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Analytical method of Cr stable isotope and its application to water pollution survey

Chinese Science Bulletin 2010年第7期55卷 664-669页

作者： GAO YongJuan 1,2,3,MA Teng 4,5,LING WenLi 1,2,LIU CunFu 4,5 & LI Li 4,5 1Faculty of Earth Science,china university of geosciences,wuhan 430074,china 2State Key laboratory of Geological Processes and Mineral Resources,china university of geosciences,wuhan 430074,china 3 Graduate School,china university of geosciences,wuhan 430074,china 4 Biogeological and environmental Geology laboratory of Ministry of Education(china university of geosciences) ,wuhan 430074,china 5 sino-hungary joint laboratory of environmental sciences and health,china university of geosciences,wuhan 430074,china Faculty of Earth Science China University of Geosciences Wuhan 430074 China State Key laboratory of Geological Processes and Mineral Resources China University of Geosciences Wuhan 430074 China Graduate School China University of Geosciences Wuhan 430074 China Biogeological and environmental Geology laboratory of Ministry of Education (china university of geosciences) Wuhan 430074 China sino-hungary joint laboratory of environmental sciences and health China University of Geosciences Wuhan 430074 China

High Cr(VI) concentration is a potential serious risk to environment and ecologic ***,it is essential to effectively monitor Cr contamination in water systems and scientifically evaluate its evolution trend.A new method of in-situ tracer technique by Cr isotopic analysis for quantitatively estimating Cr-contamination and its regional evolution in natural waters as well as a case application are reported in this *** on documented literatures,an experimental procedure for chemical separation and purification of Cr in water samples and its analytical method for Cr isotopic measurement by thermal ionization mass spectrometry(TIMS) are *** samples collected around a chemical factory in Hubei Province were analyzed by this *** samples showδ53Cr values ranging from-1.7‰to 7.3‰and an elevating trend with an increasing in distance from the sampling site to pollution source.A functional correlation following Rayleigh fractionation law was established between sample'sδ53Cr value and its extent of Cr *** study suggests that Cr isotopic analysis is an effective method to reveal the spatial distribution and its evolution trend of Cr contamination in the regional water *** is thus helpful to assessing the self-purifying ability of local water system according to Cr isotopic fractionation.

关键词：铬(VI) 水污染调查稳定同位素应用同位素分析供水系统演变趋势示踪技术

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Cardiovascular Risk Factors in china

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Journal of Geriatric Cardiology 2024年第2期21卷 153-199页

作者： Sheng-Shou HU the Writing Committee of the Report on Cardiovascular health and Diseases in china Fuwai Hospital National Center for Cardiovascular DiseasesChinese Academy of Medical Sciences and Peking Union Medical CollegeBeijingChina 不详

The Annual Report on Cardiovascular health and Diseases in china(2022) intricate landscape of cardiovascular health in china. This section dissects cardiovascular risk factors in china which including hypertension, dyslipidemia, diabetes mellitus, chronic kidney disease, metabolic syndrome and air pollution. Hypertension prevalence has steadily increased in china,with efforts to control it facing challenges in achieving optimal rates, especially in rural areas. Interventions like salt substitutes and intensive blood pressure control show promise but need improvement. Abnormal lipid levels, indicative of dyslipidemia,have risen significantly, posing a risk for cardiovascular diseases. Despite efforts, many patients struggle to achieve target lipid levels, necessitating improved treatment strategies. Both type 1 and type 2 diabetes mellitus affect millions of adults in china,with long-term complications adding to the disease burden. Early intervention and effective management are crucial to mitigate its impact. Prevalent among older adults, chronic kidney disease is associated with diabetes mellitus, hypertension, and cardiovascular diseases, necessitating comprehensive management approaches. The prevalence of metabolic syndrome, characterized by a cluster of risk factors, has increased in both adults and adolescents, calling for lifestyle modifications and public health interventions. Ambient and household air pollution remain significant environmental risk factors, despite some improvements in air quality. Continued efforts to reduce emissions are essential for mitigating associated health risks. Addressing these risk factors requires a multifaceted approach, including public health initiatives, policy interventions, and individual-level strategies to promote healthy lifestyles and reduce environmental exposures. Surveillance and research efforts are crucial for monitoring trends and developing effective strategies to lessen the burden of cardiovascular diseases in

关键词： landscape adding spite

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Evolutionary patterns of Productida (Brachiopoda) morphology during the Permian in South china

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Science china Earth sciences 2008年第11期51卷 1589-1600页

作者： ZHANG Yang1 & HE WeiHong1,2 1 Faculty of Earth sciences, china university of geosciences, wuhan 430074, china 2 Key laboratory of Biogeology and environmental Geology of Ministry of Education, china university of geosciences, wuhan 430074, china 1. Faculty of Earth sciences China University of Geosciences Wuhan 430074 China 2. Key laboratory of Biogeology and environmental Geology of Ministry of Education China University of Geosciences Wuhan 430074 China

The evolutionary patterns of Productida (brachiopod) morphology throughout the Permian show that while the percentage proportion of Productida (brachiopod) with strongly concentric and radial ornamentation declined from the Cisuralian to the Guadalupian, and then increased towards the Changhsingian via Wuchiapingian, the percentage proportion of Productida (brachiopod) with fine concentric and radial ornamentation distinctly increased from the Cisuralian to the Guadalupian, slightly declined towards the Wuchiapingian, and then increased towards the Changhsingian. From the Cisuralian to the Changhsingian, the percentage proportion of brachiopods with spinose ornamentation shows a persistent declining trend. The shell size generally indicates a miniaturization trend at species level during the Wuchiapingian to Changhsingian (including the transitional bed). These evolutionary patterns of brachiopod ornamentation and size are possibly related to the anoxia, food shortage, sea-level fluctuation, and change of substrate in the Permian (including the Permian-Triassic transitional interval) in South china.

关键词： brachiopod ornamentation size Permian South china

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Report on Cardiovascular health and Diseases in china 2023:An Updated Summary

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Biomedical and environmental sciences 2024年第9期37卷 949-992页

作者： National Center for Cardiovascular Diseases The Writing Committee of the Report on Cardiovascular health and Diseases in china Shengshou Hu .

Since 1990,china has made considerable progress in resolving the problem of“treatment difficulty”of cardiovascular diseases(CVD).The prevalent unhealthy lifestyle among Chinese residents has exposed a massive proportion of the population to CVD risk factors,and this situation is further worsened due to the accelerated aging population in *** remains one of the greatest threats to the health of Chinese *** terms of the proportions of disease mortality among urban and rural residents in china,CVD has persistently ranked *** 2021,CVD accounted for 48.98%and 47.35%of deaths in rural and urban areas,*** out of every five deaths can be attributed to *** implement a national policy“focusing on the primary health institute and emphasizing prevention”and truly achieve a shift of CVD prevention and treatment from hospitals to communities,the National Center for Cardiovascular Diseases has organized experts from relevant fields across china to compile the“Report on Cardiovascular health and Diseases in china”annually since *** 2024 report is established based on representative,published,and high-quality big-data research results from cross-sectional and cohort population epidemiological surveys,randomized controlled clinical trials,large sample registry studies,and typical community prevention and treatment cases,along with data from some projects undertaken by the National Center for Cardiovascular *** firsthand data not only enrich the content of the current report but also provide a more timely and comprehensive reflection of the status of CVD prevention and treatment in china.

关键词： Cardiovascular disease Risk factor Prevalence Mortality Rehabilitation Basic research Medical device development health economics

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Exsolution of ilmenite and Cr-Ti magnetite from olivine of garnet-wehrlite

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Science china Earth sciences 2005年第9期48卷 1368-1376页

作者： LIU Xiangwen1,2, JIN Zhenmin1,3, QU Jing2 & WANG Lu2 1. State Key laboratory of Geological Processes and Mineral Resources, china university of geosciences, wuhan 430074, china 2. Graduate School of china university of geosciences, wuhan 430074, china 3. Faculty of Earth sciences, china university of geosciences, wuhan 430074, china 1. State Key laboratory of Geological Processes and Mineral Resources China University of Geosciences 430074 Wuhan China 2. Graduate School of china university of geosciences 430074 Wuhan China 3. Faculty of Earth sciences China University of Geosciences 430074 Wuhan China

Exsolution of rod-like ilmenite (Ilm) and Cr-Ti magnetite (Mt) have been found in olivine of garnet-wehrlite from the core of Chinese Continental sciences Drilling (CCSD). Their composition, morphology, crystal structure and their topotaxies with host olivine have been studied in detail by the transmission electron microscopy (TEM) and electron probe microanaly- sis (EPMA) technique. It shows that rod-like Ilm exsolution reported in this paper has similar characteristic with that of Alpe Arami olivine, while Cr-Ti magnetite exsolution mentioned in this paper has large discrepancy with chromite exsolution in Alpe Arami olivine. These observations suggest that both of the exsolutions found in this paper should be solid solution phases in β-olivine at their first period, then experiencing decomposition of solid solution and therefore forming Ilm and Cr-Ti magnetite exsolution with the pressure decreasing. So, this garnet-wehrlite perhaps had been ever located in mantle transition zone with a minimum depth of 300 km.

关键词： garnet-wehrlite, ilmenite, magnetite, exsolution, CCSD.

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A Technique for Carbon and Chlorine Isotope Analyses of Chlorinated Aliphatic Hydrocarbons in Groundwater

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Journal of Earth Science 2013年第2期24卷 274-281页

作者：甘义群余婷婷周爱国刘运德刘存富 School of environmental Studies China University of Geosciences State Key laboratory of Biogeology and environmental Geology China University of Geosciences

Chlorinated aliphatic hydrocarbons （CAHs）, significant contaminants in groundwater, can be characterized by stable isotopic compositions of carbon and chlorine. Previously published methods were of low analytical sensitivity or not ideal for natural samples with low concentrations of CAHs. This method is reported here to carry out simultaneously carbon and chlorine isotope analyses for mieromolar concentrations of dissolved CAHs. It was executed by extracting and converting CAHs to carbon dioxide and methyl chloride （CH3CI）. Specially, a continuous-flow interface GasBench Ⅱ was used to extract CH3CI for online chlorine isotope analysis. As a result, it greatly enhances the efficiency for isotope analysis by eliminating procedures for offline CH3CI preparation and separation. Sample size requirement was reduced to approximately 11 pmol chlorine. The standard deviation of δ^＋3C and δ^37CI for both TCE solvents and water samples was better than 0.30‰ and 0.20%0 （1σ）, *** and chlorine isotope analyses can be used as an important tool to study the sources of organic contaminants in groundwater and their behaviors in the aquifers. The method is applicable to manufacturers＇ products as well as a sample from a polluted site in principle, which will be validated in our field studies.

关键词： chlorine isotope carbon isotope chlorinated aliphatic hydrocarbon (CAH) groundwater organic contamination.

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Multistage evolution of continental collision orogen:A case study for western Dabie orogen

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Chinese Science Bulletin 2009年第15期54卷 2568-2579页

作者： WU YuanBao State Key laboratory of Geological Processes and Mineral Resources, Faculty of Earth sciences, china university of geosciences, wuhan 430074, china State Key laboratory of Continental Dynamics, Department of Geology, Northwest university, Xi’an 710069, china State Key laboratory of Geological Processes and Mineral Resources Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China State Key laboratory of Continental Dynamics Department of Geology Northwest University Xi’an 710069 China

The foramtion and evolution of collisional orogen is a prominent feature along convergent plate margins, and is generally a complex process. This article presents an integrated study of zircon genesis, U-Pb age and Lu-Hf isotope composition as well as geological characteristics for the western Dabie orogen to constrain its multi-stage evolution history. The results suggest that the formation of oceanic crust in the Huwan area was constrained at ca. 400―430 Ma, which was slightly later than the collision of the northern Qinling with the North china Block. It formed in a marginal basin in the northern margin of the Yangtze Block. The peak metamorphism of eclogite in the Huwan area occurred at ca. 310 Ma, and the timing of the initial exhumation of oceanic eclogite was about 270 Ma. The high to ultrahigh pressure (HP-UHP) metamorphic rocks in the Xinxian and the Hong'an metamorphic zones have the same ages and natures as those of the HP-UHP metamorphic rocks in the other Dabie-Sulu terrains, and also have experienced multi-stage exhumation, and thus can be taken as a coherent part of the Dabie-Sulu orogen. Therefore, the Qinling-Dabie-Sulu orogen is a typical multi-stage continental collision orogen, with an amalgamation process extending more than 200 Ma.

关键词：大别造山带大陆碰撞西部演变超高压变质岩碰撞造山带苏鲁造山带变质岩区

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The Upper Devonian orbital cyclostratigraphy and numerical dating conodont zones from Guangxi,South china

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Science china Earth sciences 2005年第1期48卷 32-41页

作者： GONG Yiming, XU Ran, TANG Zhongdao & LI Baohua Faculty of Earth Science, china university of geosciences, wuhan 430074, china laboratory of Marine Geology, Tongji university, Shanghai 200092, china 1. Faculty of Earth Science China University of Geosciences 430074 Wuhan China 2. laboratory of Marine Geology Tongji University 200092 Shanghai China

The hierarchically organized laminae, bundles, bundlesets and superbundlesets which correspond to a sub-Milankovitch, obliquity or precession, eccentricity and long eccentricity cyclothems, respectively, have been distinguished from the Upper Devonian Fras-nian-Famennian (F-F) transitional carbonate successions deposited in the carbonate-basin and slope facies of Guangxi, South china. The durations of cyclothems are 8000-10000a, 16667a or 33333a, 100000a and 400000a, respectively. The ratio of eccentricity to precession, eccentricity to obliquity, and long eccentricity to eccentricity is 1 : 6, 1 : 3 and 1 : 4 in the Devonian, respectively. Orbital cyclostratigraphical studies show that the durations of the conodont falsio-valis Zone, transitans Zone, punctate Zone, Lower hassi Zone, Upper hassi Zone, jamieae Zone, Lower rhenana Zone, Upper rhenana Zone, linguiformis Zone, Lower triangularis Zone, Middle triangularis Zone and Upper triangularis Zone are 0.4, 0.4, 0.4, 0.3, 0.4, 0.2, 0.8, 0.6, 0.8, 0.3, 0.3 and 0.3 Ma from bottom to top, respectively, and the duration of the Frasnian is 4.3 Ma. The conodont is the normal marine organism of the latest mass extinction (the latest linguiformis Zone) and the first recovery (including the whole Lower triangularis and Middle triangularis Zone) in the F-F transition. The conodont mass extinction and recovery lasted 200000-100000a and 0.6 Ma, respectively. We consider that average durations of the fossil zones calculated by reported numerical ages divided by fossil zone numbers within a stage or series or system cannot discovery complications and non-uniformity of evolutionary organisms and environments.

关键词： orbital cyclostratigraphy, conodont zone, numerical dating, mass extinction, Devonian, Guangxi, South china.

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Arsenic Biomobilization from Aquifer Sediments by Indigenous Bacteria at Datong Basin and Hetao Plain,Northern china

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地学前缘 2009年第S1期16卷 4-5页

作者： Zuoming Xie,Yanxin Wang School of environmental Studies & MOE Key laboratory of Biogeology and environmental Geology,china university of geosciences(wuhan),wuhan 430074,china.

High arsenic groundwater is widely distributed at Datong Basin and Hetao Plain,northern *** investigate the effects of microbial activities on arsenic mobilization in the two high arsenic regions,the microcosm experiments were performed under various conditions of two bacterial strains(XZM001 and YH001,isolated from the two shallow aquifer sedi-

关键词： biomobilization indigenous bacteria As

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Permian carbonates of Baoshan block, Western Yunnan and their paleoclimatic implications

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Science china Earth sciences 2004年第5期47卷 385-392页

作者： YAN Jiaxin1, LIANG Dingyi1 & WU Ming2 1. Faculty of Earth sciences, china university of geosciences, wuhan 430074, china 2. College of Chemistry and Life sciences, South-Central university for Nationalities, wuhan 430074, china china Univ Geosci Fac Earth Sci Wuhan 430074 Peoples R China S Cent Univ National Coll Chem & Life Sci Wuhan 430074 Peoples R China

Recently, much attention has been paid to the climatic significance of carbonates originating in shallow water. Permian carbonates of shallow shelf origin are present in the upper part of the Dingjiazhai Formation, the upper part of the Yongde Formation, and the Shazipo Formation on the Baoshan block of Western Yunnan. Their skeleton and non-skeleton grain as-sociations have been investigated in this study. The carbonates of the Dingjiazhai Formation indicate a Bryonoderm (bryozoans-echinoderm) association without non-skeleton grains. The carbonates of Yongde and Shazipo formations show Chloroforam (green algae-foraminifers) association with peloids. Oolites develop in the Shazipo Formation. Based on the comparisons of grain association with coeval carbonates formed in different paleolatitudes (i.e. various paleo-climatic zones), the carbonates of the Dingjiazhai Formation were thought to have been accu-mulated in shelf environments of warm-temperate zone, and those of the Yongde and Shazipo formations in shelf environments of warm-water.

关键词： Early Permian, carbonate, paleoclimate, Western Yunnan.

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