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PtCu dendroframe octahedrons:Enhancing peroxidase-like activity and antibacterial efficiency through structural evolution

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Nano Research 2025年第1期18卷 100-106页

作者： Ri Feng Jiuyi Hu Liangjun Wang Jiayu Xu Jiajia Li Zeeshan ahmad shaohui Zheng Muhammad Farhan Farid Wenjing Liu Faisal saleem Key Laboratory of Flexible Electronics(KLOFE) Institute of Advanced Materials(IAM)and School of Flexible Electronics(Future Technologies)Nanjing Tech UniversityNanjing 211816China

Nanozymes,which possess enzyme-like catalytic activity,are attractive alternatives to natural *** activity is largely dependent on the structure of the ***,challenges remain in optimizing the structure-activity *** work explores the synthesis and utilization of PtCu nanostructures(Nss),focusing on their peroxidase(POD)-like properties and their potential as antibacterial *** developed PtCu dendrites that transform into unique dendroframe octahedrons(DFOs)and subsequently stabilize into solid octahedrons with unusual growth *** intermediate DFO,showed higher POD-like activity in comparison to other shapes of PtCu *** DFOs also have the better ability to consume glutathione,thus enhancing their sterilization ***,we demonstrate the effectiveness of these PtCu DFOs as powerful antibacterial *** work provides valuable information on shape dependent activities of PtCu Nss in the field of biomedicine.

关键词： nanozymes antibacterials peroxidase PtCu dendroframe octahedrons dendrites

Leaching of styrene and other aromatic compounds in drinking water from Ps bottles

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Journal of Environmental sciences 2007年第4期19卷 421-426页

作者： Maqbool ahmad ahmad s. Bajahlan Environmental Control Department Directorate General for Royal Commission at Yanbu P.O.Box 30031 Yanbu Al-SinaiyahKingdom of Saudi Arabia

Bottled water may not be safer, or healthier, than tap water. The present studies have proved that styrene and some other aromatic compounds leach continuously from polystyrene （Ps） bottles used locally for packaging. Water sapmles in contact with Ps were extracted by a preconcentration technique called as ＂purge and trap＂ and analysed by gas chromatograph-mass spectrometer （GC/Ms）. Eleven aromatic compounds were identified in these studies. Maximum concentration of styrene in Ps bottles was 29.5 μg/L. Apart from styrene, ethyl benzene, toluene and benzene were also quantified but their concentrations were much less than WHO guide line values. All other compounds were in traces. Quality of plastic and storage time were the major factor in leaching of styrene. Concentration of styrene was increased to 69.53 μg/L after one-year storage. In styrofoam and Ps cups studies, hot water was found to be contaminated with styrene and other aromatic compounds. It was observed that temperature played a major role in the leaching of styrene monomer from styrofoam cups. Paper cups were found to be safe for hot drinks.

关键词： styrene polystyrene (Ps) ethyl benzene leaching styrofoam

Comparative study of living donor kidney transplants:Right vs left

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World Journal of Transplantation 2025年第1期15卷 115-123页

作者： Taqi Khan Nadeem ahmad Qaisar Iqbal Muneeb Hassan Lajward Asnath Naveed Khan sajid shakeel Kidney Transplant Unit Rehman Medical InstitutePeshawar 25100Khyber PakhtunkhwaPakistan Department of surgery Princess Noura Binti AbdulRehman UniversityRiyadh 84428Saudi Arabia

BACKGROUND Transplant teams often hesitate to use the right kidney(RK)in living donor(LD)transplants due to the complexities of anastomosing the short,thin-walled right renal veins,which can potentially lead to graft loss or graft ***,circumstances may arise where selecting the RK over the left kidney(LK)is ***,it is crucial to thoroughly examine the implications of such a choice on the overall transplant *** To compare transplant outcomes between recipients of RK and LK while examining the factors that influence these *** We retrospectively analyzed data from adult patients who received LD kidney transplants involving meticulous patient selection and surgical techniques at our center from January 2020 to December *** included all kidney donors who were over 18,fit to donate,and had undergone diethylenetriamine pentaacetic acid split function and/or computed tomography based *** variables examined comprised donor and recipient demographics,and outcome measures included technical graft loss(TGL),delayed or slow graft function(sGF),and post-transplant serum creatinine(sC)*** used a logistic regression model to assess the likelihood of adverse outcomes considering the donor kidney *** Of the 250 transplants performed during the period,56(22%)were *** recipient demographics and transplant factors were comparable for the right and LKs,except that the donor warm and cold ischemia time were shorter for *** and sGF each occurred in 2%(n=1)of RKs and 0.5%(n=1)of LKs,the difference being *** complications,however,were not related to the venous *** RK(2%)developed delayed graft function after 48 hours,which was attributable to postoperative hypoxia rather than the surgical *** post-transplant sC trend and mean sC at the last follow-up were similar across both kidney *** The donor kidney side has little impact on post-transplant

关键词： Living donor Right kidney Right renal vein Venous anastomosis Technical graft loss Early graft function

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Journal of Rare Earths 2018年第10期36卷 1106-1111页

作者： sardar ahmad M.shafiq Rashid ahmad s.Jalali-Asadabadi Iftikhar ahmad Department of Chemistry University of Malakand Center for Computational Materials science University of Malakand Department of Physics Abbottabad University of Science and Technology Department of Physics Faculty of SciencesUniversity of Isfahan

In this paper, we explored the structural, elastic and mechanical properties of the strongly correlated electron systems, intermetallic Ln-Au（Ln = Ce, Pr, Nd, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu） in cubic structure,using PF-LAPW method within the density functional theory. structural properties of these intermetallics were investigated by treating the exchange-correlation potential with the GGA-PBE, GGA-PBEsol and GGA ＋ U. The effectiveness of the U for the structural properties as compared to other methods confirms the strong correlated nature of these compounds and the calculated lattice constants endorse the divalency of Yb. The results demonstrate the stable cubic CsCl structure of these compounds. Bulk modulus, Young＇s modulus, shear modulus, B/G ratio, Cauchy pressure, Poisson＇s ratio, anisotropic ratio,Kleinman parameters and Lame＇s coefficients were studied using the PBEsol to evaluate their importance in various types of engineering applications. The most prominent features of these compounds are their ductility, very high melting points, resistance to corrosion, and anisotropic nature.

关键词： strongly correlated electron systems Rare-earth monoaurides Mechanical properties Ab-initio calculation

Nanoscale mass sensing based on vibration of single-layered graphene sheet in thermal environments

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Acta Mechanica sinica 2014年第1期30卷 84-91页

作者： s.ahmad Fazelzadeh Esmaeal Ghavanloo school of Mechanical Engineering Shiraz University

Based on vibration analysis, single-layered graphene sheet （sLGs） with multiple attached nanoparticles is developed as nanoscale mass sensor in thermal environments. Graphene sensors are assumed to be in simplysupported configuration. Based on the nonlocal plate the- ory which incorporates size effects into the classical theory, closed-form expressions lot the frequencies and relative fre- quency shills of sLGs-based mass sensor are derived using the Galerkin method. The suggested model is justified by a good agreement between the results given by the present model and available data in literature. The effects of tem- perature difference, nonlocal parameter, the location of the nanoparticle and the number of nanoparticles on the relative frequency shift of the mass sensor are also elucidated. The obtained results show that the sensitivity of the sLGs- based mass sensor increases with increasing temperature difference.

关键词： Vibration - single-layered graphene sheet. Ther- mal environment - Nonlocal elasticity theory Relative frequency shift

Influence of soaking time in deep cryogenic treatment on the microstructure and mechanical properties of low-alloy medium-carbon HY-TUF steel

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International Journal of Minerals,Metallurgy and Materials 2016年第6期23卷 658-666页

作者： ahmad Zare s.R.Hosseini Department of Materials Engineering Maleke-ashtar University of Technology

The influence of soaking time in deep cryogenic treatment on the tensile and impact properties of low-alloy medium-carbon HY-TUF steel was investigated in this study. Microstructural studies based on phase distribution mapping by electron backscatter diffraction show that the deep cryogenic process causes a decrease in the content of retained austenite and an increase in the volume fraction of η-carbide with increasing soaking time up to 48 h. The decrease in the content of retained austenite from ~1.23vol% to 0.48vol% suggests an isothermal martensitic transformation at 77 K. The η-type precipitates formed in deep cryogenic-treated martensite over 48 h have the Hirotsu and Nagakura orientation relation with the martensitic matrix. Furthermore, a high coherency between η-carbide and the martensitic matrix is observed by high-resolution transmission electron microscopy. The variations in macrohardness, yield strength, ultimate tensile strength, and ductility with soaking time in the deep cryogenic process show a peak/plateau trend.

关键词： low alloy steel medium carbon steel cryogenic treatment microstructure mechanical properties fractography

Flow and heat transfer over hyperbolic stretching sheets

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Applied Mathematics and Mechanics(English Edition) 2012年第4期33卷 445-454页

作者： A. ahmad s. AsGHAR COMsATs Institute of Information Technology Department of Mathematics King Abdulaziz University

The boundary layer flow and heat transfer analysis of an incompressible viscous fluid for a hyperbolically stretching sheet is presented. The analytical and numer- ical results are obtained by a series expansion method and a local non-similarity （LNs） method, respectively. The analytical and numerical results for the skin friction and the Nusselt number are calculated and compared with each other. The significant observation is that the momentum and the thermal boundary layer thickness decrease as the distance from the leading edge increases. The well-known solution of linear stretching is found as the leading order solution for the hyperbolic stretching.

关键词： hyperbolic stretching sheet boundary layer flow heat transfer seriesexpansion method local non-similarity method

Interaction of Point Defects with Twin Boundaries in Copper

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Chinese Physics Letters 2007年第9期24卷 2631-2634页

作者： s. A. ahmad Razia Ramzan Department of Physics Islamia University of Bahawalpur Bahawalpur Pakistan

The interaction between small vacancy clusters and twin boundaries in copper is studied by using many-body potential developed by Ackland et aL for fcc metals. The interaction energies of single-, di- and tri-vacancy clusters with （111） and （112） twin boundaries are computed using well established simulation techniques. For （111） twins the vacancy clusters are highly repelled when they are on the adjacent planes, and are attracted when they are away from the boundary. In the case of （112） twins, vacancy clusters are more attracted to the boundary when they are near the boundary as compared to away from it. Vacancy clusters on both the sides of the boundary are also investigated, and it is observed that the clusters energetically prefer to lie on the off-mirror sites as compared to the mirror position across the twin.

关键词： CLOsE-PACKED CLUsTERs CRYsTALs VACANCIEs METALs

Flow and heat transfer of a nanofluid over a hyperbolically stretching sheet

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Chinese Physics B 2014年第7期23卷 I0004-I0006,475-478页

作者： A.ahmad s.Asghar A.Alsaedi COMsATs Institute of Information Technology Distinguished Adjunct Professor Department of MathematicsKing Abdul Aziz University

This article explores the boundary layer flow and heat transfer of a viscous nanofluid bounded by a hyperbolically stretching sheet. Effects of Brownian and thermophoretic diffusions on heat transfer and concentration of nanoparticles are given due attention. The resulting nonlinear problems are computed for analytic and numerical solutions. The effects of Brownian motion and thermophoretic property are found to increase the temperature of the medium and reduce the heat transfer rate. The thermophoretic property thus enriches the concentration while the Brownian motion reduces the concentration of the nanoparticles in the fluid. Opposite effects of these properties are observed on the sherwood number.

关键词： hyperbolically stretching sheet nanofluid boundary layer flow heat transfer