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Study on lithogeochemistry of Middle Jurassic basalts from southern china represented by the Fankeng basalts from Yongding of Fujian Province

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Science china Earth Sciences 2006年第10期49卷 1020-1031页

作者： ZHOU Jincheng1,2, JIANG Shaoyong1,2, WANG Xiaolei1,2, YANG Jinghong 1,2 & ZHANG Mengqun 3.1. State Key Laboratory of Mineral Deposit Research, nanjing university, nanjing 2.0093. china 2. Department of Earth Sciences, nanjing university, nanjing 2.0093. china 3. modern analysis center, nanjing university, nanjing 2.0093. china State Key Laboratory of Mineral Deposit Research Nanjing University Nanjing China Department of Earth Sciences Nanjing University Nanjing China modern analysis center Nanjing University Nanjing China

There exists an E-W trending Middle Jurassic volcanic zone in southern china. The Fankeng basalts in the Yongding basin of Fujian Province are considered to be a typical example. The Fankeng basalts have TiO2 contents in the range of 1.92%-3.21%. They are classified as high-Ti basalts. They also have higher total Fe (averaging FeO* = 11.09%). The Middle Jurassic Fankeng basalts from southwestern Fujian have obvious distinctive lithogeochemical features from early Cre- taceous basalts from southeastern coast of china. They have higher HFSE, such as Th, Nb, Ta, Zr and Ti. Their element ratios related with HFSE, such as Zr/Ba, La/Nb, La/Ta ,Zr/Y, Ti/Y, Ba/Nb, K/Ti and Rb/Zr are similar to those of OIB. The most samples have ε Nd(T) of-0.70-0.24, which are near chondrite. Some samples have higher ε Nd(T) of ***, these basaltic magmas might be derived from depleted asthenospheric mantle. The lithogeochemical characteristics of the Fankeng basalts may be caused by interaction between asthenosphere and lithosphere at the time. The (Early-) Middle Jurassic basalts and gabbros from southeastern Hunan, southern Jiangxi and northern Guangdong provinces show similar geochemical features to those of the Fankeng basalts from the Yongding of Fujian. Occurrence of these OIB-type basalts in the area may be regarded as the petrological mark of upwelling of asthenosphere at the time. Upwelling of asthenosphere has led to tectonic extension and the formation of rifted basin in the area.

关键词： interaction between asthenosphere and lithosphere, lithogeochemistry, basalts, Middle Jurassic, southern china.

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EPR studies of Mn^(2+) in the Loess Plateau of central china: Implication for variation of the East Asia summer monsoon

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Chinese Science Bulletin 1998年第1期43卷 72-75页

作者： CHEN Jun\+1, JI Junfeng\+1, SU Yuanxia\+2 and LU Huayu\+3.. Department of Earth Sciences, nanjing university, nanjing 2.0093. china 2. center of Material {3., nanjing university, nanjing 2.0093. china 3. Xi’an Laboratory of Loess and Qu Department of Earth Sciences Nanjing University Nanjing China center of Material analysis Nanjing University Nanjing China Xi’an Laboratory of Loess and Quaternary Geology Chinese Academy of Sciences Xi’an China

Mn 2+ EPR intensity recorded in the Chinese loess_paleosol sequence shows close correlation with magnetic susceptibility and Sr content as well as the oscillation of paleoclimate. Thus Mn 2+ EPR signal can serve as an... 详细信息

关键词： paleomonsoon loess paleosol EPR signal of Mn 2+

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Ultra-microbes are the minerogenetic constructors of oceanic polymetallic nodules

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Chinese Science Bulletin 1997年第8期42卷 617-624页

作者： CHEN Jianlin, ZHANG Fusheng and BIAN Lizeng1 Second Institute of Oceanography, State Oceanic Administration, Hangzhou 3.0012, china 2 center for Materials analysis,{3., nanjing 2.0093. china 3. Department of Earth Sciences,{3., nanjing 2.0093. china Second Institute of Oceanography State Oceanic Administration Hangzhou China Centu for Materials analysis Nanjing University Nanjing China Department of Earth Sciences Nanjing University Nanjing China

Polymetallic nodules (mangnese nodules) are a typical kind of manganese oncolites The distribution of smooth sur-face and knobbly manganese nodules is closely related to the geological background of the mine field. A systematic study on their inner laminae structure and features suggests that they are the products of millions of years reproduction and accumulation of the recently found Miniactinomyces chinensis and Spirisophaerospora pacijica .

关键词： oceanic manganese nodule stromatolite ultra-microbe biolite.

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Crystal structure and single crystal EPR of (NH_4)_2(15-crown-5)_3.Cu(mnt)_2] and (NH_4)_2(benzo-15-crown-5)_4[Cu(mnt)_2]·0.5H_2O

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Science china Chemistry 2007年第5期50卷 607-613页

作者： SUI YunXia1, WEN LiLi2, ZHANG Huan3.& MENG QingJin2 1 center of modern analysis,{3., nanjing 2.0093. china 2 State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute,{3., nanjing 2.0093. china 3.Jiangnan Institute of Computing Technology, Wuxi 214083. china center of modern analysis Nanjing University Nanjing China State Key Laboratory of Coordination Chemistry Coordination Chemistry Institute Nanjing University Nanjing China Jiangnan Institute of Computing Technology Wuxi China

The X-ray crystal structures of (NH4)2(15-crown-5)3.Cu(mnt)2] (1) and(NH4)2(benzo-15-crown-5)4-[Cu(mnt)2] ident to 0.5H2O (2) were *** single crystals arecomposed of distinct structures of ammonium-crown ether supramolecular cation and [Cu(mnt)2]^(2-)*** triple-decker dication in complex 1 and a sandwich dimmer in complex 2 wereobserved.X-Band EPR studies on the single crystals of both complex 1 and complex 2 have been carriedout at room temperature,which revealed that complex 2 showed a perfect hyperfine structure of Cuwhereas that of complex 1 could not be *** principal values and direction cosines of theprincipal axes of the g and A tensors were computed by a least-squares fitting *** spindensity of Cu(ll) was estimated according to the principal values of the A tensors and compared wellwith the results calculated based on DFT method.

关键词： supramolecular cation, H-bonding interaction, EPR, g and A tensors, DFT

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Sorption behavior of U(VI), ^(23.)U(VI) and ^(23.)U(VI) onto fracture-filling clays in Beishan granite, Gansu: Application to selecting the site of high-level radwaste repository in china

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Science china Earth Sciences 2005年第10期48卷 1649-1655页

作者： MIN Maozhong1,2, LUO Xingzhang3. WANG Ju4, JIN Yuanxin4 & WANG Rucheng1 1. Department of Earth Sciences, State Key Laboratory of Mineral Deposit Research, nanjing university, nanjing 2.0093. china 2. center of Materials {3., nanjing university, nanjing 2.0093. china 3. Department of Environmental Science and Engineering, nanjing university, nanjing 2.0093. china 4. Beijing Geology Institute, Nuclear Industry, Beijing 100029, china nanjing university Nuclear Industry

The first results of sorption experiments of U(VI), 23.U(VI) and 23.U(VI) onto original (unpurified) fracture-filling clays from No.1 monzonitic granite intrusion, Beishan area, Gansu Province, china are reported. The monzonitic granite intrusion is a potential location for a high-level radwaste (HLW) repository in china. The present experimental results show that the maximum U(VI) sorption reached 92% at near-neutral pH and the distribution coefficient (Kd) was 1226 mL/g. A high sorption capacity of the fracture-filling clays in host rock on radioactive ele-ments is necessary for HLW deep geological disposal repository. No preferential sorption of 23.U onto the clays was found. Finally, the sorption of U(VI) onto the clays was also modeled using a surface complexation model.

关键词： HLW geological disposal repository, granite, uranium, radionuclide, clay, sorption.

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Nd, Sr and O Isotopic Study on Spilite-Keratophyre in Xiqiu,,Zhejiang Province, china

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Acta Geologica Sinica(English Edition) 1992年第2期66卷 165-176页

作者： Shen Weizhou Zhang Bangtong Ling Hongfei Lai Mingyian Yang Jiedong Tao Xiancong Department of Earth Sciences, nanjing university, nanjing, Jiangsu modern {3. Centre, nanjing university, nanjing, Jiangsu Department of Earth Sciences Nanjing University Nanjing Jiangsu China

Nd, Sr and O isotopic study on the spilite-keratophyre sequence in Xiqiu shows that its ∈_(Nd) values are inthe range of 4.02-5.26, and its ∈_(Sr) values, +1.4-2.6. According to the points of these data in the ∈_(Nd)-T,∈_(Sr)-T and ∈_(Nd)-∈_(Sr) diagrams, the spilite-keratophyre is interpreted as being slightly contaminated by crustalmaterials. Its δ^(18)O values are 3.9-5.0‰. The depletion of ^(18)O in the rocks resulted from the influence ofseawater hydrothermal alteration during or soon after the rock formation. Based on the isotopic characteristicsand available geochemical data, it is believed that the spilite-keratophyre was formed in the well-developedisland-arc environment during the Late Proterozoic subduction of the palaeo-Pacific plate beneath thesoutheastern margin of the Yangtze massif.

关键词： Sr and O Isotopic Study on Spilite-Keratophyre in Xiqiu china Zhejiang Province Nd

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Origin and age of Mn deposits of the Nantuo Formation in the Sinian System

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Chinese Science Bulletin 1997年第24期42卷 2072-2075页

作者： YANG Jiedong, WANG Zongzhe, XUE Yaosong, SUN Weiguo, TAO Xiancong and ZHOU Chuanming1. center of modern analysis,{3., nanjing 2.0093. china 2. nanjing Institute of Geology and Palaeontology, Chinese Academy of Sciences, nanjing 210008, china center of modern analysis Nanjing University Nanjing China nanjing Institute of Geology and Palaeontology Chinese Academy of Sciences Nanjing China

THE tillites in the Nantuo Formation of the Sinian System is considered contemporary with theVaranger ice age. The manganese deposits in the Nantuo Formation are most suitable to iso-topic dating and may record the precious information on paleo-ocean chemistry. However,there have heen different views and disputations about their origin and age for a long time. The Sinian System in the Yangtze region is divided into 3.formations from base to top:the Nantuo Formation, the Doushantuo Formation and the Dengying Formation. The

关键词： Neoproterozoie ice age Mn deposit isotopic age.

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A new frequency scale of Chinese whispered speech in the application of speaker identification

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Progress in Natural Science:Materials International 2006年第10期16卷 1072-1078页

作者： LIN Wei, YANG Lili and XU Boling (Institute of Acoustics & Key Laboratory of modern Acoustics, nanjing university, nanjing 2.0093. china) Institute of Acoustics and Key Laboratory of modern Acoustics Nanjing University Nanjing 210093 China

In this paper, the frequency characteristics of Chinese whispered speech were investigated by a filter bank analysis. It was shown that the first and the third formants were more important than the other formants in the speaker identification of Chinese whispered speech. The experiment showed that the 800-1200 Hz and 2800-3.00 Hz ranges were the most significant frequency ranges in discriminating the speaker. Based on this result, a new feature scale named whisper sensitive scale (WSS) was proposed to replace the common scale, Mel scale, and to extract the cepstral coefficient from whispered speech signal. Furthermore, a speaker identification system in whispered speech was presented based on the modified Hidden Markov Models integrating advantages of WSCC (the whisper sensitive cepstral coefficient) and LPCC. And the new system performed better in solving the problem of speaker identification of Chinese whispered speech than the traditional method.

关键词： speaker identification Chinese whispered speech whisper sensitive scale.

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On the variational principle for the topological pressure for certain non-compact sets

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Science china Mathematics 2010年第4期53卷 1117-1128页

作者： PEI Yu 1 & CHEN ErCai 1,2,1 Department of Mathematics,nanjing Normal university,nanjing 210097,{3. 2 center for Nonlinear Science,nanjing university,nanjing 2.0093.{3. Department of Mathematics Nanjing Normal University Nanjing China center for Nonlinear Science Nanjing University Nanjing China

Let (X,d,T) be a dynamical system,where (X,d) is a compact metric space and T:X → X is a continuous *** assume that the dynamical system satisfies g-almost product property and the uniform separation *** compute the topological pressure of saturated sets under these two *** the uniform separation property does not hold,we compute the topological pressure of the set of generic *** give an application of these results to multifractal analysis and finally get a conditional variational principle.

关键词： uniform separation property g-almost product property topological pressure of non-compact sets variational principle BS-dinmension

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Alkali-silica Reactivity of Different Aggregates from Mineral and Textural Characteristics

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Journal of Wuhan university of Technology(Materials Science) 2008年第6期23卷 901-906页

作者：莫祥银 analysis and Testing center & Jiangsu Key Laboratory of Biofunctional Materials Nanjing Normal University

To identify the aggregates causing the alkali-silica reaction, and the reactivity of rocks in different parts of china, the mineral and texture characteristics of some typical coarse ag gregates and the alkali reactivity of these aggregates were systematically investigated. On one hand, petrographic examination of aggregates, combined with X-ray diffraction analysis, chemical analysis, scanning electron microscopy, was conducted for analyzing their mineralogy and texture. It was found that not only mineral characteristics, but also their interior structure would affect their potential alkali-silica reactivity. Furthermore, the alkali-silica reactivity of aggregates is due to their mineral compositions, such as containing different alkali-reactive minerals, while, different stuctures of those aggregates with similar minerals affect their reactivity to some extent. There are some amount of micro-aperture and cracks across the quartz in the aggregate, which may become the natural accesses for Na^＋, K^＋, and OH^- ions to intrude in the mortar or concrete during the process of alkali-silica reaction. Alkali-silica reactivity of the aggregates was detected by the accelerated mortar bars test. It was revealed that all the aggregates tested were alkali-silica reactive and the results were also in accordance with their mineral and structure analysis.

关键词： petrographic examination of aggregates study of thin sections x-ray diffraction analysis chemical analysis scanning electron microscopy

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