz Shafiqa Bano Mubshar hussain Muhammad Farooq Azhar Ghulam Yasin Naila Hadayat Iqra Arooj Abeer Hashem Ajay Kumar Elsayed Fathi Abd_Allah Qamar uz Zaman Department of Botany The Women UniversityMultan54500Pakistan Institute of Agronomy Bahauddin Zakariya UniversityMultan60800Pakistan Department of Forestry and Range Management Bahauddin Zakariya UniversityMultan60800Pakistan Department of Botany Division of Science&TechnologyUniversity of EducationLahore54770Pakistan Department of Microbiology&Molecular Genetics The Women UniversityMultan54500Pakistan Botany and Microbiology Department College of ScienceKing Saud UniversityRiyadh201313Saudi Arabia Amity Institute of Biotechnology Amity UniversityNoida201313India Plant Production Department College of Food and Agricultural SciencesKing Saud UniversityRiyadh11451Saudi Arabia School of Agriculture Yunnan UniversityKunmingYunan650504China Department of Environmental Sciences The University of LahoreLahore54590Pakistan

Wheat(Triticum aestivum L.)exhibits a greater capacity for cadmium(Cd)absorption compared to other cereal crops,leading to elevated daily Cd intake,and posing a signiﬁcant threat to public *** the mitigation of Cd stress in sustainable and environmentally friendly way,a pot study was designed by using exogenous application of various biostimulants,i.e.,Nigella sativa and Ocimum sanctum extracts:0%,10%,and 20%in combination with the chelating agent ethylenediaminetetraacetic acid(EDTA)using 0 and 5 mg kg^(-1) under various levels of Cd stress(i.e.,0,5,10,and 15 mg kg^(-1) soil).Results revealed that Cd stress signiﬁcantly reduced the seed emergence,growth,root,and allometric characters and yield-related parameters of wheat *** most observable reduc-tion was documented in wheat plants exposed to a higher Cd concentration(15 mg kg^(-1)),followed by the lower Cd level(control).The combined application of bio-stimulants and EDTA minimized the negative impacts of Cd *** highest increase in seedling emergence(5.44%),leaf area(50.60%),number of tillers(31.02%),grain yield per plant(24.28%),biological yield(13.97%),and decrease in Cd levels in grains(40%)was noticed where 20%foliar application of *** and 10%of *** biostimulants were done using 5 mg kg^(-1) of soil-applied *** intervention demonstrated a notable reduction in Cd-induced negative effects,highlighting the potential of these substances in promoting sustainable wheat cultivation in contaminated ***,it is an eco-friendly and approachable method at theﬁeld level able to ensure food safety.

关键词： Abiotic stress allometric characters antioxidant activity crop yield seed emergence grain yield

Hordedane diterpenoid phytoalexins restrict Fusarium graminearum infection but enhance Bipolaris sorokiniana colonization of barley roots

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Molecular Plant 2024年第8期17卷 1307-1327页

作者： Yaming Liu Dario Esposto Lisa K.Mahdi Andrea Porzel Pauline Stark Hidayat hussain Anja Scherr-Henning Simon Isfort Ulschan.Bathe Ivan F.Acosta Alga Zuccaro Gerd U.Balcke Alain Tissier Department of Cell and Metabolic Biology Leibniz Institute of Plant BiochemistryHalleGermany Institute for Plant Sciences Cluster of Excellence on Plant Sciences(CEPLAS)Cologne BiocenterUniversity of CologneCologneGermany Department of Bioorganic Chemistry Leibniz Institute of Plant BiochemistryHalleGermany Max Planck Institute for Plant Breeding Research CologneGermany Horticultural Sciences University of FloridaGainesvilleFLUSA.

Plant immunity is a multilayered process that includes recognition of patterns or effectors from pathogens to elicit defense *** include the induction of a cocktail of defense metabolites that typically restrict pathogen ***,we investigate the interaction between barley roots and the fungal pathogens Bipolaris sorokiniana(Bs)and Fusarium graminearum(Fg)at the metabolite *** identify hordedanes,a previously undescribed set of labdane-related diterpenoids with antimicrobial properties,as critical players in these *** of barley roots by Bs and Fg elicits hordedane synthesis from a 60o-kb gene *** reconstruction of the biosynthesis pathway in yeast and Nicotiana benthamiana produced several hordedanes,including one of the most functionally decorated products 19-β-hydroxy-hordetrienoic acid(19-OH-HTA).Barley mutants in the diterpene synthase genes of this cluster are unable to produce hordedanes but,unexpectedly,show reduced Bs *** contrast,colonization by Fusarium graminearum,another fungal pathogen of barley and wheat,is 4-fold higher in the mutants completely lacking ***,19-OH-HTA enhances both germination and growth of Bs,whereas it inhibits other pathogenic fungi,including *** of microscopy and transcriptomics data suggest that hordedanes delay the necrotrophic phase of *** together,these results show that adapted pathogens such as Bs can subvert plant metabolic defenses to facilitate root colonization.

关键词： barley Hordeum vulgare diterpenoid phytoalexins gene cluster pathogenic fungi Bipolaris sorokininiana Fusarium graminearum