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Preparation,crystallization,microstructure and dielectric properties of lead bismuth titanate borosilicate glass ceramics

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Journal of Advanced Ceramics 2014年第3期3卷 194-206页

作者： Chandkiram RGAUTAM abhishek MADHESHIYA Ranabrata MAZUMDER Advanced Glass and Glass Ceramic Research Laboratory Department of PhysicsUniversity of LucknowLucknow 226007India Department of Ceramic Engineering National Institute of TechnologyRouerkela 769008India

Various bulk and transparent glasses were prepared by rapid melt quenching technique in the glass system 55[(Pb_(x)Bi_(1-x))TiO_(3)]-44[2Si_(O)2B_(2)O_(3)]-La2O3(x=0-0.7).The X-ray diffraction(XRD)studies of the glass samples confirmed the amorphous *** differential thermal analyses(DTA)were carried out from room temperature to 900℃with a heating rate of 10℃/*** DTA patterns of the samples showed one or more exothermic sharp peaks shifting towards lower temperature side with increasing concentration of bismuth oxide(BiO).On the basis of DTA results,the solid solution of bismuth titanum oxide(Bi_(2)Ti_(2)O_(7))/lead bismuth titanium oxide(Pb3Bi4Ti6O21)was precipitated in borosilicate glassy matrix as a major *** glasses were subjected to 4 h and 8 h heat treatment schedules to convert into glass *** analysis of these glass ceramic samples showed that the major crystalline phase of the entire glass ceramic samples with 0≤x≤0.5 is found to have cubic crystal structure,while it is tetragonal for glass ceramic sample with x=*** scanning electron microscopy(SEM)micrographs indicated the uniform distribution of Bi_(2)Ti_(2)O_(7)and Pb3Bi4Ti6O21 crystallites in the glassy matrix.

关键词： lead bismuth titanate differential thermal analysis(DTA) crystallization scanning electron microscopy(SEM) dielectric behavior

Advances in endobariatrics:past,present,and future

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Gastroenterology Report 2023年第1期11卷 140-150页

作者： abhishek Shenoy Allison R.Schulman Division of Gastroenterology and Hepatology University of MichiganMichigan MedicineAnn ArborMIUSA Department of Surgery University of MichiganMichigan MedicineAnn ArborMIUSA

The obesity epidemic in the USA and worldwide is well documented and continues to *** metabolic and bariatric therapies may offer a less invasive approach than surgical *** article will review advances in endobariatrics over the last several decades,addressing the past and current state of bariatric and metabolic *** and Drug Administration-cleared devices and interventions currently under investigation are described including gastric devices,gastric remodeling procedures,small-bowel devices,duodenal ablation,as well as procedures to address weight regain after bariatric *** studies evaluating gastric and duodenal combination therapy,adjunctive pharmacotherapy,as well as individualized precision-health algorithms are underway.

关键词： metabolic devices endoscopic sleeve gastroplasty obesity endobariatrics bariatric therapy

Genetic Enhancement of Indigenous Cowpea with Gamma-Ray Induced Trait Variation

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American Journal of Plant Sciences 2024年第8期15卷 651-676页

作者： Mathurin Tiergnin Dabiré Minimassom Philippe Nikiéma Djibril Yonli Safiatou Sanna Wossoguim Josué Gouba Siébou Palé Hamidou Traoré Joseph T. B. Batieno Varra Prasad Zacharia Stewart Jan B. Middendorf abhishek Rathore Anupama J. Hingane Unit de Formation et de Recherches en Sciences et Technologies Dpartement des Sciences de la Vie et de la Terre Universit Norbert ZONGO Koudougou Burkina Faso Institut de lEnvironnement et de Recherches Agricoles (INERA) Ouagadougou Burkina Faso Department of Agronomy Kansas State University Manhattan USA Center for Agriculture-Led Growth Bureau for Resilience and Food Security United States Agency for International Development United States Agency for International Development Washington DC USA International Maize and Wheat Improvement Center (CIMMYT) ICRISAT Campus Patancheru India Joint FAO/IAEA Division of Nuclear Techniques in Food and Agriculture Department of Nuclear Sciences and Applications Plant Breeding and Genetics Laboratory International Atomic Energy Agency (IAEA) Seibersdorf Vienna Austria

Production of cowpea (Vigna unguiculata (L.) Walp.), a staple legume crop in Sub-Saharan Africa, faces challenges due to biotic and abiotic constraints. Induced mutagenesis was deployed to create genetic variation in two cowpea varieties (KVX396-4-5-2D and Moussa local). The radio-sensitivity tests led to determe the lethal dose 50 (LD50) corresponding to 230 Gy and 220 Gy for KVX396-4-5-2D and Moussa local varieties, respectively. Dried seeds (M0) of each variety were gamma-ray irradiated with LD50 − 50, LD50 and LD50 + 50. M1 seeds were advanced to generate M2, M3 and M4 mutants using the single-seed-descent method. M4 mutant lines were evaluated in rain-fed conditions using a randomized complete block design to assess phenotypic differences. Data on seven qualitative and eleven quantitative traits were collected. The results indicated that the mutation induced variability in three qualitative traits: in KVX 396-4-5-2D mutant lines, with flower and seed color frequencies at 2.61% and 0.56% respectively, and pod dehiscence at a frequency of 0.24%. While in Moussa local mutants, a pod color changed at a frequency of 17%. ANOVA results revealed significant differences between mutants of both varieties for all quantitative traits, including photosynthetic parameters. Positive correlations were observed between leaf diameter and 100-seed weight, and between branch number and 100-seed weight. Hierarchical clustering revealed three clusters among KVX 396-4-5-2D mutants and six clusters among Moussa local mutants. Early maturity and high foliage were induced traits in Cluster 3 of KVX 396-4-5-2D mutants while high hundred-seed weight was induced in Cluster 6 of Moussa local mutants.

关键词： Cowpea Mutagenesis Gamma Rays Radio-Sensitivity Phenotyping

Proton reduction in the presence of oxygen by iron porphyrin enabled with 2nd sphere redox active ferrocenes

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Chinese Journal of Catalysis 2021年第8期42卷 1327-1331页

作者： Biswajit Mondal Pritha Sen abhishek Dey School of Chemical Sciences Indian Association for the Cultivation of Science2A&2B Raja S.C.Mullick RoadJadavpurKolkataWest Bengal 700032India

Hydrogen evolution in the presence of atmospheric level of oxygen is a significant barrier in the quest for an alternative,sustainable and green source of energy to counter the depleting fossil fuel sources and increasing global warming due to fossil fuel *** reduction is thermodynamically more favourable than proton reduction and it often produces reactive oxygenated species upon partial reduction which deactivates the ***,catalyst development is required for efficient proton reduction in the presence of ***,we demonstrate an iron porphyrin having triazole containing 2nd sphere hydrogen bonding residues appended with redox active ferrocene moieties(α4-Tetra-2-(3-ferrocenyl-1,2,3-triazolyl)phenylporphyrin(FeFc4))as a bifunctional catalyst for fast and selective oxygen reduction to water and thus,preventing the proton reduction by the same catalyst from oxidative ***(0)is the active species for proton reduction in these iron porphyrin class of complexes and it is observed that the kinetics of proton reduction at Fe(0)state occurs at much faster rate than O2 reduction and thus,paving the way for selective proton reduction in the presence of oxygen.

关键词： Iron porphyrin Hydrogen evolution reaction Oxygen tolerance Electrocatalysis Kinetics

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Effects of defects on the electronic properties of WTe_2 armchair nanoribbons

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Journal of Semiconductors 2014年第11期35卷 10-15页

作者： Bahniman Ghosh abhishek Gupta Bhupesh Bishnoi Microelectronics Research Center 10100Burnet RoadBldg.160University of Texas at AustinAustinTX78758USA Department of Electrical Engineering Indian Institute of Technology Kanpur

We have investigated the electronic properties of WTe2 armchair nanoribbons with defects. WTe2 nanoribbons can be categorized depending on the edge structure in two types： armchair and zigzag. WTe2 in its bulk form has an indirect band gap but nanoribbons and nanosheets of WTe2 have direct band gaps. Interestingly, the zigzag nanoribbon is metallic while the armchair nanoribbons are semiconducting. Thus they can find applications in device fabrication. Therefore, it is very important to study the effect of defects on the electronic properties of the armchair nanoribbons as these defects can impair the device properties and characteristics. We have considered defects such as： vacancy, rough edge, wrap, ripple and twist in this work. We report the band gap variation with these defects. We have also studied the change in band gap and total energy with varying degrees of wrap, ripple and twist.

关键词： electronic property WTe2 armchair nanoribbons defects

Artificial intelligence powered glucose monitoring and controlling system:Pumping module

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World Journal of Experimental Medicine 2024年第1期14卷 100-112页

作者： Sravani Medanki Nikhil Dommati Hema Harshitha Bodapati Venkata Naga Sai Kowsik Katru Gollapalli Moses abhishek Komaraju Nanda Sai Donepudi Dhanya Yalamanchili Jasti Sateesh Pratap Turimerla Department of Electronics and Communication Engineering Velagapudi Ramakrishna Siddhartha Engineering CollegeVijayawada 520007Andhra PradeshIndia Department of General Medicine Siddhartha Government Medical CollegeVijayawada 520008Andhra PradeshIndia

BACKGROUND Diabetes,a globally escalating health concern,necessitates innovative solutions for efficient detection and *** glucose control is an essential aspect of managing diabetes and finding the most effective ways to control *** latest findings suggest that a basal insulin administration rate and a single,highconcentration injection before a meal may not be sufficient to maintain healthy blood glucose *** the basal insulin rate treatment can stabilize blood glucose levels over the long term,it may not be enough to bring the levels below the post-meal limit after 60 *** short-term impacts of meals can be greatly reduced by high-concentration injections,which can help stabilize blood glucose ***,they cannot provide long-term stability to satisfy the postmeal or pre-meal ***,proportional-integral-derivative(PID)control with basal dose maintains the blood glucose levels within the range for a longer *** To develop a closed-loop electronic system to pump required insulin into the patient's body automatically in synchronization with glucose sensor *** The proposed system integrates a glucose sensor,decision unit,and pumping module to specifically address the pumping of insulin and enhance system *** as the intelligence hub,the decision unit analyzes data from the glucose sensor to determine the optimal insulin dosage,guided by a pre-existing glucose and insulin level *** artificial intelligence detection block processes this information,providing decision instructions to the pumping *** with communication antennas,the glucose sensor and micropump operate in a feedback loop,creating a closed-loop system that eliminates the need for manual *** The incorporation of a PID controller to assess and regulate blood glucose and insulin levels in individuals with diabetes introduces a sophisticated and dynamic element to diabetes ***

关键词： Diabetes Hyperglycemia Insulin Micropump Closed loop systems Artificial intelligence automation

Modeling phase equilibria of semiclathrate hydrates of CH_4,CO_2 and N_2 in aqueous solution of tetra-n-butyl ammonium bromide

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Journal of Natural Gas Chemistry 2012年第4期21卷 459-465页

作者： abhishek Joshi Prathyusha Mekala Jitendra S.Sangwai Petroleum Engineering Program Department of Ocean EngineeringIndian Institute of Technology MadrasChennai-600 036India

Semiclathrate hydrates of tetra-n-butyl ammonium bromide （TBAB） offer potential solution for gas storage, transportation, separation of flue gases and CO2 sequestration. Models for phase equilibria for these systems have not yet been developed in open literatures and thus require urgent attention. In this work, the first attempt has been made to model phase equilibria of semiclathrate hydrates of CH4, CO2 and N2 in aqueous solution of TBAB. A thermodynamic model for gas hydrate system as proposed by Chen and Guo has been extended for semiclathrate hydrates of gases in aqueous solution of TBAB. A correlation for the activity of water relating to the system temperature, concentration of TBAB in the system and the nature of guest gas molecule has been proposed. The model results have been validated against available experimental data on phase equilibria of semiclathrate hydrate systems of aqueous TBAB with different gases as guest molecule. The extended Chen and Guo＇s model is found to be suitable to explain the promotion effect of TBAB for the studied gaseous system such as, methane, carbon dioxide and nitrogen as a guest molecule. Additionally, a correlation for the increase in equilibrium formation temperature （hydrate promotion temperature, ATp） of semiclathrate hydrate system with respect to pure gas hydrate system has been developed and applied to semiclathrate hydrate of TBAB with several gases as guest molecules. The developed correlation is found to predict the promotion effect satisfactorily for the system studied.

关键词： gas hydrate phase equilibria semiclathrate hydrate tetra-n-butyl ammonium bromide (TBAB)

Anticoagulant use before COVID-19 diagnosis prevent COVID-19 associated acute venous thromboembolism or not:A systematic review and meta-analysis

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World Journal of Methodology 2024年第3期14卷 141-162页

作者： Kinza Iqbal Akshat Banga Taha Bin Arif Sawai Singh Rathore abhishek Bhurwal Syeda Kisa Batool Naqvi Muhammad Mehdi Pankaj Kumar Mitali Madhu Salklan Ayman Iqbal Jawad Ahmed Nikhil Sharma Amos Lal Rahul Kashyap Vikas Bansal Juan Pablo Domecq Department of Internal Medicine Dow Medical CollegeKarachi 74200Pakistan Department of Internal Medicine Sawai Man Singh Medical CollegeJaipur 302004India Department of Internal Medicine Dr.Sampurnanand Medical CollegeJodhpur 342003RajasthanIndia Department of Gastroenterology and Hepatology Rutgers Robert Wood Johnson School of MedicineNew BrunswickNJ 08901United States Department of Internal Medicine Pandit Bhagwat Dayal Sharma Post Graduate Institute of Medical SciencesRohtak 124001HaryanaIndia Department of Nephrology and Hypertension Mayo ClinicRochesterMN 55905United States Department of Medicine Division of Pulmonary and Critical Care MedicineMayo ClinicRochesterMN 55905United States Department of Research Wellspan HealthYorkPA 17403United States

BACKGROUND Coagulopathy and thromboembolic events are associated with poor outcomes in coronavirus disease 2019(COVID-19)*** is conflicting evidence on the effects of chronic anticoagulation on mortality and severity of COVID-19 *** To summarize the body of evidence on the effects of pre-hospital anticoagulation on outcomes in COVID-19 *** A Literature search was performed on LitCovid PubMed,WHO,and Scopus databases from inception(December 2019)till June 2023 for original studies reporting an association between prior use of anticoagulants and patient outcomes in adults with *** primary outcome was the risk of thromboembolic events in COVID-19 patients taking *** outcomes included COVID-19 disease severity,in terms of intensive care unit admission or invasive mechanical ventilation/intubation requirement in patients hospitalized with COVID-19 infection,and *** random effects models were used to calculate crude and adjusted odds ratios(aORs)with 95%confidence intervals(95%CIs).RESULTS Forty-six observational studies met our inclusion *** unadjusted analysis found no association between prior anticoagulation and thromboembolic event risk[n=43851,9 studies,odds ratio(OR)=0.67(0.22,2.07);P=0.49;I2=95%].The association between prior anticoagulation and disease severity was non-significant[n=186782;22 studies,OR=1.08(0.78,1.49);P=0.64;I2=89%].However,pre-hospital anticoagulation significantly increased all-cause mortality risk[n=207292;35 studies,OR=1.72(1.37,2.17);P<0.00001;I2=93%].Pooling adjusted estimates revealed a statistically non-significant association between pre-hospital anticoagulation and thromboembolic event risk[aOR=0.87(0.42,1.80);P=0.71],mortality[aOR=0.94(0.84,1.05);P=0.31],and disease severity[aOR=0.96(0.72,1.26);P=0.76].CONCLUSION Prehospital anticoagulation was not significantly associated with reduced risk of thromboembolic events,improved survival,and lower disease seve

关键词： Prior anticoagulation COVID-19 Prehospital anticoagulation Chronic anticoagulation Mortality Severity Thromboembolic events

基于递归投影方法的电力系统平衡点计算与小扰动稳定性分析

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中国电机工程学报 2011年第16期31卷 67-73页

作者：范孟华王成山 venkataramana Ajjarapu 智能电网教育部重点实验室(天津大学) 天津市南开区300072 爱荷华州立大学电气与计算机工程系美国艾姆斯50010

递归投影方法(recursive projection method,RPM)通过对现有时域仿真程序(time-domain simulation code,TDSC)的黑箱调用来获取电力系统平衡点以及小扰动稳定信息。在RPM作用下,全状态空间被解耦为不稳定/慢不变子空间及其正交补子空间... 详细信息

递归投影方法(recursive projection method,RPM)通过对现有时域仿真程序(time-domain simulation code,TDSC)的黑箱调用来获取电力系统平衡点以及小扰动稳定信息。在RPM作用下,全状态空间被解耦为不稳定/慢不变子空间及其正交补子空间两部分,分别采用牛顿型算法以及TDSC原有的不动点迭代格式进行计算。采用QR分解方法或Arnoldi方法来构造不变子空间的基底,并通过具体算例验证RPM增强不动点迭代收敛性以及判别系统小扰动稳定状态的有效性;同时,还分析不同基底构造方式和参数设置方案对RPM计算性能的影响,并得出了RPM适宜与显式积分法结合使用的结论。

关键词：递归投影时域仿真平衡点小扰动稳定性不变子空间基底