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Carbon isotope composition of the Lower Triassic marine carbonates, Lower Yangtze Region, South China

Science China earth sciences 2006年第3期49卷 225-241页

作者： ZUO Jingxun1,2. TONG Jinnan3, QIU Haiou4.& ZHAO Laishi3 1. Nanjing Institute of Geology and Palaeontology, Chinese Academy of sciences, Nanjing 2.0008, China 2. Henan Institute of Geological Survey, Zhengzhou 4.0007, China 3. State Key Laboratory of Geological Processes and Mineral Resources at China university of {2., wuhan 430074, China 4. {4. of Material sciences and Chemical Engineering, China university of {2., wuhan 430074, China 1. Nanjing Institute of Geology and Palaeontology Chinese Academy of Sciences Nanjing 210008 China 2. Henan Institute of Geological Survey Zhengzhou 450007 China 3. State Key Laboratory of Geological Processes and Mineral Resources at China university of geosciences Wuhan 430074 China 4. faculty of Material {2. and Chemical Engineering China University of Geosciences Wuhan 430074 China

Studies on three Lower Triassic sections located on the shallow water platform, the deep water slope and in the deep water basin in the Lower Yangtze Region, South China, show the similar trend of carbon isotope evolution. Biostratigraphic correlations among the Lower Triassic sections on the basis of standard conodont zones indicate that three negative shifts occurred in the Griesbachian, the Smithian and the late Spathian stages respectively, and one distinctly positive shift occurred in the early Spathian stage. Trend of carbon isotope evolution of the Lower Triassic reflects some significant changes in the global carbon cycle. Moreover, δ 13C background values are intensively controlled by palaeogeographic environment. In general, δ 13C values from deep-water slope carbonates are lighter than those from carbonate platform and heavier than those from deep-water basin carbonates. The positive carbon isotope excursion may be induced by a significant amount of organic carbon burial in marine sediments and increase in primary productivity. The large negative carbon isotope excursions during the Early Triassic in Lower Yangtze Region are interpreted to relate to volcano eruptions based on tuffaceous claystone interlayers observed near the Permian-Triassic boundary, the Induan- Olenekian boundary and the Lower Triassic-Middle Triassic boundary.

关键词： Lower Triassic, carbon isotope compositions, palaeogeography, volcanic eruptions, Lower Yangtze Region.

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Anatexis in Himalayan crust:Evidence from geochemical and chronological investigations of Higher Himalayan Crystallines

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Science China earth sciences 2005年第9期48卷 1347-1356页

作者： YANG Xiaosong1, JIN Zhenmin2.& MA Jin1 1. State Key Laboratory of earthquake Dynamics, Institute of Geology, China earthquake Administration, Beijing 10002., China 2. {2. of earth {4., China university of geosciences, wuhan 430074, China 1. State Key Laboratory of earthquake Dynamics Institute of Geology China Earthquake Administration 100029 Beijing China 2. faculty of earth {2. China University of Geosciences 430074 Wuhan China

Migmatization in Higher Himalayan Crystallines (HHC) results from anatexis. The widely distributed migmatites in HHC are an important clue to investigate the relationship be- tween anatexis and the origins of Higher Himalayan leucogranites (HHL), and to understand the effect of anatexis on crustal evolution during the post-collision period. We studied in detail the chemical features of three basic constituent parts of the migmatites, i.e. leucosome, mesosome and melanosome, and determined the K-Ar ages of leucosomes. Our studies indicate that type-I leucosome is the product of crystallization of melt generated by partial melting of mesosome at source region, but type-II leucosome and HHL probably underwent crystallization differentiation of plagioclase during melt aggregation and migration. The age of 2..67 Ma of Type-I leucosome, which is a little older than the beginning of MCT movement, indicates that anatexis may have played an important role in the formation of MCT. That the ages of type-II leucosome (ranging from 14.82.to 18.37 Ma) are consistent with that of HHL provides new chronological evidence for the relationship between migmatization and HHL. We obtained a very young age of 6.2. Ma of Type-II leucosome that provides new time constraint on magma activity in the central segment of Higher Himalayas.

关键词： Higher Himalayan Crystallines, migmatite, anatexis, leucosome, K-Ar age.

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Petrogenesis and dating of the Kangding complex,Sichuan Province

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Science China earth sciences 2005年第5期48卷 622-634页

作者： CHEN Yuelong 1 , LUO Zhaohua 1 , ZHAO Junxiang, LI Zhihong, ZHANG Hongfei & SONG Biao 3 1. faculty of earth {2. and Natural Resources, China university of {4., Beijing 100083, China 2. faculty of earth {2., China university of {4., wuhan 430074, China 3. Beijing SHRIMP Center, Institute of Geology, Chinese Academy of Geological {2., Beijing 100037, China 1. faculty of earth {2. and Natural Resources China University of Geosciences 100083 Beijing China 2. faculty of earth {2. China University of Geosciences 430074 Wuhan China 3. Beijing SHRIMP Center Institute of Geology Chinese Academy of Geological Sciences 100037 Beijing China

An analysis of major and trace element geochemistry and SHRIMP U-Pb zircon dating of mafic, intermediate, and felsic rocks from the Mianning metamorphic complex of Si- chuan Province was conducted. One of our conclusions is that a majority of the zircons crystal- lized between 72. and 773 Ma in a magmatic regime. The complexes contain early to late Pa- leo-proterozoic relict zircons from ancient continental crust. The oldest age, 2.0}8 Ma, may rep- resent the basement of the Yangtze block. Overgrowth zircon rims and palingenetic zircons have been observed and dated, and are believed to have formed after crystallization, during Paleozoic and Mesozoic metamorphic-anatexis. We also conclude that depletion of Nb, Ta, HREE, in a spider-diagram normalized to primitive mantle and calc-alkaline association, implies that they formed in island-arc or under-plating settings.

关键词： Kangding complex, zircons, SHRIMP, tectonic setting.

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Indian Ocean-MORB-type isotopic signature of Yushigou ophiolite in North Qilian Mountains and its implications

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Science China earth sciences 2006年第6期49卷 561-572页

作者： HOU Qingye1,2. ZHAO Zhidan1,2. ZHANG Hongfei3, ZHANG Benren3 & CHEN Yuelong2.1. State Key Laboratory of Geological Processes and Mineral Resources, China university of geosciences, Beijing 100083, China 2. School of {2. Science and Mineral Resources, China university of geosciences, Beijing 100083, China 3. faculty of {2. sciences, China university of geosciences, wuhan 430074, China 1. State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Beijing 100083 China 2. School of earth Science and Mineral Resources China University of Geosciences Beijing 100083 China 3. faculty of earth {2. China University of Geosciences Wuhan 430074 China

In order to explore the disputed issue concerning the tectonic affinity ofthe ancient ocean mantle of North Qilian Mountains (NQM), geochemical and Sr, Nd, Pb isotopiccompositions of pillow basalts of the Yushigou Ophiolite (YSGO) suite from NQM have been analyzedsystematically. The pillow basalts exhibit tholeiitic characteristics, with flatchondrite-normalized REE patterns ((La/Yb)_N = 0.98—1.2.). They display no Nb, Ta, Zr, Hf negativeanomalies, and show MORB features in 2.b-Zr/4.Y and Ti/100-Zr-YX3 tectonic discrimination *** results indicate that the Yushigou ophiolite is most likely to be formed in a mid-ocean ridgeor mature back-arc basin. Their isotopic data show a relatively broad and enriched ^(87)Sr/^(86)Sr(0.70509 — 0.70700), restricted ^(14.)Nd/^(14.)Nd (0.512.55-0.512.78). Pb isotopes are in the rangeof ^(2.6)Pb/^(2.4.Pb (18.054.2..562., ^(2.7)Pb/^(2.4.Pb (15.537-15.74.) and ^(2.8)Pb/^(2.4.Pb(38.068-38.530). These isotopic data imply that the basalts originated from the depleted mantle(DMM), with the involvement of enriched mantle components (mainly EMII). Geochemical comparisonsbetween the basalts in YSGO and the MORB-type basalts of ophiolite suites occurring in the knownancient Tethyan tectonic domain indicate that the ancient oceanic mantle represented by YSGO suiteforming in early Paleozoic in the North Qilian Moutains is very similar to the Tethyan mantle inboth trace elements and isotopic compositions. The North Qilian Mountains should be a part of theTethyan tectonic domain in early Paleozoic. This further implies that the Tethyan tectonic domaincan be deduced to early Paleozoic in the study area, which will be helpful to discussing thetectonic affinity and evolution of the North Qilian Mountains.

关键词： geochemistry, Indian Ocean-MORB-type isotopic signatures, Tethyan tectonic domain, Yushigou ophiolite, North Qilian Mountains.

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Analytical method of Cr stable isotope and its application to water pollution survey

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Chinese Science Bulletin 2010年第7期55卷 664-669页

作者： GAO YongJuan 1,2,3,MA Teng 4.5,LING WenLi 1,2,LIU CunFu 4.5 & LI Li 4.5 1faculty of earth Science,China {2. of geosciences,{4. 430074,China 2State Key Laboratory of Geological Processes and Mineral Resources,China {2. of geosciences,{4. 430074,China 3 Graduate School,China {2. of geosciences,{4. 430074,China 4.Biogeological and Environmental Geology Laboratory of Ministry of Education(China {2. of geosciences) ,{4. 430074,China 5 Sino-Hungary Joint Laboratory of Environmental sciences and Health,China {2. of geosciences,{4. 430074,China faculty of earth Science China University of Geosciences Wuhan 430074 China State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Wuhan 430074 China Graduate School China University of Geosciences Wuhan 430074 China Biogeological and Environmental Geology Laboratory of Ministry of Education (China university of geosciences) Wuhan 430074 China Sino-Hungary Joint Laboratory of Environmental sciences and Health China University of Geosciences Wuhan 430074 China

High Cr(VI) concentration is a potential serious risk to environment and ecologic ***,it is essential to effectively monitor Cr contamination in water systems and scientifically evaluate its evolution trend.A new method of in-situ tracer technique by Cr isotopic analysis for quantitatively estimating Cr-contamination and its regional evolution in natural waters as well as a case application are reported in this *** on documented literatures,an experimental procedure for chemical separation and purification of Cr in water samples and its analytical method for Cr isotopic measurement by thermal ionization mass spectrometry(TIMS) are *** samples collected around a chemical factory in Hubei Province were analyzed by this *** samples showδ53Cr values ranging from-1.7‰to 7.3‰and an elevating trend with an increasing in distance from the sampling site to pollution source.A functional correlation following Rayleigh fractionation law was established between sample'sδ53Cr value and its extent of Cr *** study suggests that Cr isotopic analysis is an effective method to reveal the spatial distribution and its evolution trend of Cr contamination in the regional water *** is thus helpful to assessing the self-purifying ability of local water system according to Cr isotopic fractionation.

关键词：铬(VI) 水污染调查稳定同位素应用同位素分析供水系统演变趋势示踪技术

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Mesozoic radiolarian chert from the middle sector of the Yarlung Zangbo suture zone,Tibet and its tectonic implications

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Science China earth sciences 2006年第4期49卷 348-357页

作者： ZHU Jie1,2. DU Yuansheng1, LIU Zaoxue2. FENG Qinglai1, TIAN Wangxue2. LI Jinping2.& WANG Changping2.1. faculty of earth {2.,China university of Geology,{4., China 2. Hubei Institute of Regional Geology Survey, wuhan 4.0034. China 1. faculty of earth {2. China University of Geology Wuhan 430074 China 2. Hubei Institute of Regional Geology Survey Wuhan 430034 China

Three radiolarian fauna, aged as the Middle-Late Triassic, Late Jurassic-Early Creta- ceous and Cretaceous radiolarian fauna, have been recognised in the radiolarian cherts from the middle sector of the Yarlung Zangbo suture zone, southern Tibet, China. The average contents of SiO2.in the radiolarian cherts of the Middle-Late Triassic and Late Jurassic-Early Cretaceous are 90.2.0} and 92.58% respectively, with average ratios of Al/(Al+Fe+Mn) as 0.75 and 0.74.respectively, the average ratios of MnO/TiO2.as 0.36 and 1.2.0} the average ratios of Ce/Ce* as 1.15 and 1.03, and the average ratios of LaN/CeN as 0.85 and 0.93. These geochemical features indicate that both of them are biogenic, deposited in a continental margin basin. The SiO2.content of the Early Cretaceous radiolarian chert is 94.12., with the ratio of Al/(Al+Fe+Mn) as 0.59, ratio of MnO/TiO2.as 4.30, ratio of Ce/Ce* as 0.60, ratio of LaN/CeN as 1.59, which imply that the chert is biogenic and was deposited in a pelagic basin. The Middle-Late Triassic association of the radiolarian chert and turbidites as well as their geochemical characteristics indicates the existence of a strong rifting marginal basin in the belt of the Yarlung Zangbo River then. The association of radiolarian chert and bedded basalt indicate an initial Tethyan ocean basin in southern Tibet during the Late Jurassic-Early Cretaceous. The early Cretaceous radiolarian chert coexisting with pillow basalt in top of the ophiolite suite represents sediments from the oceanic Tethyan basin.

关键词： radiolarian chert, sedimentary geochemistry, Mesozoic, Yarlung Zangbo suture zone, Tibet.

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Science China earth sciences 2004年第10期47卷 896-911页

作者： ZHANG Changhou1,2. WU Ganguo1,2. WANG Genhou2. ZHANG Weijie2.& SONG Honglin2.1. Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology, China university of geosciences, Ministry of Education of China, Beijing 100083, China 2. School of {2. sciences and Mineral Resources, China university of geosciences, Beijing 100083, China 1. Key Laboratory of Lithospheric Tectonics and Lithoprobing Technology China University of Geosciences Ministry of Education of China 100083 Beijing China 2. School of earth sciences and Mineral Resources China University of Geosciences 100083 Beijing China

The northwest trending tectonic belt in the middle part of the Mesozoic intraplate Yanshan Orogenic Belt, northeast Hebei Province, is composed of thrusts, extensional faults, strike-slip faults and syntectonic sedimentations as well. The northeastward basement-involved major thrusting deformation occurred between 174.a and 168MaBP and was followed by an intrusion of the granitic plutonic rocks. As a part of the post-thrusting extensional deformations a northwest extending volcano-sedimentation system of Late Jurassic and Early Cretaceous formed in the southwest side of the belt. These volcano-sedimentary sequences are divided into Tuchengzi Formation, Zhangjiakou Formation, Yixian Formation and Jiufotang Formation re- spectively. They are characterized by southeastward migration as a result of the increasing down-dip slip displacement along the major extensional fault toward the southeast of the belt. The provenance area of the Jiufotang Formation north to it experienced southwestward thrusting during and after its later sedimentation. The thrusting in this stage resulted in the formation of an asymmetric footwall syncline with vergence to SW in the Jiufotang Formation in the NE side of the basin. Finally a dextral strike-slip deformation occurred along the NW tectonic belt. The striking tectono-geomorphological features and present seismic activities along this belt indicate that it has been being active since Cenozoic era and is still in the active state at present. This northwest extending tectonic belt was following the same direction and location as the existing fault systems within the basement as revealed by former geological and geophysical studies. So it is reasonable to infer the Mesozoic deformation along this belt to be a result of reactivation of the basement structures in a favorable tectonic stress field. The reactivation of basement struc- tures might be taken as one of the mechanisms of intraplate deformation and orogeny.

关键词： Yanshan Orogenic Belt, northwest extending tectonic complex, thrust system, geochronology.

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Lithospheric seismic fabrics of Sulu ultrahigh-pressure metamorphic belt

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Science China earth sciences 2005年第5期48卷 585-600页

作者： YANG Wencai 1 , YANG Wuyang 1 , JIN Zhenmin 2.& CHENG Zhenyan 1 1. Institute of Geology, Chinese Academy of Geological sciences, Beijing 100037, China 2. China university of {2., wuhan 430074, China 1. Chinese Academy of Geological sciences Institute of Geology 100037 Beijing China 2. China university of geosciences 430074 Wuhan China

Calibration of seismic reflectors appearing in the crust of the Chinese continent sci- entific drilling site can be completed through the correlation studies between direct evidences, such as the drill cores, and geophysical signatures; therefore the interpretation of geophysical data could produce reliable results of crustal structure and composition. On the other hand, there are two Cenozoic volcanoes close to the scientific drilling site; analyzing composition of xenoliths existent in the volcanoes and evaluating their seismic velocities can also offer information about the mantle and lower crust. After the calibration via cores and well-logging data, the seismic re- flectors appearing in the UHP belt can be caused by lithological changes within the UHP rock slice, ductile shearing rock-suites, and later fracture zones. Among these sources, ductile shearing resulted in displacement and detachment of original rock-sheets, producing some rock-interbeds of several hundred meters thick that are named the ductile shearing rock-suites. A suite consists of mylonized gneiss and eclogite slices that underwent shearing, becoming the major mechanism responsible to generate regional strong reflections. The UHP rock-slice is characterized by complicated structures and high density, high seismic velocity and high electri- cal resistivity, its thickness is usually less than 11 km. Velocity and density of the gneiss-layer beneath gradually tend to normal with increasing depth. Based on the xenoliths we can infer that the middle crust contains a lot of gneisses, and the lower crust consists of different granulites. The lithospheric mantle has multi-layer structures and consists mainly of spinal lherzolite and harzburgite, implying late Mesozoic lithospheric thinning. The seismic fabrics with different ori- gins were possible products of different geodynamic processes. For instance, the UHP rock-slice was produced by the UHP metamorphic process and the exhumation of subducted supe

关键词： deep seismic reflection, ultrahigh-pressure belt, Sulu China, calibration of reflectors, lithospheric fabrics.

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Sedimentary geochemistry of the Cambrian-Ordovician cherts: Implication on archipelagic ocean of North Qilian orogenic belt

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Science China earth sciences 2007年第11期50卷 1628-1644页

作者： DU YuanSheng1,2. ZHU Jie1, GU SongZhu1, 2. XU YaJun1 & YANG JiangHai1 1 faculty of earth {2., China university of {4., wuhan 430074, China 2.Key Laboratory of Biogeology and Environment Geology of Education Ministry, wuhan 430074, China 1. faculty of earth {2. China University of Geosciences Wuhan 430074 China 2. Key Laboratory of Biogeology and Environment Geology of Education Ministry Wuhan 430074 China

The Caledonian North Qilian orogenic belt lies between the North China plate and the Qaidam mi-croplates, and resulted from the collision among the Qaidam microplate, mid-Qilian block and the North China plate. The orogen initiated from the rifting of the Late Proterozoic Rodinia, and then it experi-enced stages of Cambrian rift basin and Ordovician archipelagic oceanic basin, and foreland basin during Silurian to Early-Middle Devonian. The average ratios of Al/(Al+Fe+Mn), Al/(Al+Fe), δ Ce, Lan/Ybn and Lan/Cen from cherts of Cambrian Heicigou Formation are 0.797, 0.62., 1.114. 0.994.and 1.034.re-spectively. In the NAS standardized REE distribution pattern, the cherts from Xiangqianshan is slightly HREE enriched, and the cherts from Ganluci and Shiqingdong are plane. All of these features indicated that Cambrian cherts of the Heicigou Formation originated from a continental margin rift background. On the contrary, the average ratios of Al/(Al+Fe+Mn), Al/(Al+Fe), δ Ce, Lan/Ybn, Lan/Cen of the Ordovician chert from Dakecha, Cuijiadun, Shihuigou, Laohushan, Heicigou, Maomaoshan, Bianmagou, Da-chadaban, Baiquanmen, Jiugequan and Angzanggou, are respectively 0.72. 0.58, 0.99, 1.09 and 0.96 respectively. Their NAS standardized REE distribution patterns of most Ordovician cherts are plane mode or slightly HREE enriched. The REE distribution pattern of few samples of cherts are slightly LREE enriched. Characteristics of sedimentary geochemistry and tectonic evolution demonstrated that the Cambrian-Ordovician cherts, associated with rift, oceanic, island arc and back-arc volcanic rocks, was not formed in a typical abyssal oceanic basin or mid-oceanic ridge. On the contrary, they formed in a deepwater basin of continental margin or a archipelagic ocean tectonic setting. Several Early Paleo-zoic ophiolite belts in North Qilian and adjacent periphery Qaidam microplate imply that an archipelagic ocean during Ordovician existed in the east of Pro-Tethys.

关键词： North Qilian orogenic belt,Cambrian-Ordovician,cherts sedimentary geochemistry,archipelagic ocean

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Complexity and Self-Organized Criticality of Solid earth System(Ⅰ)

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Journal of earth Science 1998年第1期17卷 30-47页

作者： Yu Chongwen faculty of earth {2., China university of {4., wuhan 430074

The author puts forward the proposition of Complexity and Self Organized Criticality of Solid earth System in the light of: (1) the science of complexity studies the mechanisms of emergence of complexity and is the science of the 2.st century, (2. the study of complexity of the earth system would be one of the growing points occupying a strategic position in the development of {2. in the 2.st century. By the proposition we try to cogitate from a new viewpoint the ancient yet ever new solid earth system. The author abstracts the fundamental problem of the solid earth system from the essence of the generalized geological systems and processes which reads: the complexity and self organized criticality of the global nature, structure and dynamical behavior of the whole solid earth system emerging from the multiple coupling and superposition of non linear interactions among the multicomponents of the earths material and the multiple generalized geological (geological, geophysical, and geochemical) processes . Starting from this cognizance the author proposes eight major themes and the methodology of researches on the complexity and self organized criticality of the solid earth system.

关键词： complexity self organization self organized criticality the solid earth system fractal chaos long range spatio temporal correlation fractal spatio temporal structure.

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