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操作参数对Corex铁水Si含量的影响

世界钢铁 2010年第1期10卷 1-6+18页

作者： p prachethan Kumar a v r p dasu M ranjan T K Naha 张海洋金达尔钢公司研发部

优质低耗的钢铁产品需求低硅低硫的优质铁水。高硅铁水是炼钢处理所不希望的,它导致处理流程成本增加、产率降低,因此,需持续努力降低铁水中Si的含量。Corex是唯一确立并被证明已成功商业运行的改变传统高炉炼铁的熔融还原技术。尽管高... 详细信息

优质低耗的钢铁产品需求低硅低硫的优质铁水。高硅铁水是炼钢处理所不希望的,它导致处理流程成本增加、产率降低,因此,需持续努力降低铁水中Si的含量。Corex是唯一确立并被证明已成功商业运行的改变传统高炉炼铁的熔融还原技术。尽管高炉硅转移原理已被熟练掌握,但Corex工艺仍然需要进一步的操作指导来控制硅转移。对超过一年的工厂运行数据进行统计分析,可以了解铁水中Si含量的影响因素,提供预测和控制铁水Si含量的方法。用回归分析得出回归方程来预测Corex铁水Si含量。简要讨论了硅预测回归分析中所涉及的各种因素,并验证操作参数,阐述了各参数间的相互关系。数据分析表明高水分、低金属化率、高挥发分、高渣比、高煤粉率、低产能直接导致高燃料比,同时炉渣高碱度和高Al2O3含量会导致铁水Si含量升高。

关键词： Corex 燃料比灰分硅炉渣高炉熔融气化炉还原竖炉

Measurement of yields and angular distributions ofγ-quanta from the interaction of 14.1 Mev neutrons with oxygen,phosphorus,and sulfur

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Chinese physics C 2024年第3期48卷 79-92页

作者： D.N.Grozdanov N.A.Fedorov S.B.Dabylova Yu.N.Kopatch I.N.ruskov v.r.Skoy T.Yu.Tretyakova C.Hramco p.I.Kharlamov G.v.pampushik p.G.Filonchik A.v.Andreev Joint Institute for Nuclear research(JINr) DubnaRussia Institute for Nuclear research and Nuclear Energy Bulgarian Academy of SciencesSofiaBulgaria Faculty of physics Lomonosov Moscow State UniversityMoscowRussia L.N.Gumilyov Eurasian National University AstanaKazakhstan Skobeltsyn Institute of Nuclear physics Moscow State UniversityMoscowRussia Institute of Chemistry of Moldova ChisinauRepublic of Moldova Moscow Institute of physics and Technology MoscowRussia

A study of the inelastic scattering of neutrons with an energy of 14.1 Mev on the nuclei of oxygen,phosphorus,and sulfur was performed at the TANGrA facility at JINr(Dubna).The experiment aimed to refine existing data and obtain new data on the yields and angular distributions ofγ-quanta emitted by the studied nuclei due to neutron-induced nuclear reactions using the tagged neutron *** types of detector systems were used to registerγ-***γ-ray yields were measured using a high-purity germanium(HpGe)*** angular distributions ofγ-rays were obtained using a system of 18 scintillation detectors based on bismuth germanite Bi_(4)Ge_(3)O_(12)(BGO)located around the *** performed experiments measured the yields of two transitions for the reaction of tagged neutrons with 16O,nine transitions for the reaction with ^(31)p,and nine transitions for the reaction with ^(32)S for the first *** angular anisotropy of theγ-radiation accompanying the inelastic scattering of neutrons with an energy of 14.1 Mev on ^(31)p nuclei was also measured for the first time.

关键词： tagged neutron method yields of gamma-quanta high-resolution gamma-spectrometry neutron-nuclear reactions neutron scattering

BaTiO3 solid solutions co-doped with Gd3+ and Eu3+:Synthesis,structural evolution and dielectric properties

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Journal of rare Earths 2024年第10期42卷 1920-1926页

作者： r.Martínez-López M.pérez-Labra J.A.romero-Serrano F.r.Barrientos-Hernández M.reyes-pérez M.I.valenzuela-Carrillo G.Urbano-reyes v.E.reyes-Cruz G.I.Dávila-pulido Academic Area of Earth Sciences and Materials Autonomous University of Hidalgo State Metallurgy and Materials Department ESIQIE-IPNUPALM Autonomous University of Coahuila Boulevard Adolfo López Mateos S/n

In this paper,the synthesis,structural evolution,and dielectric properties of BaTiO3solid solutions codoped with rare earth elements(Gd3+and Eu3+) prepared using the solid-state reaction method are *** pure precursor powders of BaCl3,TiO2,Gd2O3,and Eu2O3were mixed in stoichiometric proportions,ground in an agate mortar before being uniaxially pressed at 250 Mpa and sintered at 1300℃ in air atmosphere for 6 h to obtain Ba1-3xGd2xTi1-3xEu4xO3（x=0,0.0015,0.01 and0.1）.X-ray diffraction（XrD） and rietveld's refinement results reveal the crystal phase ferroelectric tetragonal BaTiO3for the samples with x=0,0.0015 and 0.01, as well as a consistent increment in the lattice parameters caused by the *** solubility limit of Gd3+and Eu3+in the BaTiO3structure is reached for the sample with x>0.01,and the orthorhombic Eu2TiO5and monoclinic BaTi2O5secondary phases were *** raman results show the characteristic peaks of ferroelectric tetragonal BaTiO3around 716 cm-1（LO of A1 symmetry）,515 cm-1（TO of A1 symmetry）,and 305 cm-1（B1）.The maximum relative permittivity measured at 1 kHz was recorded to be 6151.8 for the sample with x=0.0015,and a decrease in the Curie temperature to 105℃ with respect to the undoped sample was *** punctual microanalysis for the samples with x=0.0015,0.01,and 0.1 reveals grains composed of Ba,Ti,O,Gd,and Eu homogeneously distributed in the *** Ba/Ti ratios for samples with x=0.0015,0.01 and 0.1 are 2.86,2.91,and 0.68,respectively,indicating substitution at the Ti site for samples with x=0.0015 and 0.01 and a substitution at the Ba site for the sample with x=0.1.

关键词： BaTiO3 Doping Europium Gadolinium rare earths Synthesis

Wormhole solutions under the effect of dark matter in f(r,L_(m))gravity

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Communications in Theoretical physics 2024年第5期76卷 102-113页

作者： Lakhan v Jaybhaye Moreshwar Tayde pK Sahoo Department of Mathematics Birla Institute of Technology and Science-PilaniHyderabad CampusHyderabad-500078India

In the background of f(r,L_(m))gravity,this work investigates three distinct dark matter halo profiles to test the possibility of generalised wormhole geometry within the galactic halo *** current study aims to accomplish these goals by examining various dark matter profiles including universal rotation curves(UrC),Navarro-Frenk-White(NFW)model-Ⅰ,and NFW model-Ⅱinside two distinct f(r,L_(m))gravity *** to the f(r,L_(m))=r/2+L^(a)_(m)model,the dark matter(DM)halo density profiles produce suitable shape functions that meet all the necessary requirements for exhibiting the wormhole geometries with appropriate choice of free *** addition,to examine DM profiles under the f(r,L_(m))=r/2+(1+λr)L_(m) model,we consider a specific shape ***,we observed that the derived solution from both two models violates the null energy constraints,confirming that the DM supports wormholes to maintain in the galactic halo.

关键词： f(r L_(m))gravity wormhole dark matter(Some figures may appear in colour only in the online journal)

Temperature-dependent thermal conductivity and fuel performance of UN-UO_(2) and UN-X-UO_(2)(X=Mo,W)composite nuclear fuels by finite element modeling

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Journal of Materiomics 2024年第4期10卷 937-946页

作者： Faris Sweidan Diogo ribeiro Costa Huan Liu pär Olsson KTH royal Institute of Technology Nuclear EngineeringStockholm10691Sweden Westinghouse Electric Sweden AB Västerås72163Sweden

The temperature-dependent effective thermal conductivity of UN-X-UO_(2)(X=Mo,W)nuclear fuel composite was *** the experimental design,the thermal conductivity was calculated using Finite Element Modeling(FEM),and compared with analytical models for 10%,30%,50%,and 70%(in mass)uncoated/coated UN microspheres in a UO2 *** FEM results show an increase in the fuel thermal conductivity as the mass fraction of the UN microspheres increases from 1.2 to 4.6 times the UO2 reference at 2,000 *** results from analytical models agree with the thermal conductivity estimated by *** results also show that Mo and W coatings have similar thermal behaviors,and the coating thickness influences the thermal conductivity of the *** higher weight fractions,the thermal conductivity of the fuel composite at room temperature is substantially influenced by the high thermal conductivity coatings approaching that of ***,the thermal conductivity from FEM was used in the fuel thermal performance evaluation during LWr normal operation to calculate the maximum centerline *** results show a significant decrease in the fuel maximum centerline temperature ranging from−94 K for 10% UN to−414 K for 70%(in mass)UN compared to UO2 under the same operating conditions.

关键词： Accident tolerant fuel UN-X-UO_(2) Composite nuclear fuel Thermal conductivity Finite element modeling Thermal performance

Temperature and structure measurements of heavy-ion-heated diamond using in situ X-ray diagnostics

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Matter and radiation at Extremes 2024年第4期9卷 80-89页

作者： J.Lutgert p.Hesselbach M.Schorner v.Bagnoud r.Belikov p.Drechsel B.Heuser O.SHumphries p.Katrik B.Lindqvist C.Qu r.redmer D.riley G.Schaumann S.Schumacher A.Tauschwitz D.varentsov K.Weyrich X.Yu B.Zielbauer Zs.Major p.Neumayer D.Kraus Institut fur physik Universitat RostockAlbert-Einstein-Str.2318059 RostockGermany GSI Helmholtzzentrum fur Schwerionenforschung Planckstr.164291 DarmstadtGermany Institut für Angewandte physik Goethe-Universität Frankfurt am MainMax-von-Laue-Str.160438 Frankfurt am MainGermany Institut fur Geowissenschaften Goethe-Universitat Frankfurt am MainAltenhoferallee 160438 Frankfurt am MainGermany Helmholtz-Zentrum Dresden-rossendorf Bautzner Landstr.40001328 DresdenGermany European XFEL GmbH Holzkoppel 422869 SchenefeldGermany Centre for plasma physics School of Mathematics and PhysicsQueen’s University BelfastUniversity RoadBelfast BT71NNUnited Kingdom Institut für Kernphysik Technische Universität DarmstadtSchlossgartenstr.964289 DarmstadtGermany State Key Laboratory of Nuclear physics and Technology Institute of Heavy Ion PhysicsPeking UniversityBeijing 100871China Helmholtz Institut Jena Frobelstieg 307743 JenaGermany

We present in situ measurements of spectrally resolved X-ray scattering and X-ray diffraction from monocrystalline diamond samples heatedwith an intense pulse of heavy *** this way,we determine the samples’heating dynamics and their microscopic and macroscopic structuralintegrity over a timespan of several *** the ratio of elastic to inelastic scattering with state-of-the-art density functionaltheory molecular dynamics simulations allows the inference of average temperatures around 1300 K,in agreement with predictions fromstopping power *** simultaneous diffraction measurements show no hints of any volumetric graphitization of the material,butdo indicate the onset of fracture in the diamond *** experiments pave the way for future studies at the Facility for Antiproton andIon research,where a substantially increased intensity of the heavy ion beam will be available.

关键词： heated intense structure

Single atom Cu-N-C catalysts for the electro-reduction of CO_(2) to CO assessed by rotating ring-disc electrode

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Journal of Energy Chemistry 2024年第1期88卷 169-182,I0004页

作者： S.pérez-rodríguez M.Gutiérrez-roa C.Giménez-rubio D.ríos-ruiz p.Arévalo-Cid M.v.Martínez-Huerta A.Zitolo M.J.Lázaro D.Sebastián Instituto de Carboquímica(CSIC) Miguel Luesma Castán 450018 ZaragozaSpain Instituto de Catálisis y petroleoquímica(CSIC) Marie Curie 228049 MadridSpain Synchrotron SOLEIL L’Orme des MerisiersDépartementale 12891190France

The electrochemical CO_(2) reduction reaction(CO_(2)rr) to controllable chemicals is considered as a promising pathway to store intermittent renewable energy. Herein, a set of catalysts based on copper-nitrogendoped carbon xerogel(Cu-N-C) are successfully developed varying the copper amount and the nature of the copper precursor, for the efficient CO_(2)rr. The electrocatalytic performance of Cu-N-C materials is assessed by a rotating ring-disc electrode(rrDE), technique still rarely explored for CO_(2)rr. For comparison, products are also characterized by online gas chromatography in a H-cell. The as-synthesized Cu-NC catalysts are found to be active and highly CO selective at low overpotentials(from -0.6 to -0.8 v ***) in 0.1 M KHCO_(3), while H_(2) from the competitive water reduction appears at larger overpotentials(-0.9 v vs. rHE). The optimum copper acetate-derived catalyst containing Cu-N_(4) moieties exhibits a CO_(2)-to-CO turnover frequency of 997 h^(-1) at -0.9 v vs. rHE with a H_(2)/CO ratio of 1.8. These results demonstrate that rrDE configuration can be used as a feasible approach for identifying electrolysis products from CO_(2)rr.

关键词： Cu-N-C Carbon xerogel rotating ring disc electrode Carbon dioxide reduction reaction Carbon monoxide

ranking environmental and edaphic attributes driving soil microbial community structure and activity with special attention to spatial and temporal scales

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mLife 2024年第1期3卷 21-41页

作者： vadakattu v.S.r.Gupta James M.Tiedje CSIrO Agriculture&Food UrrbraeSouth AustraliaAustralia Centre for Microbial Ecology Michigan State UniversityEast LansingMichiganUSA

The incredibly complex soil microbial communities at small scales make their analysis and identification of reasons for the observed structures *** community structure is mainly a result of the inoculum(dispersal),the selective advantages of those organisms under the habitat-based environmental attributes,and the ability of those colonizers to sustain themselves over *** soil is protective,and its microbial inhabitants have long adapted to varied soil conditions,significant portions of the soil microbial community structure are likely ***,a substantial portion of the community will not correlate to often measured soil *** suggest that the drivers be ranked on the basis of their importance to the fundamental needs of the microbes:(i)those that supply energy,i.e.,organic carbon and electron acceptors;(i)environmental effectors or stressors,i.e.,pH,salt,drought,and toxic chemicals;(ii)macro-organism associations,i.e.,plants and their seasonality,animals and their fecal matter,and soil fauna;and(iv)nutrients,in order,N,p,and probably of lesser importance,other micronutrients,and *** relevance of drivers also varies with spatial and time scales,for example,aggregate to field to regional,and persistent to dynamic populations to transcripts,and with the extent of phylogenetic difference,hence phenotypic differences in organismal *** present a summary matrix to provide guidance on which drivers are important for particular studies,with special emphasis on a wide range of spatial and temporal scales,and illustrate this with genomic and population(rrNA gene)data from selected studies.

关键词： abundance community structure diversity functional microbiome microorganisms

A novel diurnal and seasonal variation analysis of BTEX in Bengaluru urban area

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research in Cold and Arid regions 2024年第1期16卷 14-19页

作者： H.N.Sowmya M.Dinamani G.p.Shivashankara H.K.ramaraju B.S.Surendra vijaya v.Shanbhag r.prajwal Department of Civil Engineering Dayananda Sagar College of EngineeringBangalore 560078India Department of Chemistry Dayananda Sagar College of EngineeringBangalore 560078India Department of physics GFGCVijayanagarBengaluru 560040India

In the urban atmosphere of Bengaluru, various volatile organic compounds(vOCs), particularly Benzene,Toluene, Ethylbenzene, and Xylene(BTEX), have shown an increasing trend in concentration. The present research was conducted during summer and monsoon seasons, focusing on Kadubeesanahalli, a high-traffic area within the Bengaluru Metropolitan City. Hourly sample data was collected using a BTEX analyzer(Model GC955-600) and subsequently transformed into daily, monthly, and seasonal values. The study revealed distinct patterns in benzene concentrations. Benzene levels were lowest during the early morning hours, specifically from 1:00 *** 7:00 a.m.. Concentrations then increased from 7:00 a.m. to 9:00 a.m. and again from 4:00 p.m. to 11:00 p.m.,corresponding to the morning and evening peak traffic hours. However, between 10:00 a.m. and 4:00 p.m., the concentration decreased due to reduced traffic levels. These diurnal variations in benzene concentration are influenced by meteorological parameters. Comparing the two seasons, higher concentrations of Benzene, EthylBenzene, and Mp-xylene were observed during the summer season. This increase is attributed to the elevated temperatures during summer, which promote the vaporization of BTEX compounds. Conversely, lower BTEX concentrations were recorded during the monsoon season due to the wet deposition process. The observed positive correlation(r > 0.5) among BTEX parameters strongly suggests a common source, most likely originating from vehicular emissions.

关键词： BTEX Summer variation Meteorological parameters Correlation