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Identification of Hercynian shoshonitic intrusive rocks in central Hainan Island and its geotectonic implications

Science Bulletin 2006年第20期51卷 2507-2519页

作者： XIE Caifu1, 2. ZHU Jinchu1, DING Shijiang3. ZHANG Yeming2. FU Tai’an2.& LI Zhihong2.1. State Key Laboratory for Mineral Deposits Research and Department of Earth Sciences, Nanjing University, Nanjing 2.0093.{2. 2. Yichang institute of geology and Mineral Resources, Yichang 4.3.03.{2. 3. Hainan Bureau of geology and Mineral Resources, Haikou 5702.6,{2. Department of Otolaryngology University Hospital VU P.O. Box 7057 1007 MB Amsterdam The Netherlands State Key Laboratory for Mineral Deposits Research and Department of Earth Sciences Nanjing University Nanjing 210093 China

An identification has been made of some shoshonitic intrusive rocks in central Hainan Island recently. These rocks are K-rich (K2.=2.9%―5.1%, K2./Na2.=0.95―2.12., distinctly enriched in LILE and LREE, strongly depleted in Nb, Ta, and moder- ately depleted in Sr and Ti, with (87Sr/86Sr)i = 0.70859―0.714.0} and ε Nd(t) = (?2.77―?7.4.). They were derived from an EMⅡ-type mantle source. The enrichment process is related to metasomatism of depleted mantle caused by a great amount of fluid-melt released from oceanic crust and terri- genous sediments at great depth (eclogite facies) during the subduction of the South china plate under the Indochina-South china Sea plate in the Carbon- iferous–Early Permian. A SHRIMP U-Pb zircon dating yields a crystallization age of 2.2.7 Ma for the sho- shonitic intrusions, which is coeval with the strongly peraluminous granites found in central Hainan Island. These two kinds of rocks generally possess syn-intrusion ductile deformation structures. Thus they are considered to have been generated during the early stage (syn-thrust phase) of a post-collisional event. The primary magma of shoshonitic rocks was produced at a depth > 80 km by decompression- dehydration melting of previously enriched litho- spheric mantle wedge, phlogopite-bearing garnet peridotite, which was in turn caused by the break-off of a descendent slab and upwelling of a hot as- thenosphere. The rising of melts was accompaniedby crustal contamination and crystallization fractiona- tion (AFC). Combining with other related data, it is proposed that the southwards subduction and amal- gamation of the South china plate with the Indo- china-South china Sea plate took place at ca. 2.7- 2.8 Ma, which was a part of the convergence proc- ess of the Pangea supercontinent. The suture zone was probably located along the line of Song Ma-Beibu Gulf-north margin of the Yunkai Moun- tains-Wuyi Mountains.

关键词： SHRIMP U-Pb dating Hercynian shoshonitic intrusive rocks post-collisional event enriched mantle Hainan Island.

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Research on the dynamics of the South china Sea opening:Evidence from analogue modeling

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Science china Earth Sciences 2006年第10期49卷 1053-1069页

作者： SUN Zhen1,2. ZHOU Di1, ZHONG Zhihong3. XIA Bin2. QIU Xuelin1, ZENG Zuoxun4.& JIANG Jianqun5 1. CAS Key Laboratory of Marginal Sea geology, South{2. Sea institute of Oceanology, {3. Academy of Sciences, Guangzhou 5103.1,{2. 2. CAS Key Laboratory of Marginal Sea geology, Guangzhou institute of Geochemistry, {3. Academy of Sciences, Guangzhou 51064.,{2. 3. Department of Technology, Shenzhen Branch of CNOOC, Guangzhou 5102.0,{2. 4. Faculty of Earth Sciences,{2. University of Geosciences, Wuhan 4.1}074.{2. 5. Hainan Oil & Gas Exploration Company, Liaohe Oilfield Petrochina, Panjin 12.010,{2. 1. CAS Key Laboratory of Marginal Sea geology South China Sea Institute of Oceanology Chinese Academy of Sciences Guangzhou 510301 China 2. CAS Key Laboratory of Marginal Sea geology Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China 3. Department of Technology Shenzhen Branch of CNOOC Guangzhou 510240 China 4. Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China 5. Hainan Oil & Gas Exploration Company Liaohe Oilfield PetroChina Panjin 124010 China

Independent of Indochina extrusion, the South china Sea experienced a process from passive continental rifting to marginal sea drifting. According to the fault patterns in the Beibu Gulf basin and the Pearl River Mouth basin, the continental rifting and early spreading stage from {2. to 2. Ma were controlled by extensional stress field, which shifted clockwise from southeastward to south southeastward. From 2. Ma on, the sea spread in NW-SE direction and ceased spreading at around 15.5 Ma. Integrated geological information with the assumption that the South china Sea developed along a pre-Cenozoic weakness zone, we did analogue experiments on the South china Sea evolu- tion. Experiments revealed that the pre-existing weakness zone goes roughly along the uplift zone between the present Zhu-1 and Zhu-2.depression. The pre-existing weakness zone is composed of three segments trending NNE, roughly EW and NEE, respectively. The early opening of the South china Sea is accompanied with roughly 15° clockwise rotation, while the SE sub-sea basin opened with SE extension. Tinjar fault was the western boundary of the Nansha block (Dangerous Ground), while Lupar fault was the eastern boundary of the Indochina, NW-trending rift belt known as Zengmu basin developed between above two faults due to block divergent of Indochina from Nansha. In the experiment, transtensional flower structures along NW-trending faults are seen, and slight inversion occurs along some NE-dipping faults. The existence of rigid massifs changed the orientations of some faults and rift belt, and also led to deformation concentrate around the massifs. The rifting and drifting of the South china Sea might be caused by slab pull from the proto South china Sea subducting toward Borneo and/or mantle flow caused by India-Asia collision.

关键词： South china Sea, rifting and drifting, clockwise rotation, analogue modeling, rigid massifs.

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Distribution characteristics of magnetic susceptibility of the surface sediments in the southern Yellow Sea

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chinese Science Bulletin 2003年第B06期48卷 37-41页

作者： GE Shulan~(1,2.3., SHI Xuefa~1 & HAN Yibing~1 1. Key Laboratory of Marine Sedimentology and Environmental geology, First {2. of Oceanography, State Oceanic Administration. Qingdao 2.6061. china 2. {2. of geology and geophysics, chinese Academy of Sciences, Beijing 10002.. china 3. Graduate School. chinese Academy of Sciences, Beijing 10003.. china 1. Key Laboratory of Marine Sedimentology and Environmental geology First Institute of Oceanography State Oceanic Administration 266061 Qingdao China 2. institute of geology and {2. Chinese Academy of Sciences 100029 Beijing China 3. Graduate School Chinese Academy of Sciences 100039 Beijing China

The characteristic distributions of magnetic susceptibility (MS) are analyzed on the basis of susceptibility of 172.surface sediment samples in the southern Yellow Sea (SYS). The preliminary results are as follows: first, the distributions clearly correspond to different modern sediment assemblages in the continental sea, which indicates different sediment origins. With the 3. μCGS isoline being taken as demarcation line, the study area can then be divided into section H (high MS value area) and section L (low MS value area). Section H is mainly adjacent to land with two main sources of the Changjiang River and the Huanghe *** L is mainly an eddy sediment area, where Yellow Sea Cold Water is entrenched all the year round. The distribution pattern of MS could tell apart strong or weak hydrodynamic conditions and has a close relation to the circulation system in this area. At the areas of the SYS Circumfluent and northern East china Sea (NECS) Circumfluent (weak hydrodynamic), the MS has low values, while in the areas of Coastal Current (strong hydrodynamic), the values are *** the same time, the oxidizing areas tend to take on higher MS, while the reducing areas have lower one. It seems safe to say that the MS in the continental sea reflects more of the sediment origin and sedimentary environment, which is different from that of loess, lake and surface soil as a climate proxy.

关键词：中国黄海表面沉积物磁化率等值线长江黄河旋涡沉积区循环系统

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Comprehensive evaluation of mechanism of "chimney effect" using principles of magnetism, geochemistry and mineralogy

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chinese Science Bulletin 1998年第9期43卷 743-748页

作者： LIU Qingsheng 1, CHENG Tongjin 2.and LIU Shugen 3.1. Department of Applied geophysics,{2. University of Geosciences, Wuhan 4.1}074.{2. 2. Center of Petroleum Geochemistry,{2. National Star Petroleum Corporation, Hefei 2.0}02.,{2. 3. The St Department of Applied geophysics China University of Geosciences Wuhan China Center of Petroleum Geochemistry China National Star Petroleum Corporation Hefei China The State Key Laboratory of Oil/Gas Reservoir geology and Exploitation of china Chengdu Institute of Technology Chengdu China

Study of forming mechanism of "chimney-effect" (CE) has important significance for basic theory and applications of non-seismic geophysical and geochemical methods locating oil/gas reservoirs. The theoretical basis of comprehensive evaluation of mechanism of CE using principles of magnetism, geochemistry and mineralogy has been reviewed, with the problems to be solved: (ⅰ) study for the relationship between process of oil/gas migration and geochemical field; (ⅱ) analysis of genesis of magnetic, geochemical and mineralogical anomaly; (ⅲ) interpretation of surface soil magnetism and geochemical anomaly combined with seismic data.

关键词： chimney effect (CE) hydrocarbon microseepage oil/gas accumulation.

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Modeling the impact of Australian Plate drift on Southern Hemisphere climate and environment

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chinese Science Bulletin 2005年第14期50卷 1495-1502页

作者： ZHOU Botao1,5, ZHAO Ping2. JIAN Zhimin3.& HE Jinhai4.1. Nansen-Zhu International Research Center, institute of Atmospheric Physics, {2. Academy of Sciences, Beijing {4.,{3. 2. institute of Climate and Environment, {2. Academy of Meteoro- logical Sciences, Beijing 100081,{3. 3. Laboratory of Marine geology, Tongji University, Shanghai 2.0092.{3. 4. Department of Atmospheric Sciences, Nanjing institute of Meteorol- ogy, Nanjing 2.004.,{3. 5. Graduate School of the {2. Academy of Sciences, Beijing 10003.,{3. Nansen-Zhu International Research Center Institute of Atmospheric Physics Chinese Academy of Sciences Beijing 100029 China Graduate School of the chinese Academy of Sciences Beijing 100039 China institute of Climate and Environment Chinese Academy of Meteorological Sciences Beijing 100081 China Laboratory of Marine geology Tongji University Shanghai 200092 China Department of Atmospheric Sciences Nanjing Institute of Meteorology Nanjing 210044 China

Using a global atmosphere-ocean coupled model with the present-day and 14.MaB.P. oceanic topogra- phy respectively, two experiments are implemented to inves- tigate the effect of different locations of Australian Plate on the atmospheric circulation in middle-high latitudes of the Southern Hemisphere. The results show that when Austra- lian Plate lay south at 14.MaB.P., both anticyclone circula- tions in the subtropical oceans and cyclone circulation around 60°-70°S are strengthened. Subtropical highs and circumpolar low pressure appear stronger, which results in much stronger Antarctic Oscillation and shorter period of Antarctic Oscillation Index (AOI) at 14.MaB.P. The rainfall and the surface air temperature also change correspondingly. The precipitation decreases around 4.°S and increases around 60°-70°S, and the surface air temperature rises in high latitudes of the South Pacific and descends over the Weddell Sea and its north side. Besides, due to the changes of the temperatures and winds, Antarctic sea ice coverage also changes with its increasing in the Ross Sea and its west re- gions and decreasing in the Weddell Sea.

关键词：半球气候地球环球澳大利亚漂流物海洋地形学

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Combination of drainage, water supply and environmental protection as well as rational distribution of water resource in Zhengzhou mining district

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Science china Earth Sciences 2005年第10期48卷 1768-1779页

作者： WU Qiang1, LI Duo1,2. DI Zhiqiang3. MIAO Ying3. ZHAO Suqi4.& GUO Qiwen5 1. Resource Exploitation Engineering College, CUMT, Beijing 100083.{4. 2. Shijiazhuang Engineering College, University of Economics, Shijiazhuang 05003.,{4. 3. Shenyang institute of {3. and Mineral Resources, Shenyang 11003.,{4. 4. State Adminstration of Coal Mine Safety, Beijing 100013.{4. 5. Zhengzhou Coal Mine Company (Group), Zhengzhou 4.2.0}1,{4. Resource Exploitation Engineering College CUMT Beijing China Shijiazhuang Engineering College University of Economics Shijiazhuang china Shenyang institute of geology and Mineral Resources Shenyang{2. State Adminstration of Coal Mine Safety Beijing china Zhengzhou Coal Mine Company (Group) Zhengzhou china

The geological condition of coalfield is much complex in china. With increasing in mining depth and drainage amount, the contradiction of drainage, water supply and environ-mental protection is becoming more and more serious. However, the contradiction can be solved by the scientific management of optimizing combination of drainage, water supply and environ-mental protection. The Philip multiple objectives simplex method used in this article has searched for a possible solution at the first step, and then it goes on searching to find out whether there is a weight number that can lead the solution to the biggest. It can reduce the randomness and diffi-culty of traditional weight method which determine the weight number artificially. Some beneficial coefficients are vague and the number is larger in the model of water resource dispatch. So the vague layer analysis method can consider these vague factors fully, combining the qualitative and quantitative analysis together. Especially, this method can quantify the experiential judge-ment of policy decider, and it will turn to be more suitable if the structure of objective factors is complex or the necessary data are absent. In the paper, the two methods above are used to solve the plans of drainage, water supply and optimizing distribution of water resource in the Zhengzhou mining district.

关键词： combination of drainage, water supply and environmental protection, Philip multiple objective simplex method, vague layer analysis method, distribution of water resource.

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Gas formation mechanism of marine carbonate source rocks in china

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Science china Earth Sciences 2005年第4期48卷 441-453页

作者： ZHAO Wenzhi1, WANG Zhaoyun1, HE Haiqing2. ZHANG Mingjie3. WANG Hongjun1, WANG Yunpeng4.& QIN Yong5 1. Research institute of Petroleum Exploration & Development, Petro{2., Beijing 100083. china 2. Petro{2. Exploration & Production, Beijing 100011, china 3. Department of geology, Lanzhou University, Lanzhou 73.000, china 4. Guangzhou Geochemical institute, {12. Academy of Sciences, Guangzhou 51064., china 5. china University of Mining and Technology, Xuzhou 2.1000, china 1. Research institute of Petroleum Exploration & Development 100083 PetroChinaBeijin China 2. Petrochina Exploration & Production 100011 Beijing China 3. Department of geology Lanzhou University 730000 Lanzhou China 4. Guangzhou Geochemical institute Chinese Academy of Sciences 510640 Guangzhou China 5. china University of Mining and Technology 221000 Xuzhou China

By breaking through the conventional ideology on the study of gas-formation mechanism of source rocks which focused on merely the characteristics of source rocks them- selves, and based on the development and distribution characteristics of marine carbonate source rocks in the medium-to-bottom parts of the chinese superimposed sedimentary basins as well as various processes in the course of gas generation and reservoir forming, the complex hydrocarbon-generating model of carbonates is established. Such a model concerns not only the “three-stage” gas formation characteristics of carbonates, but also the gas generation process due to a thermal cracking of oil and the re-generation process of gas from heated secondary organic matters during the gas-generation and reservoir-forming course. The high-quality hy- drocarbon generating matter of marine carbonate source rocks determined a high gas-oil ratio and tended to form paleo-oil-reservoirs, representing an enrichment process of organic matters. The thermal cracking of oil in palaeo-oil-reservoirs is an important means for the effective forma- tion of gas reservoirs. The secondary organic matters in carbonate reservoirs may regenerate gas after a secondary deep burial, thus becoming an effective gas source.

关键词： carbonate, three-stage hydrocarbon generation, inhibitive effect of maturity, oil-cracking gas, second-ary asphalt gas.

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Sporopollen analysis of Core B10 in the southern Yellow Sea and the reflected characteristics of climate changes

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chinese Science Bulletin 2003年第B06期48卷 42-48页

作者： FU Mingzuo~(1,2.3., LI Zhen~1, XU Xiaowei~1 & SHl Xuefa~1 1. Key Laboratory of Marine Sedimentology and Environmental geology, First {2. of Oceanography. State Oceanic Administration, Qingdao 2.6061. china 2. {2. of Oceanology, chinese Academy of Sciences, Qingdao 2.6071. china 3. Graduate School, chinese Academy of Sciences, Beijing 10003.. china 1. Key Laboratory of Marine Sedimentology and Environmental geology First institute of Oceanography State Oceanic Administration 266061 Qingdao China 2. institute of Oceanology Chinese Academy of Sciences 266071 Qingdao China 3. Graduate School Chinese Academy of Sciences 100039 Beijing China

Eight sporopollen zones have been divided based on the results of high-resolution sporopollen analysis of Core B10 in the southern Yellow Sea. Based on the results along with ^14. datings and the subbottom profiling data,climatic and environmental changes since the last stage of late Pleistocene are discussed. The main conclusions are drawn as follows: (1) the vegetation evolved in the process of coniferous forest-grassland containing broad-leaved trees→coniferous and broad-leaved mixed forest→coniferons and broad-leaved mixed forest-grassland prevailed by coniferous trees→coniferous and broad-leaved mixed forest-grassland containing evergreen broad-leaved trees→coniferons and broad-leaved mixed forest-grassland prevailed by broadleaved trees→deciduous broad-leaved forest-meadow containing evergreen broad-leaved trees→coniferous and broadleaved mixed forest-grassland prevailed by broad-leaved trees→coniferous and broad-leaved mixed forest containing evergreen broad-leaved trees; (2. eight stages of climate changes are identified as the cold and dry stage, the temperate and wet stage, the cold and dry stage, the warm and dry stage, the temperate and wet stage, the hot and dry stage, the temperate and dry stage, then the warm and dry stage in turn; (3. the sedimentary environment developed from land,to littoral zone, to land again, then to shore-neritic zone; and (4. the Yellow Sea Warm Current formed during early-Holocene rather than Atlantic stage.

关键词：中国黄海气候变化碳14.代测定底基压型数据更新世沉积环境大西洋

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Distribution of molluscan remains in the sediment of the Chukchi Sea and its vicinity, the Arctic

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Acta Oceanologica Sinica 2003年第4期22卷 607-619页

作者： Gao Aiguo 1,2. Xu Fengshan3. Sun Haiqing 1,2. Li Lon1 1. First institute of Oceanography, State Oceanic Administration, Qingdao 2.6061,{2.. 2. Key Laboratory of Marine Sedimentology and Environmental geology, State Oceanic Administration, Qingdao 2.6061,{2. 3. institute of Oceanology, chinese Academy of Sciences, Qingdao 2.6071,{2. State Ocean Adm Inst Oceanog 1 Qingdao 266061 Peoples R China State Ocean Adm Key Lab Marine Sedimentol & Environm Geol Qingdao 266061 Peoples R China chinese Acad Sci Inst Oceanol Qingdao 266071 Peoples R China

The result of an analysis of mollusca remains collected from the Chukchi Sea, Beaufort Sea and Bering Sea in the First chinese National Arctic Research Expedition, from July to September, 1999 is presented. Seventeen species of mollusca have been identified, which belong to two classes: Bivalvia and Gastropoda. The compositions of the mollusca are very simple. According to the distribution pattern two groups may be distinguished among molluscan species. The Pan-Arctic and circumboreal group comprises Nuculana pernula, ***, Nucula bellotii, Astarte montagui, Seripes groenlandicus, Macoma calcarea, M. moesta alaskana, Liocyrna fluctuosa, Mya pseudoarenaria and Turritella polaris. Three species, Cyclocardia crebricostata, Trichotrois coronata and Argobuccinum oregonense are components of the Pan-Arctic and Pacific boreal group. With regard to feeding habits, detritus feeders dominate. There are 7 species of detritus feeders, i.e., Nuculana pernula, N. radiata, Nucula bellotii, Macoma calcarea, M. moesta alaskana, Macoma sp. and Trichotropis coronata. Detritus feeders are dominant with regard to the numbers of species as well as to the frequency of occurrence. Macoma calcarea is the most abundant species.

关键词： Chukchi Sea Beaufort Sea Bering Sea molluscan remains

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Carbon and hydrogen isotopic characteristics of natural gases from the Luliang and Baoshan basins in Yunnan Province, china

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Science china Earth Sciences 2006年第9期49卷 938-946页

作者： XU Yongchang1, LIU Wenhui2. SHEN Ping1, WANG Wanchun1, WANG Xiaofeng1, Tenger1, YAN Yaomin3.& LIU Ruobin3.1. Lanzhou Center of Oil & Gas Resources, {2. of {4. and Geophsics, chinese Academy of Sciences, Lanzhou 73.000,{3. 2. Research {2. of Petroleum Exploration and Production, SINOPEC, Beijing 100083.{3. 3. South Branch of Petroleum Exploration and Production Company, SINOPEC, Kuming 650000,{3. 1. Lanzhou Center of Oil & Gas Resources Institute of Geology and Geophsics Chinese Academy of Sciences Lanzhou 730000 China 2. Research institute of Petroleum Exploration and Production SINOPEC Beijing 100083 China 3. South Branch of Petroleum Exploration and Production Company SINOPEC Kuming 650000 China

The Luliang and Baoshan basins of Yunnan Province are two small-sizedcontinental oil/gas-bearing sedimentary basins, which were developed at the bases of theCarboniferous and Devonian systems during the Late Tertiary, covering an area of 3.5 km^2.and 2.4.m^2. respectively. Since the 1990s, there have been discovered small-sized natural gas pools inthese two basins. The natural gases are composed mainly of hydrocarbon gases, with nonhydrocarbonsaccounting for less than 2.. Of the hydrocarbon gases, methane accounts for more than 99%, and thecomponents above C_2.account for less than 0.2.. On the basis of previous studies of geologicalbackground, the composition of natural gases and their carbon isotopic composition, it has beendefined that these two gas pools are of bacterial origin. In this work we have comprehensivelymeasured the carbon and hydrogen isotopic composition of natural gases from these two basins andhave gone into the details of the mechanism of gas generation. The δ^(13.C_1 values of naturalgases from the Luliang Basin are within the range of -72.1 per thousand - -73.3.per thousand, andthe δD_(CH_4. values, -2.2.per thousand - -2.0} per thousand, indicating that the bacterial gasgeneration is dominated by the way of CO_2.reduction. It has been evidenced that undercontinental-facies fresh water conditions there did occur the CO_2.reduction as a process ofbacterial gas generation. The δ^(13.C_1 values of natural gases from the Baoshan Basin are withinthe range of - 62.5 per thousand - -63.5 per thousand, and the δD_(CH_4. values, -2.2.per thousand- -2.0 per thousand. These isotopic characteristics are fallen into transitional phase of acetatefermentation and CO_2.reduction as defined by Whiticar et al. (1986). An important discovery in theLuliang Basin is the carbon isotopic composition of ethane of purely biogenetic origin, i.e., itsδ^(13.C_2.values are within the range of - 61.2.per thousand - - 66.0 per thousand. These carbonisotopic values have been r

关键词： bacterial gas, carbon and hydrogen isotope, CO2 reduction, acetate fermentation.

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