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Study on lithogeochemistry of Middle Jurassic basalts from southern China represented by the Fankeng basalts from Yongding of Fujian Province

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Science China Earth Sciences 2006年第10期49卷 1020-1031页

作者： ZHOU Jincheng1,2. JIANG Shaoyong1,2. WANG Xiaolei1,2. YANG Jinghong 1,2.& ZHANG Mengqun 3.1. State Key Laboratory of Mineral Deposit Research, nanjing university,{2., China 2. Department of Earth Sciences, nanjing university,{2., China 3. modern analysis center, nanjing university,{2., China 1. State Key Laboratory of Mineral Deposit Research Nanjing University Nanjing 210093 China 2. Department of Earth Sciences Nanjing University Nanjing 210093 China 3. modern analysis center Nanjing University Nanjing 210093 China

There exists an E-W trending Middle Jurassic volcanic zone in southern China. The Fankeng basalts in the Yongding basin of Fujian Province are considered to be a typical example. The Fankeng basalts have TiO2.contents in the range of 1.92.-3.2.%. They are classified as high-Ti basalts. They also have higher total Fe (averaging FeO* = 11.09%). The Middle Jurassic Fankeng basalts from southwestern Fujian have obvious distinctive lithogeochemical features from early Cre- taceous basalts from southeastern coast of China. They have higher HFSE, such as Th, Nb, Ta, Zr and Ti. Their element ratios related with HFSE, such as Zr/Ba, La/Nb, La/Ta ,Zr/Y, Ti/Y, Ba/Nb, K/Ti and Rb/Zr are similar to those of OIB. The most samples have ε Nd(T) of-0.70-0.2., which are near chondrite. Some samples have higher ε Nd(T) of ***, these basaltic magmas might be derived from depleted asthenospheric mantle. The lithogeochemical characteristics of the Fankeng basalts may be caused by interaction between asthenosphere and lithosphere at the time. The (Early-) Middle Jurassic basalts and gabbros from southeastern Hunan, southern Jiangxi and northern Guangdong provinces show similar geochemical features to those of the Fankeng basalts from the Yongding of Fujian. Occurrence of these OIB-type basalts in the area may be regarded as the petrological mark of upwelling of asthenosphere at the time. Upwelling of asthenosphere has led to tectonic extension and the formation of rifted basin in the area.

关键词： interaction between asthenosphere and lithosphere, lithogeochemistry, basalts, Middle Jurassic, southern China.

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EPR studies of Mn^(2.) in the Loess Plateau of central China: Implication for variation of the East Asia summer monsoon

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Chinese Science Bulletin 1998年第1期43卷 72-75页

作者： CHEN Jun\+1, JI Junfeng\+1, SU Yuanxia\+2.and LU Huayu\+3.. Department of Earth Sciences, nanjing university,{2., China 2. {2. of Material {3., nanjing university,{2., China 3. Xi’an Laboratory of Loess and Qu Department of Earth Sciences Nanjing University Nanjing China center of Material analysis Nanjing University Nanjing China Xi’an Laboratory of Loess and Quaternary Geology Chinese Academy of Sciences Xi’an China

Mn 2. EPR intensity recorded in the Chinese loess_paleosol sequence shows close correlation with magnetic susceptibility and Sr content as well as the oscillation of paleoclimate. Thus Mn 2. EPR signal can serve as an... 详细信息

关键词： paleomonsoon loess paleosol EPR signal of Mn 2.

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Crystal structure and single crystal EPR of (NH_4)_2.15-crown-5)_3.Cu(mnt)_2. and (NH_4)_2.benzo-15-crown-5)_4[Cu(mnt)_2.·0.5H_2.

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Science China Chemistry 2007年第5期50卷 607-613页

作者： SUI YunXia1, WEN LiLi2. ZHANG Huan3.& MENG QingJin2.1 center of {2. {2.,{3., nanjing 2.0093, China 2.State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute,{3., nanjing 2.0093, China 3.Jiangnan Institute of Computing Technology, Wuxi 2.4083. China 1. center of modern {2. Nanjing University Nanjing 210093 China 2. State Key Laboratory of Coordination Chemistry Coordination Chemistry Institute Nanjing University Nanjing 210093 China 3. Jiangnan Institute of Computing Technology Wuxi 214083 China

The X-ray crystal structures of (NH4)2.15-crown-5)3.Cu(mnt)2. (1) and(NH4)2.benzo-15-crown-5)4-[Cu(mnt)2. ident to 0.5H2. (2. were *** single crystals arecomposed of distinct structures of ammonium-crown ether supramolecular cation and [Cu(mnt)2.^(2.)*** triple-decker dication in complex 1 and a sandwich dimmer in complex 2.wereobserved.X-Band EPR studies on the single crystals of both complex 1 and complex 2.have been carriedout at room temperature,which revealed that complex 2.showed a perfect hyperfine structure of Cuwhereas that of complex 1 could not be *** principal values and direction cosines of theprincipal axes of the g and A tensors were computed by a least-squares fitting *** spindensity of Cu(ll) was estimated according to the principal values of the A tensors and compared wellwith the results calculated based on DFT method.

关键词： supramolecular cation, H-bonding interaction, EPR, g and A tensors, DFT

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Ultra-microbes are the minerogenetic constructors of oceanic polymetallic nodules

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Chinese Science Bulletin 1997年第8期42卷 617-624页

作者： CHEN Jianlin, ZHANG Fusheng and BIAN Lizeng1 Second Institute of Oceanography, State Oceanic Administration, Hangzhou 3.0012. China 2.center for Materials {2.,{2.,{3., China 3. Department of Earth Sciences,{2.,{3., China Second Institute of Oceanography State Oceanic Administration Hangzhou China Centu for Materials analysis Nanjing University Nanjing China Department of Earth Sciences Nanjing University Nanjing China

Polymetallic nodules (mangnese nodules) are a typical kind of manganese oncolites The distribution of smooth sur-face and knobbly manganese nodules is closely related to the geological background of the mine field. A systematic study on their inner laminae structure and features suggests that they are the products of millions of years reproduction and accumulation of the recently found Miniactinomyces chinensis and Spirisophaerospora pacijica .

关键词： oceanic manganese nodule stromatolite ultra-microbe biolite.

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Origin and age of Mn deposits of the Nantuo Formation in the Sinian System

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Chinese Science Bulletin 1997年第24期42卷 2072-2075页

作者： YANG Jiedong, WANG Zongzhe, XUE Yaosong, SUN Weiguo, TAO Xiancong and ZHOU Chuanming1. center of modern {2.,{3., nanjing 2.0093, China 2. nanjing Institute of Geology and Palaeontology, Chinese Academy of Sciences, nanjing 2.0008, China center of modern {2. Nanjing University Nanjing China nanjing Institute of Geology and Palaeontology Chinese Academy of Sciences Nanjing China

THE tillites in the Nantuo Formation of the Sinian System is considered contemporary with theVaranger ice age. The manganese deposits in the Nantuo Formation are most suitable to iso-topic dating and may record the precious information on paleo-ocean chemistry. However,there have heen different views and disputations about their origin and age for a long time. The Sinian System in the Yangtze region is divided into 3.formations from base to top:the Nantuo Formation, the Doushantuo Formation and the Dengying Formation. The

关键词： Neoproterozoie ice age Mn deposit isotopic age.

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Sorption behavior of U(VI), ^(2.0})U(VI) and ^(2.0})U(VI) onto fracture-filling clays in Beishan granite, Gansu: Application to selecting the site of high-level radwaste repository in China

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Science China Earth Sciences 2005年第10期48卷 1649-1655页

作者： MIN Maozhong1,2. LUO Xingzhang3. WANG Ju4, JIN Yuanxin4 & WANG Rucheng1 1. Department of Earth Sciences, State Key Laboratory of Mineral Deposit Research, nanjing university,{2., China 2. {2. of Materials {3., nanjing university,{2., China 3. Department of Environmental Science and Engineering, nanjing university,{2., China 4. Beijing Geology Institute, Nuclear Industry, Beijing 10002., China Department of Earth Sciences State Key Laboratory of Mineral Deposit Research Nanjing University Nanjing China center of Materials analysis{2. {3. China Department of Environmental Science and Engineering nanjing university nanjing China Beijing Geology Institute Nuclear Industry Beijing China

The first results of sorption experiments of U(VI), 2.0}U(VI) and 2.0}U(VI) onto original (unpurified) fracture-filling clays from No.1 monzonitic granite intrusion, Beishan area, Gansu Province, China are reported. The monzonitic granite intrusion is a potential location for a high-level radwaste (HLW) repository in China. The present experimental results show that the maximum U(VI) sorption reached 92. at near-neutral pH and the distribution coefficient (Kd) was 12.6 mL/g. A high sorption capacity of the fracture-filling clays in host rock on radioactive ele-ments is necessary for HLW deep geological disposal repository. No preferential sorption of 2.0}U onto the clays was found. Finally, the sorption of U(VI) onto the clays was also modeled using a surface complexation model.

关键词： HLW geological disposal repository, granite, uranium, radionuclide, clay, sorption.

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Nd, Sr and O Isotopic Study on Spilite-Keratophyre in Xiqiu,,Zhejiang Province, China

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Acta Geologica Sinica(English Edition) 1992年第2期66卷 165-176页

作者： Shen Weizhou Zhang Bangtong Ling Hongfei Lai Mingyian Yang Jiedong Tao Xiancong Department of Earth Sciences, nanjing university, nanjing, Jiangsu {2. {3. Centre, nanjing university, nanjing, Jiangsu Department of Earth Sciences Nanjing University Nanjing Jiangsu China

Nd, Sr and O isotopic study on the spilite-keratophyre sequence in Xiqiu shows that its ∈_(Nd) values are inthe range of 4.02.5.2., and its ∈_(Sr) values, +1.4-2.6. According to the points of these data in the ∈_(Nd)-T,∈_(Sr)-T and ∈_(Nd)-∈_(Sr) diagrams, the spilite-keratophyre is interpreted as being slightly contaminated by crustalmaterials. Its δ^(18)O values are 3.9-5.0‰. The depletion of ^(18)O in the rocks resulted from the influence ofseawater hydrothermal alteration during or soon after the rock formation. Based on the isotopic characteristicsand available geochemical data, it is believed that the spilite-keratophyre was formed in the well-developedisland-arc environment during the Late Proterozoic subduction of the palaeo-Pacific plate beneath thesoutheastern margin of the Yangtze massif.

关键词： Sr and O Isotopic Study on Spilite-Keratophyre in Xiqiu China Zhejiang Province Nd

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On the variational principle for the topological pressure for certain non-compact sets

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Science China Mathematics 2010年第4期53卷 1117-1128页

作者： PEI Yu 1 & CHEN ErCai 1,2.1 Department of Mathematics,nanjing Normal university,nanjing 2.0097,China 2.{3. for Nonlinear Science,nanjing university,nanjing 2.0093,China 1. Department of Mathematics Nanjing Normal University Nanjing 210097 China2. Center for Nonlinear Science Nanjing University Nanjing 210093 China

Let (X,d,T) be a dynamical system,where (X,d) is a compact metric space and T:X → X is a continuous *** assume that the dynamical system satisfies g-almost product property and the uniform separation *** compute the topological pressure of saturated sets under these two *** the uniform separation property does not hold,we compute the topological pressure of the set of generic *** give an application of these results to multifractal analysis and finally get a conditional variational principle.

关键词： uniform separation property g-almost product property topological pressure of non-compact sets variational principle BS-dinmension

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Rb-Sr isochron ages and significance of bimodal volcanic association in Baimianshi uranium ore-field, South China

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Chinese Science Bulletin 1999年第S2期44卷 3-4页

作者： CHEN Peirong~1, WANG Yinxi~2. NI Qisheng~1, KONG Xinggong~2.and ZHANG Bangtong~2.1. State Key Laboratory of Mineral Deposits, Department of Earth Sciences, nanjing university, nanjing 2.0093, China 2. {2. of {3. analysis, nanjing university, nanjing 2.0093, China State Key Laboratory of Mineral Deposits Department of Earth Sciences Nanjing University Nanjing 210093 China center of modern {2. Nanjing University Nanjing 210093 China

1 Geologic background THE volcanic U-deposits are generally associated with felsic to intermediate volcanic rock and their sedimentary derivatives. However, uranium mineralization has been found to be spatially associated with thebasalt of bimodal volcanic associations in Baimianshi uranium ore field. Baimianshi uranium ore-field islocated in Baimianshi volcanic-sedimentary basin of south Jiangxi Province. The cover rocks of the basinconsist of a suite of bimodal volcanic-sedimentary sequences. Its basement rocks are two-mica granites ofBaimianshi rock body. The basalt of cover rocks is interbedded with arkoses in lower sequence, and rhyolite or rhyolitic tuff in upper sequence. Uranium minerals mainly occur as disseminations in the

关键词： Rb-Sr isochron ages bimodal volcanic rocks uranium ore-field south China.

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A three-dimensional variational ocean data assimilation system:Scheme and preliminary results

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Science China Earth Sciences 2006年第11期49卷 1212-1222页

作者： ZHU Jiang1,2. ZHOU Guangqing1, YAN Changxiang1, FU Weiwei1 & YOU Xiaobao1,3.1. International center for Climate and Environment Sciences, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 10002., China 2. Jiangsu Key Laboratory of Meteorological Disaster,{2. of Information Science and Technology, {2. 2.0044, China 3. Beijing Institute of Applied Meteorology, Beijing 10002., China 1. International center for Climate and Environment Sciences Institute of Atmospheric Physics Chinese Academy of Sciences Beijing 100029 China 2. Jiangsu Key Laboratory of Meteorological Disaster Nanjing University of Information Science and Technology Nanjing 210044 China 3. Beijing Institute of Applied Meteorology Beijing 100029 China

A new 3.VAR-based Ocean Variational analysis System (OVALS) is developed. OVALS is capable of assimilating in situ sea water temperature and salinity observations and satellite altimetry data. As a component of OVALS, a new variational scheme is proposed to assimilate the sea surface height data. This scheme considers both the vertical correlation of background errors and the nonlinear temperature-salinity relationship which is derived from the generalization of the linear balance constraints to the nonlinear in the 3.VAR. By this scheme, the model temperature and salinity fields are directly adjusted from the altimetry data. Additionally, OVALS can assimilate the temperature and salinity profiles from the ARGO floats which have been implemented in recent years and some temperature and salinity data such as from expendable bathythermograph, moored ocean buoys, etc. A 2.-year assimilation experiment is carried out by using OVALS and the Tropical Pacific circulation model. The results show that the assimilation system may effectively improve the estimations of temperature and salinity by assimilating all kinds of observations. Moreover, the root mean square errors of temperature and salinity in the upper depth less than 42. m reach 0.63. and 0.3. psu.

关键词： data assimilation, 3.VAR, sea surface height, ARGO floats.

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