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Exsolution of ilmenite and Cr-Ti magnetite from olivine of garnet-wehrlite

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Science China earth sciences 2005年第9期48卷 1368-1376页

作者： LIU Xiangwen1,2. JIN Zhenmin1,3, QU Jing2.& WANG Lu2.1. State Key Laboratory of Geological Processes and Mineral Resources, China university of geosciences,{2., China 2. Graduate School of China university of geosciences,{2., China 3. faculty of earth sciences, China university of geosciences,{2., China 1. State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences 430074 Wuhan China 2. Graduate School of China university of geosciences 430074 Wuhan China 3. faculty of earth {2. China University of Geosciences 430074 Wuhan China

Exsolution of rod-like ilmenite (Ilm) and Cr-Ti magnetite (Mt) have been found in olivine of garnet-wehrlite from the core of Chinese Continental sciences Drilling (CCSD). Their composition, morphology, crystal structure and their topotaxies with host olivine have been studied in detail by the transmission electron microscopy (TEM) and electron probe microanaly- sis (EPMA) technique. It shows that rod-like Ilm exsolution reported in this paper has similar characteristic with that of Alpe Arami olivine, while Cr-Ti magnetite exsolution mentioned in this paper has large discrepancy with chromite exsolution in Alpe Arami olivine. These observations suggest that both of the exsolutions found in this paper should be solid solution phases in β-olivine at their first period, then experiencing decomposition of solid solution and therefore forming Ilm and Cr-Ti magnetite exsolution with the pressure decreasing. So, this garnet-wehrlite perhaps had been ever located in mantle transition zone with a minimum depth of 300 km.

关键词： garnet-wehrlite, ilmenite, magnetite, exsolution, CCSD.

Evolutionary patterns of Productida (Brachiopoda) morphology during the Permian in South China

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Science China earth sciences 2008年第11期51卷 1589-1600页

作者： ZHANG Yang1 & HE WeiHong1,2.1 faculty of earth {2., China university of {4., wuhan 430074, China 2.Key Laboratory of Biogeology and Environmental Geology of Ministry of Education, China university of {4., wuhan 430074, China 1. faculty of earth {2. China University of Geosciences Wuhan 430074 China 2. Key Laboratory of Biogeology and Environmental Geology of Ministry of Education China University of Geosciences Wuhan 430074 China

The evolutionary patterns of Productida (brachiopod) morphology throughout the Permian show that while the percentage proportion of Productida (brachiopod) with strongly concentric and radial ornamentation declined from the Cisuralian to the Guadalupian, and then increased towards the Changhsingian via Wuchiapingian, the percentage proportion of Productida (brachiopod) with fine concentric and radial ornamentation distinctly increased from the Cisuralian to the Guadalupian, slightly declined towards the Wuchiapingian, and then increased towards the Changhsingian. From the Cisuralian to the Changhsingian, the percentage proportion of brachiopods with spinose ornamentation shows a persistent declining trend. The shell size generally indicates a miniaturization trend at species level during the Wuchiapingian to Changhsingian (including the transitional bed). These evolutionary patterns of brachiopod ornamentation and size are possibly related to the anoxia, food shortage, sea-level fluctuation, and change of substrate in the Permian (including the Permian-Triassic transitional interval) in South China.

关键词： brachiopod ornamentation size Permian South China

Experimental study of ore gabbro liquid immiscibility

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Science China earth sciences 2005年第4期48卷 496-505页

作者： SANG Zunan1,2. XIA Bin1, ZHOU Yongsheng3 & JIN Zhenmin4.1. Guangzhou Institute of Geochemistry, Chinese Academy of sciences, Guangzhou 51064., China 2. wuhan {2., wuhan 4.0072. China 3. Institute of Geology, China Seismological Bureau, Beijing 10002., China {4., China {2. of geosciences, wuhan 430074, China 1. Guangzhou Institute of Geochemistry Chinese Academy of Sciences 510640 Guangzhou China 2. wuhan university 430072 Wuhan China 3. Institute of Geology China Seismological Bureau 100029 Beijing China 4. faculty of earth sciences China University of Geosciences 430074 Wuhan China

In this paper, the authors present the results of a preliminary experimental study on partial melting of fine-grained gabbro, Panzhihua, Sichuan Province, China. Experiments were conducted under (confining) pressure ranging from 4.0 to 500 MPa and temperature of 900— 12.0℃. The results show that the initial melt is distributed along grain boundaries and triple junctions. Liquid immiscibility phenomena are noted in the melt with two compositional different melt phases, i.e. matrix and sphere phases. The matrix phase is relatively rich in Si, Al and K, and is depleted in Mg, Fe, Ca, Na and Ti, whereas the sphere phase shows opposite trends. The calculation of the melt free energy indicates that the liquid immiscibility is governed by the rule of thermodynamics, as the liquid immiscibility would result in the decrease in free energy of the melt system. The field relationships suggest that the liquid immiscibility may have played an important role in the generation of ore magma of Panzhihua V-Ti magnetite ore deposit. This study thus provides experimental constraints on the mechanism of the formation of V-Ti magnetite deposite.

关键词： partial melting, experimental study, gabbro, liquid immiscibility, ore formation mechanism.

Experimental remolding on the caprock's 3D strain field of the Indosinian-Yanshanian epoch in Tongling deposit concentrating area

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Science China earth sciences 2005年第7期48卷 863-874页

作者： DENG Jun1,HUANG Dinghua2.WANG Qingfei1,WAN Li1,SUN Zhongshi3,YANG Liqiang1 & GAO Bangfei1 1. State Key Laboratory of Geological Processes and Mineral Resources,China university of geosciences,Beijing 100083,China 2. {2. of earth {4.,China university of geosciences,wuhan 430074,China 3. Department of earth {4.,Jilin university,Changchun 130061,China State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Beijing 100083 China faculty of earth {2. China University of Geosciences Wuhan 430074 China Department of earth sciences Jilin University Changchun 130061 China

Based on field observations and rheology analysis, we perform one analogue experiment and remold the 3D structural frame of Tongling deposit concentrating area firstly. Then we disassemble and dialyze the 3D structures of the model using the methods of "slicing" and "stripping". A series of sliced planes vertical to the fold hinges show similar landscapes of that in the drill hole profiles. Meanwhile, layer stripping analysis indicates that the deformation features of each layer in the model are qualitatively analogical to those obtained from field observations. Through contrasting the 3D structure between the experimental model and the field phenomena, we verify the following 3D deformation features of the caprock in this area: (1) the Tongling area mainly consists of three series of NE S-typed fold groups; (2. in the uniform stress field, the incoherent folds universally develop in different positions, along different axes as well as in different strata; (3) the faults propagate upward which are mostly inter-bedded detachment faults, while the fold amplitudes decrease while going deeper; and (4. the folds and cleavages are highly developed in the Silurian System indicating that the deformation effect of the Indosin-ian-Yanshanian structural layer terminates at this layer, which suggests that the Silurian System is the crucial layer for the inversion between brittle and plastic deformation domains and the underlying strata are subject to the control of another deformation system with distinct properties.

关键词： Tongling deposit concentrating area Indosinian-Yanshanian epoch 3D structural frame of the caprock analogue experiment slicing and stripping analysis structural model.

earthquake-controlled event deposits and its tectonic significance from the Middle Permian Wandrawandian Siltstone in the Sydney Basin, Australia

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Science China earth sciences 2005年第9期48卷 1337-1346页

作者： DU Yuansheng1, G. R. Shi1,2.& GONG Yiming1 1. faculty of earth {2., China university of {4., wuhan 430074, China 2. School of Ecology and Environment, Deakin university, Victoria 312., Australia 1. faculty of earth {2. China University of Geosciences 430074 Wuhan China 2. School of Ecology and Environment Deakin University 3125 Victoria Australia

The Sydney-Bowen basin in eastern Australia is an elongate back arc-converted foreland basin system situated between the Lachlan Fold Belt in the west and the New England Fold Belt in the east. The Middle Permian Wandrawandian Siltstone at Warden Head near Ulla- dulla in the southern Sydney Basin is dominated by fossiliferous siltstone and mudstone, with a large amount of dropstones and minor pebbly sandstone beds. Two general types of deposits are recognized from the siltstone unit in view of the timing and mechanism of formation. One is rep- resented by the primary deposits from offshore to subtidal environments with abundant drop- stones of glacial marine origin. The second type is distinguished by secondary, soft-sediment deformational deposits and structures, and comprises three layers of mudstone dykes of seismic origin. In the latter type, metre scale, laterally extensive syn-depositional slump deformation structures occur in the middle part of the Wandrawandian Siltstone. The deformation structures vary in morphology and pattern, including large-scale complex-type folds, flexural stratification, concave-up structures, faulting of small displacements accompanied by folding and brecciation. The slumps and associated syn-sedimentary structures are attributed to penecontemporaneous deformations of soft sediments (mostly silty mud) formed as a result of mass movement of un- consolidated and/or semi-consolidated substrate following an earthquake event. The occurrence of the earthquake event deposits supports the current view that the Sydney Basin was located in a back-arc setting near the New England magmatic arc on an active continental margin during the Middle Permian.

关键词： Permian, seismites, earthquake, tectonics, Sydney Basin, Australia.

Transport network and flow mechanism of shallow ore-bearing magma in Tongling ore cluster area

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Science China earth sciences 2006年第4期49卷 397-407页

作者： DENG Jun1,2. WANG Qingfei1,2., HUANG Dinghua3 , WAN Li4. YANG Liqiang1,2.& GAO Bangfei1,2.1. State Key Laboratory of Geological Processes and Mineral Resources, China university of {2., Beijing 100083, China 2. Key Laboratory of Lithosphere Tectonics and Lithoprobing Technology of Ministry of Education, China university of Geo- sciences, Beijing 100083, China 3. {4. of earth sciences, China university of {2., wuhan 430074, China 4. School of Mathematics and Information Science, Guangzhou university, Guangzhou 5104.5, China 1. State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Beijing 100083 China 2. Key Laboratory of Lithosphere Tectonics and Lithoprobing Technology of Ministry of Education China University of Geosciences Beijing 100083 China 3. faculty of earth {2. China University of Geosciences Wuhan 430074 China 4. School of Mathematics and Information Science Guangzhou University Guangzhou 510405 China

Abundant studies revealed that shallow intrusions of the Yanshanian epoch resulted in the mass mineralization of the Tongling region. Various evidences showed there existed a concealed magma chamber at ?10 km depth in the middle part of this region during Yanshanian epoch, from which the ore-forming magma was generated and then transported to the superficial layer. Yet the transport network and flow mechanism of the shallow ore-bearing magma, the key problem associ- ated with ore-forming process, was relatively little focused on. Integrate analysis of structural me- chanics, statistical fractal and geological facts suggested that NE trending high-angle fold-related thrust faults and the tessellated basement ones served as the main pathways for the shallow magma’s transporting, moreover, the saddle void spaces among adjacent strata in the folds upon this fault system provided the place for magma’s emplacement. So the folds in the upper part and faults in the lower part of the upper crust constituted the fluid’s transport and emplacement network. During the deformation of geologic body with multi-layer structure, the layers in the upper part tended to fold when received the jacking stress from the lower part, while the lower one inclined to fault undergoing loads of the upper part. And the producing probability of this structure assemblage was highly in- creased in the condition, such as in the Tongling area, that the mechanic rigidity of the lower layers was stronger than that of the upper ones. For the pre-existence of fluid-conducting network, the top magma with high volatile in the magma chamber transported rapidly to the superficial layer in dyking pattern, located in the void spaces of folds, filled and reconstructed them. The sudden drop of pres- sure caused the fluid unmixing from the magma and mass ore-forming elements concentration. Pulse activity of the dyking may be the principal reason why magmatic bodies in the Tongling area were spatially-temporally con

关键词： Tongling, structural network, magma intrusion, fractal, dyke.

Geothermal and fluid flowing simulation of ore-forming antimony deposits in Xikuangshan

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Science China earth sciences 2006年第8期49卷 862-871页

作者： YANG Ruiyan1,2. MA Dongsheng2. BAO Zhengyu3, PAN Jiayong2. CAO Shuanglin2.& XIA Fei2.1. School of Mathematics and Physics, China university of geosciences,{2., China 2. State Key Laboratory for Research of Mineral Deposits, Nanjing university, Nanjing 2.0093, China 3. {4. of earth sciences, China university of geosciences,{2., China 1. School of Mathematics and Physics China University of Geosciences Wuhan 430074 China 2. State Key Laboratory for Research of Mineral Deposits Nanjing University Nanjing 210093 China 3. faculty of earth {2. China University of Geosciences Wuhan 430074 China

The Xikuangshan Antimony Deposit located in the Mid-Hunan Basin, China, is the larg- est antimony deposit in the world. Based on the hydrogeological and geochemical data collected from four sections, Xikuangshan-Dajienao (AO), Xikuangshan-Dashengshan (BO), Xikuang- shan-Longshan (CO) and Dafengshan (DO) in the Basin, an advanced metallogenic model related to deep-cyclic meteoric water of Xikuangshan Antimony Deposit is put forward in this paper using a model of heat-gravity-driving fluid flow transportation. The simulation results show that the ore-forming fluid of the deposit mainly comes from the Dashengshan and Longshan areas where BO and CO sections are located if the overall basin keeps a constant atmospheric precipitation and infiltration rate during mineralization, and that the average transportation speed of the ore-forming fluids is about 0.2.0.4.m/a.

关键词： ore-forming fluid, numerical simulation, geothermal field, geofluid transport, Xikuangshan, antimony deposits.

Electron microscopy study of the sakhaite from endogenous borate deposit in Hunan, China

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Science China earth sciences 2004年第3期47卷 232-238页

作者： LIU Xiangwen1,2. YANG Guangming2. ZOU Huamin3, QU Jing1 & ZHAO Wenxia4.1. Graduate School, China university of {2.,{2., China 2. Test Center, China university of {2.,{2., China 3. Physics and Technology College, wuhan university, wuhan 4.0072. China 4. Test Center, Zhongshan university, Guangzhou 5102.5, China China Univ Geosci Grad Sch Wuhan 430074 Peoples R China China Univ Geosci Test Ctr Wuhan 430074 Peoples R China wuhan Univ Phys & Technol Coll Wuhan 430072 Peoples R China Zhongshan Univ Test Ctr Guangzhou 510275 Peoples R China

Sakhaite specimens from an endogenous borate deposit in Hunan Province, China have been studied in detail by means of transmission electron microscopy (TEM). The selected area electron diffraction (SAED) patterns obtained with different crystal zone axes show that the crystal system is cubic, with a = 1.4.3 nm. The convergent beam electron diffraction (CBED) patterns indicate that the point group and space group of sakhaite is m3m and Fd3m, respec-tively. The space group of synthetic sakhaite determined by Chichagov (1974. is F4.32. The possible reasons why the space groups of the natural and the synthetic sakhaites are different are discussed.

关键词： sakhaite, space group, convergent beam electron diffraction (CBED).

Distributions of fatty acids in a stalagmite related to paleoclimate change at Qingjiang in Hubei,southern China

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Science China earth sciences 2005年第9期48卷 1463-1469页

作者： XIE Shucheng1,HUANG Junhua1,WANG Hongmei2.YI Yi1,HU Chaoyong1, CAI Yanjun3 & CHENG Hai4.1. faculty of {2. Science,China {2. of geosciences,{4. 430074,China 2. School of Environmental Studies,China {2. of geosciences,{4. 430074,China 3. SKLLQG,Institute of {2. Environment,Chinese Academy of {12.,Xi’an 710075,China 4. Department of Geology and Geophysics,{2. of Minnesota,MN554.5,USA 1. faculty of earth Science China University of Geosciences 430074 Wuhan China 2. School of Environmental Studies China University of Geosciences 430074 Wuhan China 3. SKLLQG Institute of Earth Environment Chinese Academy of Sciences 710075 Xi’an China 4. Department of Geology and Geophysics University of Minnesota 55455 MN USA

Fatty acids extracted from a subtropical stalagmite at Qingjiang in Southern China’s Hubei Province were analysed using gas chromatography-mass spectrometry. These n-alkanoic acids range from C14.to C2. in carbon number, maximizing at C16, with a second dominance at C2.. In contrast to the stalagmite analysed, the overlying soils are characterized by the dominance of heavy-molecular-weight homologues (>C2.). The n-fatty acids in the stalagmite were proposed to be contributed by both the soil ecosystems and the microbes harboring in the percolating water and the cave. The ratios of unsaturated to saturated n-fatty acids (C16:1i/C16:0, C18:1/C18:0) appear to show trends comparable with the oxygen isotope records of the stalagmite carbonate, with enhanced values associated with the cold episode such as Heinrich event 1. This paleoclimate-dependent record of the n-fatty acids might reflect microbial changes in physiology and activity in response to the temperature. This record shows somewhat difference from the previous paleoclimate signal extracted from n-alkanols and n-alkan-2.ones of the same stalagmite. The acid record fails to document the well-known Younger Dryas event which was effectively shown by the latter two biomarkers derived from soil ecosystems. This discrepancy might result from the changing biogeochemical impact on different lipid fractions as well as the varied organism populations in different ecosystems.

关键词： biomarker, ecosystem, microbe, speleothem, paleoclimate, Quaternary.