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Highly selective adsorption of rhenium by amyloid-like protein material

Science China(Technological Sciences) 2024年第5期67卷 1417-1430页

作者： muhammad arif YANG QingMin KANWAL Aisha ZHAO Jian NAWAZ Mohsan REN Hao YANG Peng Key Laboratory of Applied Surface and Colloid Chemistry Ministry of Education Xi’an Key Laboratory of Polymeric Soft Matter International Joint Research Center on Functional Fiber and Soft Smart TextileSchool of Chemistry and Chemical EngineeringShaanxi Normal UniversityXi’an710119China School of Chemistry and Chemical Engineering Northwestern Polytechnical UniversityXi’an710072China

Rhenium separation from molybdenum in molybdenite minerals and waste leachate has become an emerging *** this challenge,we prepared a set of protein-based alkylamine/alkylammonium salts complexes as extractants for selective uptake of rhenium from molybdenum,where the protein component turned into the insoluble amyloid-like structure when its internal disulfide bonds were reduced,namely phase-transition *** them,the phase-transited lysozyme and methyletrioctyleammonium chloride complex(PTL-N263)exhibited the most efficient adsorption at the alkaline condition for the electrostatic interaction between negatively charged metal ions with positively charged center(R_(4)N^(+))in N263,where negatively charged protein residues hindered the ion exchange of Cl^(-)in N263 for larger size Mo species(Mo_(7)O_(24)^(6-))than smaller size Re species(ReO^(4-)).The adsorption follows the Freundlich model and pseudo-second-order kinetics,which exhibits toplevel adsorption performance with a maximum adsorption capacity of 124 mg/g and a separation factor(β_(Re/Mo))of 2.78×10^(3)for *** adsorption capacity per unit area(57.2 mg/(g m^(2)))is 1.6–41 times higher than previously reported adsorbents,and the cost for adsorbing 1 g of Re(VII)is$1.07,indicating its industrial *** adsorption strategy can be applied to separating Re from Mo in binary solutions and industrial wastewater with other competing ions.

关键词： amyloid phase-transited lysozyme selective adsorption rhenium waste leachate solution

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Impact of numerous larval diets on the biology of pink bollworm Pectinophora gossypiella(Saunders)(Lepidoptera:Gelechiidae)under laboratory conditions

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Journal of Cotton Research 2024年第1期7卷 69-78页

作者： AKHTAR Shamim arif muhammad Jalal GOGI muhammad Dildar HAQ Imran-ul Department of Entomology University of Agriculture FaisalabadPunjabPakistan Ayub Agricultural Research Institute(Entomological Research Institute) FaisalabadPunjabPakistan Department of Plant Pathology University of AgricultureFaisalabadPunjabPakistan

Background Pink bollworm,Pectinophora gossypiella(Saunders)(Lepidoptera:Gelechiidae)has become a poten-tial pest of cotton by causing substantial yield losses around the world including *** in view the facts like limited research investigations,unavailability,and high cost of artificial diet’s constituents and their premixes,the present research investigations on the dietary aspect of *** were *** larvae of *** were reared on different diets that were prepared using indigenous *** standard/laboratory diet com-prised of wheat germ meal 34.5 g,casein 30.0 g,agar–agar 20.0 g,sucrose 10.0 g,brewer’s yeast 5.0 g,α-cellulose 1.0 g,potassium-sorbate1.5 g,niplagin 0.5 g,decavitamin 0.01 g,choline-chloride 0.06 g,maize-oil 3.30 g,honey 2.0 g,and water 730.0 *** to cotton bolls and wheat germ meal were okra seed sprouts,okra fruit,cottonseed meal,and okra seed meals,which were included in the study to introduce an efficient and economic mass-rearing *** The larval development completed in 19.68d±0.05 d with a weight of 20.18mg±0.20 mg at the fourth instar fed on the cottonseed meal-based diet instead of wheat germ meal based *** the same diet,84.00%±4.00%,17.24 mg±0.03 mg,and 7.76d±0.06 d were recorded as pupae formation,pupal weight,and pupal duration,*** emergence,76.00%±1.00%was recorded from pupae collected from larvae raised on cottonseed meal-based *** male and female moths lived for 40.25d±0.10 d,and 44.34d±0.11 d,*** deposited 21.28±0.04 eggs per day with the viability of 65.78%±0.14%.The larval mortal-ity at the fourth instar was 37.20%±1.36%and malformed pupation of 12.00%±1.41%was *** of wheat germ meal with that of local meals(cottonseed and okra seed)in the standard laboratory diet has saved 463.80 to 467.10 PKR with 1.62 to 1.63 cost economic returns,*** This research is of novel nature as it provides a concis

关键词： Artificial diets Cottonseed meal Laboratory rearing Pectinophora gossypiella Wheat germ meal

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Exogenous application of bio-stimulants and growth retardants improve nutrient absorption and fiber quality in upland cotton

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Journal of Cotton Research 2024年第2期7卷 137-147页

作者： Al-Khayri Jameel M. arif muhammad Kareem Shadia Hama Salih Anwar Adeel Dehghanisanij Hossein Emami Somayeh Yasmeen Azra Aftab Komal Negm Mohamed Department of Agricultural Biotechnology College of Agriculture and Food SciencesKing Faisal University31982 Al‑AhsaSaudi Arabia Water Resources Zone Irrigation Department PunjabD.G.KhanPakistan Department of Biotechnology and Crop Science College of Agricultural Engineering SciencesUniversity of SulaimaniSulaimaniIraq Department of Agronomy PMAS-Arid Agriculture UniversityRawalpindiPakistan Agricultural Research Education and Extension OrganizationAgricultural Engineering Research InstituteKarajAlborzIran Department of Water Engineering University of TabrizTabrizIran Department of Agronomy Bahauddin Zakariya UniversityMultanPakistan Department of Plant Breeding and Genetics Bahauddin Zakariya UniversityMultanPakistan Agricultural Research Center Cotton Research InstituteGiza 12619Egypt

Background Natural and synthetic plant growth regulators are essential for plant health,likewise these regulators also play a role in increasing organic production productivity and improving quality and yield *** the present study,we have evaluated the effects of foliar applied plant growth regulators,i.e.,moringa leaf extract(MLE)and mepiquat chloride(MC)alone and in combination MC and MLE on the conventional cotton cultivar(CIM 573)and transgenic one(CIM 598).The growth regulators were applied at the start of bloom,45 and 90 days after *** The application of MC and MLE at 90 days after blooming significantly improved the relative growth rate,net assimilation rate,the number of bolls per plant,and seed cotton ***,the combined application of MLE and MC at 90 days after blooming significantly boosted the nitrogen uptake in locules,as well as the phosphorus and potassium uptake in the leaves of both cotton *** application of MLE alone has considerably improved the nitrogen uptake in leaves,and phosphorus and potassium contents in locules of Bt and conventional cotton ***,Bt cotton treated with MLE at 90 days after blooming produced significantly higher ginning out turn and oil *** in combination(MLE+MC)at 90 days after blooming produced considerably higher micronaire value,fiber strength,and staple length in conventional *** The natural growth enhancer,MLE is a rich source of minerals and zeatin,improving the nutrient absorption and quality of cotton fiber in both conventional and Bt cotton cultivars.

关键词： Bio-stimulant Cotton Fiber quality Mepiquat chloride Moringa leaf extract Potassium accumulation Oil contents

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Suppression of methane formation during Fisher-Tropsch synthesis using manganese-cobalt oxide supported on H-5A zeolite as a catalyst

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Journal of Natural Gas Chemistry 2009年第2期18卷 187-190页

作者： Syed Tajammul Hussain muhammad Mazhar muhammad arif Nadeem National Centre for Physics Quaid-i-Azam UniversityIslamabad 43520 Pakistan Department of Chemistry Quaid-i-Azam UniversityIslamabad 43520 Pakistan

In Fischer-Tropsch synthesis reaction, methane formation is one of the side reactions which must be suppressed in order to get better catalytic selectivity for light olefins. In the present study, we have modified cobalt based Fischer-Tropsch catalyst and developed a process to minimize methane production, consequently to produce maximum yield of light olefins. Manganese-cobalt oxide supported on H-5A zeolite catalyst was synthesized using modified H-5A zeolite, to increase its surface acid sites. Increased acidity of zeolite plays a major part in the suppression of methane formation during the Fischer-Tropsch reaction. The modified zeolite results in the electronic modification of catalyst surface by creating new active catalytic sites. The results are compared with other supported catalysts along with unmodified zeolite. Appreciable reduction in methane formation is achieved on modified zeolite supported catalyst in comparison with unsupported catalyst.

关键词： methane formation Fisher-Tropsch synthesis manganese cobalt suppression

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SUFFICIENT CONDITION FOR FUNCTIONS TO BE IN A CLASS OF MEROMORPHIC MULTIVALENT SAKAGUCHI TYPE SPIRAL-LIKE FUNCTIONS

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Acta Mathematica Scientia 2014年第2期34卷 575-578页

作者： muhammad arif Janusz SOK muhammad AYAZ Department of Mathematics Abdul Wali Khan University Mardan Department of Mathematics Rzeszw University of Technology

In this article, we define a subclass of meromorphic multivalent Sakaguchi type functions and obtain certain sufficient conditions for functions to be in this class. The main result presented here includes a number of... 详细信息

关键词： Sakaguchi type functions spirallike functions meromorphic functions

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Classification of Human Protein in Multiple Cells Microscopy Images Using CNN

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Computers, Materials & Continua 2023年第8期76卷 1763-1780页

作者： Lina Al-joudi muhammad arif Department of Computer Science AI(CS-AI) Umm Al Qura University(UQU)Makkah24231Saudi Arabia

The subcellular localization of human proteins is vital for understanding the structure of human *** play a significant role within human cells,as many different groups of proteins are located in a specific location to perform a particular *** these functions will help in discoveringmany diseases and developing their *** importance of imaging analysis techniques,specifically in proteomics research,is becoming more *** recent advances in deep learning techniques for analyzing microscopy images,classification models have faced critical challenges in achieving high *** protein subcellular images have a significant class *** use oversampling and under sampling techniques in this research to overcome this *** have used a Convolutional Neural Network(CNN)model called GapNet-PL for the multi-label classification task on the Human Protein Atlas Classification(HPA)*** have found that the ParametricRectified LinearUnit(PreLU)activation function is better than the Scaled Exponential LinearUnit(SeLU)activation function in the GapNet-PL model in most classification *** results showed that the GapNet-PL model with the PReLU activation function achieved an area under the ROC curve(AUC)equal to 0.896,an F1 score of 0.541,and a recall of 0.473.

关键词： CNN protein PReLU SeLU microscopy images subcellular localization multi-cells

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Structure of [Co(im)6]SiF6：Short Hydrogen Bonds Involving SiF62- Ions

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Chinese Journal of Structural Chemistry 2017年第6期36卷 965-970页

作者： NAZIR Sadia arif muhammad RASHID muhammad Abid WHITWOOD Adrian Charles Department of Chemistry Govt. College Women University Faisalabad 3800 Pakistan Institute of Chemical Sciences Bahhauddin Zakariya University Multan 60800 Pakistan Department of Chemistry University of Agriculture Faisalabad 38040 Pakistan Department of Chemistry University of York Heslington York YO10 5DD UK

A new complex C（18）H（24）CoF6N（12）Si has been synthesized by the reaction of cobalt（II） fluoride tetrahydrate with imidazole in a glass vessel. SiF62-was generated by in situ reaction of fluoride on silica. This complex has been characterized by different techniques such as elemental analysis, IR studies, magnetic measurements, electronic absorption measurements and single-crystal X-ray structure determination. The crystals are hexagonal in the R-3 space group, with a = 13.225（6）, b = 13.225（6）, c = 12.517（11） A, and g = 120°. In complex [Co（im）6]SiF6, the cobalt atom is six-coordinated to adopt a regular octahedral geometry and the SiF62-ion acts as the counter anion. The crystal displays a network structure and SiF62- bridging hexagram formation by N-（39）···F-Si interactions between imdazole and SiF62-. SiF62-plays an important role in assembling the supramolecular aggregates.

关键词： anion binding imidazole SiF62- hydrogen bonds transitionmetal fluoride complexes

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Highly active sites of NiVB nanoparticles dispersed onto graphene nanosheets towards efficient and pH-universal overall water splitting

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Journal of Energy Chemistry 2021年第7期30卷 237-246页

作者： muhammad arif Ghulam Yasin muhammad Shakeel muhammad Asim Mushtaq Wen Ye Xiaoyu Fang Shengfu Ji Dongpeng Yan Beijing Key Laboratory of Energy Conversion and Storage Materials College of ChemistryBeijing Normal UniversityBeijing 100875China State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing 100029China College of Chemistry and Molecular Engineering Zhengzhou UniversityZhengzhou 450001HenanChina

Production of hydrogen(H2) and oxygen(O2) through electrocatalytic water splitting is one of the sustainable,green and pivotal ways to accomplish the ever-increasing demands for renewable energy sources,but remains a big challenge because of the uphill reaction during overall water ***,we develop high-performance non-noble metal electrocatalysts for pH-universal water splitting,based on nickel/vanadium boride(NiVB) nanoparticles/reduced graphene oxide(rGO) hybrid(NiVB/rGO)through a facile chemical reduction approach under ambient *** virtue of more exposure to surface active sites,superior electron transfer capability and strong electronic coupling,the asprepared NiVB/rGO heterostructure needs pretty low overpotentials of 267 and 151 mV to deliver a current density of 10 mA cm^(-2) for oxygen evolution reaction(OER) and hydrogen evolution reaction(HER)respectively,with the corresponding Tafel slope of 44 and 88 mV dec^(-1) in 1.0 M ***,the NiVB/rGO electrocatalysts display a promising performance in a wide-pH conditions that require low overpotential of 310,353 and 489 mV to drive a current density of 10 mA cm^(-2) for OER under 0.5 M KOH,0.05 M H2SO4 and 1.0 M phosphate buffer solution(PBS) respectively,confirming the excellent electrocata lytic performance among state-of-the-art Ni-based electrocatalysts for overall water ***,the interfacial tuning based on incorporation of active heterostructure may pave a new route to develop bifunctional,cost-effective and efficient electrocatalyst systems for water splitting and H2 production.

关键词： Electrocatalysis Oxygen evolution reaction Hydrogen evolution reaction NiVB/rGO heterostructure pH-universal

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Analytical Hybrid Particle Swarm Optimization Algorithm for Optimal Siting and Sizing of Distributed Generation in Smart Grid

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Journal of Modern Power Systems and Clean Energy 2020年第6期8卷 1221-1230页

作者： Syed muhammad arif Akhtar Hussain Tek Tjing Lie Syed muhammad Ahsan Hassan Abbas Khan the Department of Electrical and Electronic Engineering Auckland University of TechnologyAucklandNew Zealand the Department of Electrical Engineering Incheon National UniversityIncheonKorea the Department of Electrical Engineering Lahore University of Management SciencesLahorePakistan

In this paper,the hybridization of standard particle swarm optimisation(PSO)with the analytical method(2/3 rd rule)is proposed,which is called as analytical hybrid PSO(AHPSO)algorithm used for the optimal siting and sizing of distribution *** proposed AHPSO algorithm is implemented to cater for uniformly distributed,increasingly distributed,centrally distributed,and randomly distributed loads in conventional power *** demonstrate the effectiveness of the proposed algorithm,the convergence speed and optimization performances of standard PSO and the proposed AHPSO algorithms are compared for two *** the first case,the performances of both the algorithms are compared for four different load distributions via an IEEE 10-bus *** the second case,the performances of both the algorithms are compared for IEEE 10-bus,IEEE 33-bus,IEEE 69-bus systems,and a real distribution system of *** results show that the proposed AHPSO algorithm converges significantly faster than the standard *** results of the proposed algorithm are compared with those of an analytical algorithm,and the results of them are similar.

关键词： Siting and sizing of distributed generation distribution system hybrid algorithm loss minimization particle swarm optimization(PSO)

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A Systematic Literature Review of Deep Learning Algorithms for Segmentation of the COVID-19 Infection

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Computers, Materials & Continua 2023年第6期75卷 5717-5742页

作者： Shroog Alshomrani muhammad arif Mohammed A.Al Ghamdi Department of Computer Science College of Computer and Information SciencesUmm AlQura UniversityMakkah24231Saudi Arabia

Coronavirus has infected more than 753 million people,ranging in severity from one person to another,where more than six million infected people died ***-aided diagnostic(CAD)with artificial intelligence(AI)showed outstanding performance in effectively diagnosing this virus in *** tomography is a complementary diagnostic tool to clarify the damage of COVID-19 in the lungs even before symptoms appear in *** paper conducts a systematic literature review of deep learning methods for classifying the segmentation of COVID-19 infection in the *** used the methodology of systematic reviews and meta-analyses(PRISMA)flow *** research aims to systematically analyze the supervised deep learning methods,open resource datasets,data augmentation methods,and loss functions used for various segment shapes of COVID-19 infection from computerized tomography(CT)chest *** have selected 56 primary studies relevant to the topic of the *** have compared different aspects of the algorithms used to segment infected areas in the CT *** to deep learning in the segmentation of infected areas still need to be developed to predict smaller regions of infection at the beginning of their appearance.

关键词： COVID-19 segmentation chest CT images deep learning systematic review 2D and 3D supervised deep learning

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