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Indian Ocean-MORB-type isotopic signature of Yushigou ophiolite in North Qilian Mountains and its implications

science China earth sciences 2006年第6期49卷 561-572页

作者： HOU Qingye1,2, ZHAO Zhidan1,2, ZHANG Hongfei3. ZHANG Benren3.& CHEN Yuelong2 1. State Key Laboratory of Geological Processes and Mineral Resources, China university of geosciences, Beijing 100083. China 2. School of earth {3. and Mineral Resources, China university of geosciences, Beijing 100083. China 3. faculty of earth {3.s, China university of geosciences, wuhan 43.074, China 1. State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Beijing 100083 China 2. School of earth science and Mineral Resources China University of Geosciences Beijing 100083 China 3. faculty of earth sciences China University of Geosciences Wuhan 430074 China

In order to explore the disputed issue concerning the tectonic affinity ofthe ancient ocean mantle of North Qilian Mountains (NQM), geochemical and Sr, Nd, Pb isotopiccompositions of pillow basalts of the Yushigou Ophiolite (YSGO) suite from NQM have been analyzedsystematically. The pillow basalts exhibit tholeiitic characteristics, with flatchondrite-normalized REE patterns ((La/Yb)_N = 0.98—1.27). They display no Nb, Ta, Zr, Hf negativeanomalies, and show MORB features in 2Nb-Zr/4-Y and Ti/100-Zr-YX3.tectonic discrimination *** results indicate that the Yushigou ophiolite is most likely to be formed in a mid-ocean ridgeor mature back-arc basin. Their isotopic data show a relatively broad and enriched ^(87)Sr/^(86)Sr(0.70509 — 0.70700), restricted ^(143.Nd/^(144)Nd (0.512955-0.512978). Pb isotopes are in the rangeof ^(206)Pb/^(204)Pb (18.054-20.562), ^(207)Pb/^(204)Pb (15.53.-15.743. and ^(208)Pb/^(204)Pb(3..068-3..53.). These isotopic data imply that the basalts originated from the depleted mantle(DMM), with the involvement of enriched mantle components (mainly EMII). Geochemical comparisonsbetween the basalts in YSGO and the MORB-type basalts of ophiolite suites occurring in the knownancient Tethyan tectonic domain indicate that the ancient oceanic mantle represented by YSGO suiteforming in early Paleozoic in the North Qilian Moutains is very similar to the Tethyan mantle inboth trace elements and isotopic compositions. The North Qilian Mountains should be a part of theTethyan tectonic domain in early Paleozoic. This further implies that the Tethyan tectonic domaincan be deduced to early Paleozoic in the study area, which will be helpful to discussing thetectonic affinity and evolution of the North Qilian Mountains.

关键词： geochemistry, Indian Ocean-MORB-type isotopic signatures, Tethyan tectonic domain, Yushigou ophiolite, North Qilian Mountains.

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Exsolution of ilmenite and Cr-Ti magnetite from olivine of garnet-wehrlite

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science China earth sciences 2005年第9期48卷 1368-1376页

作者： LIU Xiangwen1,2, JIN Zhenmin1,3. QU Jing2 & WANG Lu2 1. State Key Laboratory of Geological Processes and Mineral Resources, China university of geosciences, wuhan 43.074, China 2. Graduate School of China university of geosciences, wuhan 43.074, China 3. faculty of earth sciences, China university of geosciences, wuhan 43.074, China 1. State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences 430074 Wuhan China 2. Graduate School of China university of geosciences 430074 Wuhan China 3. faculty of earth sciences China University of Geosciences 430074 Wuhan China

Exsolution of rod-like ilmenite (Ilm) and Cr-Ti magnetite (Mt) have been found in olivine of garnet-wehrlite from the core of Chinese Continental sciences Drilling (CCSD). Their composition, morphology, crystal structure and their topotaxies with host olivine have been studied in detail by the transmission electron microscopy (TEM) and electron probe microanaly- sis (EPMA) technique. It shows that rod-like Ilm exsolution reported in this paper has similar characteristic with that of Alpe Arami olivine, while Cr-Ti magnetite exsolution mentioned in this paper has large discrepancy with chromite exsolution in Alpe Arami olivine. These observations suggest that both of the exsolutions found in this paper should be solid solution phases in β-olivine at their first period, then experiencing decomposition of solid solution and therefore forming Ilm and Cr-Ti magnetite exsolution with the pressure decreasing. So, this garnet-wehrlite perhaps had been ever located in mantle transition zone with a minimum depth of 3.0 km.

关键词： garnet-wehrlite, ilmenite, magnetite, exsolution, CCSD.

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Water in peridotite xenoliths from South China

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science China earth sciences 2011年第10期54卷 1511-1522页

作者： WANG Rong 1,2,3.& ZHANG BaoMin 3.1 faculty of Land Resource Engineering, Kunming university of science and Technology, Kunming 650093. China 2 State Key Laboratory for Mineral Deposits Research, Nanjing university, Nanjing 210093. China 3.faculty of earth science, China university of geosciences, wuhan 43.074, China 1. faculty of Land Resource Engineering Kunming University of Science and Technology Kunming 650093 China2. State Key Laboratory for Mineral Deposits Research Nanjing University Nanjing 210093 China3. Faculty of Earth Science China University of Geosciences Wuhan 430074 China

The water contents of nominally anhydrous clinopyroxene （cpx）, orthopyroxene （opx） and olivine （ol） in peridotite xenoliths hosted by Cenozoic basalts from Yingfengling, Zhangchouchun, Fujitian and Lindi, South China, were measured by Micro- FTIR. All cpx and opx grains contained a certain amount of water, which was indicated by the presence of hydroxyls in the crystal structure. The water contents （H20, ppm） of cpx and opx from peridotite xenoliths of the study areas were 293.981, 183.752, 73.586 and 51-423.ppm, and 82-471, 74-571, 53.170 and 9-13. ppm, respectively. No prominent OH absorption bands were detected for any ol grains, indicating that the water contents were below the detection limit （approximately 2 ppm）. The entire rock contents recalculated according to mineral volume proportions were 49-163. 48-168, 21-111 and 8-40 ppm, respectively. Combined with previously reported data describing the water contents of peridotite xenoliths worldwide, the results presented here suggest that water distribution in the continental lithospheric mantle is spatially heterogeneous at a global scale. The lithospheric mantle of South China is much richer in water than that of the North China Craton, and is close to that typical of off-craton localities, such as the Basin and Range Province, and Massif Central.

关键词： FTIR water peridotite xenoliths South China

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Experimental remolding on the caprock's 3. strain field of the Indosinian-Yanshanian epoch in Tongling deposit concentrating area

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science China earth sciences 2005年第7期48卷 863-874页

作者： DENG Jun1,HUANG Dinghua2,WANG Qingfei1,WAN Li1,SUN Zhongshi3.YANG Liqiang1 & GAO Bangfei1 1. State Key Laboratory of Geological Processes and Mineral Resources,China university of geosciences,Beijing 100083.China 2. faculty of {3. sciences,China university of geosciences,wuhan 43.074,China 3. Department of {3. sciences,Jilin university,Changchun 13.061,China State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Beijing 100083 China faculty of earth sciences China University of Geosciences Wuhan 430074 China Department of earth sciences Jilin University Changchun 130061 China

Based on field observations and rheology analysis, we perform one analogue experiment and remold the 3. structural frame of Tongling deposit concentrating area firstly. Then we disassemble and dialyze the 3. structures of the model using the methods of "slicing" and "stripping". A series of sliced planes vertical to the fold hinges show similar landscapes of that in the drill hole profiles. Meanwhile, layer stripping analysis indicates that the deformation features of each layer in the model are qualitatively analogical to those obtained from field observations. Through contrasting the 3. structure between the experimental model and the field phenomena, we verify the following 3. deformation features of the caprock in this area: (1) the Tongling area mainly consists of three series of NE S-typed fold groups; (2) in the uniform stress field, the incoherent folds universally develop in different positions, along different axes as well as in different strata; (3. the faults propagate upward which are mostly inter-bedded detachment faults, while the fold amplitudes decrease while going deeper; and (4) the folds and cleavages are highly developed in the Silurian System indicating that the deformation effect of the Indosin-ian-Yanshanian structural layer terminates at this layer, which suggests that the Silurian System is the crucial layer for the inversion between brittle and plastic deformation domains and the underlying strata are subject to the control of another deformation system with distinct properties.

关键词： Tongling deposit concentrating area Indosinian-Yanshanian epoch 3. structural frame of the caprock analogue experiment slicing and stripping analysis structural model.

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Sm-Nd and zircon SHRIMP U-Pb dating of Huilanshan mafic granulite in the Dabie Mountains and its zircon trace element geochemistry

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science China earth sciences 2005年第12期48卷 2081-2091页

作者： HOU Zhenhui1, LI Shuguang1, CHEN Nengsong2, LI Qiuli1 & LIU Xiaoming3.1. School of earth and Space sciences, university of science and Technology of China, Hefei 23.026, China 2. The Key Laboratory of Continental Dynamics of the Ministry of Education, Northwest university, Xi’an 710069, China 3. faculty of earth sciences, China university of geosciences, wuhan 43.074, China 1. School of earth and Space sciences University of Science and Technology of China 230026 Hefei China 2. The Key Laboratory of Continental Dynamics of the Ministry of Education Northwest University 710069 Xi’an China 3. faculty of earth sciences China University of Geosciences 430074 Wuhan China

The mafic granulites from Huilanshan are outcropped on the center of the Luotian dome in the northern Dabie Mountains. The Sm-Nd isochron defined by granulite-facies meta-morphic minerals (garnet + clinopyroxene + hypersthene) yields an age of 13. ± 18 Ma indicating the early Cretaceous granulite-facies metamorphism. The cathodoluminescence (CL) images of zircons from the granulite show clearly core-mantle-rim structures. The zircon cores are charac-terized by typical oscillatory zoning and highly HREE enriched patterns, which suggests their magma origin. Some zircon cores among them with little Pb loss give SHRIMP U-Pb ages rang-ing from 753.to 780 Ma, which suggests that the protolith of Huilanshan granulite is Neopro-terozoic mafic rocks. The zircon mantles usually cut across the oscillatory zone of the zircon cores have 3.10 times lower REE, Th, U, Y, Nb and Ta contents than the igneous zircon cores but have high common Pb contents. These characteristics suggest that they were formed by hydrothermal alteration of the igneous zircons. The part of zircon mantles with little Pb loss give a similar SHRIMP U-Pb age (716―780 Ma) to the igneous zircon cores, which implies that the hydrothermal events occurred closely to the magmatic emplacement. In view of the strong early Cretaceous magmatism in the Luotian dome, consequently, the Huilanshan mafic granulite was formed by heating of the Neoproterozoic mafic rocks in mid-low crust, which caused the granu-lite-facies metamorphism underneath the Dabie Mountains. The similarity between the granulite metamorphic age (13. ± 18 Ma) defined by Sm-Nd isochron and K-Ar age of 123.127 Ma given by amphible from the gneiss in Luotian dome suggests a rapid uplifting of the Luotian dome, which may result in further exhumation of the ultrahigh pressure metamorphic rocks in the Dabie Mountains.

关键词： Dabie orogen, granulite, zircon U-Pb ages, Sm-Nd age.

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Petrogenesis and dating of the Kangding complex,Sichuan Province

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science China earth sciences 2005年第5期48卷 622-634页

作者： CHEN Yuelong 1 , LUO Zhaohua 1 , ZHAO Junxiang, LI Zhihong, ZHANG Hongfei & SONG Biao 3.1. faculty of earth sciences and Natural Resources, China {3. of geosciences, Beijing 100083. China 2. faculty of earth sciences, China {3. of geosciences, wuhan 43.074, China 3. Beijing SHRIMP Center, Institute of Geology, Chinese Academy of Geological sciences, Beijing 10003., China 1. faculty of earth sciences and Natural Resources China University of Geosciences 100083 Beijing China 2. faculty of earth sciences China University of Geosciences 430074 Wuhan China 3. Beijing SHRIMP Center Institute of Geology Chinese Academy of Geological Sciences 100037 Beijing China

An analysis of major and trace element geochemistry and SHRIMP U-Pb zircon dating of mafic, intermediate, and felsic rocks from the Mianning metamorphic complex of Si- chuan Province was conducted. One of our conclusions is that a majority of the zircons crystal- lized between 721 and 773.Ma in a magmatic regime. The complexes contain early to late Pa- leo-proterozoic relict zircons from ancient continental crust. The oldest age, 2468 Ma, may rep- resent the basement of the Yangtze block. Overgrowth zircon rims and palingenetic zircons have been observed and dated, and are believed to have formed after crystallization, during Paleozoic and Mesozoic metamorphic-anatexis. We also conclude that depletion of Nb, Ta, HREE, in a spider-diagram normalized to primitive mantle and calc-alkaline association, implies that they formed in island-arc or under-plating settings.

关键词： Kangding complex, zircons, SHRIMP, tectonic setting.

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Experimental study of ore gabbro liquid immiscibility

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science China earth sciences 2005年第4期48卷 496-505页

作者： SANG Zunan1,2, XIA Bin1, ZHOU Yongsheng3.& JIN Zhenmin4 1. Guangzhou Institute of Geochemistry, Chinese Academy of sciences, Guangzhou 510640, China 2. wuhan university, wuhan 43.072, China 3. Institute of Geology, China Seismological Bureau, Beijing 100029, China 4. faculty of earth sciences, China university of geosciences, wuhan 43.074, China 1. Guangzhou Institute of Geochemistry Chinese Academy of Sciences 510640 Guangzhou China 2. wuhan university 430072 Wuhan China 3. Institute of Geology China Seismological Bureau 100029 Beijing China 4. faculty of earth sciences China University of Geosciences 430074 Wuhan China

In this paper, the authors present the results of a preliminary experimental study on partial melting of fine-grained gabbro, Panzhihua, Sichuan Province, China. Experiments were conducted under (confining) pressure ranging from 450 to 500 MPa and temperature of 900— 1200℃. The results show that the initial melt is distributed along grain boundaries and triple junctions. Liquid immiscibility phenomena are noted in the melt with two compositional different melt phases, i.e. matrix and sphere phases. The matrix phase is relatively rich in Si, Al and K, and is depleted in Mg, Fe, Ca, Na and Ti, whereas the sphere phase shows opposite trends. The calculation of the melt free energy indicates that the liquid immiscibility is governed by the rule of thermodynamics, as the liquid immiscibility would result in the decrease in free energy of the melt system. The field relationships suggest that the liquid immiscibility may have played an important role in the generation of ore magma of Panzhihua V-Ti magnetite ore deposit. This study thus provides experimental constraints on the mechanism of the formation of V-Ti magnetite deposite.

关键词： partial melting, experimental study, gabbro, liquid immiscibility, ore formation mechanism.

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The role of aerial algae in the formation of the landscape of the Yunnan Stone Forest,Yunnan Province, China

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science China earth sciences 2004年第9期47卷 846-864页

作者： TIAN Youping1,3. ZHANG Jie2, SONG Linhua1 & BAO Haosheng2 1. Institute of Geographic sciences and Natural Resources Research, Chinese Academy of sciences, Beijing 100101, China 2. Department of Geography, Nanjing university, Nanjing 210093. China 3. School of {3. sciences and Resources, China university of geosciences, Beijing 100083. China Institute of Geographic sciences and Natural Resources Research Chinese Academy of Sciences Beijing 100101 China Department of Geography Nanjing University Nanjing 210093 China School of earth sciences and Resources China University of Geosciences Beijing 100083 China

Aerial algae on the surface of carbonate rocks at the Stone Forest, Shilin County, Yunnan Province, China, and their bioerosion were investigated in the field and studied in the laboratory in detail. Through the observation, identification and statistics of more than one hun- dred algal samples and rock samples with the optical microscopes (stereomicroscope, biological microscope) and the scanning electronic microscope (SEM), the relationships between erosional forms on the surface of the Stone Forest and algae and/or algal communities and the genetic mechanism for the formation of erosional forms were analyzed. It is suggested that aerial algae play an active role in bioerosive processes that may affect the formation of karst erosional forms. These effects include both direct and indirect ones. The direct effect is the initiative control (algal shape-controlling role) of algae on the formation of karst forms of various scales, mostly mi- cro-scale (3.) and minor-scale (10-3.10-1m) erosional forms. The algal shape-controlling roles can be divided into the algal individual shape-controlling role and the algal community shape-controlling role. The former mostly controls the formation of micro-scale erosional forms, while the latter mostly controls the formation of micro-scale and smaller minor-scale erosional forms. The indirect effect refers to the promoting role of algae in the formation of karst forms, which may affect the formation of karst forms of all types and scales. The bioerosion of algae accelerates the weathering process of the whole Stone Forest karst landforms.

关键词： aerial algae, bioerosion, the Stone Forest, Yunnan Province, China.

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Geothermal and fluid flowing simulation of ore-forming antimony deposits in Xikuangshan

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science China earth sciences 2006年第8期49卷 862-871页

作者： YANG Ruiyan1,2, MA Dongsheng2, BAO Zhengyu3. PAN Jiayong2, CAO Shuanglin2 & XIA Fei2 1. School of Mathematics and Physics, China university of geosciences, wuhan 43.074, China 2. State Key Laboratory for Research of Mineral Deposits, Nanjing university, Nanjing 210093. China 3. faculty of earth sciences, China university of geosciences, wuhan 43.074, China 1. School of Mathematics and Physics China University of Geosciences Wuhan 430074 China 2. State Key Laboratory for Research of Mineral Deposits Nanjing University Nanjing 210093 China 3. faculty of earth sciences China University of Geosciences Wuhan 430074 China

The Xikuangshan Antimony Deposit located in the Mid-Hunan Basin, China, is the larg- est antimony deposit in the world. Based on the hydrogeological and geochemical data collected from four sections, Xikuangshan-Dajienao (AO), Xikuangshan-Dashengshan (BO), Xikuang- shan-Longshan (CO) and Dafengshan (DO) in the Basin, an advanced metallogenic model related to deep-cyclic meteoric water of Xikuangshan Antimony Deposit is put forward in this paper using a model of heat-gravity-driving fluid flow transportation. The simulation results show that the ore-forming fluid of the deposit mainly comes from the Dashengshan and Longshan areas where BO and CO sections are located if the overall basin keeps a constant atmospheric precipitation and infiltration rate during mineralization, and that the average transportation speed of the ore-forming fluids is about 0.2―0.4 m/a.

关键词： ore-forming fluid, numerical simulation, geothermal field, geofluid transport, Xikuangshan, antimony deposits.

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Distributions of fatty acids in a stalagmite related to paleoclimate change at Qingjiang in Hubei,southern China

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science China earth sciences 2005年第9期48卷 1463-1469页

作者： XIE Shucheng1,HUANG Junhua1,WANG Hongmei2,YI Yi1,HU Chaoyong1, CAI Yanjun3.& CHENG Hai4 1. faculty of earth science,China {3. of geosciences,wuhan 43.074,China 2. School of Environmental Studies,China {3. of geosciences,wuhan 43.074,China 3. SKLLQG,Institute of earth Environment,Chinese Academy of sciences,Xi’an 710075,China 4. Department of Geology and Geophysics,{3. of Minnesota,MN55455,USA 1. faculty of earth science China University of Geosciences 430074 Wuhan China 2. School of Environmental Studies China University of Geosciences 430074 Wuhan China 3. SKLLQG Institute of Earth Environment Chinese Academy of Sciences 710075 Xi’an China 4. Department of Geology and Geophysics University of Minnesota 55455 MN USA

Fatty acids extracted from a subtropical stalagmite at Qingjiang in Southern China’s Hubei Province were analysed using gas chromatography-mass spectrometry. These n-alkanoic acids range from C14 to C26 in carbon number, maximizing at C16, with a second dominance at C22. In contrast to the stalagmite analysed, the overlying soils are characterized by the dominance of heavy-molecular-weight homologues (>C20). The n-fatty acids in the stalagmite were proposed to be contributed by both the soil ecosystems and the microbes harboring in the percolating water and the cave. The ratios of unsaturated to saturated n-fatty acids (C16:1i/C16:0, C18:1/C18:0) appear to show trends comparable with the oxygen isotope records of the stalagmite carbonate, with enhanced values associated with the cold episode such as Heinrich event 1. This paleoclimate-dependent record of the n-fatty acids might reflect microbial changes in physiology and activity in response to the temperature. This record shows somewhat difference from the previous paleoclimate signal extracted from n-alkanols and n-alkan-2-ones of the same stalagmite. The acid record fails to document the well-known Younger Dryas event which was effectively shown by the latter two biomarkers derived from soil ecosystems. This discrepancy might result from the changing biogeochemical impact on different lipid fractions as well as the varied organism populations in different ecosystems.

关键词： biomarker, ecosystem, microbe, speleothem, paleoclimate, Quaternary.

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