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chinese Journal of Chemistry 2004年第7期22卷 714-718,615页

作者：魏琴吴丹杜斌张慧欧庆瑜lanzhou institute of chemical physics chinese academy of sciences lanzhou Gansu 73.000 china School of Chemistry & chemical Engineering Jinan University Jinan Shandong 250022 China Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou Gansu 730000 China School of Chemistry & chemical Engineering Jinan University Jinan Shandong 250022 China

The application of 5'-nitrosalicylfluorone (5'-NSF)-molybdenum(VI) complex as a spectroscopic probe was studied. In the buffer medium of HOAc-NaOAc at 3.45 and in the presence of PVA 124 microemulsion, 5'-NSF-Mo(VI) complex combines protein rapidly to form a stable compound, leading to an absorbance decrease at 525 nm of 5'-NSF-Mo(VI) complex. According to this change, microdetermination of protein has been described. Bovine serum albumin (BSA) could be determined in the linear range of 0—16 g昺L-1 with the detection limit of 11 ngmL-1. Many amino acid and metal ions studied do not interfere with the assay. The method possesses high sensitivity as well as high selectivity. It can be used to determine protein in human urine and milk powder successfully. The relative standard deviations are in all instances less than 4.7%, and the recoveries are between 97.6% and 106.0%. Moreover, the binding number of BSA with the complex, which is determined by using molar ratio, Rosenthanl graphic and slope ratio methods, is in good agreement with each other.

关键词： protein spectrophotometry 5'-NSF-Mo(VI) complex microemulsion

Characterization and Tribological Behavior of Octadecene,Dodecene and Undecenoic Acid Films on Si Substrate

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Journal of Materials Science & Technology 2005年第5期21卷 671-674页

作者： Jinfang ZHOU+ and Shengrong YANGState Key Laboratory of Solid Lubrication, lanzhou institute of chemical physics, chinese academy of sciences, lanzhou73.000, china State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China

The films of octadecene, dodecene, and undecenoic acid were prepared on H-terminated Si surface in the presence of ultraviolet irradiation. The resulted films were characterized with water-contact angle measurement and infrared spectroscopy. The friction-reducing behavior of the prepared films was examined on a static-dynamic friction coefficient measurement apparatus and on an atomic force microscope. It was found that all the reacted films on the Si substrate showed good friction-reducing ability; especially, the film of the octadecene exhibited the best friction-reducing ability. This was attributed to the transfer of the reacted films onto the counter face with formation of a transfer film on the counterpart surface, which led to the transformation of the sliding between the reacted films and the hard ceramic to fiat between the reacted films and its transfer film on the counterpart surface. The macroscopic and microscopic friction behaviors of the prepared films were dependent on their molecular chain lengths. Thus the octadecene reacted film with the highest degree of ordering arrangement showed the best friction-reducing and antiwear abilities in sliding against Si3N4.

关键词： Alkese Reaction film Hydrogen-terminated silicon Tribological behavior

The solid lubricating material experiment device for Shenzhou-7 Spaceship

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Science china(Technological sciences) 2010年第9期53卷 2521-2527页

作者： WANG Ke1,2,REN WeiJia1,WANG ShiDa1 & WENG LiJun3 1 academy of Opto-Electronics,chinese academy of sciences,Beijing 100190,china 2 Graduate University of chinese academy of sciences,Beijing 100049,china 3.lanzhou institute of chemical physics,chinese academy of sciences,lanzhou 73.000,china 1. academy of Opto-Electronics Chinese Academy of Sciences Beijing 100190 China2. Graduate University of Chinese Academy of Sciences Beijing 100049 China3. Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China

A solid lubricating material exposure experiment in space is one of the missions during the seventh manned spaceflight of china,and the key is to develop a device which can be fixed reliably outside of the orbital module and can be fetched conveniently by an astronaut during space *** solid lubricating material experiment device needs to be locked reliably in a vibrating and impacting environment during the launch phase,and should meet the requirement that it can be unlocked and fetched reliably by the astronaut wearing an extravehicular spacesuit via simple operations in orbit in an environment of high and low *** for the device we developed,the environmental characteristic of the mission was analyzed,the mechanical analysis and thermal analysis were carried out,and then a mechanism with functions of mechanical locking,structural self-locking and manual unlocking was *** device was verified by a sequence of experiments and was fetched by the astronaut during the flight of the Shenzhou-7 Spaceship.

关键词： manned spaceflight exposure experiment mechanism unlock

C_(19)-DITERPENOID ALKALOIDS OF DELPHINIUM MOLLIPILUM

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chinese chemical Letters 1995年第2期6卷 101-102页

作者： Suo Ming ZHANG Qing Yu Ou(lanzhou institute of chemical physics, chinese academy of sciences, lanzhou 73.000) chinese Acad Sci Lanzhou Inst Chem Phys Lanzhou 730000 Peoples R China

Five C19-diterpenoid alkaloids were isolated from the aerial parts of Delphinium mollipilum ***. Four proved to be the known talitine B,talitine A, browniine and delcosine, while the fifth was a new C19-diterpenoid al...

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MECHANISM OF SULFUR POISONING AND REGENERATION METHODS FOR SUPPORTED METAL CATALYSTS Ⅰ. MECHANISM OF SULFUR POISONING OF Pd(Pt)/Al_2O_3 CATALYSTS IN H_2-O_2 REACTION

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分子催化 1990年第S1期4卷 23-32页

作者： Deng Youquan An Lindun(lanzhou institute of chemical physics, chinese academy of sciences, lanzhou, china)

Sulfur poisoning mechanism of Pd（Pt）/Al2O3 catalysts for H2—O2 reaction was studied by means of micro-catalytic reaction chromatograph, TPR, XPS, AES, XRD and IR. The results show that the tolerance of Pd/Al2O3 catalysts to surfur poisoning is significantly affected by the O2/H2 ratio and enhanced with the increase of the ratio. In″weak″oxidizing atmosphere, the deactivation is swift and irreversible because of the active components, particularly at the surface, being seriously sulfided by S-2. In ″strong″ oxidizing atmosphere, the poisoning caused by S-2 is reversible to great extent owing to the reaction Ms—S/Al2O3（O2,H2O）/catalyst（Ms（MsO）/Al2O3-SO3-H2O）where Ms signifies Pd or Pt on the surface. But, when the sulfate in catalyst is accumulated in large amount, it could cover or block the active sites, which may be an important cause of the catalyst deactivation in addition to the sulfidization of metal components.

关键词： poisoning oxidizing seriously irreversible accumulated sulfur Pt Sulfur appearance latter

Enthalpy and entropy interaction parameters of sodium chloride with some monosaccharides in water

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Science china Chemistry 2004年第1期47卷 59-66页

作者： ZHUO Kelei, WANG Jianji, BAI Guangyue, YAN Haike & WANG HangingSchool of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453002, china institute of Chemistry, chinese academy of sciences, Beijing 100080, china lanzhou institute of chemical physics, chinese academy of sciences, lanzhou 73.000, china 1. School of Chemistry and Environmental Science Henan Normal University 453002 Xinxiang China 2. institute of Chemistry Chinese Academy of Sciences 100080 Beijing China 3. lanzhou institute of chemical physics Chinese Academy of Sciences 730000 Lanzhou China

Dilution enthalpies of sodium chloride and some monosaccharides (glucose, galactose, xylose, arabinose, and fructose) in water and mixing enthalpies of aqueous sodium chloride and these monosaccharide solutions were measured by using an improved precision semimicro-titration calorimeter. Transfer enthalpies of sodium chloride from water to aqueous saccharide solutions were evaluated as well as enthalpy interaction parameters of sodium chloride with these monosaccharides in water. Combined with Gibbs energy interaction parameters, entropy interaction parameters were also obtained. The results show that interactions of the saccharides with sodium chloride depend on the stereochemistry of saccharide molecules. These interaction parameters can identify stereochemical structure of saccharide molecules. Keywords sodium chloride - monosaccharide - enthalpy interaction parameter - entropy interaction parameter - calorimetry

关键词： sodium chloride, monosaccharide, enthalpy interaction parameter, entropy interaction parameter, calorimetry.

Reaction Chemistry of W-Mn/SiO2 Catalyst for the Oxidative Coupling of Methane

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Journal of Natural Gas Chemistry 2003年第1期12卷 1-9页

作者： Shuben LiState Key Laboratory for Oxo Synthesis and Selective Oxidation, lanzhou institute of chemical physics, chinese academy of sciences, lanzhou 73.000, china State Key Laboratory for Oxo Synthesis and Selective Oxidation Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China

Reaction chemistry of the OCM reaction on W-Mn/SiO_2 catalyst has beenreviewed in this account. Initial activity and selectivity, stability in a long-term reaction,reaction at elevated pressures and a modelling test in a stainless-steel fluidized-bed reactor showthat W-Mn/SiO_2 has promising performance for the development of an OCM process that directlyproduces ethylene from natural gas. A study on surface catalytic reaction kinetics and used catalyststructure characterization revealed a possible reason why C_2 and CO_x selectivity changed duringthe long-term reaction. Further improvement of the catalyst composition and preparation methodshould be a future direction of study on OCM reaction over W-Mn/SiO_2 catalyst.

关键词： W-Mn/SiO_2 catalyst oxidative coupling of methane elevated pressure methane

Rem-meter correction factor for measuring high energyneutrons outside concrete shielding

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Nuclear Science and Techniques 1998年第2期9卷 109-112页

作者： Li Gui-Sheng (institute of Modern physics, the chinese academy of sciences, lanzhou 73.000) Inititute of Modern physics Chinese Academy of Sciences Lanzhou 730000 China

Correction factors of both Rem-meters, the 10 inch diameter single-sphere Remmeter and the standard A-B Rem-meter, were estimated for measuring high energy neutron dose equivalent outside a concrete shielding wall and the effects that the emitted neutron spectra become remarkably "harder" penetrated through a concrete shielding wall, and the energy response of the Rem-meter were taken in account. The estimated results could be applied in the measurement of neutron dose equivalent for the intermediate energy heavy ion reactions to avoid the difficulty induced by the energy response of the Rem-meters.

关键词：高能中子混凝土屏蔽雷姆米修正因子

Organic geochemical studies of sinking particulate material in china sea area Ⅱ——Geochemical significance of compositional features of ketone, aldehyde and alcohol compounds

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chinese Science Bulletin 1997年第22期42卷 1894-1898页

作者： DUAN Yi,CUl Mingzhong, MA Lanhua, SONG Jinming, ZHOU Shixin and LUO Binjie1. lanzhou institute of Geology, chinese academy of sciences, lanzhou 73.000, china 2. Earthquake Research institute of lanzhou, SSB, lanzhou 73.000, china 3. institute of Oceanology, chinese academy of sciences, Qingdao 266071, china lanzhou institute of Geology Chinese Academy of Sciences Lanzhou China Earthquake Research institute of lanzhou SSB Lanzhou China institute of Oceanology Chinese Academy of Sciences Qingdao China

SINKING particulate organic matter of the sea plays an important role in marine environment. Itnot only provides food for marine organisms and takes part in chemical cycling, but also pro-vides sedimentary organic matter for marine sediments. Therefore, researchers always payclose attention to the source and processes of transport and transformation of marine sinkingparticulate organic matter. Its transport process can be understood by measuring the

关键词： marine sinking paniculate material composition of lipid compounds organic matter source and biochemical pro-cesses.

Catalytic Activity and Stability of Mo_2N in CO Oxidation

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chinese chemical Letters 1998年第6期9卷 579-581页

作者： Guo Huang XIE Zhi Cheng JIANG Ting Fang BAI Han Qing WANG(lanzhou institute of chemical physics, chinese academy of sciences,lanzhou 73.000) chinese Acad Sci Lanzhou Inst Chem Phys Lanzhou 730000 Peoples R China

Molybdenum nitride powder with 115 m^2g^(-1) of Sg has been prepared by atemperature programmed reaction of MoO_3 in H_2/N_2 mixture. It exhibited high catalyticactivity in CO oxidation at low temperatures. DTA in airflow showed that the crystalphase of Mo_2N was maintained under 500℃. The suitable operation temperature isbelow 500℃ in CO oxidation.

关键词： Mo_2N CO oxidation stability