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Analytical method of Cr stable isotope and its application to water pollution survey

Chinese Science Bulletin 2010年第7期55卷 664-669页

作者： GAO YongJuan 1,2,3.MA Teng 4,5,LING WenLi 1,2,LIU CunFu 4,5 & LI Li 4,5 1Faculty of earth Science,china university of {3.,Wuhan 43.074,china 2State Key Laboratory of Geological Processes and Mineral resources,china university of {3.,Wuhan 43.074,china 3.Graduate school,china university of {3.,Wuhan 43.074,china 4 Biogeological and Environmental Geology Laboratory of Ministry of Education(china university of {3.) ,Wuhan 43.074,china 5 Sino-Hungary Joint Laboratory of Environmental sciences and Health,china university of {3.,Wuhan 43.074,china Faculty of earth Science China University of Geosciences Wuhan 430074 China State Key Laboratory of Geological Processes and Mineral resources China University of Geosciences Wuhan 430074 China Graduate school China University of Geosciences Wuhan 430074 China Biogeological and Environmental Geology Laboratory of Ministry of Education (china university of {2.) Wuhan 430074 China Sino-Hungary Joint Laboratory of Environmental sciences and Health China University of Geosciences Wuhan 430074 China

High Cr(VI) concentration is a potential serious risk to environment and ecologic ***,it is essential to effectively monitor Cr contamination in water systems and scientifically evaluate its evolution trend.A new method of in-situ tracer technique by Cr isotopic analysis for quantitatively estimating Cr-contamination and its regional evolution in natural waters as well as a case application are reported in this *** on documented literatures,an experimental procedure for chemical separation and purification of Cr in water samples and its analytical method for Cr isotopic measurement by thermal ionization mass spectrometry(TIMS) are *** samples collected around a chemical factory in Hubei Province were analyzed by this *** samples showδ53.r values ranging from-1.7‰to 7.3.and an elevating trend with an increasing in distance from the sampling site to pollution source.A functional correlation following Rayleigh fractionation law was established between sample'sδ53.r value and its extent of Cr *** study suggests that Cr isotopic analysis is an effective method to reveal the spatial distribution and its evolution trend of Cr contamination in the regional water *** is thus helpful to assessing the self-purifying ability of local water system according to Cr isotopic fractionation.

关键词：铬(VI) 水污染调查稳定同位素应用同位素分析供水系统演变趋势示踪技术

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Ultrahigh pressure (>7 GPa) gneissic K-feldspar (-bearing) garnet clinopyroxenite in the Altyn Tagh, NW china: Evi- dence from clinopyroxene exsolution in garnet

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Science china earth {2. 2005年第7期48卷 1000-1010页

作者： LIU Liang1,3. CHEN Danling1, ZHANG Anda1, SUN Yong1, WANG Yan1, YANG Jiaxi1,2.& LUO Jinhai1 1. Key Laboratory of Continental Dynamics of the Ministry of Education of china, Northwest {2., Xi’an 710069, china 2. College of {3. Science and Land resources, Chang’an {2., Xi’an 710054, china 3. The Laboratory of Orogen and Basin of the Ministry of Education, Peking {2., Beijing 100871, china Key Laboratory of Continental Dynamics Ministry of Education of China Northwest University Xi'an 710069 China Laboratory of Orogen and Basin Ministry of Education Peking University Beijing 100871 China College of earth Science and Land resources Chang'an University Xi'an 710054 China

The exsolution of clinopyroxene and rutile in coarse-grain garnet is found in the gneissic K-feldspar(-bearing) garnet clinopyroxenite from Yinggelisayi in the Altyn Tagh, NW china. The maximum content of the exsolved clinopyroxene in the garnet is up to >5% by volume. The reconstructed precursor garnet (Grt1) before exsolution has a maximum Si content of 3.061 per formula uint, being of supersilicic or majoritic garnet. The peak-stage metamorphic pressure of >7 GPa is estimated using the geobarometer for volume percentage of exsolved pyroxene in garnet and the Si-(Al+Cr) geobarometer for majoritic garnet, and the temperature of about 1000℃ using the ternary alkali-feldspar geothermometer and the experimental data of ilmen- ite-magnetite solid solution. The protoliths of the rocks are intra-plate basic and intermediate ig- neous rocks, of which the geochemical features indicate that they are probably the products of the evolution of basic magma deriving from the continental lithosphere mantle. The rocks are in outcrops associated with ultrahigh pressure garnet-bearing lherzolite and ultrahigh pressure garnet granitoid gneiss. All of these data suggest that the ultrahigh pressure metamorphic rocks in the Altyn Tagh are the products of deep-subduction of the continental crust, and such deep- subduction probably reaches to >2.0 km in depth. This may provide new evidence for further discussion of the dynamic mechanism of the formation and evolvement of the Altyn Tagh and the other collision orogenic belts in western china.

关键词： Altyn Tagh gneissic K-feldspar (-bearing) garnet clinopyroxenite clinopyroxene exsolution in garnet ultra-high pressure metamorphism.

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Discovery of submicron diamonds within kimberlite in Liaoning Province, china and its significance

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Chinese Science Bulletin 1997年第11期42卷 939-941页

作者： BAO Yanan, T. V. Dubuchick and T. D. Liabchekov1. Graduate school in Beijing, Chinese Mining university, Beijing {2. {3. 2. Moscow resources Institute of Mineral Materials, Russia 3. resources Institute of Deposit Geology, Russian Academy of sciences, Russia Graduate school in Beijing Chinese Mining University Beijing China Moscow resources Institute of Mineral Materials Russia resources Institute of Deposit Geology Russian Academy of Sciences Russia

ALTHOUGH a lot of research work on diamond mineralogy has already been done,the formationand development of diamond leave much to be *** have done some researches onthe diamond samples with obvious crystal-growing cha... 详细信息

关键词： submicron diamond lath-shape aggregative parent material.

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Study on lithogeochemistry of Middle Jurassic basalts from southern china represented by the Fankeng basalts from Yongding of Fujian Province

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Science china earth {2. 2006年第10期49卷 1020-1031页

作者： ZHOU Jincheng1,2. JIANG Shaoyong1,2. WANG Xiaolei1,2. YANG Jinghong 1,2.& ZHANG Mengqun 3.1. State Key Laboratory of Mineral Deposit Research, Nanjing university, Nanjing 2.0093. china 2. Department of earth {3., Nanjing university, Nanjing 2.0093. china 3. Modern Analysis Center, Nanjing university, Nanjing 2.0093. china 1. State Key Laboratory of Mineral Deposit Research Nanjing University Nanjing 210093 China 2. Department of earth sciences Nanjing University Nanjing 210093 China 3. Modern Analysis Center Nanjing University Nanjing 210093 China

There exists an E-W trending Middle Jurassic volcanic zone in southern china. The Fankeng basalts in the Yongding basin of Fujian Province are considered to be a typical example. The Fankeng basalts have TiO2.contents in the range of 1.92.-3.2.%. They are classified as high-Ti basalts. They also have higher total Fe (averaging FeO* = 11.09%). The Middle Jurassic Fankeng basalts from southwestern Fujian have obvious distinctive lithogeochemical features from early Cre- taceous basalts from southeastern coast of china. They have higher HFSE, such as Th, Nb, Ta, Zr and Ti. Their element ratios related with HFSE, such as Zr/Ba, La/Nb, La/Ta ,Zr/Y, Ti/Y, Ba/Nb, K/Ti and Rb/Zr are similar to those of OIB. The most samples have ε Nd(T) of-0.70-0.2., which are near chondrite. Some samples have higher ε Nd(T) of ***, these basaltic magmas might be derived from depleted asthenospheric mantle. The lithogeochemical characteristics of the Fankeng basalts may be caused by interaction between asthenosphere and lithosphere at the time. The (Early-) Middle Jurassic basalts and gabbros from southeastern Hunan, southern Jiangxi and northern Guangdong provinces show similar geochemical features to those of the Fankeng basalts from the Yongding of Fujian. Occurrence of these OIB-type basalts in the area may be regarded as the petrological mark of upwelling of asthenosphere at the time. Upwelling of asthenosphere has led to tectonic extension and the formation of rifted basin in the area.

关键词： interaction between asthenosphere and lithosphere, lithogeochemistry, basalts, Middle Jurassic, southern china.

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Geochemistry of high-Mg andesites from the early Cretaceous Yixian Formation, western Liaoning: Implications for lower crustal delamination and Sr/Y variations

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Science china earth {2. 2006年第9期49卷 904-914页

作者： WANG Xiaorui1, GAO Shan1,2. LIU Xiaoming1, YUAN Honglin1, HU Zhaochu1, ZHANG Hong1,3.& WANG Xuance4 1. State Key Laboratory of Continental Dynamics, Department of Geology, Northwest university, Xi`an 710069, {2. 2. State Key Laboratory of Geological Processes and Mineral resources,{3., Wuhan 43.074, {2. 3. Shenyang Institute of Geology and Mineral resources, Shenyang 11003., {2. 4. Guangzhou Institute of Geochemistry, Chinese Academy of sciences, Guangzhou 510640, {2. 1. State Key Laboratory of Continental Dynamics Department of Geology Northwest University Xi’an 710069 China 2. State Key Laboratory of Geological Processes and Mineral resources China University of Geosciences Wuhan 430074 China 3. Shenyang Institute of Geology and Mineral resources Shenyang 110032 China 4. Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China

85 volcanic rocks of the Yixian Formation from the Sihetun type section werecollected and analyzed for geochemical and isotopic compositions. Major element compositionsindicate that the Sihetun volcanic rocks are high magnesium andesites with some basalts occurring atthe bottom of section. The Sihetun high magnesium andesites (SiO_2.= 52.82.59.3. wt%, Al_2._3.14.15-16.3.wt%) show many characteristics of adakites such as depletion in heavy rare-earth elements(HREE; Yb = 1.03.1.88 μg/g) and Y(12.2. μg/g) and high Sr (62.-13.3.μg/g) and Sr/Y(3.-88), withhigh La_N/Yb_N ratio (10-2.). They share similar major and trace element characteristics to volcanicrocks from the Xinglonggou Formation except their lower Nd isotope ratios (^(143.Nd/^(144)Nd(13.Ma) = 0.5118-0.5119, ε_(Nd) (13.Ma) = -11.6-13.8, ^(87)Sr/^(86)Sr (13. Ma) = *** were interpreted in a way that eclogite that formed at the base of thickened Archean lowercrust of the North china craton foundered into the convecting mantle and subsequently melted andinteracted with peridotite. However, compared to the Xinglonggou volcanic rocks, the source of theSihetun magma contained more ancient continental crustal material in order to explain its evolved Ndisotopes. The age of the Sihetun Formation was 12. to 13. Ma, and this indicates that delaminationlasted to the early Cretaceous period. The Sr contents and Sr/Y ratios of the Sihetun high-Mgandesites show significant negative correlations with SiO_2.for samples with SiO_2.> 56%. Thesesuggest that the Sr and Sr/Y values were reduced due to fractional crystallization of ***, the effect of crystallization on volcanic Sr and Sr/Y ratio has to be taken intoaccount.

关键词： High-Mg andesite, Adakite, Yixian Formation, North china Craton, delamination.

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Southeastern extension of the Red River fault zone (RRFZ) and its tectonic evolution significance in western South china Sea

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Science china earth {2. 2006年第8期49卷 839-850页

作者： LIU Baoming1,2.3. XIA Bin1, LI Xuxuan1,3. ZHANG Minqiang1,3. NIU Binhua2. ZHONG Lifeng1, JIN Qinghuan1,4 & JI Shaocheng1,5 1. Key Laboratory of Marginal Sea Geology and resources, Chinese Academy of sciences,Guangzhou 510640, china 2.{3. (Beijing), Beijing 100083. china 3. Research Center of Science & Technology Department, CNOOC, Beijing 10002., china 4. Guangzhou Marine Geological Survey, Ministry of Land & resources, Guangzhou 510075, china 5. Ecole Polytechnique Montreal, H3.3.7, Canada 1. Key Laboratory of Marginal Sea Geology and resources Chinese Academy of Sciences Guangzhou 510640 China 2. china university of geosciences (Beijing) Beijing 100083 China 3. Research Center of Science & Technology Department CNOOC Beijing 100027 China 4. Guangzhou Marine Geological Survey Ministry of Land & Resources Guangzhou 510075 China 5. Ecole Polytechnique Montreal H3C3A7 Canada

Recent geophysical surveys and basin modeling suggest that the No.1 fault in the Ying- gehai basin (YGHB) is the seaward elongation of the Red River fault zone (RRFZ) in the South china Sea (SCS). The RRFZ, which separates the South china and Indochina block, extends first along the Yuedong fault, offshore of Vietnam, and then continues southward and breaks off into two branches: the Lupar fault and the Tinjia fault. The southern extension of the Lupar fault dies out beneath the NW Borneo while the Tinjia fault extends southeast and reaches the Brunei-Sabah area. According to the gravity and geomagnetic data, and the tectonic evolution of the basins, there are different evolution histories between the Wan’an basin (WAB) and the basins in the Nansha block. The Tinjia fault may be the boundary between the Balingian block and the Nansha block. Hence, the line linking the Yue- dong fault and the Tinjia fault, which both are continental margin faults and strike-slip ones in the geological evolution histories, constitute the boundary between the Indochina and Nansha block. The Lupar fault, in contrast, is an intraplate fault within the Indochina block. The results provide new hints for reconstructing the tectonic evolution history of the RRFZ and the opening of the SCS, and also a framework for hydrocarbon prospecting in the region.

关键词： Red River fault zone, tectonic evolution, fault, extension, western South china Sea.

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Laser Ablation ICP-MS Titanite U-Th-Pb Dating of the Tonglushan Cu-Fe-Au Skarn Deposit,Southeastern Hubei Province

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矿物学报 2009年第S1期29卷 314-316页

作者： LI Jian-wei 1,2.DENG Xiao-dong1,2.ZHOU Mei-fu3.LIU Yong-sheng1(1. State Key Laboratory of Geological Processes and Mineral resources,{2. university of {3.,Wuhan 43.074,{2. 2. Faculty of earth resources,{2. university of {3.,Wuhan 43.074,{2. 3. Department of earth sciences,the university of Hong Kong,Hong Kong)

Titanite(CaTi2.iO5) is an important accessory mineral not only in magmatic and metamorphic rocks,but also commonly in hydrothermal mineral deposits. It incorporates appreciable amounts(usually 10×10-6 s to 100×10-6 s) of U and Th into its structure and has a closure temperature of Pb diffusion higher than 660～700 ℃(Scott and St-Onge,1995) ,making it an ideal U-Th-Pb geochronometer. The Daye metallogenic district is located in the west of the giant Middle-Lower Yangtze River(MLYR) Cu-Fe-Au province,eastern china and is well endowed with Fe,Cu,and polymetallic skarn deposits.

关键词： Pb Laser Ablation ICP-MS Titanite U-Th-Pb Dating of the Tonglushan Cu-Fe-Au Skarn Deposit,Southeastern Hubei Province Th Fe ICP Cu MS

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Theory of truth degrees of propositions in the logic system Ln^＊

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Science in china(Series F) 2006年第4期49卷 471-483页

作者： LI Jun1,2.& WANG Guojun1,3.1. Institute of Mathematics, Shaanxi Normal university, Xi’an 710062. {2. 2. school of {3., Lanzhou university of Technology, Lanzhou 73.050, {2. 3. Research Center for Science, Xi’an Jiaotong university, Xi’an 710049, {2. 1. Institute of Mathematics Shaanxi Normal University Xi’an 710062 China 2. school of sciences Lanzhou University of Technology Lanzhou 730050 China 3. Research Center for Science Xi’an Jiaotong University Xi’an 710049 China

By means of infinite product of uniformly distributed probability spaces of cardinal n the concept of truth degrees of propositions in the n-valued generalized Lu- kasiewicz propositional logic system Ln^＊ is introduced in the present paper. It is proved that the set consisting of truth degrees of all formulas is dense in [0,1], and a general expres- sion of truth degrees of formulas as well as a deduction rule of truth degrees is then obtained. Moreover, similarity degrees among formulas are proposed and a pseudo-metric is defined therefrom on the set of formulas, and hence a possible framework suitable for developing approximate reasoning theory in n-valued generalized Lukasiewicz propositional logic is established.

关键词： truth degree similarity degree approximate reasoning.

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The Crustal Shortening and Reconstruction of the Main Terranes Through Mesozoic-Cenozoic in Qinghai-Tibet Plateau

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地学前缘 2009年第S1期16卷 270-271页

作者： Meifeng Shi~(1,2.,Yalin Li~2.Ke Cao~2.1.Chengdu Institute of Geology and Mineral resources,Chengdu 610082.china. 2.{2. of {3. sciences and resources,china university of geosciences(Beijing),Beijing 100083.china

It is one of hot issues in Tibetan research that is to study the mode,process and kinetics of the crustal shortening during *** this paper, on the basis of systematic collection,analysis and research of the existing data and results from Himalayas,Lhasa and Qiangtang terranes,we conducted the balanced cross-section *** the north Qiangtang,the line-balanced cross-section

关键词： Qinghai-Tibet Plateau crustal shortening shortening value terrane

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EPR studies of Mn^(2.) in the Loess Plateau of central china: Implication for variation of the East Asia summer monsoon

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Chinese Science Bulletin 1998年第1期43卷 72-75页

作者： CHEN Jun\+1, JI Junfeng\+1, SU Yuanxia\+2.and LU Huayu\+3.. Department of earth {2., Nanjing university, Nanjing 2.0093. {3. 2. Center of Material Analysis, Nanjing university, Nanjing 2.0093. {3. 3. Xi’an Laboratory of Loess and Qu Department of earth sciences Nanjing University Nanjing China Center of Material Analysis Nanjing University Nanjing China Xi’an Laboratory of Loess and Quaternary Geology Chinese Academy of Sciences Xi’an China

Mn 2. EPR intensity recorded in the Chinese loess_paleosol sequence shows close correlation with magnetic susceptibility and Sr content as well as the oscillation of paleoclimate. Thus Mn 2. EPR signal can serve as an... 详细信息

关键词： paleomonsoon loess paleosol EPR signal of Mn 2.

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