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Corrosion of titanium in supercritical water oxidation environments

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中国有色金属学会会刊：英文版 2002年第6期12卷 1054-1057页

作者：卢建树毛志远张九渊college of chemical engineering Zhejiang university of technology 马淳安college of chemical engineering Zhejiang university of technology 毛信表college of chemical engineering Zhejiang university of technology 李肖华college of chemical engineering Zhejiang university of technology college of chemical engineering Zhejiang University of Technology college of Materials and chemical engineering Zhejiang University

Supercritical water oxidation (SCWO) can effectively destroy many kinds of civilian and military wastes. The high temperature and high pressure SCWO operation conditions generate very corrosive environment that many engineering materials fail to withstand. Preliminary test shows that titanium may be a promising material in most of SCWO conditions. Commercially pure titanium is tested in four kinds of SCWO environments. Phenol, sodium dodecyl benzosulfonate, n amine phenol, and chlorpyrifos were chosen as typical target pollutants. The results show that titanium is only superficially attacked in the first three SCWO environments while in chlorpyrifos SCWO medium titanium is corroded. The corrosion is temperature dependent, with heavier corrosion occurring at near critical temperature. X ray diffraction analysis shows that the corrosion products consist of titanium oxy phosphates and titanium oxide, in which Ti 5O 4(PO 4) 4 is the main phase.

关键词：钛腐蚀超临界水氧化

Mathematical Model for the Drying Process of Granular Materials in a Fluidized Bed

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International Journal of Minerals,Metallurgy and Materials 2000年第4期14卷 296-300页

作者： Xiulan Huai, Li Wang, Zhiyun Qu ( Mechanical engineering School, university of Science and technology Beijing, Beijing 100083, china chemical Industry Research Institute of Shanxi, taiyuan 030031, china) Mechanical engineering School University of Science and Technology Beijing Beijing 100083 China chemical Industry Research Institute of Shanxi Taiyuan 030031 China

The experiment of granular materials, barley, drying in a fluidized bed was carried out to investigate the influence of the factors, inlet air temperature, air moisture, bed height and original moisture content of the dried materials on drying process. Based on the experimental data, a corresponding mathematical model is presented. As a conclusion, a higher inlet air temperature and a reasonable bed height should be used so as to increase the dring rate and to improve the product quality.

关键词： fluidization granular materials drying, experimental investigation mathematical model Information

Mesoporous Si-MCM-48 membrane prepared by pore-filling method

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Science china(Technological Sciences) 2010年第4期53卷 1064-1068页

作者： XU DeKan & FAN YiQun State Key Laboratory of Materials-Oriented chemical engineering,college of chemistry and chemical engineering,Nanjing university of technology,Nanjing 210009,china 1. State Key Laboratory of Materials-Oriented chemical engineering College of Chemistry and Chemical Engineering Nanjing University of Technology Nanjing 210009 China

Mesoporous MCM-48 membranes were prepared on asymmetric zirconia tubular support with an average pore size of 0.2 μm by hydrothermal *** support should be pretreated with H2O as a pore-filling substance to prevent the sol solution from infiltrating into the support *** SEM showed that the MCM-48 membrane was composed of tightly-connected spherical *** single gas N2 and H2 permeation experiments confirm that crack-free membrane could be prepared by pore-filling method.N2 permeance of MCM-48 membrane,synthesized by secondary growth,can reach 5.66×10-7 mol/Pa·s·m2,and the H2/N2 separation factor was 3.47 under trans-membrane pressure of 0.05 MPa.

关键词： MCM-48 mesoporous membrane pore-filling

Effect of strontium substitution on the activity of La_(2-x)Sr_xNiO_4(x=0.0-1.2)in NO decomposition

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Science china chemistry 2007年第1期50卷 41-46页

作者： ZHU JunJiang 1 ,YANG XiangGuang 2 ,XU XueLian 3 &WEI KeMei 1 1 National Research Center of chemical Fertilizer Catalysts,Fuzhou university,Fuzhou 350002,china 2 Changchun Institute of Applied chemistry,Chinese Academy of Sciences,Changchun 130022,china 3college of chemistry&chemical engineering,Fuzhou university,Fuzhou 350002,china 1. National Research Center of chemical Fertilizer Catalysts Fuzhou University Fuzhou 350002 China 2. Changchun Institute of Applied chemistry Chinese Academy of Sciences Changchun 130022 China 3. college of chemistry & chemical engineering Fuzhou University Fuzhou 350002 China

The aim of this work is to study the effect of Sr substitution on the redox properties and catalytic ac- tivity of La2-xSrxNiO4(x=0.0-1.2)for NO *** suggest that the x=0.6 sample shows the highest *** characterization(TPD,TPR,etc.)of samples indicates that the x=0.6 sample possesses suitable abilities in both oxidation and reduction,which facilitates the proceeding of oxygen desorption and NO *** temperature below 700℃,the oxygen desorption is difficult, and is the rate-determining step of NO *** the increase of reaction temperature(T> 700℃),the oxygen desorption is favorable and,the active adsorption of NO on the active site(NO+Vo+ Ni2+→NO^--Ni3+)turns out to be the rate-determining *** existence of oxygen vacancy is the prerequisite condition for NO decomposition,but its quantity does not relate much to the activity.

关键词： NO decomposition La2-xSrxNiO4 TPD TPR oxygen vacancy

Influence of steric and intramolecular inductive effects on the variable trends in R-X (R=Alkyl) bond dissociation energy

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Science china chemistry 2009年第7期52卷 943-951页

作者： CAO ChenZhong School of chemistry and chemical engineering, Hunan university of Science and technology, Xiangtan 411201, china School of chemistry and chemical engineering Hunan University of Science and Technology Xiangtan 411201 China

The question "why are the variation trends of R-X bond dissociation energy different?" is answered. The R-X bond dissociation energy (BDE) may be influenced by three main factors: the C-X intrinsic bond energy, the 1,3 geminal repulsion, and the intramolecular charge-induced dipole. In the presence of atom X, the variation trend of BDE in R-X (R= Me, Et, i-Pr, t-Bu) is dominated by two factors, the 1,3 geminal repulsion and the intramolecular charge-induced dipole. The former decreases the R-X BDE, and the latter either increases or decreases the R-X BDE. For the series of R-X with the R-C bond (such as R-Me, R-CH == CH2, R-C≡CH, and R-CN), the 1,3 geminal repulsion decreases the R-X BDE, and the variation trends of R-C BDE decrease from Me to t-Bu. As regards the series of R-X (such as R-H, R-BH2, and R-SiH2) in which the electronegativity of atom X is smaller than that of the carbon atom, the above two factors decrease the R-X BDE, and the variation trends of the R-X BDE decrease from Me to t-Bu. As to the series of R-X (such as R-F, R-OH, R-Cl, R-Br, R-I, and R-NH2) in which the electronegativity of atom X is larger than that of the carbon atom, the 1,3 geminal repulsion decreases the R-X BDE, while the intramolecular charge-induced dipole increases the R-X BDE. In this case, the variation trends of R-X BDE depend on the competition of the two factors. As a result, some of them (e. g., R-F, R-OH) increase from Me to t-Bu, some (e. g., R-I) decrease from Me to t-Bu, and some (e. g., R-Br) change very little.

关键词： bond dissociation energy charge-induced dipole geminal repulsion ionic configuration

Theoretical analysis of alloy multiplying factor by the empirical electron theory of solids and molecules

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Science china(Technological Sciences) 2007年第6期50卷 807-814页

作者： SONG YuePeng1,2, LIU GuoQuan2, LI ZhiLin3, FENG ChengMing1 1 Mechanical and Electronic engineering college, Shandong Agricultural university, Tai’an 271018, china 2 college of Materials Science and engineering, university of Science and technology, Beijing 100083, china 3 college of Material Science and engineering, Beijing university of chemical technology, Beijing 100029, china Mechanical Electronic engineering college Shandong Agricultural University Tai’an 271018 China college of Materials Science engineering University of Science technology Beijing 100083 China college of Material Science engineering Beijing University of Chemical Technology Beijing 100029 China

By introducing the distribution probability of structural units in austenite contain- ing alloying elements and considering its effects on phase transformation, this paper establishes a calculation model of distribution probability of structural units. A new valence electron structure (VES) parameter-transformation effect coefficient of alloying elements (HL), is defined and then studied both theoretically and ex- perimentally. The relationship between the parameter HL and the multiplying factor (the quenching capability factor) of alloying elements is studied. The results indi- cate that the two parameters (HL and the quenching capability factor) have the same variation characteristic and substance feature. Therefore, the multiplying factor virtually expresses the relative quantity of structural units in the alloying elements-containing austenite.

关键词： multiplying factor (the quenching capability factor), empirical electron theory of solids and molecules, transformation effect coefficient of alloying elements, structural units in austenite containing alloying elements

Hydroisomerization of n-heptane over bimetal-bearing H_3PW_(12)O_(40) catalysts supported on dealuminated USY zeolite

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Science china chemistry 2008年第2期51卷 120-127页

作者： WEI RuiPing1,2, GU YanBo1 & WANG Jun1 1 State Key Laboratory of Materials-Oriented chemical engineering, college of chemistry and chemical engineering, Nanjing Uni- versity of technology, Nanjing 210009, china 2 college of chemistry and chemical engineering, Southeast university, Nanjing 211189, china State Key Laboratory of Materials-Oriented chemical engineering College of Chemistry and Chemical EngineeringNanjing University of TechnologyNanjing 210009China college of chemistry and chemical engineering Southeast UniversityNanjing 211189China

The bimetal-bearing (CePt or LaPt) 12-tungstophosphoric acid (H3PW12O40 (PW)) catalysts supported on dealuminated USY zeolite (DUSY) were prepared by impregnation and characterized by XRD, BET, IR, and H2-chemisorption. Their catalytic activities were tested in the hydroisomerization of n-heptane with a continuous atmospheric fixed-bed reactor. After the steam treatment combined with the acid leaching, as well as the supporting with PW and the bimetals, the DUSY support retains the Y zeolite porosity and the PW well keeps its Keggin structure in catalysts. The doping of Ce into the catalysts enhances the dispersion of Pt on the catalyst surface. The Pt-bearing PW catalysts doped with Ce or La, especially Ce, exhibit much higher catalytic activity and selectivity than the catalysts without dopants at lowered reaction temperatures. At the optimal reaction conditions, i.e., the reaction temperature of 250℃ and WHSV of 1.4 h1, the catalyst with a Pt loading of 0.4%, PW loading of 10% and a molar ratio of Ce to Pt of 15:1 shows a conversion of n-heptane of 70.3% with a high selectivity for isomerization products of 94.1%.

关键词： hydroisomerization of n-heptane bimetal catalyst heteropoly acid USY platinum

Effects of Oxalic Acid Addition on the Hydrothermal Synthesis of Kaolinite

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Journal of Central South university 2000年第1期12卷 34-36页

作者： LIU Su qin,HUANG Ke long (college of chemistry and chemical engineering, Central South university of technology, Changsha 410083, china) 1. college of chemistry and chemical engineering Central South University of Technology 410083 Changsha China

Kaolinite was hydrothermally synthesized from alumina gel and silicate by dissolving alumina gel in oxalic acid before it was mixed with silicate, effects of the amount of addition on the species of synthetic products were discussed. The reaction product was characterized by X ray diffraction (XRD) and transmission electron microscopy (TEM). The results show that analcite is the only phase of the reaction solution without oxalic acid, the proportion of kaolinite in product increases with the amount of addition, and kaolinite is the main species when the molar ratio of oxalic acid to alumina reaches 0.6∶1.0. This is because oxalic acid addition is beneficial to the formation of kaolinite through changing the coordination number of aluminium from four to six, while the mixture of alumina gel, before it was dissolved in oxalic acid with silicate interfered with the crystallization of kaolinite.

关键词： kaolinite hydrothermal synthesis oxalic acid

Study on the Absorption Properties of C_(60) in Micellar Aqueous Solutions and Mechanisms for Solubilisation

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Chinese chemical Letters 1999年第2期10卷 161-164页

作者： Jin Li QIAO Wei Jun JIN Chuan DONG Chang Song LIU(Department of chemistry, Shanxi university. taiyuan, 030006)(taiyuan technology university, taiyuan, 030021) Department of chemistry Shanxi University Taiyuan 030006 China taiyuan technology university Taiyuan 030021 China

C60 is successfully solubilized in micelle of six kinds of surfactants and UV/Vis spectra ofC60 in micellar system are studied. It is found that Brij-35 is the most efficient surfactant forsolubilization of C60 and the possible states of C60 existed in surfactants are also *** of surface tension show that the sites for solubilization of C60 not only depend on thesorts of surfactants but also on their structures.

关键词： C_(60) absorption micelle solubilization