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Degradation of acid fuchsine by a modified electro-Fenton system with magnetic stirring as oxygen supplying

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Journal of environmental Sciences 2010年第4期22卷 547-554页

作者： Yiping Sheng,Limin Zhen,Xiuli Wang,Ning Li,Qi Tong College of environmental and chemical engineering,yanshan university,qinhuangdao,Hebei 066004.china. [a] College of environmental chemical engineering Yanshan University Qinhuangdao Hebei 066004 China

The current modified electro-Fenton system was designed to develop a more convenient and efficient undivided system for practical wastewater treatment. The system adopted a cathode portion that employed magnetic stirring instead of common oxygen gas diffusion or gas sparging to supply oxygen gas for the electrolyte solution. Key factors influencing the cathode fabrication and activit） were investigated. The degradation of acid fuchsine with a self-made graphite-polytetrafluorethylene cathode was studied using spectrophotometer. It was found that the cathode generated hydrogen peroxide with high current efficiency and the hydrogen peroxide yield of the cathode did not decay after 10 times reuse. With the Pt anode at a ferrous ion concentration of 0.5 mmol/L, a pH of 3, and using magnetic stirring, dye decolorization could be rapidly accomplished but the destruction of benzene rings and intermediates was fairly difficult. With a Fe anode, dye degradation was more complete.

关键词： electro-Fenton system oxygen gas magnetic stirring acid fuchsine degradation

Hydrogen metabolic pathways of Rhodospirillum rubrum under artificial illumination

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Chinese Science Bulletin 2010年第1期55卷 32-37页

作者： ZHU RuiYan1,2,3 & LI JiLun1 1 College of Biological Sciences, State Key Laboratory for Agrobiotechnology, china Agricultural university, Beijing 100193, china 2 College of environmental and chemical engineering, yanshan university, qinhuangdao 066004. china 3 engineering Research Center for Bioenergy of Hebei Province, qinhuangdao 066004. china College of Biological Sciences State Key Laboratory for Agrobiotechnology China Agricultural University Beijing 100193 China College of environmental and chemical engineering Yanshan University Qinhuangdao 066004 China engineering Research Center for Bioenergy of Hebei Province Qinhuangdao 066004 China

Multiple enzymes involved in hydrogen metabolism have been detected in photosynthetic bacterium Rhodospirillum rubrum un-der various growth conditions. To investigate hydrogen metabolic pathways and the contribution of each pathway to hydrogen photoproduction in R. rubrum under the artificial illumination condition, three mutants were constructed, including nifHanfDG double mutant lacking both Fe-nitrogenase and Mo-nitrogenase, anfDG mutant lacking Fe-nitrogenase and nifHhupL double mu-tant (uptake hydrogenase deficient mutant). Comparison of the hydrogen production of these 3 mutants with R. rubrum wild type and the uptake hydrogenase deficient mutant showed that there was a third pathway involved in hydrogen production besides Mo-nitrogenase and Fe-nitrogenase, which mainly contributed to hydrogen evolution. Only a small portion of hydrogen was gen-erated by the third pathway. The hydrogen produced by Mo-nitrogenase, Fe-nitrogenase and the third pathway was about 93.5%, 4.9% and 1.5%, respectively, while the hydrogen consumed by uptake hydrogenase was about 13.3%. The investigation of the formate-linked hydrogenase activity indicated that the third pathway for hydrogen production was not mediated by the for-mate-linked hydrogenase, but probably by some unknown enzyme.

关键词：氢代谢人工照明代谢途径红螺菌固氮酶脱氢酶突变体体吸收

Development on transparent conductive ZnO thin films doped with various impurity elements

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Rare Metals 2011年第2期30卷 175-182页

作者： ZHAO Lin SHAO Guangjie SONG Shitao QIN Xiujuan HAN Sihuizhi School of environmental and chemical engineering Yanshan University Qinhuangdao 066004 China State Key Laboratory of Metastable Materials Science and Technology Yanshan University Qinhuangdao 066004 China Hebei Normal university of Science and Technology Qinhuangdao 066004 China

A general review of recent research progress in fabricating transparent conductive ZnO thin films by means of intentional doping and codoping with In, Ga, A1, Mg, Li, F, H, N, and P, divided into metals and nonmetals, is presented in this article. The main emphasis is placed on introducing and discussing the recent research achievements on the mechanisms of the incorporation of these impurities, and their effects on the electrical and optical properties. Lastly, this article concludes with a summary of the present state of investigations on doping elements in fabricating functional ZnO thin films for photoelectric applications, and with our personal view of the perspective of future studies on doped ZnO thin films.

关键词： thin films conductive films zinc oxide doping electric properties optical properties

Influence of La-dopant on the Material Characteristics and Supercapacitive Performance of MnO_2 Electrodes

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Journal of Wuhan university of Technology(Materials Science) 2011年第1期26卷 33-37页

作者：吕彦玲邵光杰 department of Environment and chemical engineering Yanshan University

Manganese dioxide was synthesized by electrodeposition method with Mn （CH3COO）24H2O as a raw material. La（NO3）3？6H2O was doped in electroyte during the preparing process to improve the performance of MnO2 electrodes. The micrographs, crystal structure and element content of electrodes were analyzed by SEM, XRD and atomic absorption spectroscopy, respectively. It is found that the La content ratio in the dioxide can be easily controlled by adjusting the composition of the plating solution. Appropriate amount of doped La can increase the surface area of Mn/La materials, resulting in the supercapacitive behavior enhancement. Electrochemical tests show that the specific capacitance is significantely increased from 198.72 F？g-1 to 276.60 F？g-1 by La-doping.

关键词： manganese dioxide nanomaterials deposition rare earth doping specific capacitance

Effect of commercial AB_5 alloy addition on the electrochemical properties of Ml-Mg-Ni-based hydrogen storage alloys

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Rare Metals 2008年第4期27卷 429-433页

作者： HU Lin HAN Shumin LI Jinhua ZHU Xilin LI Yuan State Key Laboratory of Metastable Materials Science and Technology Yanshan University Qinhuangdao 066004 China College of environmentaland chemical engineering Yanshan University Qinhuangdao 066004 China

A commercial AB5 hydrogen storage alloy was used as an additive to improve the electrochemical properties of Ml-Mg-Ni-based hydrogen storage alloys. The effect of AB5 alloy addition on the phase structure, charge/discharge characteristics, and electrochemical kinetics of Ml0.90Mg0.10Ni3.08Mn0.13Co0.63Al0.14 alloy was investigated. The maximum discharge capacity of Ml0.90Mg0.10Ni3.08Mn0.13Co0.63Al0.14 ＋ 4 wt.% AB5 electrode reaches 406 mAh/g. The anodic polarization, cyclic voltammetry, and potential step discharge experiments show that the electrochemical kinetics of the electrode with additives was promoted, with the LaNi5 phase of AB5 alloy acting as electro-catalytic sites in the electrode alloy. The high-rate dischargeability of Ml0.90Mg0.10Ni3.08Mn0.13Co0.63Al0.14 ＋ 4 wt.% AB5 alloy electrode at 1100 mA/g reaches 60.9%, which is 9.4% higher than that of Ml0.90Mg0.10Ni3.08Mn0.13Co0.63Al0.14 alloy electrode. The cycling stability of the electrode with 4 wt.% AB5 alloy has also been improved

关键词： hydrogen storage alloys additive rare earths electrochemical properties electrochemical kinetics

Photoresponsive organogel and organized nanostructures of cholesterol imide derivatives with azobenzene substituent groups

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Progress in Natural Science:Materials International 2012年第1期22卷 64-70页

作者： Tifeng Jiao a,b,c,Yujin Wang a,Fengqing Gao a,Jingxin Zhou a,Faming Gao a a Hebei Key Laboratory of Applied Chemistry,College of environmental and chemical engineering,yanshan university,qinhuangdao 066004.china b College of Chemistry & Materials engineering,Wenzhou university,Wenzhou 325027,china c State Key Laboratory of Solid Lubrication,Lanzhou Institute of chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,china [a] Hebei Key Laboratory of Applied Chemistry College of Environmental and Chemical Engineering Yanshan University Qinhuangdao 066004 China [b] College of Chemistry & Materials engineering Wenzhou University Wenzhou 325027 China [c] State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China

Two new cholesterol imide derivatives with azobenzene substituent groups have been *** compounds possess headgroups of hydrogen or methyl units,*** gelation test revealed that a subtle change in the headgroup of azobenzene segment produced a dramatic change in the gelation behavior of both *** compound with headgroups of hydrogen units only gelated N,N-Dimethylformamide(DMF),while the other compound with headgroups of methyl units cannot gelate any solvent tested *** DMF gel and solution of the gelator,the reversible photoisomerization transitions by irradiation with ultraviolet(UV) and visible light are investigated by UV-vis absorption spectra,Fourier transform infrared spectrometer,scanning electron microscope,atomic force microscope,and X-ray diffraction *** UV irradiation of the gel,trans-cis photoisomerization of the azobenzene groups occurs,the change in molecular polarity leads to the breaking of van der Waals interactions,resulting in the gel-sol *** gel can be recovered by the reverse cis-trans photoisomerization after exposure to visible *** and spectral studies reveal that the gelator molecules selfassemble into one-dimensional fibers,which further crossed-linked to form regular *** results afford useful information for the development of new versatile low molecular mass gelators and soft matter.

关键词： Organogel Cholesterol Azobenzene Photoisomerization Soft material

Molecular mechanism of dehydrin in response to environmental stress in plant

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Progress in Natural Science:Materials International 2007年第3期17卷 237-246页

作者： ZHANG Yuxiu , WANG Zi and XU Jin (department of Bioengineering, School of chemical and environmental engineering, china university of Mining and Technology (Beijing), Beijing 100083, china department of Biology, Graduate university of Chinese Academy of Sciences, Beijing 100049, china) [a]department of Bioengineering School of Chemical and Environmental Engineering China University of Mining and Technology (Beiing) Beijing China [b]department of Biology Graduate University of Chinese Academy of Sciences Beijing China

Dehydrins, known as the D-11 subgroup of late embryogenesis abundant (LEA) protein, are an immunologically distinct family of proteins, which typically accumulate in desiccation-tolerant seed embryo or in vegetative tissues in response to various environmental stresses such as drought, salinity and freezing. The existence of conservative sequences designated as K, S, and Y segments is a structural feature of dehydrins, and the K segment found in all dehydrins represents a highly conserved 15 amino acid motif (EKKGIMDKIKEKLPG) and forms an amphiphilicα-helix. According to the arrangement of these domains and clustering analysis, dehydrins are subdivided into 5 subtypes: YnSK, Kn, KnS, SKn and YnK. Different types of dehydrins are induced by different environmental stress in plants. Study results showed that dehydrins might play important protective roles under abiotic stress via a number of different mechanisms, including improving or protecting enzyme activities by the cryoprotective activity in responding to freeze/thaw or dehydration; stabilizing vesicles or other endomembrane structures by function as the membrane stabilizer during freeze induced dehydration, and preventing the membrane system from the oxidative damage induced by reactive oxygen radicals as the radical scavenger. Here, the gene expression and molecular mechanisms of dehydrin in response to stress in plants are discussed.

关键词： dehydrin stress mechanism.

Biogas recovery from microwave heated sludge by anaerobic digestion

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Science china(Technological Sciences) 2010年第1期53卷 144-149页

作者： QIAO Wei1,WANG Wei2,ZHU CuiPing3 & ZHANG ZhongZhi1 1 College of chemical Science and engineering,china university of Petroleum,Beijing 102249,china 2 department of environmental Science and engineering,Tsinghua university,Beijing 10084,china 3 J & K china Cleaning Energy Technology Co.Ltd.,Beijing 100085,china 1. College of chemical Science and engineering China University of Petroleum Beijing 102249 China2. Department of Environmental Science and Engineering Tsinghua University Beijing 10084 China3. J & K China Cleaning Energy Technology Co. Ltd. Beijing 100085 China

Biogas generated from sewage sludge,livestock waste,and food waste by anaerobic digestion is a valuable renewable energy ***,conventional anaerobic digestion is not an efficient process.A long hydraulic retention time and low biogas recovery rate hinder the applications of those *** effective pretreatment method to destroy sludge microbial cells has been one of the major concerns regarding improvement of the biogas *** article focuses on the effects of microwave heating on sludge anaerobic *** suspended solid(VSS) and chemical organic demand solubilization of heated sludge were *** heating was found to be a rapid and efficient process for releasing organic substrates from *** increase of organic dissolution ratio was not obvious when holding time was over 5 min with microwave *** effect of the VSS solubilization was primarily dependent on heating *** highest value of VSS dissolving ratio,36.4%,was obtained at 170°C for 30 *** COD dissolving ratio was about 25% at 170°*** organic carbon of treated sludge liquor was 1.98 and 2.73 g/L at 150°C and 170°C for 5 min,respectively.A biochemical methane potential(BMP) test of excess sludge and a mixture of primary and excess sludge demonstrated an increase in biogas *** total biogas from microwave treated mixture sludge increased by 12.9% to 20.2% over control after 30 days of *** production was 11.1% to 25.9% higher for excess sludge than for untreated *** VS removal ratios of mixture sludge and excess sludge were 12% and 11% higher,respectively,compared to the untreated sludge.

关键词： biogas recovery microwave heating sludge anaerobic digestion

Estimate of ammonia transfer from Lake Dianchi water to the air

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Journal of environmental Sciences 1995年第4期7卷 478-483页

作者： Dai Shugui Zhuang Yuanyi Jin Zhaohui(department of environmental Science, Nankai university/, Tianjin 300071 , china)Zhang Mingshun(china environmental Protection Management Cadre College,qinhuangdao 066000 , china)

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关键词： ammonia transfer Lake Dianchi.