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Hydrocarbon accumulation in network and its application in the continental rift basin

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Science china Earth Sciences 2008年第S2期51卷 88-100页

作者： PANG XiongQi1,2,CHEN DongXia1,ZHANG ShanWen3,HAO Fang1,LIU Zheng1,LIU KeYu3,SONG GuoQi4,WANG YongShi4,LUO XiaoRong5 & WU XiaoChun61 State Key Laboratory of petroleum Resource and Prospecting,Chinese University of petroleum,beijing 102249,china 2 Basin and Reservoir Center,Chinese University of petroleum,beijing 102249,china 3 SINOPEC Shengli Oilfield,Dongying 257051,china 4 CSIRO petroleum,P. O. Box 113.,Bentley,WA 6102,Australia 5 Institute of Geology and Geophysics,Chinese Academy of Science,beijing 100029,china 6 china National petroleum {13.,beijing 100724,china State Key Laboratory of petroleum Resource and Prospecting Chinese University of Petroleum Beijing China Basin and Reservoir Center Chinese University of Petroleum Beijing China SINOPEC Shengli Oilfield Dongying China CSIRO petroleum Bentley Australia Institute of Geology and Geophysics Chinese Academy of Science Beijing China china National petroleum corporation Beijing China

The concept of hydrocarbon accumulation in network was presented on basis of the overall analysis of the formation and evolution characteristics of the continental faulted basin and of the systemic re-search on the major controlling factors on the hydrocarbon accumulation. The hydrocarbon accumu-lation in network can be defined as hydrocarbon accumulation in a three-dimensional network system which is constituted by the hydrocarbon migration passages under multiple dynamics,following the hydrocarbon generation from source rocks. The research shows that the hydrocarbon accumulation in network is composed of four elements,i.e.,hydrocarbon source (source rock kitchen),hydrocarbon accumulation terminal (trap),network pathway connecting source and terminal (transporting system),and network potential driving hydrocarbon migration in the network pathway (migration dynamics). Compared with other networks,hydrocarbon accumulation in network has three basic characteristics: the irreversible geological process of material and information flow in the network; the loss of material and information in the flow process in the network; the multiple dynamics in the flow process. Interac-tion of all the elements in the geological process can be called hydrocarbon accumulation in network. There are three basic models for hydrocarbon accumulation in network,that is,hydrocarbon accumu-lation in the network source area,hydrocarbon accumulation in the network pathway,and hydrocarbon accumulation in the network terminal. The key in the application of the hydrocarbon accumulation models in network in practice is to confirm the major accumulation stage and the function range of the four elements controlling the hydrocarbon firstly,to predict the profitable accumulation region by su-perposition of the favorable areas confirmed by four elements consequently,and to evaluate the oil-bearing property of the trap as well as confirm drilling targets. This paper takes the Dongying De-pression in the

关键词： continental rift basin hydrocarbon accumulation theory hydrocarbon network hydrocarbon accumulation in network Bohai Bay Basin

Characteristics and genetic mechanism of deep-buried clastic eureservoir in china

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Science china Earth Sciences 2008年第S2期51卷 11-19页

作者： ZHONG DaKang & ZHU XiaoMin china University of petroleum,beijing 102249,china china University of petroleum Beijing China

Systematic researches to the clastic reservoirs in various types and various geological ages basins in china indicate that the present burial depth of deep buried clastic eureservoir ranges from 3000 to 6000 m,and its geological ages from Paleozoic,Mesozoic to Cenozoic. It mainly deposited in delta (including braid delta,fan delta,normal delta),river,also shore,shallow lake,gravity flow channel and turbidity fan facies. The quartzose sandstone is the main reservoir rock of deep-buried clastic eureservoir in the shore facies in Paleozoic,but the arenite and arkose sandstones are the main reservoir rock types in delta,river,shallow lake and gravity flow facies in Mesozoic and Cenozoic. The porosity of most of deep-buried clastic eureservoir is more than 10% and permeability more than 10×10?3 μm2. The forma-tion of the deep-buried eureservoir was related to the paleotectonics,paleotemperature,sedimentary environment,the deep dissolution caused by organic acid or carbonic acid,burial style,the abnormal high pore fluid pressure,early hydrocarbon charging,gyprock sealing,hot convective fluid flow and the mode of sand-mud interbedded,etc. The paleotectonics controls the burial style of sandstones,and the paleotemperature controls the diagenesis process. The sedimentary environment is the precondi-tion and foundation,the dissolution is the direct reason to generate the deep buried clastic eureservoir. The abnormal high pore fluid pressure,gyprock sealing,the mode of sand-mud interbedded,early hy-drocarbon charging and the structure fractures were the assistant factors of generating the deep buried clastic eureservoir.

关键词： deep buried clastic eureservoir characteristics genetic mechanism controlling factors

Large pore volume mesoporous aluminum oxide synthesized via nano-assembly

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Science china Chemistry 2009年第12期52卷 2114-2124页

作者： WANG DingCong Fushun Research Institute of petroleum and Petrochemicals,china petroleum and Chemical corporation (SINOPEC),Fushun 113.01,china Fushun Research Institute of petroleum and Petrochemicals China Petroleum and Chemical Corporation (SINOPEC) Fushun China

A new nano-assembly approach has been proposed for the preparation of macropore volume mesoporous aluminum oxide supports. Secondary nano-assembly and a frame structure mechanism for large pore volume mesoporous supports have been proposed. In a primary nano-assembly supersoluble micelle,aluminum hydroxide nanoparticles were precipitated in situ in surfactants with a volume balance (VB) less than 1,followed by secondary nano-assembly in linear and cylindrical shapes. The secondary nano-assembly of cylindrical aluminum hydroxides was calcined to form nano cylindrical aluminum oxides. For the formation of macropore volume mesoporous supports,we utilized a frame structure mechanism of mesoporous support,in which the exterior surface of the carrier may not be continuous. This macropore volume support has been used for the hydrotreatment of a residual oil catalyst,which possesses the following physical characteristics:pore volume 1.8―2.7 mL·g-1,specific surface area 180―429 m2·g-1,average pore diameter 17―57 nm,average pore diameter more than 10 nm (81%―94%),porosity 87%―93%,and crush strength 7.7―25 N·mm-1.

关键词： pore volume mesopore aluminum oxide nano-assembly supersolubility pore size porosity

Development Scenario of china Polyolefin Industry in 2009 and Its Prospect During Twelfth Five-year-plan Period

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中国塑料 2010年第4期24卷 125-128页

作者： LIU Jian (china petroleum Materials corporation,beijing 100029,china) LI Ying

The development situation of the polyolefin industry during the first four years of the Elevemth Five-year-plan was *** supply and demand of polyolefins at the period of the Twelfth Five-year-plan were analyzed and *** was pointed out that production capacity of polyolefin in china will be increased significantly and market demand will keep a steady ***-scale industrial equipment of polyolefin will be developed to meet the increasing demand.

关键词： polyolefin polyethylene polypropylene the twelfth five-year plan supply demand

Characteristics of fluid substitution in porous rocks

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petroleum Science 2009年第2期6卷 139-145页

作者： Li Shengjie School of Resource and Information Technology China University of Petroleum Beijing 102249 China State Key Laboratory of petroleum Resource and Prospecting China University of Petroleum Beijing 102249 China Key Laboratory of CNPC Geophysical Exploration China University of Petroleum Beijing 102249 China

Analysis of the effect of changes in fluid properties of rocks on the compressional-wave velocity VP and shear-wave velocity Vs is very important for understanding the rock physical properties, especially in oilfield exploration and development. The fluid substitution process was analyzed by using ultrasonic measurement and theoretical calculations. The results showed that the effect of fluid substitution on the rock elastic modulus was mainly controlled by fluid properties, saturation, and confining pressure. For a rock with specific properties and porosity, the result of theoretical prediction for fluid substitution accorded with the experimental result under high confining pressure （higher than 60 MPa for our experimental data）, but failed to describe the trend of experimental result under low confining pressure and VP predicted by Gassmann＇s equation was higher than that measured by experiment. A higher porosity resulted in stronger sensitivity of the bulk modulus of saturated rocks to the change of fluid properties.

关键词： Fluid substitution velocity bulk modulus porosity saturation

Effects of abnormally high heat stress on petroleum in reservoir——An example from the Tazhong 18 Well in the Tarim Basin

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Science china Earth Sciences 2008年第4期51卷 515-527页

作者： ZHU DongYa1, JIN ZhiJun1, HU WenXuan2 & ZHANG XueFeng3 1 petroleum Exploration and Production Institute, china petroleum & Chemical corporation, beijing 100083, china 2 Department of Earth Sciences, Nanjing University, Nanjing 210093, china 3 School of Resource and Information, china University of petroleum, beijing 102249, china petroleum Exploration and Production Institute China Petroleum & Chemical Corporation Beijing China Department of Earth Sciences Nanjing University Nanjing China School of Resource and Information China University of Petroleum Beijing China

An igneous intrusion of 94m thick was discovered intruding into the Silurian sandstone from Tazhong 18 Well. The petroleum previously preserved in the Silurian sandstone reservoir was altered into black carbonaceous bitumen by abnormally high heat stress induced by the igneous intrusion. The reflec-tance of the carbonaceous bitumen reaches as high as 3.54%, indicating that the bitumen had evolved into a high thermal evolution level. Similar to the Silurian samples from the neighboring Tazhong 11, Tazhong 12, Tazhong 45 and Tazhong 47 wells, the distribution of C27, C28 and C29 steranes of the car-bonaceous bitumen is still "V" -shaped and can still be employed as an efficient parameter in oil source correlation. The "V" -shaped distribution indicates that the hydrocarbons from the Tazhong 18 and the neighboring wells were all generated from the Middle-Upper Ordovician hydrocarbon source rocks. However, the oil source correlation parameters associated with and terpanes had been changed greatly by the high heat stress and can no longer be used in oil source correlation. The δ 13. values of the pe-troleum from the neighboring wells are between -32.53‰ and -33.37‰, coincident with those of the Paleozoic marine petroleum in the Tarim Basin. However, the δ 13. values of the carbonaceous bitumen from the Tazhong 18 Well are between -27.18‰ and -29.26‰, isotopically much heavier than the pe-troleum from the neighboring wells. The content of light hydrocarbons (nC14-nC20) of the saturated hydrocarbon fraction in the carbonaceous bitumen is extremely higher than the content of heavy hy-drocarbons. The light/heavy hydrocarbon ratios (ΣnC21-/ΣnC22+) are between 4.56 and 39.17. In the saturated fraction, the even numbered hydrocarbons are predominant to the odd numbered, and the OEP (Odd to Even Predominance) values are between 0.22 and 0.49. However, the content of light hy-drocarbons in the petroleum from the neighboring wells is relatively low and the content of the even numb

关键词： Tarim Basin igneous intrusive abnormally high heat stress bitumen carbon isotope PAH

A kind of coccoid dinoflagel-lates-like fossils gives a new explanation of source of dinosterane in the Early-Middle Cambrian

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Chinese Science Bulletin 2001年第5期46卷 420-423,442页

作者： BIAN Lizeng, ZHANG Shuichang, ZHANG Baomin, MAO Shaozhi & YIN LeimingDepartment of Earth Sciences, Nanjing University, Nanjing 210093,china Key Laboratory of petroleum Geochemistry, china National petroleum corporation, beijing 100083, china Research Institute of petroleum Exploration and Development, china National petroleum corporation, beijing 100083, china china University of Geosciences, beijing 100083, china Nanjing Institute of Geology and Palaeontology, Chinese Academy of Sciences, Nanjing 210008, china Department of Earth Sciences Nanjing University Nanjing China Key Laboratory of petroleum Geochemistry China National Petroleum Corporation Beijing China Research Institute of petroleum Exploration and Development China National Petroleum Corporation Beijing China china University of Geosciences Beijing China Nanjing Institute of Geology and Palaeontology Chinese Academy of Sciences Nanjing China

The coccoid fossils covered with thick gelatinous envelop containing several gametes are discovered in gyps and salt deposits of Cambrian, H4 well and chert bed of the base of Yuertus Formation (∈11) of Xiaoerbulake Section. The fossils are described and compared with coccoid dinoflagellates. These fossils may be a coccoid life-cycle stage (vegetative cyst) of coccoid dinoflagellates. If this identification is correct, the coccoid dinoflagellates-like fossils could give a reasonable explanation of the dinoflagellate-specific biomarkers from Cambrian, H4 well, Tarim Basin.

关键词： coccoid dinoflagellates-like fossils dinoflagellate-specific biomarkers Cambrian Tarim Basin.

A PHYSICAL MODEL FOR PREDICTING THE PRESSURE DROP OF GAS-LIQUID SLUG FLOW IN HORIZONTAL PIPES

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Journal of Hydrodynamics 2007年第6期19卷 736-742页

作者： LI Guo-zhen YAO Yue-dong DONG Shou-ping Faculty of Mechanical and Electronic Engineering China University of Petroleum （Beijing） Beijing 102249 China CMOE Key Laboratory of petroleum Engineering China University of Petroleum （Beijing） Beijing 102249China Faculty of Mechanical and Electronic Engineering China University of Petroleum （Beijing） Beijing 102249China

A comprehensive treatment of all sources of pressure drop within intermittent gas-liquid flow is presented. A slug unit is divided into three parts and the pressure gradient of each part is calculated separately. In the mixing zone the momentum theory is employed and the mixing process between the film and slug is simulated by a two-dimensional wall jet entering a large reservoir to calculate the mixing length. The boundary layer theory is utilized to calculate the pressure drop for the slug body and the momentum equation of the film zone is integrated to calculate the pressure drop for the film zone. The pressure drop predicted in present model is in good agreement with all the measurements.

关键词： slug flow gas-liquid flow pressure drop,physical model

Contributors and potential of hydrocarbon generation of source rocks by solid-state ^(13.C NMR spectroscopy

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Chinese Science Bulletin 1997年第6期42卷 478-481页

作者： WANGZhaoyun, ZHAO Changyi, CHENG Keming and LU Qinghua1. Research Institute of petroleum Exploration and Development, china National petroleum corporation, beijing 100083, china:2. University of petroleum, beijing, 100083 china Research Institute of petroleum Exploration and Development China National Petroleum Corporation Beijing China University of petroleum Beijing China

SOLID-STATE 13. nuclear magnetic resonance （NMR） technique is an effective method to study the texture of material. Under the condition of high magnetic field （400 MHz） and by the application of cross polarization... 详细信息

SOLID-STATE 13./sup>C nuclear magnetic resonance （NMR） technique is an effective method to study the texture of material. Under the condition of high magnetic field （400 MHz） and by the application of cross polarization, magic angle spinning （CP/MAS）, total sideband suppression （TOSS）, etc., the content of different textural carbons in kerogen has been quantitatively analyzed by the solid-state 13./sup>C NMR spectroscopy of a series of kerogen of thermal simulation samples with Ro value ranging from 0.64% to 1.76%. The results show that

关键词： solid 13. NMR analysis aliphatic carbon potential of hydrocarbon generation of source rocks.