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Hydro-uvarovite from Mantle Peridotites of Naga Hills Ophiolite: A Mineral Tracer for Neo-Tethyan Mantle Wedge Metasomatism

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Acta Geologica Sinica(English Edition) 2024年第4期98卷 867-877页

作者： Anisha VERENCAR abhishek saha Nilanjana SORCAR Sohini GANGULY Pankaj KUMAR Atul Kumar SINGH CSIR-National Institute of Oceanography Dona PaulaGoa 403004India School of Earth Ocean and Atmospheric SciencesGoa UniversityTaleigao PlateauGoa 403206India National Centre for Earth Science Studies ThiruvananthapuramKeralaIndia Inter University Accelerator Centre(IUAC) New Delhi 110067India North-Eastern Hill University ShillongMeghalaya 793022India

Hydrous Cr-bearing uvarovite garnets are rare in natural occurrences and belong to the ugrandite series and exist in binary solid solutions with grossular and andradite garnets. Here, we report the occurrence of hydrous uvarovite garnet having Cr_(2)O_(3) upto 19.66 wt% and CaO of 32.12–35.14 wt% in the serpentinized mantle peridotites of Naga Hills Ophiolite(NHO), India. They occur in association with low-Cr diopsides. They are enriched in LILE(Ba, Sr), LREEs, with fractionating LREE-MREE [avg.(La/Sm)_(N) = 2.16] with flat MREE/HREE patterns [avg.(Sm/Yb)_(N) = 0.95]. Raman spectra indicate the presence of hydroxyl(OH^(–)) peaks from 3500 to 3700 cm^(-1). Relative abundances in fluid mobile elements and their close association with clinopyroxenes are suggestive of the formation of uvarovite garnets through low temperature metasomatic alteration of low-Cr diopsides by hydrothermal slab fluids. The high LREE concentration and absence of Eu anomaly in the garnet further attest to alkaline nature of the transporting slab dehydrated fluid rather the involvement of low-p H solution. The chemical characteristics of the hydroxyl bearing uvarovite hosted by the mantle peridotite of NHO deviate from the classical features of uvarovite garnet, and their origin is attributed to the fluid-induced metasomatism of the sub arc mantle wedge in a suprasubduction zone regime.

关键词： uvarovite hydroxyl metasomatic alteration low-Cr diopsides serpentinization mantle peridotite

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Implications of REE incorporation and host sediment influence on the origin and growth processes of ferromanganese nodules from Central Indian Ocean Basin

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Geoscience Frontiers 2021年第3期12卷 609-623页

作者： Simontini Sensarma abhishek saha Arghya Hazra CSIR-National Institute of Oceanography Dona PaulaGoa 403004India Indian Institute of Science BangaloreKarnataka 560012India School of Earth Ocean and Atmospheric SciencesGoa UniversityGoa 403206India

This study presents new major,trace and REE data for thirty-five ferromanganese nodules recovered from areas representing three different sediment types(siliceous,red clay and their transition zone)in the Central Indian Ocean Basin(CIOB)to address their genetic aspects,classification,growth rate,nature of host sediments and influence of REE in the processes of nodule *** nodules from CIOB are mostly either hydrogenetic(metals coming from oxygenated bottom water)and diagenetic(metals coming from suboxic sediment pore water)or a combination of both,depending on the source of supply of ***,a number of biogeochemical processes mediate this supply of metals which again changes from time to time,making the nodule growth process highly *** study suggests that at the initial stage of nodule growth,host sediments do not play much role in controlling the growth processes for which REEs can enter both Mn and Fe oxyhydroxide phases ***,the bottom water signature is imprinted in these early formed nodules irrespective of their host sediment substrate but with gradual growth and burial in the sediment,the main mode of metal enrichment becomes diagenetic through sediment pore *** tends to increase the concentration of Mn,Ni and Cu over other elements which are retained in the sediment *** the REEs,Ce concentration of the nodules shows significant positive anomaly due to variation in redox potential and hence its magnitude can be used to get an idea about the metal enrichment procedure and the genetic type of the ***,based on host sediment only,not much difference is found in the magnitude of Ce anomaly in these *** the other hand,discrimination diagram,based on HFSE and REY chemistry,indicates that most of these nodules are of diagenetic origin under oxic condition with a trend towards hydrogenetic ***,the genetic type of the ferromanganese nodules from the CIOB are more effectively differentiated

关键词： Central Indian Ocean Basin Ferromanganese nodules Deep-sea sediments Rare earth elements Geochemical discrimination

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Tectono-magmatic evolution of Tethyan oceanic lithosphere in supra subduction zone fore arc regime:Geochemical fingerprints from crust-mantle sections of Naga Hills Ophiolite

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Geoscience Frontiers 2021年第3期12卷 19-41页

作者： Anisha Verencar abhishek saha Sohini Ganguly Manikyamba C. CSIR-National Institute of Oceanography Dona PaulaGoa 403004India School of Earth Ocean and Atmospheric SciencesGoa UniversityTaleigão PlateauGoa 403206India CSIR-National Geophysical Research Institute Uppal RoadHyderabad 500007India

The Naga Hills Ophiolite(NHO)belt in the Indo-Myanmar range(IMR)represents a segment of Tethyan oceanic crust and upper mantle that was involved in an eastward convergence and collision of the Indian Plate with the Burmese Plate during the Late ***,we present a detailed petrological and geochemical account for the mantle and crustal sections of NHO,northeastern India to address(i)the mantle processes and tectonic regimes involved in their genesis and(ii)their coherence in terms of the thermo-tectonic evolution of Tethyan oceanic crust and upper *** NHO suite comprises well preserved crustal and mantle sections discretely exposed at Moki,Ziphu,Molen,Washelo and Lacham *** ultramafic-mafic lithologies of NHO are mineralogically composed of variable proportions of olivine,orthopyroxene,clinopyroxene and *** primary igneous textures for the mantle peridotites have been overprinted by extensive serpentinisation whereas the crustal section rocks reflect crystal cumulation in a magma *** normalised REE profiles for the cumulate peridotite-olivine gabbro-gabbro assemblage constituting the crustal section of NHO show flat to depleted LREE patterns consistent with their generation from depleted MORB-type precursor melt in an extensional tectonic setting,while the mantle peridotites depict U-shaped REE patterns marked by relative enrichment of LREE and HREE over *** features collectively imply a dual role of depleted MORB-type and enriched arc-type mantle components for their genesis with imprints of melt-rock and fluid-rock ***,studied lithologies from NHO correspond to a boninitic to slab-proximal Island Arc Tholeiite affinity thereby conforming to an intraoceanic supra subduction zone(SSZ)fore-arc regime coherent with the subduction initiation *** geochemical attributes for the crustal and mantle sections of NHO as mirrored by Zr/Hf,Zr/Sm,Nb/Ta,Zr/Nb,Nb/U,Ba/Nb,Ba/Th,Ba/La and Nd/

关键词： Tethyan Ocean Naga Hills Ophiolite Suprasubduction Zone Subduction initiation Fore arc extension Mantle refertilisation

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Geochemistry and petrogenesis of Rajahmundry trap basalts of Krishna-Godavari Basin,India

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Geoscience Frontiers 2015年第3期6卷 437-451页

作者： C.Manikyamba Sohini Ganguly M.Santosh abhishek saha G.Lakshminarayana CSIR-National Geophysical Research Institute Department of Geology University of Calcutta School of Earth Sciences and Resources China University of Geosciences Midwest Group Banjara Hills

The Rajahmundry Trap Basalts （RTB） are erupted through fault-controlled fissures in the Krishna-Godavari Basin （K-G Basin） of Godavari Triple Junction, occurring as a unique outcrop sandwiched between Cretaceous and Tertiary sediments along the east coast of India. Detailed geochemical studies have revealed that RTB are mid-Ti （1.74-1.92） to high-Ti （2.04-2.81） basalts with a distinct quartz tholeiitic parentage. MgO （6.2-13.12 wt.%）, Mg# （29-50） and Zr （109-202 ppm） suggest that these basalts evolved by fractional crystallization during the ascent of the parent magma along deep-seated fractures. Mod- erate to high fractionation of HREE, as indicated by （Gd/Yb）N ratios （1.71-2.31） of RTB, suggest their generation through 3-5% melting of a Fe-rich mantle corresponding to the stability fields of spinel and garnet peridotite at depths of 60-100 km. Low K2O/P2O5 （0.26-1.26）, high TiO2/P2O5 （6.74-16.79）, La/Nb （0.89-1.45）, Nb/Th 〉 8 （8.35-13）, negative anomalies at Rb reflect minimum contamination by granitic continental crust. （Nb/La）PM ratios （0.66-1.1） of RTB are attributed to endogenic contamination resulted through recycling of subducted oceanic slab into the mantle. Pronounced Ba enrichment with relative depletion in Rb indicates assimilation of Infra- and Inter-trappean sediments of estuarine to shallow marine character. Geochemical compositions such as A1203/TiO2 （3.88-6.83）, medium to high TiO2 （1.74 -2.81 wt.%）, positive Nb anomalies and LREE enrichment of these RTB attest to their mantle plume origin and indicate the generation of parent magma from a plume-related enriched mantle source with EM 1 signature. Ba/Th （46-247）, Ba/La （3.96-28.51） and Th/Nb （0.08-0.13） ratios suggest that the source enrichment process was marked by recycling of subduction-processed oceanic crust and lithospheric components into the mantle. Zr/Hf （37-41） and Zr/Ba （0.51-3.24） indicate involvement of an asthenospheric mantle source. The Rajahmundry basalts show affinity towards FOZO （

关键词： Rajahmundry Trap Basalts (RTB) Fault-controlled fissures Fractional crystallization Enriched mantle source Plume-lithosphere interaction

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Geochemical cycling during subduction initiation:Evidence from serpentinized mantle wedge peridotite in the south Andaman ophiolite suite

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Geoscience Frontiers 2018年第6期9卷 1755-1775页

作者： abhishek saha M.Santosh Sohini Ganguly C.Manikyamba Jyotisankar Ray Jagadish Dutta CSIR-National Institute of Oceanography Dona PaulaGoa 403 004India School of Earth Science and Resources China University of GeosciencesBeijing100083China Department of Earth Sciences University of AdelaideAdelaideSA 5005Australia Department of Earth Science Goa UniversityTaleigao PlateauGoa 403206India CSIR-National Geophysical Research Institute Uppal RoadHyderabad500 007India Department of Geology University of Calcutta35Ballygunge Circular RoadKolkata700 019India

The ophiolite suite from south Andaman Islands forms part of the Tethyan Ophiolite Belt and preserves the remnants of an ideal ophiolite sequence comprising a basal serpentinized and tectonised mantle peridotite followed by ultramafic and mafic cumulate units, basaltic dykes and spilitic pillow basalts interlayered with arkosic wacke. Here, we present new major, trace, rare earth(REE) and platinum group(PGE) element data for serpentinized and metasomatized peridotites(dunites) exposed in south Andaman representing the tectonized mantle section of the ophiolite suite. Geochemical features of the studied rocks, marked by Al_2 O_3/TiO_2 > 23, LILE-LREE enrichment, HFSE depletion, and U-shaped chondrite-normalized REE patterns with(La/Sm)N > 1 and(Gd/Yb)N <1, suggest contributions from boninitic mantle melts. These observations substantiate a subduction initiation process ensued by rapid slab roll-back with extension and seafloor spreading in an intraoceanic fore-arc regime. The boninitic composition of the serpentinized peridotites corroborate fluid and melt interaction with mantle manifested in terms of(i) hydration, metasomatism and serpentinization of depleted, MORB-type, sub-arc wedge mantle residual after repeated melt extraction; and(ii) refertilization of refractory mantle peridotite by boninitic melts derived at the initial stage of intraoceanic subduction. Serpentinized and metasomatized mantle dunites in this study record both MOR and intraoceanic arc signatures collectively suggesting suprasubduction zone affinity. The elevated abundances of Pd(4.4-12.2 ppb) with highΣPPGE/∑IPGE(2-3) and Pd/Ir(2-5.5) ratios are in accordance with extensive melt-rock interaction through percolation of boninitic melts enriched in fluid-fluxed LILE-LREE into the depleted mantle after multiple episodes of melt extraction. The high Pd contents with relatively lower Ir concentrations of the samples are analogous to characteristic PGE signatures of boninitic magmas and might have r

关键词： South Andaman Ophiolite Mantle peridotite Metasomatism Geochemical cycling Subduction initiation

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Improving Heat Transfer in Parabolic Trough Solar Collectors by Magnetic Nanofluids

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Energy Engineering 2024年第4期121卷 835-848页

作者： Ritesh Singh abhishek Gupta Akshoy Ranjan Paul Bireswar Paul Suvash C.saha Department of Applied Mechanics Motilal Nehru National Institute of Technology AllahabadPrayagrajIndia Department of Mechanical and Mechatronic Engineering University of Technology SydneySydneyAustralia

A parabolic trough solar collector(PTSC)converts solar radiation into thermal ***,low thermal efficiency of PTSC poses a hindrance to the deployment of solar thermal power *** performance of PTSC is enhanced in this study by incorporating magnetic nanoparticles into the working *** circular receiver pipe,with dimensions of 66 mm diameter,2 mm thickness,and 24 m length,is exposed to uniform temperature and velocity *** working fluid,Therminol-66,is supplemented with Fe3O4 magnetic nanoparticles at concentrations ranging from 1%to 4%.The findings demonstrate that the inclusion of nanoparticles increases the convective heat transfer coefficient(HTC)of the PTSC,with higher nanoparticle volume fractions leading to greater heat transfer but increased pressure *** thermal enhancement factor(TEF)of the PTSC is positively affected by the volume fraction of nanoparticles,both with and without a magnetic ***,the scenario with a 4%nanoparticle volume fraction and a magnetic field strength of 250 G exhibits the highest TEF,indicating superior thermal *** findings offer potential avenues for improving the efficiency of PTSCs in solar thermal plants by introducing magnetic nanoparticles into the working fluid.

关键词： Parabolic trough solar collector(PTSC) magnetic nanofluid(MNF) heat transfer convective heat transfer coefficient(HTC) thermal enhancement factor(TEF)

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Customer Targeting Framework:Scalable Repeat Purchase Scoring Algorithm for Large Databases

Customer Targeting Framework:Scalable Repeat Purchase Scorin...

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The 2012 4th International Conference on Machine Learning and Computing（ICMLC 2012）

作者： Biswajit Pal Ritwik Sinha abhishek saha Peter Jaumann Subhasish Misra Global Analytics Corporate Marketing-Customer Intelligence

A major question in database marketing is that of identifying the customers who are most likely to make a repeat purchase in the near *** information helps us to preferentially target these customers in any marketing *** likelihood of a customer to make a repeat purchase depends on two questions: "Has the customer churned?" and "What is the frequency of transactions of the customer?" In this paper we develop a methodology using a Bayesian analysis to answer these questions;we further design a scalable regression method that approximates the Bayesian *** the answer to these questions as inputs we predicted the likelihood of a customer making a transaction within a time span into the future （*** the next six months）.Our algorithm can score massive databases for repeat purchase in real *** proposed algorithm was tested on a recent Back to School campaign run by consumer exchange and has yielded promising results.

关键词： Repeat purchase Bayesian analysis Regression Real time scoring Targeted marketing

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