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SYNTHESIS AND CHARACTERIZATION OF NEW STABILIZERS WITH OPTIMAL MOLECULAR WEIGHT

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chinese Journal of Polymer Science 2001年第4期19卷 341-350页

作者： Jiang-qing Pan institute of chemistry chinese Academy of sciences, beijing 100080 china 中科院化学所北京

Over 2 x 10(8) tons of polymers are produced every year, and a large portion of polymers faces the degradation problem. There are many effective methods to protect polymers against degradation and the addition of stabilizers to polymer remains the most convenient and effective way of enhancing polymer life and performance. In this article, a series of effective stabilizers with optimal molecular weight (MW), including common, monomeric and polymeric stabilizers (antioxidant and light stabilizer) were synthesized using isocyanation, controlled isocyanation, hydrosilylation, epoxide addition, macroreaction of stabilizing functional compounds and polymerization of monomeric stabilizers. The structure and performance of these new stabilizers were characterized by using IR, NMR, MS, UV-spectra, XPS and elemental analysis. The current development of stabilizer synthesis was also reviewed.

关键词： preparation of stabilizer antioxidant hindered amine light stabilizer isocyanation hydrosilylation

PREPARATION AND PROPERTIES OF ETHYL-CYANOETHYL CELLULOSE/POLYACRYLIC ACID COMPOSITE FILMS WITH REFLECTION COLORS

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chinese Journal of Polymer Science 2001年第3期19卷 277-282页

作者： Yong Huang institute of chemistry, chinese Academy of sciences, beijing 100080 china Laboratory of Cellulose and Lignocellulosics chemistry Guangzhou institute of chemistry chinese Academy of sciences, Guangzhou 510650, china 中科院化学所北京

Ethyl-cyanoethyl cellulose [(E-CE)C]/acrylic acid (AA) becomes a cholesteric liquid crystalline solution withvivid colors when the (E-CE)C concentration is 42 wt%～52 wt%. (E-CE)C/polyacrylic acid (PAA) composites withcholesteric structure were prepared by polymerzing AA in (E-CE)C/AA liquid crystalline solutions. The layers of orderedpolymer chains in the cholesteric phase were inclined during polymerization and the degree of the inclination depended onthe polymerization temperature and the concentration of the solution before polymerization. The cholesteric structure in thecomposites could not be changed when temperature was lower than 100℃. Cross-linking of the PAA in compositesimproved their water-resistance. The cholesteric order of the composites without cross-linking was destroyed when theywhere immersed in water. The color derived from the selective reflection of the cholesteric phase of the cross-linkedcomposites turned from blue to red after the composites absorbed water. The color of the composites could be returned to theoriginal one when the absorbed water was removed from the swollen composites.

关键词： Cholesteric structure Composites Selective reflection Liquid crystalline solutions

Being the Pioneer of Life sciences in china——Introduction to beijing Genomics institute

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Genomics, Proteomics & Bioinformatics 2004年第1期2卷 59-63页

作者： Xin Zhang beijing Genomics institute, beijing 101300, china. beijing Genomics institute Beijing 101300 China

The beijing Genomics institute (BGI) of chinese Academy of sciences (CAS) wasofficially founded in December 2003. Its predecessor, beijing Huada Genomics Research Center, haspresented significant contributions to the development of life sciences in china by its excellentscientific innovations and achievements in the last five years. From the participation ofInternational Human Genome Project (HGP) to the independent completion of the whole-genome draft andfine maps of chinese super hybrid rice genome, from the porcine genome research cooperated withDenmark to the international chicken genome research, and from the silkworm genome projectaccomplished together with The Southwest Agriculture University of china to the great contributionsto the national campaign against SARS, all these facts illustrate that BGI not only has afirst-class scientific research power in the world but also is full of devotion to the flourish ofscience and nation. During these years, we have upheld the strategy of ''Advance through projects,strive for innovation, grow through cooperation'', in the aim of making BGI as one of the pioneers ofCAS climbing the peak of life sciences in the world.

关键词： chinese Academy of sciences beijing Genomics institute innovation life sciences

2023 Guideline for the management of hypertension in the elderly population in china

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Journal of Geriatric Cardiology 2024年第6期21卷 589-630页

作者： Hypertension Branch of chinese Geriatrics Society,beijing Hypertension Association,National Clinical Research Center of the Geriatric Diseases Qi HUA Li FAN Zeng-Wu WANG Jing LI 不详 Xuanwu Hospital Capital Medical UniversityBeijingChina chinese PLA General Hospital BeijingChina Fuwai Hospital Chinese Academy of Medical Sciences and Peking Union Medical CollegeBeijingChina

Preamble Hypertension is one of the most common chronic diseases and the primary risk factor for stroke,myocardial infarction and even cardiovascular *** than half of the elderly population has high blood *** people are a unique group,and strategies for the prevention,diagnosis,evaluation,and treatment of hypertension in elderly individuals differ significantly from those in the general population.

关键词： hypertension prevention diagnosis

STUDY ON THE SYNTHESIS AND PROPERTIES OF POLY(ESTER-IMIDEETHER)MULTIBLOCK COPOLYMERS

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chinese Journal of Polymer Science 2000年第1期18卷 9-13页

作者： Zu-yao Shan Zhen-yi Li institute of chemistry, chinese Academy of sciences, beijing 100080, china 中科院化学所北京

A new class of poly(ester-imide-ether) multiblock copolymers was synthesized by transes-terification and melt copolymerization of dimethyl terephthalate (DMT) and N-(4-carbomethoxyphenyl)-4-(carbomethoxy)-phthalimide with ethylene glycol (EG) and polytetramethylene glycol (PTMG). The structure of the above copolymers was characterized by H-1-NMR and IR spectroscopy. Some properties of the coplymers were also examined. It was found that their mechanical properties and heat stability, compared with poly(ether-ester) copolymers, were obviously improved.

关键词： N-(4-carbomethoxyphenyl)-4-(carbomethoxy)-phthalimide polyester-polyether copolymer poly-(ester-imidether) multiblock copolymer imide modification

Zonal propagation of kinetic energy and convection in the South china Sea and Indian monsoon regions in boreal summer

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Science china Earth sciences 2004年第12期47卷 1076-1084页

作者： CHEN Longxun 1 ,GAO Hui 2 ,HE Jinhai 2 ,TAO Shiyan 3 & JIN Zuhui 3 1.chinese Academy of Meteorological sciences,beijing 100081,china 2.Nanjing institute of Meteorology,Nanjing 210044,china 3.institute of Atmospheric Physics,chinese Academy of sciences,beijing 100029,china chinese Academy of Meteorological sciences Beijing China Nanjing institute of Meteorology Nanjing China chinese Academy of sciences Institute of Atmospheric Physics Beijing China

Zonal propagation of kinetic energy (KE) and convection in the South china Sea (SCS) and Indian summer monsoon areas are examined in present study. Results suggest that the SCS and Indian summer monsoon prevailed regions (5 —15°N) are dominated by the southwesterly wind, however, the disturbances of KE at 850 hPa and convection are observed mainly coming from the western Pacific Ocean (140—150°E), after passing through the SCS, and westward propagated into the Bay of Bengal (90—100°E). In the Indian summer monsoon domain, where the disturbances of KE are found mainly coming from the Arabian Sea (AS) and eastward propagated into the Bay of Bengal. Therefore, the SCS and the Indian summer mon- soon are quite different in zonal propagation of KE and convection. The SCS summer monsoon is mainly affected by the KE and convection coming from the tropical western Pacific. The Indian summer monsoon, however, can be partly influenced by the AS and the SCS summer monsoon. The analysis also suggests that the interaction region between the SCS and the Indian summer monsoon is around 90—95°E, rather than 105°E as proposed by earlier studies.

关键词： zonal propagation of KE and convection, East Asian monsoon, Indian monsoon.

Spectrophotometric determination of cationic surfactants by formation of ternary complexes with Fe(Ⅲ) and chrome azurol S

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chinese Journal of chemistry 1996年第3期14卷 228-234页

作者： SONG, Ming LIANG, Shu-Quan institute of chemistry, chinese Academy of sciences, beijing 100080, china institute of chemistry Chinese Academy of Sciences Beijing 100080 China

An extraction-free spectrophotometric method for the determination of cationic surfactants, such as cetylpyridinium chloride, cetyltrimethylammonium bromide and zephiramine is proposed, which is based on the formation of ternary complexes with Fe(Ⅲ) and chrome azurol S. The molar ratio of the complex is 2:1:1 (Fe(Ⅲ):chrome azurol S:cationic surfactant). The method is simple, rapid and sensitive, giving an apparent molar absorptivity of 4.5×104 ***-1 and a linear range of 0.1-6.0 umol/L cationic surfactants. The total cationic surfactant content can be determined directly in aqueous solutions by measuring the absorbance at 680 nm (pH 5.8). The method has been successfully applied to water samples.

关键词： Cationic surfactant determination spectrophotometry ternary complex Fe(Ⅲ) chrome azurol S

Mass Spectrometric Evidence of Heparin Disaccharides for the Catalytic Characterization of A Novel Endolytic Heparinase

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Acta Biochimica et Biophysica Sinica 2004年第12期36卷 840-844页

作者： Yapeng CHAO1,3, Shaoxiang XIONG2, Xiulan CHENG1, and Shijun QIAN1* 1institute of Microbiology, chinese Academy of sciences, beijing 100080, china 2Center of Mass Spectrometry, institute of chemistry, chinese Academy of sciences, beijing 100080, china 3Graduate School of the chinese Academy of sciences, beijing 100039, china institute of Microbiology Chinese Academy of SciencesBeijing 100080 China Graduate School of the chinese Academy of sciencesbeijing 100039 China Center of Mass Spectrometry Institute of Chemistry Chinese Academy of SciencesBeijing 100080 China

Heparinase from different sources can eliminate heparin or/and heparan sulfate into various low-molecular weight heparins with different characteristics. Porcine intestinal mucosa heparin was de- graded into a series of oligosaccharides by a novel heparinase from the species Sphingobacterium. Disaccha- ride components from the digests were separated and purified by ultrafiltration and HPLC. Five major peaks appeared as three types according to their retention time. The mass spectrometry of peak I mainly gave the non-sulfated disaccharide with the mass of 379 Da. Peak II and III were indicated as two major monosulfated disaccharides with molecular mass of 417 and 459 Da respectively. Moreover, the peak III represented an N- acetyl disaccharide. Both peak IV and V showed the same mass of 496 Da, hinting that they were disulfate- substituted disaccharides. No trisulfate-substituted disaccharides were detected in the mixture of the heparin digest though they were abundant in the heparin structure. The results revealed that the heparinase might specifically cut the sites with low sulfated domain in heparin.

关键词： electrospray ionization-mass spectrometry heparin disaccharides heparinase high perfor- mance liquid chromatography Sphingobacterium sp.

PHASE STRUCTURE AND PROPERTIES OF EPOXY RESIN MODIFIED BY POLYSILOXANE BEARING PENDANT AMINO GROUPS

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chinese Journal of Polymer Science 2000年第2期18卷 133-138页

作者： Bing Zhang Xiang-luan Liu Ying Huang Center of Molecular sciences, institute of chemistry, chinese Academy of sciences, beijing 100080, china 中科院化学所北京

Polysiloxane-modified epoxy resins were prepared through the reaction of epoxy resin with polydimethylsiloxanes bearing pendant N-(beta-aminoethyl)-gamma-aminopropyl groups. The morphology and properties of the cured epoxy resins modified by the polysiloxanes were investigated. It was found that the phase structure and properties of the cured epoxy resins depend mainly on the amino group content in the polydimethylsiloxane and the level of the modifier. The change of phase structure in the cured epoxy resin systems was responsible for the dramatic change in their mechanical and surface properties.

关键词： phase structure polysiloxane epoxy resin mechanical property