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Chinese Journal of Chemistry 1993年第1期11卷 21-29页

作者： LANG,Jian-Ping ZHU,Hui-Zhen XIN,Xin-Quan Department of Chemistry,Nanjing university,Nanjing 210008CHEN,Ming-Qin LIU,Kun ZHENG,Pei-Ju center of analysis and measurement,Fudan university,Shanghai 2004.3

Reactions of [NH_4._2[MS_4.(M=Mo,W),CuX(X=Br,I)and PPh_3 in the solid state produced four mixed-metal sulfur containing clusters{Cu_3MS_3X}(PPh_3)_3S(M=Mo,W;X=Br,I),two of which (1:M=Mo,X=I;2:M=W,X=Br)were structurally *** of 1 and 2 are triclinic, space group P(1:a=11.895(3),b=13.107(1),c=20.4.3(2),α=74.95(6),β=84.87(8),γ=64.27(7)°, Z=2,V=2776.1 ,Rw=0.064.for 64.3 observed reflections.2:α=11.876 (1),b=13.065 (2),c= 20.325(2),α=74.95(1),β=85.39(1),γ=64.09(1)°,Z=2,V=2737.3,R_w=0.055 for 5303 observed reflections).The results of the structure determination showed that the central units of the two cubane- like cluster compounds are composed of four metal atoms and four non-metal atoms situated at alter- nate *** differences of cubane-like cluster compounds obtained from solid state reactions and from solution reactions are discussed.

关键词： Solid state syntheses and crystal structures of cluster compounds and Cu3WS3Br PPh3 WS Br XL

Studies on solid state reactions of coordination compounds *** state syntheses of a family of Ag-Mo(W)-S cubane-like cluster compounds:Crystal structures of{Ag_3MoS_3I}(PPh_3)_3S and{Ag_3WS_3Cl}(PPh_3)_3S·0.5P(S)Ph_3·3H_2O^+

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Chinese Journal of Chemistry 1993年第2期11卷 126-136页

作者： LANG,Jian-Ping BAO,Shi-An ZHU,Hui-Zhen XIN,Xin-Quan Coordination Chemistry Institute,Nanjing university,Nanjing 210008YU,Kai-Bei Chengdu center of analysis and measurement,Chinese Academy of Sciences,Ckengdu 610015 1Coordination Chemistry Institute Nanjing University Nanjing 2100082Chengdu Center of Analysis and Measurement Chinese Academy of Sciences Chengdu 610015

Reactions of[NH_4._2[MS_4.(M=Mo,W),AgX(X=Cl,Br,I,CN,SCN)and PPh_3 in the solid state produced six new mixed-metal sulfur containing cluster compounds,two of which,{Ag_3MoS_3I}(PPh_3)_3S(1)and{Ag_3WS_3Cl}(PPh_3)_3S·0.5P(S)Ph_3·3H_2O(2),were determined by single crystal X-ray *** crystal data:1,triclinic,P(?),a=12.114.2),b=13.4.0(2), c=20.34.(3)(?),α=74.53(1),β=86.73(1),γ=63.74.1)°,Z=2,R=0.04. for 4.05 independent data;2,hexagonal,R3,a=b=16.201(3),c=4..091(10)(?),Z=6,R=0.04. for 2729 independent *** central unit{Ag_3MS_3X}(M=Mo,W;X=Cl,I)of the two compounds can be des- cribed as a slightly distorted cube,four corners being formed by the MS_4.(2-) ligand(with a ter- minal S atom).The remaining corners are occupied by one X(Cl or I)atom and three Ag atoms(with one PPh_3 ligand bound to each of the latter).The generation of different types of Ag-Mo(W)-S cluster compounds prepared from solid state reactions under different reaction temperatues is discussed.

关键词： Ag CI Mo WS

Synthesis of a new salt containing polyoxometallate anion and M-Cu-S cluster cation [MS_4.u_4.γ-MePy)_8][M_6O_19] (M = Mo,W).Crystal structure of [WS_4.u_4.γ-MePy)_8][W_6O_19]

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Chinese Journal of Chemistry 1995年第1期13卷 40-46页

作者： POPE, Michael T. Department of Chemistry, Georgetown university, Washington DC S0057, U.S.A.LANG, Jian-PingDepartment of Chemistry, Suzhou university, Suzhou, Jiangsu 215006, chinaXIN, Xin-Quan Coordination Chemistry Institute, Nanjing university, Nanjing, Jiangsu S1000S, chinaYU, Kai-BeiChengdu center of analysis and measurement, Chinese Academy of Sciences, Chengdu, Sichuan 61004., china Chengdu center of analysis and measurement Chinese Academy of Sciences Chengdu Sichuan 610041 China

Reactions of (NH4.2MS4. AgBr and CuBr in r-methylpyridine produced one new compound, [MS4.u4.r-MePy)8]M6O19] (1, M = W; 2, M = Mo), of which 1 was characterized by single crystal X-ray analysis. The crystal data: orthorhombic, Pbcn, a = 15.4.4.4.,b= 16.732(2), c = 28.657(7) A, V = 74.0.8(8) A3, Z = 4. R = 0.072 for 3121 independent data. The compound is the first example which contains both polyoxotnngstate anion and heteropolynuclear cluster cation. In the structure of the cation four edges of the tetrahedral WS4.- core are coordinated by four copper atoms, giving a WS4.u4.aggregate of approximate D2h symmetry. The differences between the reaction of Cu+ with MS4.- and that of Ag+ with MS4.- in pyridine and its derivatives are discussed.

关键词： Mo(W)-Cu-S cluster cation polyoxometallate anion crystal structure.

Synthesis and Crystal Structure of{(PPh_3)_2CIRuCIRu(PPh_3) B_(10)H_8[OCH(CH_3)_2)]_2}

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Chinese Journal of Structural Chemistry 1998年第1期17卷 13-17页

作者： YAO Hat-Jun LI Wen HU Chun-Hua DOU Jian-MinJIN Ruo-Shut HUANG Zu-En ZHENG Pei-Ju(Department of Chemimistry, Fudan university, Shanghai 2004.3)(Research center of analysis and measurement, Fudan Uniersity, Shanghai 2004.3) Department of Chemistry Fudan University Shanghai 200433 China Res. Ctr. of Anal. and measurement Fudan University Shanghai 200433 China

The title compound has been synthesized by the reaction of [RuCl2-(PPh3)3], closo-[B10H10]2- and PhCH(OH)COOH in (CH3)2CHOH solution. Crystalsof the title compound suitable for a single crystal X-ray diffraction analysis were recrystallized from n-pentane/CH2Cl2 solution. The crystal is monoclinic, space group P21,/n,Mr=1294. 19, with a=11. 591 (6), b=23. 993(4., c=24. 900(4. A, β=90. 52(2), V= 6925(4. A3, Dc= 1.24. g/cm3, Z=4. A(MoKa) =0. 71073 A, P=6. 2cm-1, F(000)=264., R=0. 04., wR2=0. 083, S=1. 09. The cluster is a bimetallicspecies in which the second ruthenium center is bound exopolyhedrally to the compound{(PPh3)2RuB10H8[OCH (CH3)2]2 } via an Ru (1) -C;(1)-Ru (2) bridge and Ru (2) B(6) and Ru(2)-B(7) bonds.

关键词： crystal structure metallaborane ruthenaborane

CRYSTAL STRUCTURE OF UO2（PMBP）2（H2O） THF

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结构化学 1986年第3期 166-171页

作者： Wang Ming Zheng Peiju Xu Jun Li Xingfu Yu Zhihui center of analysis and measurement, Fudan university, Shanghai Chemistry Department,{4., Hangzhou Application Department, The Institute of High Energy Physics, Academia Sinica, Beijing

C34.28N4.7U·C4.4. Mr=910.7, monoclinic, Cc, a=12.999(1), b=15.4.8(2), c=18.4.1(2) A, β=100.18(2)°, Z=4. DC=1.656 g/cm-3, V=3652.3 A3, final R = 0.035 for 34.7 observable reflections. Uranyl ion is coordinated equa... 详细信息

关键词： monoclinic coordinated distorted observable pyramid chelate jugate unsaturated rings 七八

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水仙花开放期间香气组分变化的研究

分析测试学报 2004年第5期23卷 110-113页

作者：黄巧巧冯建跃浙江大学分析测试中心浙江杭州310027

采用活性炭吸附丝累积采集水仙花花开过程中不同时段的活体香气成分 ,采用居里点裂解器热解吸直接导入色谱 -质谱仪进行定性定量分析 ,鉴定了苯甲醛、芳樟醇、柠檬烯、乙酸苄酯等55种香气组分 ,同时研究了水仙花开放过程中香气释放的变... 详细信息

采用活性炭吸附丝累积采集水仙花花开过程中不同时段的活体香气成分 ,采用居里点裂解器热解吸直接导入色谱 -质谱仪进行定性定量分析 ,鉴定了苯甲醛、芳樟醇、柠檬烯、乙酸苄酯等55种香气组分 ,同时研究了水仙花开放过程中香气释放的变化规律。本方法操作简单 ,无需进行样品的预处理 ,可以方便地进行鲜花“活体”

关键词：色谱-质谱水仙花香气成分香气变化吸附丝

STUDIES ON SOLID STATE REACTIONS OF COORDINATION COMPOUNDS(LXⅡ)Solid state synthesis and crystal structure of the complex ICu_(0.84.Au_(0.16)(PPh_3)_2(SC(Ph)NHPh)CIJ·0.5CS_2

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Chinese Chemical Letters 1992年第12期3卷 1027-1028页

作者： Shi An BAO Jian Ping LANG Xin Quan XIN Coordination Chemistry Institute,Nanjing university,Nanjing 210008Kai Bei YU Chengdu center of analysis and measurement,Academica Sinica,Chengdu 610015

[Cu_(0.84.Au_(0.16)(PPh_3)_2(SC(Ph)NHPh)Cl]·0.5CS_2=,Mr=895.79,monoclinic,space group P2_1/a,a=17.231(3),b=14.611(2),c=18.000(3) ,β=105.56(2)°,V=4.65(1) ~3, Z=4.D_c=1.37g/cm^3.,λ(MoK_α)=0.71073 ,μ=12.15cm^(-1),F(000)=1855,R=0.052, R_W=0.04. for 3930 observed reflections with Ⅰ>1.5σ(Ⅰ).The central metal atom has a dis. torted tetrahedral geometry with bond lengths Cu-S=2.384.2) (Au-S=2.389(4.), Cu-Cl=2.4.1(3)(Au-Cl=2.4.4.1))and Cu-P=2.269(2)-2.289(2)(Au-P=2.270(4.-2.279(4.) .

关键词： STUDIES ON SOLID STATE REACTIONS OF COORDINATION COMPOUNDS CS Ph)NHPh)CIJ Au LX PPh3 Solid state synthesis and crystal structure of the complex ICu SC

Induction of Hypersensitive Response and Nonhost Resistance by a Cladosporium fulvum elicitor CfHNNI1 is Dose-dependent and Negatively Regulated by Salicylic Acid

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Induction of Hypersensitive Response and Nonhost Resistance ...

CRYSTAL STRUCTURE OF UO2 （PMBP）2 （TBPO）（HPMBP=1-Phenyl-3-Methyl-4.Benzoylpyrazolone-5,TBPO=Bu4.O）

中国植物病理学会2012年学术年会

作者： XU You-Ping~(1.2) CHEN Hui-Ying~1 LU Lin-Hui~1 ZHOU Xin~1 CAI Xin-Zhong~(1**) (1.Institute of Biotechnology,College of Agriculture and Biotechnology, zhejiang university,Hangzhou 310058,.china 2.center of analysis and {4.,zhejiang university,Hangzhou 310058,.china)

＜正＞Nonhost resistance is a phenomenon that enables plants to protect themselves against the majority of potential pathogens,and thus has a great potential for application in plant *** recently found that CfHNNI1（for Cladosporium fulvum host and nonhost plant necrosis inducer 1 ） is an inducer of plant hypersensitive response（HR） and nonhost *** this study,its functional mechanism was ***1 was a single copy gene in *** *** functional ORF of the CfHNNI1 cDNA was ATG3～TAG780,which shown homology with genes encoding bZIP transcription factors. The functional ORF included in frame an inner one ATG273～TAG780,which was sufficient to induce HR in ***1 induced plant HR in a dose-dependent ***1-induced necrosis in NahG transgenic tomato plants was significantly stronger than in their wild type ***,that in Nr and defl tomato mutants was similar to that in their corresponding wild type *** data demonstrate that induction of HR and nonhost resistance by CfHNNI1 is negatively regulated by salicylic acid signalling pathway but independent of ethylene and jasmonic acid signalling pathways.

关键词： CfHNNI1 Cladosporium fulvum ethylene hypersensitive response jasmonic acid nonhost resistance salicylic acid

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结构化学 1989年第3期 173-176页

作者： Wang Ming Zheng Pei-Ju Xu Jun Lin Xing-Fu Yu Zhi-HuiResearch center of analysis and measurement, Fudan university, ShanghaiChemistry Department,{4. university,HangzhouApplication Department,The Institute of High Energy Physics, Acadenaa Sinica, Beijing

C4.H4.N4.7PU, Mr = 1033. 89, monoclinic space group C2/c,a= 24. 110(3),b= 16. 879(2),c=27. 751(4. A ,B=96. 69(1),V= 11216. 5A3,Z=8, Dc=1.224.gcm-2, (MoKa) = 0. 71073A,u= 28.123cm-1,F(000) = 511, final R = 0. 052 for 3806 observable reflections. The uranyl ion UO|+ in the title complex forms a distorted pentagonal bipyramidal geometry with five oxygen atoms in the equatorial plane from two PMBP and one TBPO groups.

关键词： PMBP CRYSTAL STRUCTURE OF UO2 TBPO

Identification of Genes Required for Cf-dependent hypersensitive response

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Identification of Genes Required for Cf-dependent hypersensi...