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Effect and mechanism of stresses on rock permeability at different scales

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Science china Earth Sciences 2006年第7期49卷 714-723页

作者： YIN Shangxian1 & WANG Shangxu2 1. Safety Engineering College, North china institute of Science and Technology, Yanjiao, beijing 101601, china 2. Key Laboratory of Geophysics exploration, china University of petroleum, beijing 100083, china Safety Engineering College North China Institute of Science and Technology Yanjiao Beijing China Key Laboratory of Geophysics exploration China University of Petroleum Beijing China

The effect of geo-stress fields on macroscopic hydro-geological conditions or micro-cosmic permeability of water-bearing media should follow some laws or principles. Cases study and tests show that: (1) At macro-geologic large scale, deformed and crashed rocks which were induced by geo-stress fields changing provided space for groundwater storage and flow. Groundwater adjusts water-bearing space and dilatants fractures by flowing and press transferring. Coupling of liquid and solid can be implemented for rocks and groundwater. Although tectonic fields witness several times of change and build-up in geological time, stress fields forming regional tectonic framework are coherent with seepage fields, orientation of the maximum horizontal stress demonstrates main seepage direc-tions. (2) At macro-geologic middle scale, zones of stresses changing sharply, quite low stresses, stress or shear concentration can be used to show locations and types of main fractures, zones of geo-stresses changing equably can be acted as normal base media zones of tri-porosity media. (3) At micro-geologic small scale, tri-porosity media include fractured rocks, porous rocks and capillary rocks. Investigations indicate that porosity or permeability is functions of effective stresses, and po-rosity or permeability changing rules of porous rocks with variation of effective stresses can be de-scribed as the index model, the model of power exponent functions is suitable for those of fractured rocks, the model of the second power parabola for capillary rocks. The porosity and permeability loss in fractured rocks, which are greater than that in porous rocks, are shown by calculation of effective compressive coefficient and closing pressure in cracks. The calculations can also explain the mecha-nism why porosity changes are always larger than permeability changes. It is proved by the thick wall cylinder theory that the second power parabola relation between porosity or permeability loss and effective

关键词： geo-stress fields, seepage fields, tri-porosity media, effective stresses, permeability, porosity,scale.

Geochemical characteristics of pyrolysis gas from epimetamorphic rocks in the northern basement of Songliao Basin,Northeast china

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Science china Earth Sciences 2008年第S1期51卷 140-147页

作者： YANG Chun 1 ,LUO Xia 2 ,LI Jian 2 ,LI ZhiSheng 2 ,LIU QuanYou 3 &Wang YuLin 4 1 Department of Earth Sciences,Zhejiang University,Hangzhou 310027,china 2 Research institute of petroleum exploration and Development(Langfang Branch),Langfang 065007,china 3 Research institute of petroleum exploration and Development,beijing 100083,china 4 Department of Source and Environment,Liaoning Technical University,Fuxin 123000,china Department of Earth Sciences Zhejiang University Hangzhou China Research institute of petroleum exploration and Development (Langfang Branch) Langfang China Research institute of petroleum exploration and Development Beijing China Department of Source and Environment Liaoning Technical University Fuxin China

The Xushen gas field,located in the north of Songliao Basin,is a potential giant gas area for china in the *** proved reserves have exceeded 1000×10 8 m 3 by the end of ***,the origin of natural gases from the deep strata is still in *** rocks as a potential gas source are widely spreading in the northern basement of Songliao *** to pyrolysis experiments for these rocks in the semi-confined system,gas production and geochemistry of alkane gases are discussed in this *** Carboniferous-Permian epimetamorphic rocks were heated from 300℃to 550℃,with temperature interval of 50℃.The gas production was quantified and measured for chemical and carbon isotopic *** show thatδ13C 1 is less than?20‰,carbon isotope trend of alkane gas isδ13C 1 δ13C 3 ,these features suggest that the gas would be coal-type gas at high-over maturity,not be inorganic gas with reversal trend of gaseous alkanes (δ13C 1 >δ13C 2 >δ13C 3 ).These characteristics of carbon isotopes are similar with the natural gas from the basin basement,but disagree with gas from the Xingcheng ***,the mixing gases from the pyrolysis gas with coal-typed gases at high-over maturity or oil-typed gases do not cause the reversal trend of carbon *** gas generation intensity for epimetamorphic rocks is 3.0×10 8 ―23.8×10 8 m 3 /km 2 ,corresponding to Ro from 2.0%to 3.5%for organic matter.

关键词： Northern Songliao Basin epimetamorphic rock pyrolysis experiment gas generation potential carbon isotope

Classification and origin of natural gases from Lishui Sag,the East china Sea Basin

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Science china Earth Sciences 2008年第S1期51卷 122-130页

作者： CHEN JianPing 1,2 ,GE HePing 3 ,CHEN XiaoDong 3 ,DENG ChunPing 1,2 &LIANG DiGang 1,2 1 Research institute of petroleum exploration&Development,Petrochina,beijing 100083,china 2 Key Lab of petroleum Geochemistry,CNPC,beijing 100083,china 3 Shanghai Division,CNOOC,Shanghai 200030,china Research institute of petroleum exploration & Development PetroChina Beijing China Key Lab of petroleum Geochemistry CNPC Beijing China Shanghai Division CNOOC Shanghai China

Natural gases discovered up to now in Lishui Sag,the East china Sea Basin,differ greatly in gaseous compositions,of which hydrocarbon gases amount to 2%―94%while non-hydrocarbon gases are dominated by *** hydrocarbon gases,without exception,contain less than 90%of methane and over 10%of C2 + heavier hydrocarbons,indicating a wet *** isotopic analyses on these hydrocarbon gases showed thatδ13C 1 ,δ13C 2 andδ13C 3 are basically lighter than-44‰,-29‰and-26‰, *** difference in carbon isotopic values between methane and ethane is great,suggesting a biogenic oil-type gas produced by the mixed organic matter at peak generation.δ13C CO2 values of nonhydrocarbon gases are all heavier than-10‰,indicating a typical abiogenic *** simulation experiment on hydrocarbon generation of organic matter in a closed gold-tube system showed that the proportion of methane in natural gases produced by terrigenous organic matter in the Lingfeng Formation marine deposit is obviously higher than that in natural gases derived from the aquatic and terrigenous mixed organic matter in the Yueguifeng Formation lacustrine deposit,consequently the proportion of heavier hydrocarbons of the former is remarkably lower than that of the ***, δ13C 1 values of natural gases produced by terrigenous organic matter in the Lingfeng Formation marine deposit are about 5‰heavier than those of natural gases derived from the aquatic and terrigenous mixed organic matter in the Yueguifeng Formation lacustrine deposit whileδ13C 2 andδ13C 3 values of the former are over 9‰heavier than those of the *** the LS36-1 oil-gas pool is the only commercial oil-gas reservoir in Lishui Sag,where carbon isotopic compositions of various hydrocarbon components differ greatly from those of natural gases produced by the Lingfeng Formation organic matter but are very similar to those of natural gases derived from the Yueguifeng Formation organic matter,therefore,natural gases in the

关键词： Lishui Sag natural gas biogenesis abiogenesis lacustrine source rock marine source rock coal-measures source rock

Physical simulation of fluid flow and production performance in extra-low permeability porous media

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petroleum Science 2009年第4期6卷 415-420页

作者： You Yuan Yue Xiang’an Li Mingyi Zhao Chunpeng Zhang Tao Key Laboratory of petroleum Engineering Ministry of EducationChina University of PetroleumBeijing 102249China Enhanced Oil Recovery Research Center China University of PetroleumBeijing 102249China Jilin Oil Field PetroChinaSongyuanJilin 138000China exploration&production Research institute SinopecBeijing 100083China exploration Department Changqing Oil FieldPetroChinaXi’anShaanxi 710018China

For extra-low permeability reservoirs, with a permeability of about 0.3×10?3 μm2, fluid flow and production performance in cores were studied. A long core holder with a multi-location piezometric measurement was specially designed. An artificial long core, about 700 mm long and with a cross section of 45mm×45mm, was used. In the experiment, pressure distribution along the core can be measured in real time. Single phase flow in the core was investigated. Different modes of production in long cores were also simulated including natural depletion, water flooding, and advanced water flooding. Through physical simulation, flow parameters were collected and production characteristics in extra-low permeability cores were studied. From experimental results, it can be seen that fluid flow in extra-low permeability cores is different from that in high permeability cores. Transmission of pressure in extra-low permeability cores is very slow, and it needs a long time for the pressure to become stable. The distribution curve of pressure along the core is nonlinear and the production rate in extra-low permeability reservoirs decreases sharply. The development effects of different production modes in extra-low permeability cores were compared with one another. Among the production modes, advanced water flooding has much potential for effective development of extra-low permeability reservoirs. Natural depletion and conventional water flooding can also be used in early production periods. In addition, the countermeasures and some ideas especially for the potential development of extra-low permeability reservoirs are suggested.

关键词： Extra-low permeability reservoirs physical simulation fluid flow production performance

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中国油气资源潜力及勘探战略

石油学报 2004年第2期25卷 1-6页

作者：潘继平金之钧石油大学盆地与油藏研究中心北京102249 中石化勘探开发研究院北京100083

保障经济的持续高速发展给油气资源勘探开发提出了更高的要求。在石油供求矛盾日益突出的新形势下 ,加强油气勘探 ,实现资源战略接替 ,增储上产 ,增强国内油气资源对经济社会可持续发展的保障能力已迫在眉睫。近年勘探实践和资源评价表... 详细信息

保障经济的持续高速发展给油气资源勘探开发提出了更高的要求。在石油供求矛盾日益突出的新形势下 ,加强油气勘探 ,实现资源战略接替 ,增储上产 ,增强国内油气资源对经济社会可持续发展的保障能力已迫在眉睫。近年勘探实践和资源评价表明 ,我国沉积盆地发育 ,油气资源总量多 ,勘探潜力较大 ,但勘探难度加大。为此提出了“深化东部 ,加强西部 ,加快海上 ,开拓新区”

关键词：中国油气资源油气勘探资源潜力勘探战略

A Study of Sedimentary Environment and Reservoir Quality of the Carboniferous Donghe Sandstonein the Tarim Basin

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Acta Geologica Sinica(English Edition) 1996年第4期70卷 395-406,454页

作者： Gu JiayuResearch institute of petroleum exploration and Development, beijing Research institute of petroleum exploration and Development Beijing

Very thick, fine-grained quartzose sandstone of the Lower Carboniferous (called the Donghe sandstone) was discovered in Donghe-1 well in the Tarim basin. Highly-productive commercial oil and gas flows were obtained when a well completion test was conducted. This important discovery proved that the quartzose sandstone is a prospecting target with good prospects. After that, other two paying oil and gas flows were found in the Lower Carboniferous in the Tazhong-4 and Tazhong-10 structures (Tazhong means central Tarim), equivalent to the Donghe sandstone. The Tazhong-4 structural oil field is the biggest oil field ever discovered. Therefore it is of guiding importance in oil and gas exploration to deepen the study of sedimentary and reservoir features and the sedimentary environment of the Donghe sandstone and to build a sedimentary model in order to understand the reservoir distribution pattern.

关键词： Donghe sandstone sedimentary facies sedimentary model tempestite pore type dissolved pore

Stratigraphic thermohistory and its implications for regional geoevolution in the Tarim Basin,NW china

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Science china Earth Sciences 2010年第10期53卷 1495-1505页

作者： WANG TieGuan1,DAI ShiFeng2,LI MeiJun1,ZHANG WeiBiao1,3,Qiu NanSheng1 & WANG GuangLi1 1 State Key Laboratory of petroleum Resources and Prospecting,china University of petroleum,beijing 102249,china 2 State Key Laboratory of Coal Resources & Safe Mining,china University of Mining & Technology,beijing 100083,china 3 exploration Research Center,exploration & Development institute,china Petrochemical Corporation,beijing 100083,china State Key Laboratory of petroleum Resources and Prospecting China University of Petroleum Beijing China State Key Laboratory of Coal Resources & Safe Mining China University of Mining & Technology Beijing China exploration Research Center Exploration & Development Institute China Petrochemical Corporation Beijing China

Fourteen vitrinite reflectance profiles from the Tarim Basin,NW china,show that the vitrinite reflectance profiles of individual wells follow a faulted and dislocated dual-stage pattern in the eastern section of the Tazhong Uplift and in the Tabei *** reflectance values in these profiles change sharply at the unconformity beneath the Lower Carboniferous Bachu or Upper Devonian Donghetang Formations,where the overlying Triassic to Carboniferous strata are still in a mature phase within the "liquid oil window".However,the underlying Lower Paleozoic reached the overmature phase beyond the "liquid oil window" towards the end of the Silurian,or in the Early Devonian at the *** the vitrinite reflectance profiles are attributed to a continuous,single-stage pattern in the western section of the Tazhong Uplift,in which the Lower Paleozoic is also in an overmature phase,their overmaturity would have been achieved relatively late in geological *** stratigraphic thermohistory has the following implications to regional geoevolution:(1) The overmature Lower Ordovician to Cambrian strata in the eastern section of the Tazhong Uplift and in the Tabei Uplift,as well as in the Manjiaer Depression,could not have acted as the source kitchen for normal oil(so-called black oil);(2) The dissimilarity in vitrinite reflectance profiles between the eastern and western sections of the Tazhong Uplift reveals Early Paleozoic paleotectonic features,i.e.,lower at the east and higher at the west,whereas recent tectonic features formed since the Late Paleozoic are in reverse,i.e.,higher in the east and lower at the west;(3) Reconstruction of the denuded thickness of sediments overlying the Lower Ordovician strata suggests reconsideration on the paleotectonic features in the Tarim Basin;(4) Based on the sustained duration of the "liquid oil window" for overmature source beds,it is predicted that the Suntuoguole Lower Uplift between the Awati and Manjiaer Depressions is a

关键词： vitrinite reflectance profile faulted and dislocated dual-stage pattern paleotectonic features sustained "liquid oil window" period source kitchen

The components and carbon isotope of the gases in inclusions in reservoir layers of Upper Paleozoic gas pools in the Ordos Basin,china

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Science china Earth Sciences 2008年第S1期51卷 115-121页

作者： MI JingKui 1 ,DAI JinXing 1 ,ZHANG ShuiChang 1 ,ZHANG WenZheng 2 ,GONG Se 1 &LI XianQing 3 1 Research institute of petroleum exploration and Development,Petrochina,beijing 100083,china 2 exploration and Development Research institute of Petrochina Changqing Oilfield Company,Xi’an 710021,china 3 Key Laboratory of Coal Resources,Ministry of Education,china University of Miningand Technology,beijing 100083,china Research institute of petroleum exploration and Development PetroChina Beijing China exploration and Development Research institute of Petrochina Changqing Oilfield Company Xi’an China Key Laboratory of Coal Resources Ministry of Education China University of Miningand Technology Beijing China

The components and carbon isotope of gases in inclusions are one of the most important geochemical indexes for gas *** analysis results of the components and carbon isotope of gases from inclusions in reservoir layers of Upper Palaeozoic gas pools in the Ordos Basin show that most inclusions grown in reservoir sandstone are primary *** is only a little difference about the components and carbon isotope between the well gases and the secondary inclusions *** indicated that the epigenetic change of gas pools is *** difference between the well gases and the secondary inclusions gases is caused by two reasons:(i)The well gases come from several disconnected sand bodies buried in a segment of depth,while the inclusion gases come from a point of depth.(ii)The secondary inclusions trapped the gases generated in the former stage of source rock gas generation,and the well gases are the mixed gases generated in all the *** is irresponsible to reconstruct the palaeo-temperature and palaeo-pressure under which the gas pool formed using carbon dioxide inclusions.

关键词： Ordos Basin Upper Paleozoic inclusion gas components carbon isotope

Advances in DCC Process and Catalyst for Propylene production from Heavy Oils

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china petroleum Processing & Petrochemical Technology 2011年第1期13卷 1-5页

作者： Liu Yujian Long Jun Tian Huiping Xu Yun Zhao Liuzhou (Research institute of petroleum Processing,sinopec,beijing 100083) Research institute of petroleum Processing SINOPEC Beijing 100083 China

In the past several decades,sinopec has devoted continuously great efforts to the development of DCC technology,the only commercial process using heavy feeds aiming at propylene ***,a series of research breakthroughs have been achieved in molecular *** on the detailed analysis on the complex DCC reaction network,an innovative catalyst technology has been developed to Optimize Catalysis Kinetics (OCK in brief).The deep-cracking process can be improved with optimizing the availability of the active *** updated MFI and beta zeolites are used to boost the propylene *** latest generation catalyst DMMC-1 has been applied *** with the best historical records in the past,the propylene yield upon application of the catalyst DMMC-1 increases by 2.4 m% coupled with an improved distribution of *** DCC technology continues to assume a leading position for manufacturing propylene from heavy feedstocks.

关键词： petrochemical engineering propylene catalytic cracking catalyst catalysis kinetics