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Status and prospects for symmetric organic redox flow batteries

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Journal of Energy chemistry 2025年第1期100卷 125-143页

作者： Md Al raihan c.Adam Dyker Department of chemistry University of New Brunswick

As environmental concerns from fossil fuel consumption intensify, large-scale energy storage becomes imperative for the integration of renewable sources like wind, hydro, and solar with the electrical *** flow batteries, particularly those employing organic molecules, are positioned as a key technology for this purpose. This review explores the growing field of symmetric organic redox flow batteries(OrFBs) within this context. Unlike traditional asymmetric designs based on unique active materials for each electrode, symmetric OrFBs involve a single bipolar species for both electrodes. This review highlights the benefits of a symmetric design, and categorizes five distinct classes of organic bipolar molecules used in both aqueous and non-aqueous solvents. By providing a comprehensive overview of their cell cycling and performance characteristics, the strengths and weaknesses of the diverse categories of bipolar molecules are highlighted for both solvent systems, as are opportunities for future development. This should guide new research directions and advance the development of practical symmetric OrFBs.

关键词： redox flow battery Symmetric battery Organic battery Aqueous electrolyte Non-aqueous electrolyte

US children with special health care needs and ethnic discrimination: results from multivariate modeling

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World Journal of Pediatrics 2019年第2期15卷 182-189页

作者： Guillermo montes St.John Fisher college Alesi 106C3690 East Ave.RochesterNY 14618USA children's Institute Inc. RochesterNYUSA

Background To determine the prevalence of parent-reported ethnic/racial discrimination,and to determine if children with special health care needs are more likely to experience ethnic discrimination than other children who have similar family income,age,sex,race,parental education and Hispanic *** Using the National Survey of children's Health 2011-2012 (n =95,677),ethnic discrimination was measured by two questions that asked 'was child ever treated or judged unfairly because of his/her race or ethnic group?' and if so,how often it occurred in the last 12 months prior to the *** An estimated 3 million US children aged 0-17 years have experienced parent-reported ethnic discrimination (1.4% White,9.1% Black,9.9% other race,4.7% Hispanic).The likelihood to experience ethnic discrimination is much higher for Black and other race children,compared to White *** with special health care needs were two times more likely to experience ethnic discrimination frequently in the 12 months prior to the survey than comparable children in terms of age,sex,race,family income,parental education,and social *** family income did not prevent the exposure to ethnic discrimination but was associated with fewer *** Theoretical frameworks,such as social determinants of health,must account for the bidirectional nature of the relationship between health and ethnic *** care must assess if ethnic discrimination has occurred and whether trauma-informed approaches are needed.

关键词： children with special health care needs Ethnic discrimination United States

Influence of B4c and ZrB2 reinforcements on microstructural,mechanical and wear behaviour of AA 2014 aluminium matrix hybrid composites

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Defence Technology（防务技术） 2024年第10期40卷 242-254页

作者： ramesh Babu r rajendran c Saiyathibrahim A rajkumar Velu Department of Mechanical Engineering Karpagam Institute of TechnologyCoimbatore 641105India Department of Mechanical Engineering Sri Krishna College of Engineering and TechnologyCoimbatore 641008India Department of Mechanical Engineering Indian Institute of Technology JammuJammu and Kashmir 181221India

considering their affordability and high strength-to-weight ratio,lightweight aluminium alloys are the subject of intensive research aimed at improving their properties for use in the aerospace *** research effort aims to develop novel hybrid composites based on AA 2014 alloy through the use of liquid metallurgy stir casting to reinforce dual ceramic particles of Zirconium Diboride(ZrB_(2))and Boron carbide(B4c).The weight percentage(wt%)of ZrB_(2) was varied(0,5,10,and 15),while a constant 5 wt%of B4c was maintained during this *** as-cast samples have been assessed using an Optical Microscope(OM)and a Scanning Electron Microscope(SEM)with Energy Dispersive Spectroscopy(EDS).The properties such as hardness,tensile strength,and wear characteristics of stir cast specimens were assessed to examine the impact of varying weight percentages of reinforcements in AA 2014 *** particular,dry sliding wear behaviour was evaluated considering varied loads using a pin-on-disc *** the weight%of ZrB_(2) grew and B4c was incorporated,hybrid composites showed higher hardness,tensile strength,and wear ***,the incorporation of a cumulative reinforcement consisting of 15 wt%ZrB_(2) and 5 wt%B4c resulted in a significant 31.86%increase in hardness and a 44.1%increase in tensile strength compared to AA 2014 *** addition,it has been detected that wear resistance of hybrid composite pin(containing 20 wt%cumulative reinforcement)is higher than that of other stir cast wear test pins during the whole range of applied *** surfaces of tensile specimens showed ductile fracture in the AA 2014 matrix and mixed mode for hybrid *** surfaces obtained employing higher applied load indicated abrasive wear with little plastic deformation for hybrid composites and dominant adhesive wear for matrix ***,the superior mechanical and tribological performance of hybrid composites can be attributed to dual reinforcement pa

关键词： AA 2014 alloy Stir casting Hybrid composite Hardness Tensile strength Specific wear rate

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Acquired sensorineural hearing loss,oxidative stress,and microrNAs

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Neural regeneration research 2025年第9期20卷 2513-2519页

作者： Desmond A.Nunez ru c.Guo Division of Otolaryngology–Head&Neck Surgery Department of SurgeryFaculty of MedicineThe University of British ColumbiaVancouverBCCanada Division of Otolaryngology–Head&Neck Surgery Gordon&Leslie Diamond Health Care CentreVancouver General HospitalVancouverBCCanada Faculty of Medicine–The University of British columbia VancouverBCCanada

Hearing loss is the third leading cause of human ***-related hearing loss,one type of acquired sensorineural hearing loss,is largely responsible for this escalating global health ***-induced,ototoxic,and idiopathic sudden sensorineural are other less common types of acquired hearing *** etiology of these conditions is complex and multi-fa ctorial involving an interplay of genetic and environmental *** stress has recently been proposed as a likely linking cause in most types of acquired sensorineural hearing *** non-coding rNA sequences known as microrNAs(mirNAs)have increasingly been shown to play a role in cellular hypoxia and oxidative stress responses including promoting an apoptotic *** hair cell death is a central histopathological finding in sensorineural hearing *** these cells do not regenerate in humans,it underlies the irreversibility of human age-related hearing *** EMBASE,Ovid MEDLINE,Web of Science core collection,and *** databases over the period August 1,2018 to July 31,2023 were searched with"hearing loss,""hypoxamirs,""hypoxia,""microrNAs,""ischemia,"and"oxidative stress"text words for English language primary study publications or registered clinical *** red clinical trials known to the senior author we re also assessed.A total of 222studies were thus *** excluding duplicates,editorials,retra ctions,secondary research studies,and non-English language articles,39 primary studies and clinical trials underwent full-text *** resulted in 11 animal,in vitro,and/or human subject journal articles and 8 registered clinical trial database entries which form the basis of this narrative *** mir-34a and mir-29b levels increase with age in *** mirNAs were demonstrated in human neuroblastoma and murine cochlear cell lines to target Sirtuin 1/peroxisome proliferato r-activated receptor gamma coactivator-1-alpha(SIrT1/P Gc-1α),SIrT

关键词： hearing loss hypoxia microrNAs oxidative stress sensorineural

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Serological surveillance for SArS-coV-2 antibodies among students,faculty and staff within a large university system during the pandemic

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World Journal of Virology 2025年第1期14卷 99-107页

作者： Marcos G Pinheiro Gabriela G O Alves Maria Eduarda r conde Sofia L costa regina c S Sant’Anna Isa M F Antunes Mônica c carneiro Fabio S ronzei Julia c Scaffo Felipe r Pinheiro Lialyz S Andre Helvecio c Povoa Valéria T Baltar Fabíola Giordani Eduarda S Hemerly Gisele c Alexandre Karla c de Paula Márcio Watanabe Antonio claudio L da Nóbrega Jackeline christiane P Lobato Fabio Aguiar-Alves Laboratory of Molecular Epidemiology and Biotechnology Rodolpho Albino University LaboratoryFluminense Federal UniversityNiterói 24241000Rio de JaneiroBrazil Estácio de SáUniversity Nova Friburgo 28611135Rio de JaneiroBrazil Pathology Program Medicine schoolFluminense Federal UniversityNiterói 24070090Rio de JaneiroBrazil Department of Pharmaceutical Sciences Lloyd L.Gregory School of PharmacyPalm Beach Atlantic UniversityWest Palm BeachFL 33401United States Health Institute of Nova Friburgo Fluminense Federal UniversityNova Friburgo 28613001Rio de JaneiroBrazil Department of Epidemiology and Biostatistics Institute of Collective Health(ISC)Fluminense Federal UniversityNiterói 24033900Rio de JaneiroBrazil Institute of Physical Education Fluminense Federal UniversityNiterói 24020005Rio de JaneiroBrazil Department of Statistics Fluminense Federal UniversityNiterói 24210200Rio de JaneiroBrazil Department of Physiology and Pharmacology Fluminense Federal UniversityNiterói 24210130Rio de JaneiroBrazil

BAcKGrOUND At the end of December 2019,the world faced severe acute respiratory syndrome-coronavirus 2(SArS-coV-2),which led to the outbreak of coronavirus disease 2019(cOVID-19),associated with respiratory *** virus has shown significant challenges,especially for senior citizens,patients with other underlying illnesses,or those with a sedentary *** tests conducted early on have helped identify how the virus is transmitted and how to curb its *** study hypothesis was that the rapid serological test for SArS-coV-2 antibodies could indicate the immunoreactive profile during the cOVID-19 pandemic in a university *** To conduct active surveillance for serological expression of anti-SArS-coV-2 antibodies in individuals within a university setting during the cOVID-19 *** This sectional study by convenience sampling was conducted in a large university in Niteroi-rJ,Brazil,from March 2021 to July *** study population consisted of students,faculty,and administrative staff employed by the university.A total of 3433 faculty members,60703 students,and 3812 administrative staff were invited to *** were gathered through rapid serological tests to detect immunoglobulin(Ig)M and IgG against ***χ²or Fisher's exact test was used to conduct statistical analysis.A 0.20 significance level was adopted for variable selection in a multiple logistic regression model to evaluate *** A total of 1648 individuals were enrolled in the *** proportion of cOVID-19 positivity was 164/1648(9.8%).The adjusted logistic model indicate a positive association between the expression of IgM or IgG and age[odds ratio(Or)=1.16,95%cI:1.02-1.31](Pcontact with a cOVID-19-positive case(Or=3.49,95%cI:2.34-5.37)(Preceived the cOVID-19 vaccine(Or=2.33,95%cI:1.61-3.35)(Pcial isolation(Or=0.59,95%cI:0.41-0.84)(P<0.004).The likelihood of sho

关键词： Serological surveillance SArS-coV-2 antibodies cOVID-19 Serological rapid test risk factors for cOVID-19

Experimental and computational study of smoke dynamics from multiple fire sources inside a large-volume building

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Building Simulation 2021年第4期14卷 1147-1161页

作者： Gabriele Vigne Wojciech Węgrzyński Alexis cantizano Pablo Ayala Guillermo rein cándido Gutiérrez-montes Fluid Dynamics Division of the Department of Mining and Mechanical Engineering Universidad de JaénJaénSpain Institute for research in Technology ICAIUniversidad Pontificia ComillasMadridSpain Building research Institute(ITB) WarsawPoland Imperial college London LondonUK JVVA Fire&risk MadridSpain

Fire in large-volume buildings poses separate and distinct challenges from compartmented *** particular,the risk it poses on life safety is mostly due to the smoke it produces,its effects on the evacuation process,and how it can affect the firefighters when they approach the building to fight the fire and rescue the *** is why smoke control in large-volume enclosures is of utter importance for life safety,property protection and business *** research presents an experimental and numerical study of the smoke dynamics from four fire sources(combined heat release rate of 5.2 MW)with different ignition times and under transient ventilation conditions,inside a 20 m high cubic *** measurements in the plume and close to the walls have been recorded using 59 *** data was used in the determination of the smoke layer interface height,with the least-square and the N-Percent *** show that significantly worse conditions are induced by multiple sources than those in a single fire of equal *** results have been obtained using the computational fluid dynamics code FDS(Fire Dynamics Simulator,v6.7.1).The comparison shows that in the far field the temperature predictions are a.c.r.te inside the smoke layer(10 m and 15 m)with discrepancies lower than 10%,whereas higher significant discrepancies were observed at the smoke layer interface,i.e.5 m high,with discrepancies up to 20%.Furthermore,a grid analysis has been performed showing that grid resolutions,D*/δ,based on the global Hrr of the fire might be sufficient to predict the fire induced conditions far from the *** analysis confirmed the applicability of FDS to the assessment of the smoke dynamics under complex fire conditions away from ***,the present work shows the importance of considering fires with multiple sources due to the faster smoke production compared with single fires.

关键词： experiments simulation fire buildings FDS cFD

A comprehensive investigation on nonlinear vibration and bending characteristics of bio-inspired helicoidal laminated composite structures

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Applied Mathematics and Mechanics(English Edition) 2025年第1期46卷 81-100页

作者： S.SAUrABH r.KIrAN D.SINGH r.VAISH V.S.cHAUHAN School of Mechanical and Materials Engineering Indian Institute of Technology Mandi

Bio-inspired helicoidal composite laminates, inspired by the intricate helical structures found in nature, present a promising frontier for enhancing the mechanical properties of structural designs. Hence, this study provides a comprehensive investigation into the nonlinear free vibration and nonlinear bending behavior of bio-inspired composite plates. The inverse hyperbolic shear deformation theory(IHSDT) of plates is employed to characterize the displacement field, with the incorporation of Green-Lagrange nonlinearity. The problem is modeled using the c0finite element method(FEM), and an in-house code is developed in the MATLAB environment to solve it numerically. Various helicoidal layup configurations including helicoidal recursive(Hr), helicoidal exponential(HE), helicoidal semi-circular(HS), linear helicoidal(LH), and Fibonacci helicoidal(FH)with different layup sequences and quasi-isotropic configurations are studied. The model is validated, and parametric studies are conducted. These studies investigate the effects of layup configurations, side-to-thickness ratio, modulus ratios, boundary conditions, and loading conditions at different load amplitudes on the nonlinear vibration and nonlinear bending behaviors of bio-inspired composite plates. The results show that the laminate sequence exerts a substantial impact on both nonlinear natural frequencies and nonlinear bending behaviors. Moreover, this influence varies across different side-to-thickness ratios and boundary conditions of the bio-inspired composite plate.

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Multiple sclerosis is at a checkpoint: advancing the program

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Neural regeneration research 2025年第3期20卷 811-812页

作者： Brandon c.Smith Jessica L.Williams Department of Neurosciences Lerner Research InstituteCleveland ClinicClevelandOHUSA Department of Biological Geologicaland Environmental SciencesCleveland State UniversityClevelandOHUSA

Multiple sclerosis(MS) is a.c.r.nic inflammatory and demyelinating disease of the central nervous system(cNS). Patients with MS experience sensory and motor function loss due to myelin and/or axon damage perpetuated b... 详细信息

关键词： Hauser sclerosis damage

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rare Top Decay <i>t</i>→<i>cγ</i>in General THDM-III

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Journal of Quantum Information Science 2017年第2期7卷 57-66页

作者： r. Gaitán-Lozano J. H. montes de Oca r. Martinez Departamento de Física FES-Cuautitlan UNAM Estado de México México Departamento de Física Universidad Nacional de Colombia Bogotá D.C. Colombia

We study the decay t →cγ?with flavor-changing neutral interactions in scalar sector of the type III Two Higgs Doublet Model (THDM-III) with mixing between neutral scalar fields as a result of considering the most general scalar potential. The branching ratio of the decay Br (t?→cγ) is calculated as function of the mixing parameters and masses of the neutral scalar fields. We obtain a Br (t?→cγ) of the order of 10−8 for the considered regions of the mixing parameters. Finally, one upper bound for the possible events is estimated to be n=18 by assuming an expected luminosity of the order of 300 fb−1.

关键词： Two Higgs Doublet Models rare Top Decays