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Co-pyrolysis of waste biomass and waste plastics(polystyrene and waste nitrile gloves)into renewable fuel and value-added chemicals

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Carbon Resources Conversion 2020年第1期3卷 145-155页

作者： Ranjeet Kumar mishra Kaustubha Mohanty Department of Chemical Engineering Indian Institute of Technology GuwahatiGuwahati 781039India

The present study addresses the influence of blending of waste plastics(i.e.,polystyrene,PS and waste nitrile gloves,WNG)with mahua seeds(MH)for co-pyrolytic liquid yield and its fuel *** blends of waste plastics were mixed with biomass(10,20 and 30 wt%)and pyrolyzed in a semi-batch reactor at an optimized environment(550℃ temperature,80℃ min^(-1) heating rate,and 100 mL min^(-1) N_(2) flow rate).Physicochemical results displayed its ability to yield renewable fuel and valuable ***-pyrolysis outcomes showed that blending of waste plastics at 20 wt%,yielded maximum liquid(44.18±1.2 wt%and 45.89±1.4 wt%for MH+WNG and MH+PS respectively)which was higher than thermal pyrolysis of individual MH(39.26±1.2 wt%).Further,characterization results revealed a substantial reduction in viscosity,oxygen content,moisture,and a positive increment in gross heating value,carbon content and *** examination exposed the attendance of mainly aromatics,acids,phenols,water,esters and ***,NMR analysis of pyrolytic oil confirmed an increase in aromaticity by blending of waste plastics(20 wt%)while there was a reduction in paraffinic ***-MS investigation revealed substantial improvement in hydrocarbons and minimization in the oxygen-rich products by blending of waste plastics at 20 wt%.

关键词： Waste biomass Plastics Co-pyrolysis Pyrolytic oil Fuel characterization

Upper ocean high resolution regional modeling of the Arabian Sea and Bay of Bengal

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Acta Oceanologica Sinica 2019年第5期38卷 32-50页

作者： Dwivedi Suneet mishra Alok Kumar Srivastava Atul K Banerjee Centre of Atmospheric and Ocean Studies and M N Saha Centre of Space Studies University of Allahabad

In this paper, effort is made to demonstrate the quality of high-resolution regional ocean circulation model in realistically simulating the circulation and variability properties of the northern Indian Ocean(10°S–25°N,45°–100°E) covering the Arabian Sea(AS) and Bay of Bengal(BoB). The model run using the open boundary conditions is carried out at 10 km horizontal resolution and highest vertical resolution of 2 m in the upper *** surface and sub-surface structure of hydrographic variables(temperature and salinity) and currents is compared against the observations during 1998–2014(17 years). In particular, the seasonal variability of the sea surface temperature, sea surface salinity, and surface currents over the model domain is studied. The highresolution model's ability in correct estimation of the spatio-temporal mixed layer depth(MLD) variability of the AS and BoB is also shown. The lowest MLD values are observed during spring(March-April-May) and highest during winter(December-January-February) seasons. The maximum MLD in the AS(BoB) during December to February reaches 150 m (67 m). On the other hand, the minimum MLD in these regions during March-April-May becomes as low as 11–12 m. The influence of wind stress, net heat flux and freshwater flux on the seasonal variability of the MLD is discussed. The physical processes controlling the seasonal cycle of sea surface temperature are investigated by carrying out mixed layer heat budget analysis. It is found that air-sea fluxes play a dominant role in the seasonal evolution of sea surface temperature of the northern Indian Ocean and the contribution of horizontal advection, vertical entrainment and diffusion processes is small. The upper ocean zonal and meridional volume transport across different sections in the AS and BoB is also computed. The seasonal variability of the transports is studied in the context of monsoonal currents.

关键词： Indian Ocean modeling Arabian Sea and Bay of Bengal mixed layer depth transport

Blockchain-Based SQKD and IDS in Edge Enabled Smart Grid Network

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Computers, Materials & Continua 2022年第2期70卷 2149-2169页

作者： Abdullah Musaed Alkhiari Shailendra.mishra Mohammed AlShehri Department of Information Technology College of Computer and Information SciencesMajmaah UniversityMajmaah11952Saudi Arabia Department of Computer Engineering College of Computer and Information SciencesMajmaah UniversityMajmaah11952Saudi Arabia

Smart Grid is a power grid that improves flexibility,reliability,and efficiency through smart *** to extensive data exchange over the Internet,the smart grid faces many security challenges that have led to data loss,data compromise,and high power ***,the lack of hardware protection and physical attacks reduce the overall performance of the smart grid *** proposed the BLIDSE model(Blockchain-based secure quantum key distribution and Intrusion Detection System in Edge Enables Smart Grid Network)to address these *** proposed model includes five phases:The first phase is blockchain-based secure user authentication,where all smart meters are first registered in the blockchain,and then the blockchain generates a secret *** blockchain verifies the user ID and the secret key during authentication matches the one authorized to access the *** secret key is shared during transmission through secure quantum key distribution(SQKD).The second phase is the lightweight data encryption,for which we use a lightweight symmetric encryption algorithm,named *** third phase is the multi-constraint-based edge selection;the data are transmitted to the control center through the edge server,which is also authenticated by blockchain to enhance the security during the data *** proposed a perfect matching algorithm for selecting the optimal *** fourth phase is a dual intrusion detection system which acts as a firewall used to drop irrelevant packets,and data packets are classified into normal,physical errors and attacks,which is done by Double DeepQNetwork(DDQN).The last phase is optimal user privacy *** this phase,smartmeter updates and revocations are done,forwhichwe proposed Forensic based Investigation Optimization(FBI),which improves the security of the smart grid *** simulation is performed using network simulator NS3.26,which evaluates the performance in terms of computational complexity,accurac

关键词： Smart grid edge computing intrusion detection system blockchain quantum key distribution deep reinforcement learning

A laboratory scale study on arsenic(V) removal from aqueous medium using calcined bauxite ore

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Journal of Environmental Sciences 2008年第6期20卷 683-689页

作者： Debasish Mohapatra Debaraj mishra Kyung Ho Park DAEIL Development Co. Ltd. Research and Development CenterAnsan 425 836 Korea. Minerals and Materials Processing Division Korea Institute of Geosciences and Mineral ResourcesDaejeon 305 350 Korea

The present work deals with the As（Ⅴ） removal from an aqueous medium by calcined refractory grade bauxite （CRB） as a function of solution pH, time, As（Ⅴ） concentration and temperature. The residual As（Ⅴ） was lowered from 2 mg/L to below 0.01 mg/L in the optimum pH range 4.0-7.0 using a 5 g/L CRB within 3 h contact time. The adsorption data fits well with Langmuir isotherm and yielded Langmuir monolayer capacity of 1.78 mg As（Ⅴ）/g of CRB at pH 7.0. Presence of anions such as silicate and phosphate decreased As（Ⅴ） adsorption efficiency. An increase temperature resulted a decrease in the amount of As（Ⅴ） adsorbed by 6%. The continuous fixed bed column study showed that at the adsorbent bed depth of 30 cm and residence time of 168 min, the CRB was capable of treating 340 bed volumes of As（V） spiked water （C0 = 2 mg/L） before breakthrough （Ce = 0.01 mg/L）. This solid adsorbent, although not reusable, can be considered for design of adsorption columns as an efficiency arsenic adsorption media.

关键词： adsorption As(Ⅴ) calcination adsorption isotherm column study

Settling characteristics of ultrafine iron ore slimes

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International Journal of Minerals,Metallurgy and Materials 2012年第2期19卷 95-99页

作者： Chinthapudi Eswaraiah Surendra Kumar Biswal Barada Kanta.mishra Institute of Minerals and Materials Technology (IMMT) Council of Scientific and Industrial Research (CSIR) Bhubaneswar 751 013 India

The slurry settling characteristics are the most important to design a thickener in process industries. In this work, the iron ore slurry from the screw classifier overflow was used for the settling study. It was observed that the original slurry exhibited a low settling velocity and a turbid supernatant during the settling process. Commercial flocculating agents with anionic, cationic, and nonionic characters were used to improve the settling behavior of suspensions, which were added into the slurry at different ranges of slurry pH values, respectively. The settling results show that the use of flocculants increase the settling rate by several times. Compared with the cationic and non-ionic flocculants, the anionic flocculant is more effective in enhancing the slurry settling rate. The small dose of the anionic flocculant is found to be more effective, but the other flocculants are less effective even at higher dosages. The simulation of an industrial thickener was carried out based on the laboratory settling data, and the appropriate design and selection parameters of the industrial thickener were estimated.

关键词： iron ores dewatering flocculation thickener design

Web Security:Emerging Threats and Defense

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Computer Systems Science & Engineering 2022年第3期40卷 1233-1248页

作者： Abdulwahed Awad Almutairi Shailendra.mishra Mohammed AlShehri Department of Information Technology College of Computer and Information SciencesMajmaah UniversityMajmaah11952Saudi Arabia Department of Computer Engineering College of Computer and Information SciencesMajmaah UniversityMajmaah11952Saudi Arabia

Web applications have become a widely accepted method to support the internet for the past *** they have been successfully installed in the business activities and there is a requirement of advanced functionalities,the configuration is growing and becoming more *** growing demand and complexity also make these web applications a preferred target for intruders on the *** with the support of security specialists,they remain highly problematic for the complexity of penetration and code reviewing *** requires considering different testing patterns in both codes reviewing and penetration *** a result,the number of hacked websites is increasing day by *** of these vulnerabilities also occur due to incorrect input validation and lack of result validation for lousy programming practices or coding *** scanners for web applications can detect a few vulnerabilities in a dynamic *** are quite easy to use;however,these often miss out on some of the unique critical vulnerabilities in a different and static *** these are time-consuming,they can find complex vulnerabilities and improve developer knowledge in coding and best *** scanners choose both dynamic and static approaches,and the developers can select them based on their requirements and *** research explores and provides details of SQL injection,operating system command injection,path traversal,and cross-site scripting vulnerabilities through dynamic and static *** also examines various security measures in web applications and selected five tools based on their features for scanning PHP,and JAVA code focuses on SQL injection,cross-site scripting,Path Traversal,operating system ***,this research discusses the approach of a cyber-security tester or a security developer finding out vulnerabilities through dynamic and static approaches using manual and automated web vulnerability scanners.

关键词： SQL injection attack cross-site scripting attack command injection attack path traversal attack

Effect of bioflocculants on the coagulation activity of alum for removal of trihalomethane precursors from low turbid water

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Journal of Environmental Sciences 2018年第8期30卷 1-10页

作者： Tanwi Priya Abhrajyoti Tarafdar Bramha Gupta Brijesh Kumar mishra Department of Environmental Science and Engineering Indian Institute of Technology (Indian School of Mines)

Reactivity of chlorine towards hydrophobic groups present in natural organic matter（NOM）provokes the formation of carcinogenic disinfection byproducts such as trihalomethanes in chlorinated water. The present study aimed to investigate the variations in coagulant activity of alum using two different bioflocculants（coagulant aid） namely, Moringa oleifera and Cyamopsis tetragonoloba for the removal of hydrophobic fractions of NOM and subsequent chlorine consumption by treated water. Effect of dual coagulants on trihalomethane surrogate parameters such as total organic carbon, dissolved organic carbon, UV absorbing materials and prominent hydrophobic species such as phenolic groups along with aromatic chromophores, polyhydroxy aromatic moiety have also been studied. The concept of differential spectroscopy and absorbance slope index has been employed to understand the combined effects of alum-bioflocculants on the reactivity of NOM with chlorine. Our result shows that the combination of alum and C. tetragonoloba is more efficient for reducing trihalomethane surrogates from chlorinated water as compared to M. oleifera. C. tetragonoloba elicited synchronized effects of sweep coagulation and particle bridging-adsorption which eventually facilitated efficient removal of hydrophobic fractions of NOM. The variation in the mechanistic approach of bioflocculants was due to the presence of cationic charge on M. oleifera and adhesive property of C. tetragonoloba.

关键词： Natural organic matter Bioflocculants Disinfection byproducts Trihalomethanes Differential spectroscopy Absorbance slope index

Effects of silver nanoparticle size,concentration and coating on soil quality as indicated by arylsulfatase and sulfite oxidase activities

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Pedosphere 2022年第5期32卷 733-743页

作者： Yutong XUE Prashank mishra Frieda EIVAZI Zahra AFRASIABI Environmental Studies Concentration Soka University of AmericaAliso Viejo CA 92656(USA) Nicholas School of the Environment Duke UniversityDurham NC 27707(USA) Department of Agriculture and Environmental Sciences Lincoln UniversityJeferson City MO 6510l(USA)

Recently, the nanotechnology industry has seen a growing interest in integrating silver nanoparticles(AgNPs) into agricultural products, which increases soil exposure to these particles. This demands an investigation into the effect of AgNPs on soil health. Changes in soil enzyme activities upon exposure to AgNPs can serve as early indicators of any adverse effects that these particles may have on soil quality. This study aimed to determine the effects of AgNP size, concentration, coating, and exposure time on the activities of two sulfur cycle enzymes, arylsulfatase and sulfite oxidase. To investigate the sensitivity of soil enzyme activity to AgNP contamination, silt loam soil samples were treated with 30, 80, and 200 nm-sized AgNPs coated with citrate, lipoic acid,and polyvinylpyrrolidone at 1, 10, and 100 mg Ag kgsoil, with the changes in enzyme activities monitored at 3 h, 3 d, and 30 d after treatment. For comparison, the effects of silver(Ag) ions on the enzyme activities were studied under similar treatment conditions. For most of the concentrations tested, the inhibitory effects of AgNPs on different enzymes differed, with a much stronger effect on sulfite oxidase activity than on arylsulfatase activity. The AgNP concentration and exposure time played much important roles than coating type and particle size in the effects of AgNPs on soil enzyme activities.

关键词： citrate lipoic acid polyvinylpyrrolidone soil health sulfur cycle enzyme

Effect of orientation on the drag of a cone settling in a Bingham plastic fluid

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Particuology 2019年第2期17卷 157-170页

作者： Pragya.mishra A.K. Tiwari R.P. Chhabra Department of Chemical Engineering. Indian Institute of Technology Kanpur 208016 India M2NeT Laboratory Wilfrid Laurier University 75 University Avenue West Waterloo ON N2L 3C5 Canada

Effects of the orientation and apex angle on the settling velocity of conical particles in Bingham plas-tic fluids are numerically investigated over a Reynolds number range of 1 ≤Re ≤100, Bingham number range of 0 ≤ Bn ≤ 100, and cone angle range of 20 ≤α≤ 150°. Governing equations (of continuity and momentum) are solved numerically using the finite element method to obtain velocity and pressure fields that are postprocessed to obtain values of the drag ***, the effect of cone ori-entation on the flow field is visualized and explored in terms of streamline contours and the morphology of yielded/uny ielded regions. Finally, the obtai ned values of drag are correlated via a simple predictive expression in terms of the modified Reynolds number. The effect of the cone angle on drag is found to be moderate because the drag force acting on the lateral surface is a small fraction of the overall drag.

关键词： Bingham number Reynolds number Yielded/unyielded regions Drag