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Journal of Wuhan university of technology(Materials Science) 2010年第3期25卷 499-503页

作者：李晶 college of chemistry and chemical engineering Zhongkai University of Agriculture and Engineering

The breakthrough curves of benzene and water on modified activated carbons（ACs） were ***-programmed desorption（TPD） experiments were conducted to measure the TPD curves of benzene and water on modified and unmodified ACs and to estimate the activation energy for the desorption of benzene on the modified *** with unmodified ACs,two modified ACs were prepared by using two different types of silane,designated by KH560 and *** results showed that the activation energy for the desorption of benzene on KH560/AC and 1706/AC was higher than that on unmodified *** addition,the activation energy for the desorption of water on KH560/AC and 1706/AC was lower than that on unmodified *** breakthrough curves of benzene obtained from the experimental observations under different humidity conditions were compared with the results of the TPD *** results show that the modified ACs are less affected by water,whereas the unmodified ACs are more affected by water,indicating that surface modification by organosilane compounds can improve the adsorption of benzene on the activated carbo,which weakens the adsorption of water.

关键词： activated carbon benzene water TPD activation energy of desorption breakthrough curves

A Novel Sulfided Mo/C Catalyst for Direct Vapor Phase Carbonylation of Methanol at Atmospheric Pressure

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Journal of Natural Gas chemistry 2003年第1期12卷 31-36页

作者： Feng PengDepartment of chemical engineering, South china university of technology, Guangzhou 510640, china Department of chemical engineering South China University of Technology Guangzhou 510640 China

The direct carbonylation of methanol, without any halide in the feed as apromoter, is presented. A series of Mo catalysts supported on activated carbon, γ-Al_2O_3 and SiO_2were prepared. The results show that the support greatly affects the Mo catalyst in the directvapor-phase carbonylation of methanol, and activated carbon is the best supports of the investigatedsupports. In addition, the relationships between adsorptions of NH_3 and CO and carbonylation ofmethanol were investigated. A novel sulfided Mo/C catalyst had high activity and selectivity for thevapor phase carbonylation of methanol to methyl acetate without the addition of a CH_3I promoter tothe feed. The reaction conditions were optimized at a reaction temperature of 573 K, a methanolconcentration of 23 mol% and a carbon monoxide space velocity of 3,000 L/(kg·h). Under theseoptimal conditions a methanol conversion of 50%, carbonylation selectivity of 80 rnol%, andspace-time yield of 8.0 mol/(kg·h) were obtained. The active phase of this novel sulfided Mo/Ccatalyst is the non-crystalline phase, and the active component is present as MoS_(2.5) on thesurface of the activated carbon.

关键词： methanol carbonylation sulfided catalyst molybdenum catalystsupport activated carbon heterogeneous catalysis

Further study of sources of the imported cobalt-blue pigment used on Jingdezhen porcelain from late 13 to early 15 centuries

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Science china(Technological Sciences) 2008年第3期51卷 249-259页

作者： DU Feng1 & SU BaoRu2 1 Institute of chemistry & Molecular engineering, Qingdao university of Science & technology, Qingdao 266000, china 2 college of Information Science technology, Qingdao university of Science & technology, Qingdao 266000, china Institute of chemistry & Molecular engineering Qingdao University of Science & Technology Qingdao 266000 China college of Information Science technology Qingdao University of Science & Technology Qingdao 266000 China

Based on the conclusion of modern scientific analysis: the cobalt-blue pigment applied on Jingdezhen official porcelain during Yuan Dynasty and prior to Xuande reign of Ming Dynasty (1271―1425) contains high iron and low manganese con- tents, and the cobalt during Xuande and after Xuande periods (after 1426) of Ming Dynasty contains high manganese and low iron contents, in combination with the traditional archaeological method, the related historical textual records were in- vestigated and analyzed, the imported cobalt employed on Jingdezhen official porcelain was studied comprehensively, systematically and logically. In fact, 'Su Ma Li Qing' (Samarra-blue) and 'Su Bo Ni Qing' (Sumatra-blue) are definitely different cobalt ores originated in different places, because of their very similar translitera- tions in Chinese, the confusion has appeared in ancient books for more than 400 years, which considered 'Su Ma Li Qing' and 'Su Bo Ni Qing' as the same co- balt-blue pigment. In this article the mistake was corrected, the possible producing places and the approximate eras of the two pigments imported to china and used at Jingdezhen were also suggested.

关键词： imported cobalt-blue pigments employed on official blue-and-white porcelain Yuan Dynasty early Ming Dy- nasty Mn/Fe content ratio Su Ma Li Qing (Samarra-blue) Su Bo Ni Qing (Sumatra-blue) scientific archae- ological research transliteration

Study on the Synthesis of Octyl Acetate by Phosphotungstate Heteropolyacid with Keggin Structure

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复旦学报（自然科学版） 2007年第5期46卷 769-,775页

作者： Han Jie-li, Li Hai-feng, Wang Zi-wei, Wu Chuan, Ren Jian-guo(School of chemistry and chemical engineering, Shanxi university, taiyuan 030006,china)

1 Results Octyl Acetate is an important chemical *** is widely used as solvent in many industries,such as plasterer,artificial leather,and lacquer varnish,spice and medicine *** the present time,it is prepared with acetic acid and 1-octanol in industry,by using sulfuric acid as the *** technique has many shortcomings,which include erosion of facility,many side reactions and difficulties of *** most severe problem is its pollution to the environment[1-2],so this...

关键词： octyl acetate phosphotungstate heteropolyacid Kaggin Structure

Study on the properties of polyaniline for med in KOH solution

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西南师范大学学报(自然科学版) 1999年第5期24卷 562-565页

作者： Li Nianbing 1,Zhang Shengtao 2,Ding Peidao 3 1 college of chemistry and chemical engineering,Southwest china Normal university,Chongqing 400715 2 college of chemistry and chemical engineering,Chongqing university,Chongqing 400044 3 college of Materi 西南师范大学重庆重庆大学重庆

Electropolymerization of aniline in KOH solution and properties of the polymer were studied by in situ reflex ellipsometry, cyclic voltammetry and fluorescence spectroscopic method. The process of electropolymerization of aniline was different in alkaline and in acidic aqueous media. The complex refractive indices and the fluorescence spectra indicated that the polyaniline was a sort of luminous material.

关键词： polyaniline electropolymerization alkaline solution ellipsometry fluorescence luminous material

Biogas recovery from microwave heated sludge by anaerobic digestion

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Science china(Technological Sciences) 2010年第1期53卷 144-149页

作者： QIAO Wei1,WANG Wei2,ZHU CuiPing3 & ZHANG ZhongZhi1 1 college of chemical Science and engineering,china university of Petroleum,Beijing 102249,china 2 Department of Environmental Science and engineering,Tsinghua university,Beijing 10084,china 3 J & K china Cleaning Energy technology Co.Ltd.,Beijing 100085,china 1. college of chemical Science and engineering China University of Petroleum Beijing 102249 China2. Department of Environmental Science and Engineering Tsinghua University Beijing 10084 China3. J & K China Cleaning Energy Technology Co. Ltd. Beijing 100085 China

Biogas generated from sewage sludge,livestock waste,and food waste by anaerobic digestion is a valuable renewable energy ***,conventional anaerobic digestion is not an efficient process.A long hydraulic retention time and low biogas recovery rate hinder the applications of those *** effective pretreatment method to destroy sludge microbial cells has been one of the major concerns regarding improvement of the biogas *** article focuses on the effects of microwave heating on sludge anaerobic *** suspended solid(VSS) and chemical organic demand solubilization of heated sludge were *** heating was found to be a rapid and efficient process for releasing organic substrates from *** increase of organic dissolution ratio was not obvious when holding time was over 5 min with microwave *** effect of the VSS solubilization was primarily dependent on heating *** highest value of VSS dissolving ratio,36.4%,was obtained at 170°C for 30 *** COD dissolving ratio was about 25% at 170°*** organic carbon of treated sludge liquor was 1.98 and 2.73 g/L at 150°C and 170°C for 5 min,respectively.A biochemical methane potential(BMP) test of excess sludge and a mixture of primary and excess sludge demonstrated an increase in biogas *** total biogas from microwave treated mixture sludge increased by 12.9% to 20.2% over control after 30 days of *** production was 11.1% to 25.9% higher for excess sludge than for untreated *** VS removal ratios of mixture sludge and excess sludge were 12% and 11% higher,respectively,compared to the untreated sludge.

关键词： biogas recovery microwave heating sludge anaerobic digestion

X-ray and Magnetoresistance Measurements of Electrodeposited Cu-Co Granular Films

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Journal of Materials Science & technology 2005年第3期21卷 307-310页

作者： Suwei YAO, Haixia WU, Weiguo ZHANG and Hongzhi WANG Sugiyama Laboratory of Surface technology, Department of Applied chemistry, School of chemical engineering and technology, Tianjin university, Tianjin 300072, china Department of Applied chemistry School of Chemical Engineering and Technology Tianjin University Tianjin 300072 China

Granular CoxCu1-x alloy films were prepared by electrodeposition at room temperature directly onto semiconducting Si substrate. X-ray diffraction (XRD) revealed that the as-deposited films formed single phase metastable fcc alloy structure. The fcc lattice parameter α was found to decrease linearly with increasing Co concentration x in the studied range. The giant magnetoresistance (GMR) of the films was improved after annealing. Pure Co fcc diffraction peaks were observed in the diffractogram of the annealed sample, indicating phase separation occurred upon annealing. The optimal annealing temperature was 450℃. The maximum of magnetoresistance (MR) ratio 8.21% was obtained for the Co20Cu80 thin film after annealing at 450℃ for 1 h. The saturation field decreased upon annealing in the MR curves of Co20Cu80 film.

关键词： Electrodeposition Giant magnetoresistance (GMR) Granular Phase separation

Integration of chemical product development, process design and operation based on a kilo-plant

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Progress in Natural Science:Materials International 2006年第6期16卷 600-606页

作者： QIAN Yu, WU Zhihui and JIANG Yanbin (School of chemical engineering, South china university of technology, Guangzhou 510640, china) [a] School of chemical engineering South China University of Technology Guangzhou China

Presented in this paper is an integrated approach of computer-aided product development, process design and operation analysis based on a kilo-plant. The implemented kilo-plant, as a research platform to manufacture product in kilogram-scale, was designed especially for fine and specialty chemicals. The characteristics of product synthesis, process operation and product quality control are investigated coupled with computer-aided monitoring, online modeling, simulation and operation process optimization. In this way, chemical product discovery, process design and operation are integrated in a systematic approach, in the aim to respond to rapid changing marketplace demands to new products.

关键词： integration kilo-plant product development process operation process analysis.

Preparation and Characterization of Chitosan/Carboxymethylated Konjac Glucomannan Blend Films

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Wuhan university Journal of Natural Sciences 2002年第1期7卷 107-112页

作者： Zheng Hua 1 , Du Yu-min 2 1. Department of chemical engineering, Wuhan university of technology, Wuhan 430070, Hubei, china 2. college of chemistry and Molecular Sciences, Wuhan university, Wuhan 430072, Hubei, china Wuhan university of technology Department of Chemical Engineering Wuhan Hubei China (GRID:grid.162110.5) (ISNI:***) Wuhan university College of Chemistry and Molecular Sciences Wuhan Hubei China (GRID:grid.49470.3e) (ISNI:***)

In order to improve the mechanical and water swelling properties of the chitosan (CS) film, a series of transparent films were prepared by blending 2%(weight) chitosan acetic acid solution with 1.5%(weight) carboxymethylated konjac glucomannan (CMKGM) aqueous solution according to predetermined ratio and drying at 30°C. The morphological structure, miscibility, thermal stability, mechanical properies, and swelling capacity of the blend films were studied by infrared (IR), X-ray diffraction (XRD), differential thermal analysis (DTA), scanning electron micrograph (SEM), and measurements of the mechanical properties and swelling properties. The results demonstrated that there was strong interaction and good miscibility between CS and CMKGM resulted from intermolecular hydrogen bonding and electrostatic force. The mechanical properties in dry state and wet state, thermostability, and water swelling properties of the blend films were obviously improved. The best values of the tensile strength in the dry and wet state achieved 89 MPa and 49 MPa, respectively, when the CMKGM content was 30%(weight). The CS/ CMKGM blend films provided promising biomedical applications.

关键词： Key words chitosan carboxymethylated konjac glucomannan blend films structure characterization

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利用半导体薄膜光催化降解苯酚

燃料化学学报 2001年第Z1期29卷 222-224页

作者：武正簧太原理工大学化学工程与技术学院山西太原030024

用有机钛镀膜 ,在光催化下对苯酚进行降解。结果表明 :镀膜时底物温度、鼓泡速度、溶液酸度、膜厚、光催化时间。

关键词：二氧化钛薄膜光催化降解