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Aoyitake plagiogranite in western Tarim Block, NW china: Age, geochemistry, petrogenesis and its tectonic implications

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Science china Earth Sciences 2006年第11期49卷 1121-1134页

作者： ZHANG Chuanlin1,2, YU Haifeng3, YE Haimin2, ZHAO Yu2 & ZHANG Dongsheng4.1. Key Laboratory of Isotope Geochronology and Geochemistry, Guangzhou institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 51064., china 2. Nanjing institute of geology and Mineral Resources, Nanjing 210016, china 3. Tianjin institute of geology and Mineral Resources, Tianjin 300170, china 4. The 2nd Regional Geological Investigation Party, Xinjiang Bureau of geology and Mineral Resources, Changji 831100, china 1. Key Laboratory of Isotope Geochronology and Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China 2. Nanjing institute of geology and Mineral Resources Nanjing 210016 China 3. Tianjin institute of geology and Mineral Resources Tianjin 300170 China 4. The 2nd Regional Geological Investigation Party Xinjiang Bureau of Geology and Mineral Resources Changji 831100 China

SHRIMPP U-Pb zircon age and geochemical and Nd isotopic data are reported for the Aoyitake plagiogranite in western Tarim Block, NW china. The plagiogranite intruded the Middle Pro- terozoic and Lower Carboniferous with an exposure area of ca. 60 km2 and crystallized at 330.7±4.8 Ma. Rock types mainly include tonalite, trondhjemite and minor amounts of diorite and quartz-diorite. Feldspars in the rocks are dominated by oligoclase-andesine, and minor perthite observed locally. The granites are sodic with Na/K ratios (molar) between 4.and 87. Total REE (50-220 ppm) show a clear positive correlation with SiO2. There is no LRRE/HREE fractionation (LaN/YbN=0.5-1.5), me- dium negative Eu anomalies (δ Eu=0.3-0.6), high Y content and low Sr/Y ratio (~1.0). These granites exhibit relatively juvenile Nd T2DM model ages of 4.0 to 580 Ma and positive εNd(331 Ma) values of 6.23 to 7.65. The aforementioned characteristics are similar to those of ocean island or ocean ridge plagiogranites. However, the regional geology, especially its scale, precludes that the plagiogranite pluton was derived directly from fractionational crystallization of mantle-derived basaltic magma. We interpreted that the primary magma of the pluton might be tonalitic in composition generated by ca. 50% partial melting of the juvenile basaltic crust. The primary magma experienced intensive frac- tionational crystallization, and intruded into the middle to upper crusts to form the granite pluton. In combination with the previous regional geological data, it is concluded that the plagiogranite pluton was emplaced within the Tarim Block in respond to the Carboniferous continental rifting along the Tianshan orogenic belt.

关键词： western Tarim, Aoyitake plagiogranite, age, geochemistry, tectonic implications.

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Progress and review of the studies on the end-Triassic mass extinction event

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Science china Earth Sciences 2005年第12期48卷 2049-2060页

作者： DENG Shenghui1,2, LU Yuanzheng1,2,3 & XU Daoyi4.1. Research institute of Petroleum Exploration and Development, Beijing 100083, china 2. Key Laboratory of Oil and Gas Reservoir of Petrochina, Beijing 100083, china 3. china University of Geosciences, Beijing 100083, china 4. institute of geology, china Earthquake Administration, Beijing 10002., china 1. Research institute of Petroleum Exploration and Development 100083 Beijing China 2. Key Laboratory of Oil and Gas Reservoir of Petrochina 100083 Beijing China 3. china University of Geosciences 100083 Beijing China 4. institute of geology China Earthquake Administration 100029 Beijing China

The mass extinction at the end-Triassic is one of the five biggest in the Phanerozoic. However,it is the least well understood among these five events, and only till last decade it became a great academic interesting subject to geologists. The evidences for this event come obviously from bivalves, brachiopods, ammonites, corals, radiolaria, ostracods and foraminifera of marine habitats, and plants and tetrapods of terrestrial realm. By contrast, for some of other groups, such as marine gastropods and marine vertebrates, no mass extinction has been recog-nized yet. The extinction event is strongly marked at specific level but shown a complicated situa-tion at generic and family levels. Dramatic changing of the environment, such as the temperature raise due to the greenhouse effect, the marine anoxic habitats caused by a sudden transgression after the regression at the end of Triassic, has been claimed to be the main cause of the extinction. Many hypotheses have been suggested to demonstrate the mechanisms of the environment changing, among which two popular ones are the bolide impact and volcanic eruption. The Triassic-Jurassic (Tr-J) boundary mass extinction event is still poorly understood because no enough data have been obtained from the Tr-J boundary successional sections of both marine and terrestrial sediments, and most of these studies were regionally restricted. The basic aspects of the event and its associated environmental conditions remain poorly characterized and the causal mechanism or mechanisms are equivocal. Some authors even doubt its occurrence. china has many successionally developed terrestrial and marine Tr-J sections. Detailed studies of these sections may be important and significant for well understanding of the event.

关键词： progress, review, end-Triassic, mass extinction, mechanism, Tr-J boundary.

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Sorption behavior of U(VI), ^(234.U(VI) and ^(238)U(VI) onto fracture-filling clays in Beishan granite, Gansu: Application to selecting the site of high-level radwaste repository in china

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Science china Earth Sciences 2005年第10期48卷 1649-1655页

作者： MIN Maozhong1,2, LUO Xingzhang3, WANG Ju4. JIN Yuanxin4.& WANG Rucheng1 1. Department of Earth Sciences, State Key Laboratory of Mineral Deposit Research, Nanjing University, Nanjing 210093, china 2. Center of Materials Analysis, Nanjing University, Nanjing 210093, china 3. Department of Environmental Science and Engineering, Nanjing University, Nanjing 210093, china 4. Beijing geology {4., nuclear industry, Beijing 10002., china Department of Earth Sciences State Key Laboratory of Mineral Deposit Research Nanjing University Nanjing China Center of Materials Analysis Nanjing University Nanjing china Department of Environmental Science and Engineering Nanjing University Nanjing china Beijing geology institute nuclear industry Beijing china

The first results of sorption experiments of U(VI), 234.(VI) and 238U(VI) onto original (unpurified) fracture-filling clays from No.1 monzonitic granite intrusion, Beishan area, Gansu Province, china are reported. The monzonitic granite intrusion is a potential location for a high-level radwaste (HLW) repository in china. The present experimental results show that the maximum U(VI) sorption reached 92% at near-neutral pH and the distribution coefficient (Kd) was 1226 mL/g. A high sorption capacity of the fracture-filling clays in host rock on radioactive ele-ments is necessary for HLW deep geological disposal repository. No preferential sorption of 234. onto the clays was found. Finally, the sorption of U(VI) onto the clays was also modeled using a surface complexation model.

关键词： HLW geological disposal repository, granite, uranium, radionuclide, clay, sorption.

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Experimental study of ore gabbro liquid immiscibility

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Science china Earth Sciences 2005年第4期48卷 496-505页

作者： SANG Zunan1,2, XIA Bin1, ZHOU Yongsheng3 & JIN Zhenmin4.1. Guangzhou institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 51064., china 2. Wuhan University, Wuhan 4.0072, china 3. institute of {4., china Seismological Bureau, Beijing 10002., china 4. Faculty of Earth Sciences, china University of Geosciences, Wuhan 4.0074. china 1. Guangzhou institute of Geochemistry Chinese Academy of Sciences 510640 Guangzhou China 2. Wuhan University 430072 Wuhan China 3. institute of geology China Seismological Bureau 100029 Beijing China 4. Faculty of Earth Sciences China University of Geosciences 430074 Wuhan China

In this paper, the authors present the results of a preliminary experimental study on partial melting of fine-grained gabbro, Panzhihua, Sichuan Province, china. Experiments were conducted under (confining) pressure ranging from 4.0 to 500 MPa and temperature of 900— 1200℃. The results show that the initial melt is distributed along grain boundaries and triple junctions. Liquid immiscibility phenomena are noted in the melt with two compositional different melt phases, i.e. matrix and sphere phases. The matrix phase is relatively rich in Si, Al and K, and is depleted in Mg, Fe, Ca, Na and Ti, whereas the sphere phase shows opposite trends. The calculation of the melt free energy indicates that the liquid immiscibility is governed by the rule of thermodynamics, as the liquid immiscibility would result in the decrease in free energy of the melt system. The field relationships suggest that the liquid immiscibility may have played an important role in the generation of ore magma of Panzhihua V-Ti magnetite ore deposit. This study thus provides experimental constraints on the mechanism of the formation of V-Ti magnetite deposite.

关键词： partial melting, experimental study, gabbro, liquid immiscibility, ore formation mechanism.

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The crustal structure under Sanjiang and its dynamic implications:Revealed by seismic reflection/refraction profile between Zhefang and Binchuan,Yunnan

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Science china Earth Sciences 2005年第9期48卷 1329-1336页

作者： ZHANG Zhongjie1, BAI Zhiming1, WANG Chunyong2, TENG Jiwen1, Lü Qingtian3, LI Jiliang1, LIU Yifeng1 & LIU Zhenkuan4.1. institute of geology and Geophysics, Chinese Academy of Sciences, Beijing 10002., china 2. institute of Geophysics, china Seismological Bureau, Beijing 100085, china 3. institute of Deposition Resource, Chinese Academy of Geosciences, Beijing 100037, china 4. School of Exploration and Information, china University of Geosciences, Beijing 100083, china 1. institute of geology and Geophysics Chinese Academy of Sciences 100029 Beijing China 2. institute of Geophysics China Seismological Bureau 100085 Beijing China 3. institute of Deposition Resource Chinese Academy of Geosciences 100037 Beijing China 4. School of Exploration and Information China University of Geosciences 100083 Beijing China

The fault belts in Sanjiang mainly include Jinshajiang-Honghe fault, Lancangjiang fault and Nujiang fault (called Sanjiang faults) in western Yunnan Province, china. By interpreting the wide-angle seismic reflection/refraction profile between Zhefang and Binchuan, which crosses Tengchong and Baoshan blocks in Dianxi (western Yunnan) tectonic zone, we recon- struct the crustal structure with seismic traveltime tomography for crustal P-wave velocity and the seismic scattering image for crustal seismic reflection structure. In this paper, we firstly present the crustal structure images of P-wave velocity and seismic reflection under the wide-angle seismic profile. These results demonstrate that, the crustal velocity structure and seismic reflec- tion structure along the profile can be divided into 3 segments, and there is an obvious difference of crustal structure among the eastern, the western and the middle segment. Generally, crustal P-wave velocities in the Baoshan segment are 0.1―0.2 km/s slower and seismic reflection am- plitudes from Moho discontinuity are stronger than the other 2 segments. In the studied area, crustal thickness is about 4. km, and shows the thickening tendency from west to east along the profile. Additionally, it can be seen that there is one strong-amplitude seismic reflection event as bright points at the depths of 8―10 km, along the segment of 80―115 km of the profile (south- ward of Tengchong); and seismic reflection wave-field from Moho discontinuity varies obviously along the lateral direction. Finally, we make some discussions on the crustal thickening pattern in the Sanjiang fault belt, structural environment of earthquake development and the contact rela- tionship between the Tengchong block, Banshan block and Luxi trough.

关键词： Sanjiang area wide-angle seismic profile crustal structure.

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Carbon isotope composition of the Lower Triassic marine carbonates, Lower Yangtze Region, South china

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Science china Earth Sciences 2006年第3期49卷 225-241页

作者： ZUO Jingxun1,2, TONG Jinnan3, QIU Haiou4.& ZHAO Laishi3 1. Nanjing institute of geology and Palaeontology, Chinese Academy of Sciences, Nanjing 210008, china 2. Henan institute of Geological Survey, Zhengzhou 4.0007, china 3. State Key Laboratory of Geological Processes and Mineral Resources at china University of Geosciences, Wuhan 4.0074. china 4. Faculty of Material Sciences and Chemical Engineering, china University of Geosciences, Wuhan 4.0074. china 1. Nanjing institute of geology and Palaeontology Chinese Academy of Sciences Nanjing 210008 China 2. Henan institute of Geological Survey Zhengzhou 450007 China 3. State Key Laboratory of Geological Processes and Mineral Resources at china University of Geosciences Wuhan 430074 China 4. Faculty of Material Sciences and Chemical Engineering China University of Geosciences Wuhan 430074 China

Studies on three Lower Triassic sections located on the shallow water platform, the deep water slope and in the deep water basin in the Lower Yangtze Region, South china, show the similar trend of carbon isotope evolution. Biostratigraphic correlations among the Lower Triassic sections on the basis of standard conodont zones indicate that three negative shifts occurred in the Griesbachian, the Smithian and the late Spathian stages respectively, and one distinctly positive shift occurred in the early Spathian stage. Trend of carbon isotope evolution of the Lower Triassic reflects some significant changes in the global carbon cycle. Moreover, δ 13C background values are intensively controlled by palaeogeographic environment. In general, δ 13C values from deep-water slope carbonates are lighter than those from carbonate platform and heavier than those from deep-water basin carbonates. The positive carbon isotope excursion may be induced by a significant amount of organic carbon burial in marine sediments and increase in primary productivity. The large negative carbon isotope excursions during the Early Triassic in Lower Yangtze Region are interpreted to relate to volcano eruptions based on tuffaceous claystone interlayers observed near the Permian-Triassic boundary, the Induan- Olenekian boundary and the Lower Triassic-Middle Triassic boundary.

关键词： Lower Triassic, carbon isotope compositions, palaeogeography, volcanic eruptions, Lower Yangtze Region.

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Geochemistry of high-Mg andesites from the early Cretaceous Yixian Formation, western Liaoning: Implications for lower crustal delamination and Sr/Y variations

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Science china Earth Sciences 2006年第9期49卷 904-914页

作者： WANG Xiaorui1, GAO Shan1,2, LIU Xiaoming1, YUAN Honglin1, HU Zhaochu1, ZHANG Hong1,3 & WANG Xuance4.1. State Key Laboratory of Continental Dynamics, Department of geology, Northwest University, Xi`an 710069, china 2. State Key Laboratory of Geological Processes and Mineral Resources, china University of Geosciences, Wuhan 4.0074. china 3. Shenyang {4. of geology and Mineral Resources, Shenyang 110032, china 4. Guangzhou {4. of Geochemistry, Chinese Academy of Sciences, Guangzhou 51064., china 1. State Key Laboratory of Continental Dynamics Department of Geology Northwest University Xi’an 710069 China 2. State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Wuhan 430074 China 3. Shenyang institute of geology and Mineral Resources Shenyang 110032 China 4. Guangzhou institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China

85 volcanic rocks of the Yixian Formation from the Sihetun type section werecollected and analyzed for geochemical and isotopic compositions. Major element compositionsindicate that the Sihetun volcanic rocks are high magnesium andesites with some basalts occurring atthe bottom of section. The Sihetun high magnesium andesites (SiO_2 = 52.82-59.31 wt%, Al_2O_3=14.15-16.35wt%) show many characteristics of adakites such as depletion in heavy rare-earth elements(HREE; Yb = 1.03-1.88 μg/g) and Y(12-20 μg/g) and high Sr (620-1323 μg/g) and Sr/Y(32-88), withhigh La_N/Yb_N ratio (10-25). They share similar major and trace element characteristics to volcanicrocks from the Xinglonggou Formation except their lower Nd isotope ratios (^(14.)Nd/^(14.)Nd(130Ma) = 0.5118-0.5119, ε_(Nd) (130Ma) = -11.6-13.8, ^(87)Sr/^(86)Sr (130 Ma) = *** were interpreted in a way that eclogite that formed at the base of thickened Archean lowercrust of the North china craton foundered into the convecting mantle and subsequently melted andinteracted with peridotite. However, compared to the Xinglonggou volcanic rocks, the source of theSihetun magma contained more ancient continental crustal material in order to explain its evolved Ndisotopes. The age of the Sihetun Formation was 120 to 130 Ma, and this indicates that delaminationlasted to the early Cretaceous period. The Sr contents and Sr/Y ratios of the Sihetun high-Mgandesites show significant negative correlations with SiO_2 for samples with SiO_2 > 56%. Thesesuggest that the Sr and Sr/Y values were reduced due to fractional crystallization of ***, the effect of crystallization on volcanic Sr and Sr/Y ratio has to be taken intoaccount.

关键词： High-Mg andesite, Adakite, Yixian Formation, North china Craton, delamination.

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SHRIMP zircon U-Pb geochronology of early Mesozoic felsic igneous rocks from the southern Lancangjiang and its tectonic implications

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Science china Earth Sciences 2006年第10期49卷 1032-1042页

作者： PENG Touping1,2, WANG Yuejun1, FAN Weiming1, LIU Dunyi3, SHI Yuruo3 & MIAO Laicheng4.1. Key Laboratory of Isotope Geochronology and Geochemistry, Guangzhou institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 51064., china 2. Graduate University of Chinese Academy of Sciences, Beijing 100039, china 3. SHRIMP isotope Laboratory, Chinese Academy of Geological Sciences, Beijing 100037, china 4. institute of geology and Geophysics, Chinese Academy of Sciences, Beijing 10002., china Key Laboratory of Isotope Geochronology and Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China Graduate University of Chinese Academy of Sciences Beijing China SHRIMP isotope Laboratory Chinese Academy of Geological Sciences Beijing China institute of geology and Geophysics Chinese Academy of Sciences Beijing China

The SHRIMP zircon U-Pb geochronology of three typical samples, including two monzo nitic granites from the Lincang batholith and a rhyolite from the Manghuai Formation are presented in the southern Lancangjiang, western Yunnan Province. The analyses of zircons for the biotite monzonitic granites from the northern (02DX-137) and southern (20JH-10) Lincang batholith show the single and tight clusters on the concordia, and yield the weighted mean 206Pb/238U ages of 229.4.± 3.0 Ma and 230.4.± 3.6 Ma, respectively, representing the crystallized ages of these granites. The zircons for the rhyolitic sample (02DX-95) from the Manghuai Formation give a weighted mean 206Pb/238U age of 231.0 ± 5.0 Ma. These data suggest that the igneous rocks from the Lincang granitic batholith and Manghuai Formation have a similar crystallized age. In combination with other data, it is inferred that both were generated at a narrow age span (~230 Ma) and were originated from the postcollisional tectonic regime. An early Proterozoic 206Pb/238U apparent age of 1977±4. Ma is additionally obtained from one zircon from the biotite monzonitic granite (southern Lincang batholith), indicative of devel- opment of the early Proterozoic Yangtze basement in the region. These precisely geochronological data provide important constraints on better understanding the Paleozoic tectonic evolution of the Tethys, western Yunnan Province.

关键词： SHRIMP zircon U-Pb dating, Middle Triassic, Lincang granitic batholith, Manghuai Formation rhyolite, southern Lancangjiang.

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Zijinshan-Bitian Cu-Au-Mo orefield, SW Fujian——An example of gold-rich PCS zoning

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Chinese Science Bulletin 1999年第S2期44卷 134-135页

作者： QI Jianzhong~1, LI Zhaonai~2, ZHANG Dequan~3, FANG Xiheng~4.and XIAO Huiliang~1 1. Nanjing institute of geology and Mineral Resources, Chinese Academy of Geological Sciences, Nanjing 210016, china 2. institute of geology, Chinese Academy of Geological Sciences, Beijing 100037, china 3. institute of Mineral Deposits, Chinese Academy of Geological Sciences, Beijing 100037, china 4. institute of geology, Ministry of nuclear industry, Beijing 100013, china Nanjing institute of geology and Mineral Resources Chinese Academy of Geological Sciences Nanjing 210016 China institute of geology Chinese Academy of Geological Sciences Beijing 100037 China institute of Mineral Deposits Chinese Academy of Geological Sciences Beijing 100037 China institute of geology Ministry of Nuclear Industry Beijing 100013 China

THE Zijinshan-Bitian Cu-Au-Mo orefield is spread to north of the Shanghang County, SW *** geological structure it is located at the plunging end of NE-trending Xuanhe anticlinorium, in the NE rim ofthe NW trending Shanghang volcano-sedimentary basin. Orefield basement is composed of the Archean-Middle Proterozoic low-grade metamorphic rock formations, containing marine basic metavolcanic sequenses. Lower Cretaceous subaerial volcanic rocks of andesite-trachy andesite-rhyolite composition fill inthe volcano-sedimentary basin. Pre-mineralization granitic batholith dated 14.Ma（Rb-Sr）and 157Ma（U-Pb） occupies the axial part of the plunging anticlinorium, which was regarded as crust-remelting typegranitoids. Mineralization-affiliated subvolcanic dacite porphyrite, co-volcanic granodiorite and quartzdiorite porphyrite （102.2 Ma（Rb-Sr）, Sr1 = 0.708 9） belong to syntactic type in genesis and

关键词： gold-rich porphyre copper system zoning Fujian Zijinshan.

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Application of backflush and micro-flow techniques to the analysis of C5—C13 hydrocarbons in crude oils and its geochemical significance

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Progress in Natural Science:Materials International 2007年第11期17卷 1382-1387页

作者： Wang Peirong1,2, Zhao Hong2,3, Xu Guanjun1,4. Zhu Cuishan2,3, Xiao Tingrong4. Zhang Min2,3 and Zhang Bin1,4.1. Key Laboratory of Petroleum Geochemistry, china National Petroleum Corporation, Beijing 100083, china 2. Geochemistry Department of Yangtze University, Jingzhou 4.4.23, china 3. Key Laboratory of Exploration Technologies for Oil and Gas Resources, Ministry of Education, Yangtze University, Jingzhou 4.4.23, china 4. Petroleum {4. Central Laboratory, Research institute of Petroleum Exploration and Development, Petrochina, Beijing 100083, china) Key Laboratory of Petroleum Geochemistry China National Petroleum Corporation Beijing 100083 China Geochemistry Department of Yangtze University Jingzhou 434023 China Key Laboratory of Exploration Technologies for Oil and Gas Resources Ministry of Education Yangtze University Jingzhou 434023 China Petroleum geology Central Laboratory Research Institute of Petroleum Exploration and Development PetroChina Beijing 100083 China

An Agilent 6890N GC equipped with both FID and Agilent 5975 MSD analyzer has been employed to analyze C5—C13 hydrocarbon fractions of crude oils. A technical combination of program temperature volatilizer injection, backflush and micro-flow controller afforded a fine separation of C5—C13 compounds on a PONA column with the heavy part of crude oils being cut off before entering the analytical column. Both GC-FID chromatogram and GC-MS mass chromatograms (MID and full scan) could be obtained at the same time. The retension time differences of nC6—nC13 alkanes between GC and TIC were in the range of 0.02—0.58 minutes. Totally 286 peaks have been assigned group compositions. Results on 8 typical oil samples from CNPC Key Laboratory Crude Oil Library showed that the characteristics of C6—C13 hydrocarbon group composition could be used in oil-oil correlation studies.

关键词： GC analysis GC/MS analysis backflush micro-flow controller light fraction in crude oil

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