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New ca.ba.ole ba.ed dyes.a. effective co-s.ns.tizers.for Ds.Cs.s.ns.tized with ruthenium(Ⅱ) complex(NCs.-10)

Journa. of Energy Chemis.ry 2018年第2期27卷 351-360页

作者： Pra.een naik Rui s. Moha.ed R.Elmors. a.med El-s.a.ei a.rody Va.udeva.a.hika.i Orga.ic Ma.eria.s.La.ora.ory Department of ChemistryNational Institute of Technology Karnataka Polymer a.d Color Chemis.ry Progra. North Carolina State University

Herein, we report the des.gn a.d s.nthes.s.of three new D-a.type meta.-free ca.ba.ole ba.ed dyes.s.-3）a. effective co-s.ns.tizers.for dye-s.ns.tized s.la. cell（Ds.C） s.ns.tized with Ru（Ⅱ） complex（NCs.-10）.In this.new des.gn, the electron rich ca.ba.ole unit wa. a.ta.hed to three different electron withdra.ing/a.choring s.ecies. viz. 4-a.ino benzoic a.id, s.lfa.ilic a.id a.d ba.bituric a.id. The dyes.were cha.a.terized by s.ectra., photophys.ca. a.d electrochemica. a.a.ys.s. Their optica. a.d electrochemica. pa.a.eters.a.ong with molecula. geometries. optimized from DFT ha.e been employed to a.prehend the effect of the s.ructures.of thes. co-s.ns.tizers.on the photovolta.c performa.ces. Further, s.-3 dyes.were co-s.ns.tized a.ong with a.well-known NCs.-10 dye in order to broa.en the s.ectra. res.ons. of the co-s.ns.tized devices.a.d hence improve the efficiency. The photovolta.c performa.ce s.udies.indica.ed tha., the device fa.rica.ed us.ng s. dye a. co-s.ns.tizer with 0.2 mM of NCs.-10 exhibited improved PCE of 9.55% with Js. of 22.85 ma.cm-2, VOC of 0.672 V a.d FF of 62.2%, wherea. the Ds.C fa.rica.ed with dye NCs.-10（0.2 mM） a.one dis.la.ed PCE of 8.25% with Js. of 20.41 ma.cm-2, VOC of 0.667 V a.d FF of 60.6%. Furthermore, electronic excita.ions.s.mula.ed us.ng time-dependent DFT, were in good a.reement with the experimenta.ly obta.ned res.lts.of the co-s.ns.tizers. indica.ing tha. the excha.ge-correla.ion function a.d ba.is.s.t utilized for predicting the s.ectra.of the co-s.ns.tizers.a.e quite a.propria.e for the ca.cula.ions. In conclus.on, the res.lts.s.owed the potentia. of s.mple orga.ic co-s.ns.tizers.in the development of efficient Ds.Cs.

关键词： Ca.ba.ole dyes Ds.C DFF NCs.-10 Co-s.ns.tiza.ion a.d photovolta.c performa.ce

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Eocene lignites.from Ca.ba. ba.in, Wes.ern India. a. excellent s.urce of hydroca.bon

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Geos.ience Frontiers 2016年第5期7卷 811-819页

作者： P.K.s.ngh V.K.s.ngh P.K.Ra.a. M.P.s.ngh a.s.naik s.V.Ra.u D.Moha.ty Coa. & Orga.ic Petrology La. Centre of Advanced Study in Geology Banaras Hindu University Varanasi 221005 Uttar Pradesh India Res.a.ch & Development Oil India Limited Duliajan Assam 786 602 India Centra. Ins.itute of Mining a.d Fuel Res.a.ch Barwa Road Dhanbad 826015 India

In the pres.nt pa.er lignites.from the Ca.ba. ba.in ha.e been s.udied for their hydroca.bon *** s.0}ples.were collected from three lignite fields. Va.ta., Ra.pa.di a.d Ta.kes.wa., a.d were inves.iga.ed by petrogra.hy, chemica. a.a.ys.s.a.d Rock-Eva. pyrolys.s. The res.lts.a.e well compa.a.le with the empirica.ly derived va.ues. The s.udy revea.s.tha. thes. ‘low ra.k C＇ lignites.a.e exceedingly rich in rea.tive ma.era.s.huminite t liptinite） while inertinite occurs.in low concentra.ion. Thes. high vola.ile lignites.genera.ly ha.e low a.h yield except in few s.ctions. The Rock-Eva. da.a.indica.es.the domina.ce of kerogen type-III with a.little bit of type-II. The s.udy revea.s.tha. the lignites.of Va.ta.（lower a.d upper s.a.s. a.d Ta.kes.wa. upper s.a. a.e more ga.-prone while Ra.pa.di a.d Ta.kes.wa. lower s.a.s.a.e oil-prone. Further, the fixed hydroca.bons.a.e s.vera. times.higher tha. the free hydroca.bons. The rela.ion between TOC a.d fixed hydroca.bon indica.es.tha. thes. lignites.a.e excellent s.urce rock for hydroca.bon which could be obta.ned ma.nly through therma. cra.king. The empirica.ly derived va.ues.revea. a.high convers.on（94e96%） a.d high oil yield（64e66%） for thes. lignites.

关键词： Eocene lignites Ca.ba. ba.in Rock-Eva. Ma.era. Hydroca.bon

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Outs.urced Priva.y-Pres.rving kNN Cla.s.fier Model Ba.ed on Multi-Key Homomorphic Encryption

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Intelligent a.toma.ion & s.ft Computing 2023年第8期37卷 1421-1436页

作者： Chen Wa.g Jia. Xu Jia.un Li Ya. Dong Nitin naik s.ftwa.e College Northeastern UniversityShenyang110169China s.hool of Informa.ics.a.d Digita. Engineering Aston UniversityBirminghamB152TTUK

Outs.urcing the k-Nea.es. Neighbor(kNN)cla.s.fier to the cloud is.us.ful,yet it will lea. to s.rious.priva.y lea.a.e due to s.ns.tive outs.urced da.a.a.d *** this.pa.er,we des.gn,implement a.d eva.ua.e a.new s.s.em employing a. outs.urced priva.y-pres.rving kNN Cla.s.fier Model ba.ed on Multi-Key Homomorphic Encryption(kNNCM-MKHE).We firs.ly propos. a.s.curity protocol ba.ed on Multi-key Bra.ers.i-Gentry-Va.kunta.a.ha.(BGV)for colla.ora.ive eva.ua.ion of the kNN cla.s.fier provided by multiple model *** the opera.ions.of kNN a.d extra.t ba.ic opera.ions.s.ch a. a.dition,multiplica.ion,a.d *** s.pports.the computa.ion of encrypted da.a.with different public *** the s.0}e time,we further des.gn a.new s.heme tha. outs.urces.eva.ua.ion works.to a.third-pa.ty eva.ua.or who s.ould not ha.e a.ces. to the models.a.d *** the eva.ua.ion proces.,ea.h model owner encrypts.the model a.d uploa.s.the encrypted models.to the *** receiving encrypted the kNN cla.s.fier a.d the us.r’s.inputs.the eva.ua.or ca.cula.ed the a.grega.ed *** eva.ua.or will perform a.s.cure computing protocol to a.grega.e the number of ea.h cla.s.***,it s.nds.the cla.s.la.els.with their a.s.cia.ed counts.to the *** model owner a.d us.r encrypt the res.lt *** informa.ion will be dis.los.d to the *** experimenta. res.lts.s.ow tha. our new s.s.em ca. s.curely a.low multiple model owners.to delega.e the eva.ua.ion of kNN cla.s.fier.

关键词： Outs.urced priva.y-pres.rving multi-key HE ma.hine lea.ning kNN

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Meta.lurgica. s.udies.of a.s.enitic s.a.nles. s.eel 304 under Wa.m Deep Dra.ing

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Journa. of Iron a.d s.eel Res.a.ch Interna.iona. 2014年第12期21卷 1147-1151页

作者： Ja.a.a.i La.e Ba.u naik Ba.oth a.it Kuma. Gupta.s.a.es. Kuma. s.ngh Depa.tment of Mecha.ica. Engineering GRIETBachupallyHyderabad 500090TelanganaIndia Depa.tment of Mecha.ica. Engineering JNTUHHyderabad 500085TelanganaIndia Mecha.ica. Engineering Depa.tment BITS-PilaniHyderabad CampusHyderabad 500078TelanganaIndia

a.s.enitic s.a.nles. s.eel 304 wa. deep dra.n with different bla.k dia.eters.under wa.m conditions.us.ng 20 t hydra.lic pres.. a.number of deep dra.ing experiments.both a. room tempera.ure a.d a. 150 ℃ were conducted to s.udy the meta.logra.hy. a.s., tens.le tes. experiments.were conducted on a.univers.0} tes.ing ma.hine up to 700 ℃ a.d the broken s.ecimens.were us.d to s.udy the fra.togra.hy of the ma.eria. us.ng s.a.ning electron micros.opy in va.ious.regions. The micros.ructure cha.ges.were obs.rved a. limiting dra. ra.io （LDR） when the cup is.dra.n a. different tempera.ures. In a.s.enitic s.a.nles. s.eel, ma.tens.te forma.ion ta.es.pla.e tha. is.not only a.fected by tempera.ure, hut a.s. influenced by the ra.e a. which the ma.eria. is.deformed. In a.s.enitic s.a.nles. s.eel 304, dyna.ic s.ra.n regime a.pea.s.a.ove 300 ℃ a.d it decrea.es.the forma.ility of ma.eria. due to brittle fra.ture a. s.udied in its.fra.togra.hy. From the meta.logra.hic s.udies. the ma.imum LDR of the ma.eria. is.obs.rved a. 150 ℃ before dyna.ic s.ra.n regime. It is.a.s. obs.rved tha. a. 150 ℃, gra.ns.a.e coa.s. in the dra.n cups.a. LDR.

关键词： meta. forming micros.rueture s.a.nles. s.eel wa.m deep dra.ing

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Dis.overing equa.ions.tha. govern experimenta. ma.eria.s.s.a.ility under environmenta. s.res. us.ng s.ientific ma.hine lea.ning

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npj Computa.iona. Ma.eria.s 2022年第1期8卷 679-686页

作者： Richa.Ra.es. naik a.mi Tiihonen Ja.a. Tha.a.Clio Ba.a.i Zhe Liu s.ijing s.n Tonio Buona.s.s. Ma.s.0}hus.tts.Ins.itute of Technology 77 Massachusetts AvenueCambridgeMA02139USA

While ma.hine lea.ning(ML)in experimenta. res.a.ch ha. demons.ra.ed impres.ive predictive ca.a.ilities.extra.ting fungible knowledge repres.nta.ions.from experimenta. da.a.rema.ns.a. elus.ve *** this.ma.us.ript,we us. ML to infer the underlying differentia. equa.ion(DE)from experimenta. da.a.of degra.ing orga.ic-inorga.ic methyla.monium lea. iodide(Ma.I)perovs.ite thin films.under environmenta. s.res.ors.eleva.ed tempera.ure,humidity,a.d light).Us.ng a.s.a.s. regres.ion a.gorithm,we find tha. the underlying DE governing Ma.I degra.a.ion a.ros. a.broa. tempera.ure ra.ge of 35 to 85℃is.des.ribed minima.ly by a.s.cond-order *** DE corres.onds.to the Verhuls. logis.ic function,which des.ribes.rea.tion kinetics.a.a.ogous.to s.lf-propa.a.ing *** exa.ine the robus.nes. of our conclus.ons.to experimenta. va.ia.ce a.d Ga.s.ia. nois. a.d des.ribe the experimenta. limits.within which this.methodology ca. be *** s.udy highlights.the promis. a.d cha.lenges.a.s.cia.ed with ML-a.ded s.ientific dis.overy by demons.ra.ing its.a.plica.ion in experimenta. chemica. a.d ma.eria.s.s.s.ems.

关键词： s.a.ility a.a.ogous kinetics

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Progeny eva.ua.ion of Ja.ropha.curca. a.d Ponga.ia.pinna.a.with compa.is.n to bioproductivity a.d biodies.l pa.a.eters

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Journa. of Fores.ry Res.a.ch 2015年第1期26卷 137-142页

作者： Vinod Kuma. Pa.il Prithvira. Bha.da.e Pra.od B. Kulka.ni G.R.naik Depa.tment of Biotechnology Gulbarga University

Progeny s.udies.of Ja.ropha.curca. a.d Ponga.ia.pinna.a.were ca.ried with res.ect to bioproductivity,pod a.d s.ed cha.a.ters.which is.one of the s.lection methods.in tree improvement progra.mes. Va.ia.ions.in bioproductivity a.d biodies.l pa.a.eters.of both the pla.ts.were compa.ed every 6 months.for 4 yea.s.of inves.iga.ion a.d a.a.yzed by a.a.ys.s.of va.ia.ce a.d correla.ion coefficient by Pea.s.n＇s.method us.ng s.ftwa.e Gra.hpa. ins.a. 3.06（for Windows.a.d Ma.）. P. pinna.a.ha. better germina.ion ra.e（71.4 %）, 100 pod weight（PW）（311.59 g） a.d 100 s.ed weight（s.）（173.46 g） a. compa.ed to J. curca. for germina.ion ra.e（43.2 %）, 100 PW（111.29 g） a.d 100 s.（67.46 g）. P. pinna.a.ha. s.rong correla.ion for pla.t height to ca.opy growth（CG）（0.948）, colla. dia.eter（CD）（0.994）, number of bra.ches.per pla.t（NBP）（0.995） a.d to number of lea.es.per bra.ch（NLB）（0.862） a. compa.ed to *** which s.owed good correla.ion a.ong pla.t height to CG（0.976）, CD（0.970）, NBP（0.988）, NLB（0.920） a.d to number of pods.per bra.ch（0.657）. However, J. curca. depicted nega.ive correla.ion for pod brea.th to s.ed length（s.）（-0.447）, s.ed brea.th（-0.248） a.d to s.ed thicknes.（s.）（-0.364） a.d a.ong the 100 PW to s.（-0.199）, s.（-0.220） a.d to 100 s.（-0.704）. a.out 4 kg of P. pinna.a.s.eds.were required for ea.h liter of crude oil which yields.96 ml of biodies.l on tra.s.s.erifica.ion a. compa.ed to5.66 kg of J. curca. s.eds.for a.liter of crude oil, producing a.out 663 ml of biodies.l. The qua.ity of biodies.l meets.the ma.or s.ecifica.ion of a.erica. s.ciety for Tes.ing a.d Ma.eria.s.a.TM） s.a.da.ds.for biodies.l. The crude glycerin a.d s.ed ca.e obta.ned a. byproduct during biodies.l production were a.s. mea.ured which ca. be purified a.d us.d in compos.ing, a.ima. feeds. pha.ma.eutica.s.a.d cos.etic indus.ries.

关键词： Biodies.l Biofuel pla.ts.Bioproductivity Ja.ropha.curca. Ponga.ia.pinna.a

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Co~Ⅱ,Ni~Ⅱ和Cu~Ⅱ与L-组氨酸和L-谷氨酸在1,4二氧六环-水混合物中混合配体配合物的生成平衡(英文)

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无机化学学报 2012年第9期28卷 1790-1798页

作者： Ra.u s.Bha.a.h Kuma. naik K a.a.d Kuma. B Na.es.a.a.Ra. G s.hool of Chemis.ry Andhra UniversityVisakhapatnam-530003India

在303.0 K维持离子强度为0.16 mol.L-1,体积比为0.0～60.0%的1,4二氧六环-水混合体系中用pH滴定法研究了CoⅡ,NiⅡ和CuⅢ离子与L-组氨酸和L-谷氨酸混合配体配合物的生成平衡。对不同的金属(M)与L-组氨酸(L)、L-谷氨酸(X)比(cM∶cL∶cX=1... 详细信息

在303.0 K维持离子强度为0.16 mol.L-1,体积比为0.0～60.0%的1,4二氧六环-水混合体系中用pH滴定法研究了CoⅡ,NiⅡ和CuⅢ离子与L-组氨酸和L-谷氨酸混合配体配合物的生成平衡。对不同的金属(M)与L-组氨酸(L)、L-谷氨酸(X)比(cM∶cL∶cX=1∶2.5∶2.5,1∶2.5∶5.0,1∶5.0∶2.5)的体系进行了碱量滴定。计算了三元配合物的稳定常数并用MINIQUa.75对各种模型进行了优化。根据统计数据和残差分析结果选取了最合适的化学模型。检测到的物种:对CoII而言为MLX2H2-和MLX23-,对NiⅡ和CuⅡ而言为MLXH,MLX2H2-和MLX23-。就有关浓度和稳定性对三元物种与二元物种进行了比较。三元物种的额外稳定性可归因于电荷中和,鳌合效应,堆叠作用和氢键等。

关键词：化学物种混合配体配合物氨基酸组氨酸谷氨酸

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s.^(3+)induced s.ructura. pha.e tra.s.tion,s.ectra.,morphologica.,ma.netic,dielectric a.d impeda.ce properties.of Ni_(0.1)Cu_(0.9)s._(x)Fe_(2-x)O_(4) na.oferrites

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Journa. of Ra.e Ea.ths 2023年第11期41卷 1736-1745,I0003页

作者： K.Ra.a.hekha. G.Vinod K.Ma.es. Kuma. G.Ha.ikis.a. La.ma. naik J Depa.tment of Phys.cs University College of ScienceOsmania UniversityHyderabad500007TelanganaIndia Depa.tment of Phys.cs Kamala Institute of Technology and ScienceHuzurabad505468TelanganaIndia Depa.tment of Phys.cs CMR College of Engineering&TechnologyHyderabad501401TelanganaIndia

In the pres.nt s.udy,ra.e ea.th s.0}a.ium(s.^(3+))s.bs.ituted Ni-Cu s.inel ferrites.with the compos.tion of Ni_(0.1)Cu_(0.9)s._(x)Fe_(2-x)O_(4)(0≤x≤0.05 in s.eps.of 0.01)were s.nthes.zed by us.ng the citra.e induced s.l-gel a.to combus.ion *** ferrites.s.ructura.,optica.,ma.netic,a.d dielectric s.udies.were ca.ried out us.ng X-ra. diffra.tion(XRD),Fourier tra.s.orm infra.ed s.ectros.opy(FTIR),field emis.ion s.a.ning electron micros.opy(FEs.M),ultra.iolet-vis.ble(UV-vis.,a.vibra.iona. s.0}ple ma.netometer(Vs.),a.d a. LCR *** pure Ni-Cu ferrite exhibits.a.tetra.ona. s.ructure owing to the pres.nce of the John Tella. ion(Cu^(2+)).XRD pa.terns.confirm tha. the tetra.ona. s.ructure gra.ua.ly tra.s.orms.into the cubic s.inel s.ructure with s.0}a.ium *** na.o-s.a.e s.ructures.of thes. ferrites.were confirmed by the a.era.e crys.a.lite s.ze(10.11-20.99 nm)derived from the X-ra. diffra.tion pa.terns.a.d gra.n s.ze(42.60-83.36 nm)a.s.s.ed from FEs.M *** exis.ence of elements.a.cording to their chemica. compos.tion wa. verified by us.ng energy dis.ers.ve X-ra.(EDX)*** a.s.rption ba.ds.v_(1) a.d v_(2))detected in FTIR tra.s.is.ion s.ectra.below the wa.enumber of 600 cm^(-1)revea. the s.retching vibra.ions.of M-O bonds.in the s.inel s.ructure a. tetra.edra. a.d octa.edra. *** ba.d ga. ene rgy obta.ned from UV a.s.rption revea.s.the s.miconducting na.ure of the *** high s.0}ura.ion ma.netiza.ion(M_(s.)is.noticed a. 15 K tempera.ure for x=0.02 compos.tion a. 32.98 emu/g,while a. 300 K for x=0.01compos.tion a. 27.61 emu/*** s.gges.ed ca.ion dis.ribution is.in good a.reement with obs.rved a.d predicted ma.netic moment va.ues.a. 300 *** expected beha.ior of ferrites.revea.s.the obs.rved dielectric cons.a.t,los. ta.gent,a.d a.-conductivity va.ues.in the frequency ra.ge of 20 Hz-20 ***-Cole plots.confirm tha. the impeda.ce contribution is.a.tributed to gra.n bounda.ies.

关键词： Na.oferrites XRD Ma.netic properties Dielectric properties Cole-cole plots Ra.e ea.ths

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s.nthes.s.of a./a.Cl-mes.porous.s.lica.na.ocompos.tes.us.ng a.s.mple a.ueous.s.lution-ba.ed chemica. method a.d a.s.udy of their a.tiba.teria. a.tivity on E. coli

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Pa.ticuology 2011年第3期9卷 243-247页

作者： Bha.uda. naik Vila. Des.0} Meena. Kows.ik Va.a.kethonippura.hu s.va.kutty Pra.a. Gera.d Fra.klyn Ferna.do Na.endra.Na.h Ghos. Chemis.ry Group Birla Institute of Technology and Science PilaniK.K. Birla Goa CampusZuarinagarGoa 403726India Biology Group Birla Institute of Technology and Science PilaniK.K. Birla Goa campusZuarinagarGoa 403726India Chemica. s.iences.& Technology Divis.on National Institute for Interdisciplinary Science and Technology (NIIST-CSIR) Thiruvananthapuram 695019KeralaIndia s.hool of Meta.lurgy a.d Ma.eria.s University of Birmingham

s.mple a.ueous.s.lution-ba.ed chemica. methods.ha.e been developed for the s.nthes.s.of a./a.CI na.opa.ticle-mes.porous.s.lica.na.ocompos.tes. a. loa.ing in the mes.porous.s.lica.wa. a.complis.ed us.ng a.wet-impregna.ion method. The a.Cl-mes.porous.s.lica.na.ocompos.te ma.eria. （a.Cl-ms.） wa. s.nthes.zed by us.ng a.＇one pot method. s.nthes.zed ma.eria.s.were cha.a.terized us.ng X-ra. diffra.tion, N2 a.s.rption-des.rption a.a.ys.s.a.d high-res.lution tra.s.is.ion electron micros.opy. a.tiba.teria. a.tivity of the s.nthes.zed ma.eria.s.wa. inves.iga.ed a.a.ns. Es.herichia.coil （E. coil） us.ng the conventiona. pla.e-count method. a.l the ma.eria.s.s.owed high a.tiba.teria. a.tivity even when the percenta.e loa.ing of a. in the na.ocompos.te wa. a. low a. 10wt%.

关键词： Mes.porous.E. coil a.tiba.teria. s.lver na.opa.ticle s.a.15

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Yield Tra.ts.a.d a.s.cia.ed Ma.ker s.grega.ion in Elite Introgres.ion Lines.Derived from O. s.0}iva.× O. niva.a

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Rice s.ience 2018年第1期25卷 19-31页

作者： G.Ha.ITHa.B.P.M.s.a.Y M.L.naik B.JYOTHI B.DIVYa.s.Ma.a.HI N.s.0}LA India. Council of a.ricultura. Res.a.ch Indian Institute of Rice Research Pla.t Breeding Genetics and Biotechnology Division International Rice Research Institute

Introgres.ion lines.ILs.derived from inters.ecific cros.es.a.e a.s.urce of new genetic va.ia.ility.a.tota. of 55 ILs.derived from two cros.es.s.a.na.*** IRGC81848(popula.ion a.a.d s.a.na.*** IRGC81832(popula.ion B)were cha.a.terized for yield a.d yield-rela.ed tra.ts.*** of 103 s.mple s.quence repea.(s.R)ma.kers.a.s.cia.ed with yield-rela.ed QTLs.wa. *** a.s.owed a. a.era.e of 12.6%homozygous.*** a.leles.a.d popula.ion B s.owed 10.6%.Interes.ingly,three s.R ma.kers.RM223,RM128 a.d RM517,s.owed cons.icuous.pa.tern of *** dis.ribution of pa.enta. a.leles.a. three loci RM223,RM128 a.d RM517 linked to yield-rela.ed tra.ts.wa. *** ma.kers.fla.ked to s.vera. yield-rela.ed ***223,fla.king to qyld8.3,wa. heterozygous.in a.mos. a.l the 55 ILs.except in IL10-3s.a.d ***128 on chromos.me 1 a.d RM517 on chromos.me 3 were mutua.ly exclus.ve in 46 out of 55 *** 46 ILs.s.owed either of the ma.ker a.lele RM128 or RM517 from *** but not ***166s.ha. both RM128a.d RM517 from *** a.d the other ILs.s.owed homozygous.s.a.na.a.lele a. RM517 except *** s.ructure a.s.gned the 55 ILs.to three s.b-popula.ions.ba.ed on their genomic ***65s.IL166s.IL248s.IL7K a.d IL250K s.owed high yields.in multi-loca.ion tria.s.a.d IL248s.wa. relea.ed for cultiva.ion a. DRRDha. 40.

关键词： introgres.ion line heterozygos.ty Oryza niva.a wild rice popula.ion s.ructure yield s.mple s.quence repea.

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